Abstract: A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

Abstract: Chlorine and sulfide species are separately introduced to a flue gas passing through a scrubber in order to remove the elemental and oxidized mercury from the gas through the precipitation of mercuric sulfide at near 100% efficiency.

Abstract: An annular heat-exchange reactor vessel allows for selectively controlled heat transfer between a first fluid and second fluid flowing through the vessel. Optionally, catalyst means may be added to further convert either fluid into a desired end product. In this regard, it is envisioned that the present invention will have particular utility in fuel processing systems. Additional, in-line upstream or downstream annular modules may also be incorporated to create a more complete, efficient and/or compact system. Various methods for constructing this reactor system are also disclosed.

Abstract: A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

Abstract: A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

Abstract: A method for producing chromium carbide coatings on steel provides a steel component having a surface which is carburized to contain at least about 0.40% by weight carbon and is followed by chromizing the surface to form a chromium carbide coating on the surface.

Abstract: A method for reducing or eliminating sagging in plasma arc keyhole welds adds a fluxing agent to the weld. The fluxing agent may be titanium nitride and/or titanium carbonitride. The fluxing agent is added using physical vapor deposition or by painting a slurry onto the weld surface.

Abstract: A fume sensor system that measures the concentration of fume particulate in a boiler and suppresses background noise.

Abstract: A method for reducing or eliminating sagging in plasma arc keyhole welds adds a fluxing agent to the weld. The fluxing agent may be titanium nitride and/or titanium carbonitride. The fluxing agent is added using physical vapor deposition or by painting a slurry onto the weld surface.

Abstract: A burner, particularly for use in thermophotovoltaic (TPV) applications, is provided having a fuel distribution tube with integrated swirl vanes adjacent exit holes in the sides of the fuel distribution tube, a ceramic burner cap attached the top end of the fuel distribution tube and a liquid fuel being provided through a fuel feed tube protruding through the bottom end of the fuel distribution tube, thereby forming a burner assembly. The burner assembly fits slidably into a cylindrical burner sleeve which forces primary combustion air through a passage formed between the sleeve and the swirl vanes. The primary combustion air mixes with the fuel in the vanes and burner slot formed between the burner cap and sleeve. The fuel feed tube used to supply fuel to the burner is a heated tube having a small orifice at the burner end. The tube is heated using an internal heater that vaporizes the fuel and can also use recuperated heat from the burner combustion process.

Abstract: An apparatus and method for sulfur recovery uses a scrubber tower with a plurality of vertically spaced scrubber trays in the tower. Sulfide-lean liquor is supplied to each of the trays and an acid gas is supplied to the tower below the trays. A downcomer extends in the tower and through the trays for accumulating liquid from the trays and moving the liquid to the bottom of the tower. The sulfide-lean liquor and acid gas are selected to form a sulfite-rich or sulfide-rich liquor in each of the trays which are brought to the bottom of the tower through the downcomer for removal from the tower.

Abstract: An improved process for chromizing and chrome-siliconizing 400-series stainless steel components, and in particular, 430 stainless steel components, such as boiler panel studs. The process includes the addition of between 0.12%-0.25% by weight of calcium fluoride salt to the conventional 4% by weight of ammonium chloride activator salt to the coating composition used in known diffusion coating processes. In a more preferred embodiment, small amounts of silicon powder, such as between about 0.12%-0.25% by weight, are added to the two salts and the diffusion coating material. A coating composition is provided as well.

Abstract: A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

Abstract: A method and apparatus for separating a wellhead fluid mixture containing oil and gas phases obtained from hydrocarbon production systems into its constituent parts employs a pressure vessel having an inlet for entry of the wellhead fluids mixture and an outlet for exit of a separated gas referred to as export gas. A primary centrifugal separator is provided in the pressure vessel for centrifugally separating a first portion of the oil from the wellhead fluids mixture to produce a wet gas containing some remaining oil. A second centrifugal separator is also provided in the vessel and performs a second centrifugal separation operation on the wet gas to remove substantially all of the remaining oil from the wet gas to produce the export gas which is conveyed out of the pressure vessel. The oil and remaining oil separated from the wellhead fluids mixture is conveyed from the pressure vessel via another outlet.

