Patents Assigned to Matsumoto Yushi-Seiyaku Co., Ltd.
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Publication number: 20150044125Abstract: An acrylic-fiber finish for carbon fiber production is prepared into a stable emulsion and applied to a carbon-fiber precursor to prevent gumming up of finish components in precursor production and carbon fiber fusing in baking process. The acrylic-fiber finish is used for carbon-fiber production and includes a modified silicone having a modifying group containing a nitrogen atom and an acidic phosphate ester represented by the following chemical formula (1). where R1 represents a C6-22 alkyl or alkenyl group, A represents a C2-4 alkylene group, and AO represents an oxyalkylene group, n represents a mole number of oxyalkylene group and is an integer ranging from 0 to 20, and each of a and b is an integer of 1 or 2 and meets the equation a+b=3.Type: ApplicationFiled: February 14, 2013Publication date: February 12, 2015Applicant: MATSUMOTO YUSHI-SEIYAKU CO., LTD.Inventors: Yoshio Hashimoto, Takeyoshi Nakayama, Jun Takaya, Mikio Nakagawa
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Patent number: 8852684Abstract: A finish for acrylic fiber to be processed into carbon fiber includes an ester compound having at least three ester groups in its molecule and a silicone compound, wherein the silicone compound constitutes 10 to 50 weight percent of the whole of the nonvolatile matter of the finish. A method of manufacturing carbon fiber includes the processes of applying the finish for acrylic fiber to be processed into carbon fiber to acrylic fiber to be processed into carbon fiber; oxidative-stabilizing the finish-applied acrylic fiber in an oxidizing atmosphere at 200 to 300 deg. C. to convert the fiber into oxidized fiber; and carbonizing the oxidized fiber in an inert atmosphere at 200 to 3000 deg. C.Type: GrantFiled: November 16, 2006Date of Patent: October 7, 2014Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Yoshinobu Okabe, Yoshiaki Tanaka, Yoshio Hashimoto, Mikio Nakagawa
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Patent number: 8754141Abstract: A method that produces heat-expandable microspheres includes the use of a shell of thermoplastic resin and a non-fluorine blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin. The method includes a step of dispersing an oily mixture containing a polymerizable component, the blowing agent, and a polymerization initiator containing a peroxydicarbonate in an aqueous dispersing medium to polymerize the polymerizable component contained in the oily mixture. The resultant heat-expandable microspheres have a shell which is less apt to become thinner than its theoretical value, contain minimum amount of resin particle inside their shell, and have excellent heat-expanding performance.Type: GrantFiled: October 9, 2012Date of Patent: June 17, 2014Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Toshiaki Masuda, Kenichi Kitano, Katsushi Miki, Takeshi Inohara, Takayuki Aoki
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Patent number: 8534333Abstract: A tread rubber is made of a rubber composition containing 100 pbw of a diene rubber, 30 to 100 pbw of a reinforcing filler including at least 10 pbw of silica, and 1 to 20 pbw of microcapsules each encapsulating a heat-expandable substance. A sulfur-containing silane coupling agent is mixed in the rubber composition in an amount of 3 to 15 wt. % based on the weight of the silica. A shell material of each microcapsule is made of a thermoplastic resin which essentially contains a nitrile monomer. A vapor pressure of the heat-expandable substance is 1.4 to 3.0 MPa at 150° C. An average diameter of the microcapsules is 20 to 30 ?m before vulcanization of the rubber composition. An average diameter of the microcapsules expanded due to the vulcanization is 40 to 80 ?m. The tread rubber has a proportion of a cell-occupying area of 5 to 30%.Type: GrantFiled: February 13, 2009Date of Patent: September 17, 2013Assignees: The Yokohama Rubber Co., Ltd., Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Takamasa Kitamura, Shigeki Ito, Kenichi Kitano, Takeshi Inohara
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Patent number: 8486531Abstract: The present invention provides heat-expanded microspheres having high packing efficiency, and a production method thereof. The heat-expanded microspheres are produced by expanding heat-expandable microspheres, which comprise shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin and have an average particle size from 1 to 100 micrometer, at a temperature not lower than their expansion initiating temperature, and the heat-expanded microspheres result in a void fraction not higher than 0.70.Type: GrantFiled: January 23, 2012Date of Patent: July 16, 2013Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Toshiaki Masuda, Ichiro Takahara, Kenichi Kitano, Katsushi Miki, Takeshi Inohara, Takayuki Aoki
