Abstract: A process for recovering non-ferrous metals from a solid matrix may include: (a) leaching the solid matrix with an aqueous-based solution containing chloride ions, ammonium ions, and Cu2+ ions, having a pH of 6.5-8.5, in a presence of oxygen, at a temperature of 100° C.-160° C. and a pressure of 150 kPa-800 kPa, so as to obtain an extraction solution comprising leached metals and solid leaching residue; (b) separating the solid leaching residue from the extraction solution; and/or (c) subjecting the extraction solution to at least one cementation so as to recover the leached metals in elemental state. The pH may be greater than or equal to 6.5 and less than or equal to 8.5. Temperature may be greater than or equal to 100° C. and less than or equal to 160° C. Pressure may be greater than or equal to 150 kPa and less than or equal to 800 kPa.
Type:
Grant
Filed:
February 15, 2018
Date of Patent:
January 14, 2020
Assignee:
METALS TECHNOLOGY DEVELOPMENT COMPANY LLC
Inventors:
Massimo Giuseppe Maccagni, Jonathan Hylkjier Nielsen, William Leonard Lane, David Michael Olkkonen, Timothy Roy Hymer
Abstract: A method of recovering metal values from metal-bearing materials such as slags and drosses includes the steps of pulverizing the material to particles less than about 100 ?m; leaching the pulverized material with a solution of ammonium chloride, sodium chloride, and potassium chloride; sequentially recovering at least two metals from the leachate by the addition of zinc using a sequential cementation process; and recovering zinc from the solution by electrowinning.
Type:
Grant
Filed:
October 13, 2014
Date of Patent:
April 17, 2018
Assignee:
METALS TECHNOLOGY DEVELOPMENT COMPANY, LLC
Inventors:
Timothy Roy Hymer, Bruce David Chamberlain, Karl Friedrich Schneider, Massimo Giuseppe Maccagni
Abstract: A process for recovering non-ferrous metals from a solid matrix may include: leaching the solid matrix with an aqueous-based solution, in a presence of oxygen, to obtain an extraction solution including leached metals and solid leaching residue; separating the solid leaching residue from the extraction solution; and subjecting the extraction solution to at least one cementation to recover the leached metals in elemental state. The leaching solution may include chloride ions. The leaching solution may further include ammonium ions. A pH of the leaching solution may be greater than or equal to 6.5 and less than or equal to 8.5. A leaching temperature may be greater than or equal to 100° C. and less than or equal to 160° C. A leaching pressure may be greater than or equal to 150 kPa and less than or equal to 800 kPa.
Type:
Grant
Filed:
April 10, 2013
Date of Patent:
April 17, 2018
Assignee:
METALS TECHNOLOGY DEVELOPMENT COMPANY, LLC
Inventors:
Massimo Giuseppe Maccagni, Jonathan Hylkjier Nielsen, William Leonard Lane, David Michael Olkkonen, Timothy Roy Hymer
Abstract: The present invention relates to a process for recovering non-ferrous metals from a solid matrix comprising the following phases: (a) leaching the solid matrix with an aqueous-based solution containing chloride ions and ammonium ions and having a pH within the range of 6.5-8.5, in the presence of oxygen, at a temperature ranging from 100° C. to 160° C. and a pressure within the range of 150 kPa-800 kPa, so as to obtain an extraction solution comprising the leached metals and a solid leaching residue; (b) separating said solid leaching residue from said extraction solution; (c) subjecting said extraction solution to at least one cementation so as to recover the metals in the elemental state.
Type:
Application
Filed:
April 10, 2013
Publication date:
April 30, 2015
Applicant:
METALS TECHNOLOGY DEVELOPMENT COMPANY LLC
Inventors:
Massimo Giuseppe Maccagni, Jonathan Hylkjier Nielsen, William Leonard Lane, David Michael Olkkonen, Timothy Roy Hymer
Abstract: A system for recovering lead from lead-bearing materials by circulating an aqueous solution of ferric fluoroborate in fluoroboric acid through a leaching vessel to leach lead from the lead-bearing material and an electrolytic cell for recovering the lead includes a cooler for cooling at least a portion of the circulating solution sufficiently to precipitate alkali salts and alkali-earth salts, and a filter for removing the precipitated salts from the solution. A process for recovering lead from lead-bearing materials by leaching the lead from the lead-bearing material with a solution of ferric fluoroborate in fluoroboric acid and recovering the lead from the solution includes cooling at least a portion of the circulating solution sufficiently to precipitate alkali salts and alkali-earth salts, and filtering the salts from the solution.
Type:
Grant
Filed:
April 11, 2012
Date of Patent:
May 6, 2014
Assignee:
Metals Technology Development Company, LLC
Inventors:
Massimo Giuseppe Maccagni, Jonathan Hylkjier Nielson, William Leonard Lane, David Michael Olkkonen