Abstract: A method for capturing and reducing the mercury content of an industrial flue gas such as that produced in the combustion of a fossil fuel or solid waste adds a chelating agent, such as ethylenediaminetetraacetic acid (EDTA) or other similar compounds like HEDTA, DTPA and/or NTA, to the flue gas being scrubbed in a wet scrubber used in the industrial process. The chelating agent prevents the reduction of oxidized mercury to elemental mercury, thereby increasing the mercury removal efficiency of the wet scrubber. Exemplary tests on inlet and outlet mercury concentration in an industrial flue gas were performed without and with EDTA addition. Without EDTA, mercury removal totaled 42%. With EDTA, mercury removal increased to 71%.

Abstract: A method for improving the fracture toughness for aluminum-based diffusion coatings by thermal spray means to simultaneously apply aluminum, chromium, boron, and/or silicon onto a steel workpiece, followed by heat treatment of the workpiece for a sufficient time to cause the aluminum, chromium, boron, and/or silicon to diffuse into the workpiece. The resulting diffusion coating demonstrates improved fracture toughness and does not necessitate the use of a slurry.

Abstract: A fiber optic acoustic emission (FOAE) sensor particularly suitable for vibration sensing in a hostile environment has a pair of optical fibers each having an end face. In one embodiment, a hollow tube or core having opposite open ends receives the end faces of the optical fibers. Means are provided for fixing the optical fibers in the hollow core with the end faces facing each other and spaced by a distance from each other in the core. A signal processing unit is connected to the optical fibers for supplying light to, and for receiving light from, the optical fibers and for measuring variations in optical phase which result in changes in the light intensity due to vibrations of the hollow core. The hollow core is fixed in a resonant cylinder, and the resonant cylinder is fixed in a housing to complete the sensor.

Abstract: An EMAT device for non-destructive inspection of the surface of a tube for cracks using acoustic surface waves includes a pulsed magnet having an active surface for facing the surface of a tube to be inspected. A receive emat coil is on the active surface and a transmit emat coil is on the opposite surface of the receive coil. The transmit emat coil has a scan surface for scanning over the tube surface. A transmitter for generating and transmitting an RF signal to the transmit emat coil is provided for generating a transmitted acoustic wave signal along the tube, the transmitted wave creating a reflected acoustic wave if a crack in the tube is encountered, the reflected wave generating a reflection signal in the receive emat coil. A receiver is connected to the receive emat coil for receiving the reflection signal.

Abstract: A method and apparatus for reducing mercury in industrial gases such as the flue gas produced by the combustion of fossil fuels such as coal adds hydrogen sulfide to the flue gas in or just before a scrubber of the industrial process which contains the wet scrubber. The method and apparatus of the present invention is applicable to installations employing either wet or dry scrubber flue gas desulfurization systems. The present invention uses kraft green liquor as a source for hydrogen sulfide and/or the injection of mineral acids into the green liquor to release vaporous hydrogen sulfide in order to form mercury sulfide solids.

Abstract: An apparatus and method for sensing temperature within a broad temperature range, includes a fiber optic having an etalon at one end for reflecting light supplied at an opposite end by a pair of light sources operating at different wavelengths. The light sources are either applied to the optical fiber at different times for discriminating between the wavelengths and producing a temperature signal based on the two wavelengths, or the light is simultaneously applied to the optical fiber from both sources and thereafter divided into its component wavelengths before reflected and reference light detectors detect light signals at the different wavelengths. Known etalon/optical fiber based temperature sensors having a usual maximum temperature range of 500° C. are thus modified to increase their range to as much as double this range.