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Publication number: 20130123407Abstract: A sizing agent for reinforcement fibers which imparts good bonding performance to a reinforcement fiber is used to reinforce thermoplastic matrix resin, and provide a synthetic fiber strand applied with the sizing agent and a fiber-reinforced composite reinforced with the synthetic fiber strand. The sizing agent essentially contains a neutralization product of a modified polypropylene resin and an amine compound having at least two hydroxyl groups or amino groups in the molecule, and the nonvolatile component of the sizing agent exhibits an endothermic heat of fusion not higher than 50 J/g in determination with a differential scanning calorimeter (DSC).Type: ApplicationFiled: July 27, 2011Publication date: May 16, 2013Applicant: MATSUMOTO YUSHI-SEIYAKU CO., LTD.Inventors: Yoshio Hashimoto, Yusuke Shimizu, Mikio Nakagawa
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Publication number: 20130030065Abstract: A method that produces heat-expandable microspheres includes the use of a shell of thermoplastic resin and a non-fluorine blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin. The method includes a step of dispersing an oily mixture containing a polymerizable component, the blowing agent, and a polymerization initiator containing a peroxydicarbonate in an aqueous dispersing medium to polymerize the polymerizable component contained in the oily mixture. The resultant heat-expandable microspheres have a shell which is less apt to become thinner than its theoretical value, contain minimum amount of resin particle inside their shell, and have excellent heat-expanding performance.Type: ApplicationFiled: October 9, 2012Publication date: January 31, 2013Applicant: MATSUMOTO YUSHI-SEIYAKU CO., LTD.Inventor: Matsumoto Yushi-Seiyaku Co., Ltd.
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Patent number: 8329298Abstract: A method that heat-expandable microspheres includes the use of a shell of thermoplastic resin and a non-fluorine blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin. The method includes, a step of dispersing an oily mixture containing a polymerizable component, the blowing agent, and a polymerization initiator containing a peroxydicarbonate in an aqueous dispersing medium to polymerize the polymerizable component contained in the oily mixture. The resultant heat-expandable microsphres have a shell which is less apt to become thinner than its theoretical value, contain minimum amount of resin particle inside their shell, and have excellent heat-expanding performance.Type: GrantFiled: October 4, 2006Date of Patent: December 11, 2012Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Toshiaki Masuda, Kenichi Kitano, Katsushi Miki, Takeshi Inohara, Takayuki Aoki
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Patent number: 8324286Abstract: Heat-expandable microspheres include a shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin, have a maximum expanding ratio not lower than 50 times, and are thermally expanded into hollow particulates having a repeated-compression durability not lower than 75 percent. The method of producing the heat-expandable microspheres includes the steps of dispersing an oily mixture containing a polymerizable component and the blowing agent in an aqueous dispersing medium containing a specific water-soluble compound and polymerizing the polymerizable component contained in the oily mixture.Type: GrantFiled: November 16, 2006Date of Patent: December 4, 2012Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Toshiaki Masuda, Ichiro Takahara, Kenichi Kitano, Katsushi Miki, Takeshi Inohara, Takeyoshi Fukuda, Takayuki Aoki, Satoshi Kawanami
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Patent number: 8323743Abstract: An acrylic-fiber finish for use in carbon-fiber production contributes to high tenacity of resultant carbon fiber. The acrylic-fiber finish for carbon-fiber production includes an epoxy-polyether-modified silicone and a surfactant. The weight ratios of the epoxy-polyether-modified silicone and the surfactant in the total of the non-volatile components of the finish respectively range from 1 to 95 wt % and from 5 to 50 wt %. The carbon fiber production method includes a fiber production process for producing an acrylic fiber for carbon-fiber production by applying the finish to an acrylic fiber which is a basic material for the acrylic fiber for carbon-fiber production; an oxidative stabilization process for converting the acrylic fiber produced in the fiber production process into oxidized fiber in an oxidative atmosphere at 200 to 300 deg.C.; and a carbonization process for carbonizing the oxidized fiber in an inert atmosphere at 300 to 2,000 deg.C.Type: GrantFiled: May 21, 2010Date of Patent: December 4, 2012Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Takeyoshi Nakayama, Yoshio Hashimoto, Mikio Nakagawa
