Abstract: Digital metamorphic alloy (DMA) buffer structures for transitioning from a bottom crystalline layer to a lattice mismatched top crystalline layer, and methods for manufacturing such layers are described. In some embodiments, a layered crystalline structure includes a first layer of a first crystalline material having a first in-plane lattice constant and a second layer of a second crystalline material disposed over the first layer and having a second in-plane lattice constant that is lattice mismatched with the first crystalline material. Multiple sets of buffer layers may be disposed between the first layer and the second layer. Each set is a digital metamorphic alloy including a buffer layer of a third crystalline material and a buffer layer of a fourth crystalline material where an effective in-plane lattice constant of each set falls between the first lattice of the first layer and the second lattice constant of the second layer.