Abstract: This invention relates to a metallic composite membrane for separating hydrogen from a mixed gas, a membrane module and a manufacturing method thereof. The composite membrane consists of a three-layer sandwich structure, e.g. the porous metal substrate, an intermediate layer and the hydrogen-selective dense thin metal layer. In the embodiments of the invention, the porous metal substrates were first pretreated to reduce their surface roughness without reducing their gas permeability. The pretreated substrates were coated with intermediate layer, wherein the intermediate layer served as not only a barrier layer to prevent interdiffusion between the substrate and the hydrogen-selective layer, but also a surface modifier to reduce surface roughness and pore size of the substrate. A hydrogen-selective metal layer was then deposited on the intermediate layer-coated substrate by coating methods.
Type:
Application
Filed:
May 8, 2009
Publication date:
November 12, 2009
Applicant:
MEMBRANE REACTOR TECHNOLOGIES LTD.
Inventors:
Anwu LI, John Ross GRACE, Choon Jim LIM
Abstract: A reactor configuration for fluidized bed reactors in which large exposed fixed surface area per unit reactor volume is required. The configuration uses a serpentine or hairpin bend arrangement of continuously connected and communicating thin channels, with the containing surfaces of these channels being vertical. This configuration enables uniform fluidization of particles throughout the cross-sectional area of the reactor and facilitates dispersal of membrane surfaces, heat transfer surface and baffles in gas-solid fluidized bed reactors.
Type:
Application
Filed:
November 16, 2007
Publication date:
May 22, 2008
Applicant:
MEMBRANE REACTOR TECHNOLOGIES LTD.
Inventors:
John R. Grace, Choon Jim Lim, Alaa-Eldin M. Adris, Heping Cui, David Anthony Boyd
Abstract: This invention relates to a method of bonding a metallic membrane with metallic part involving pressing a smooth surface of the metallic membrane against the smooth surface of the metallic part, and heating the metallic membrane and metallic part to a temperature above the half melting point of the metallic membrane while subjecting the metallic membrane and metallic part to a controlled environment of a proper gas atmosphere. The metallic membrane can comprise palladium and the pressurized gas can comprise one of hydrogen, an inert gas or their mixture.
Abstract: This invention relates to a novel fluidized bed membrane reactor for autothermal operations. More particularly, this invention pertains to a unique fluidized bed membrane reactor which includes internal catalyst solids circulation for conveying heat between a reforming zone and an oxidation zone.
Type:
Grant
Filed:
August 11, 2003
Date of Patent:
November 28, 2006
Assignee:
Membrane Reactor Technologies Ltd.
Inventors:
John Grace, Choon Jim Lim, Alaa-Eldin M. Adris, Donglai Xie, David Anthony Boyd, Warren MacKay Wolfs, Clive M. H. Brereton
Abstract: This invention relates to a novel fluidized bed membrane reactor for autothermal operations. More particularly, this invention pertains to a unique fluidized bed membrane reactor which includes internal catalyst solids circulation for conveying heat between a reforming zone and an oxidation zone.
Type:
Application
Filed:
August 11, 2003
Publication date:
February 17, 2005
Applicant:
Membrane Reactor Technologies Ltd.
Inventors:
John Grace, Choon Lim, Alaa-Eldin Adris, Donglai Xie, David Boyd, Warren Wolfs, Clive Brereton