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Patent number: 8247465Abstract: Heat-expandable microspheres include a shell of thermoplastic resin and core material encapsulated in the shell. The core material include a blowing agent having a boiling point not higher than the softening point of the thermoplastic resin and a gas migration inhibitor having a boiling point higher than the softening point of the thermoplastic resin. The ratio of the gas migration inhibitor to the core material is at least 1 weight percent and below 30 weight percent. The average particle size of the heat-expandable microspheres ranges from 1 to 100 micrometers.Type: GrantFiled: October 9, 2008Date of Patent: August 21, 2012Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Takeshi Inohara, Yoshiaki Shirakabe, Ikuo Yosejima, Kenichi Kitano, Toshiaki Masuda
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Patent number: 8216952Abstract: The object of the present invention is to provide a fabric treating agent to satisfy good sewability required to interior material fabrics for vehicles including automobiles and trains, the good sewability which arises from the trend toward ultrafiner fibers for manufacturing the fabrics, change in fabric structure from weave to knit, and increasing sewing machine speed. The present invention provides the fabric treating agent comprising at least one wax (a) selected from the group consisting of a paraffin wax having a melting point of 60° C. or higher, an oxidized paraffin wax having a melting point of 60° C. or higher, a polyethylene wax having a melting point of 100° C. or higher, and an oxidized polyethylene wax having a melting point of 100° C. or higher; and a nonionic surfactant (b). The present invention also provides a process for producing fabrics applied with the fabric treating agent, and provides vehicle interior material fabrics.Type: GrantFiled: October 17, 2007Date of Patent: July 10, 2012Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Tatsuya Oki, Masateru Kotera, Yoshihiro Kando
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Patent number: 8206826Abstract: A production method for heat-expandable microspheres, which have high expanding ratio and are thermally expanded into hollow particulates having excellent repeated-compression durability, and application thereof are provided. The method produces heat-expandable microspheres a shell of thermoplastic resin and a blowing agent being encapsulated therein and having a boiling point not higher than the softening point of the thermoplastic resin.Type: GrantFiled: May 14, 2008Date of Patent: June 26, 2012Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Hiroki Naito, Satoshi Kawanami, Katsushi Miki, Ikuo Yosejima, Kenichi Kitano
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Publication number: 20120121907Abstract: The present invention provides heat-expanded microspheres having high packing efficiency, and a production method thereof. The heat-expanded microspheres are produced by expanding heat-expandable microspheres, which comprise shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin and have an average particle size from 1 to 100 micrometer, at a temperature not lower than their expansion initiating temperature, and the heat-expanded microspheres result in a void fraction not higher than 0.70.Type: ApplicationFiled: January 23, 2012Publication date: May 17, 2012Applicant: MATSUMOTO YUSHI-SEIYAKU CO., LTD.Inventors: Toshiaki MASUDA, Ichiro TAKAHARA, Kenichi KITANO, Katsushi MIKI, Takeshi INOHARA, Takayuki AOKI
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Publication number: 20120080131Abstract: In heat-expandable microspheres as a starting material for hollow fine particles, which have excellent performances required for giving not only a durability in steady running region but also a durability in high-speed running region to a tire-rim assembly, and each consisting of an outer shell made of a thermoplastic resin obtained by polymerizing a monomer component in the presence of a polymerization initiator, and a foaming agent encapsulated in the outer shell and having a boiling point not higher than a softening point of the thermoplastic resin, the polymerization initiator comprises a peroxydicarbonate as an essential component, and the foaming agent comprises a fluorine-containing compound having an ether structure and a carbon number of 2-10 and containing no chlorine atom and bromine atom.Type: ApplicationFiled: November 21, 2011Publication date: April 5, 2012Applicants: MATSUMOTO YUSHI-SEIYAKU CO., LTD., BRIDGESTONE CORPORATIONInventors: Hiroyuki TERATANI, Toshiaki MASUDA, Kenichi KITANO, Katsushi MIKI, Takayuki AOKI, Takeshi INOHARA
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Publication number: 20120064347Abstract: Heat-expandable microspheres having high heat resistance and high solvent resistance, a production process thereof include a shell of a thermoplastic resin and a thermally vaporizable blowing agent being encapsulated therein. The thermoplastic resin includes a copolymer produced by polymerizing a polymerizable component containing a carboxyl-group-containing monomer. The surface of the heat-expandable microspheres is treated with an organic compound containing a metal of the Groups from 3 to 12 in the Periodic Table.Type: ApplicationFiled: May 21, 2010Publication date: March 15, 2012Applicant: MATSUMOTO YUSHI-SEIYAKU CO., LTD.Inventors: Yu Kita, Katsushi Miki
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Patent number: 8129020Abstract: Heat-expanded microspheres having high packing efficiency are produced by expanding heat-expandable microspheres, which include a shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin and have an average particle size from 1 to 100 micrometer, at a temperature not lower than their expansion initiating temperature, and the heat-expanded microspheres result in a void fraction not higher than 0.70.Type: GrantFiled: September 14, 2006Date of Patent: March 6, 2012Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Toshiaki Masuda, Ichiro Takahara, Kenichi Kitano, Katsushi Miki, Takeshi Inohara, Takayuki Aoki
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Patent number: 8112980Abstract: A finish for synthetic filament yarn which decreases broken filaments and ends down in friction false-twist texturing includes 40 to 98 wt % of a polyether compound, and essentially comprises components (A) and (B); wherein the component (A) is at least one member selected from the group consisting of (A1) a C1-C10 fatty acid, (A2) a C1-C10 hydroxyfatty acid, (A3) a sarcosine derivative, and salts thereof, and the amount of the component (A) in the finish ranges from 0.05 to 5 wt %; and wherein the component (B) is an alkylphosphate salt and the amount of the component (B) in the finish ranges from 0.01 to 3 wt %.Type: GrantFiled: September 2, 2008Date of Patent: February 14, 2012Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Shinichi Tatemoto, Tatsuo Harada, Kaori Kimoto
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Publication number: 20120021125Abstract: An acrylic-fiber finish for use in carbon-fiber production contributes to high tenacity of resultant carbon fiber. The acrylic-fiber finish for carbon-fiber production includes an epoxy-polyether-modified silicone and a surfactant. The weight ratios of the epoxy-polyether-modified silicone and the surfactant in the total of the non-volatile components of the finish respectively range from 1 to 95 wt % and from 5 to 50 wt %. The carbon fiber production method includes a fiber production process for producing an acrylic fiber for carbon-fiber production by applying the finish to an acrylic fiber which is a basic material for the acrylic fiber for carbon-fiber production; an oxidative stabilization process for converting the acrylic fiber produced in the fiber production process into oxidized fiber in an oxidative atmosphere at 200 to 300 deg.C.; and a carbonization process for carbonizing the oxidized fiber in an inert atmosphere at 300 to 2,000 deg.C.Type: ApplicationFiled: May 21, 2010Publication date: January 26, 2012Applicant: MATSUMOTO YUSHI-SEIYAKU CO., LTD.Inventors: Takeyoshi Nakayama, Yoshio Hashimoto, Mikio Nakagawa
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Patent number: 7994229Abstract: The present invention provides a process for producing thermo-expansive microspheres comprising a thermoplastic resinous shell and a blowing agent being encapsulated in the shell, the blowing agent which is a fluorine-containing C2-10 compound having ether linkage, being free of chlorine and bromine atoms and gasifying at a temperature not higher than the softening point of the thermoplastic resin. The thermo-expansive microspheres have preferably an average particle size ranging from 1 to 100 ?m and a CV, or coefficient of variation, of particle size distribution being 30% or less, and a retaining ratio of blowing agent encapsulated being 90% or more.Type: GrantFiled: February 6, 2008Date of Patent: August 9, 2011Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Katsushi Miki, Toshiaki Masuda, Ichiro Takahara, Takashi Fujie, Ikuo Yosejima