Patents Assigned to Metglas Inc.
  • Patent number: 11613101
    Abstract: A magnetic piece, a multilayer magnetic piece and a multilayer core with an adhesive agent of excellent saturation magnetic flux density are provided. The magnetic piece includes a soft magnetic amorphous alloy ribbon 1 and a resin layer 2 provided on at least one surface of the soft magnetic amorphous alloy ribbon. The resin layer contains a resin whose Shore D hardness is not more than 60. The resin may have a Shore D hardness of not more than 25 or may have a Shore D hardness of not less than 1.
    Type: Grant
    Filed: October 25, 2018
    Date of Patent: March 28, 2023
    Assignees: HITACHI METALS, LTD., METGLAS, INC.
    Inventors: Akio Uchikawa, Nakao Moritsugu, Daichi Azuma
  • Patent number: 11322281
    Abstract: A multilayer block core includes a multilayer block in which nanocrystalline alloy ribbon pieces are layered, the nanocrystalline alloy ribbon pieces having a composition represented by the following Composition Formula (A). Fe100-a-b-c-dBaSibCucMd??Composition Formula (A) In Composition Formula (A), each of a, b, c, and d is an atomic percent; the expressions 13.0?a?17.0, 3.5?b?5.0, 0.6?c?1.1, and 0?d?0.5 are satisfied; and M represents at least one element selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, and W.
    Type: Grant
    Filed: February 27, 2017
    Date of Patent: May 3, 2022
    Assignees: HITACHI METALS, LTD., Metglas, Inc.
    Inventor: Motoki Ohta
  • Patent number: 11264156
    Abstract: A magnetic core includes a nanocrystalline alloy ribbon having a composition represented by FeCuxBySizAaXb, where 0.6?x<1.2, 10?y?20, 0?(y+z)?24, and 0?a?10, 0?b?5, all numbers being in atomic percent, with the balance being Fe and incidental impurities, and where A is an optional inclusion of at least one element selected from Ni, Mn, Co, V, Cr, Ti, Zr, Nb, Mo, Hf, Ta and W, and X is an optional inclusion of at least one element selected from Re, Y, Zn, As, In, Sn, and rare earth elements. The nanocrylstalline alloy ribbon has a local structure such that nanocrystals with average particle sizes of less than 40 nm are dispersed in an amorphous matrix and are occupying more than 30 volume percent of the ribbon.
    Type: Grant
    Filed: January 7, 2015
    Date of Patent: March 1, 2022
    Assignees: METGLAS, INC., HITACHI METALS, LTD.
    Inventors: Motoki Ohta, Naoki Ito
  • Patent number: 11230754
    Abstract: A nanocrystalline alloy ribbon has an alloy composition represented by FebalCuxBySizAaXb where 0.6?x<1.2, 10?y?20, 0<z?10, 10(y+z)24, 0?a?10, O?b?5, with the balance being Fe and incidental impurities, where A is an optional inclusion of at least one element selected from Ni, Mn, Co, V, Cr, Ti, Zr, Nb, Mo, Hf, Ta and W, and X is an optional inclusion of at least one element selected from Re, Y, Zn, As, In, Sn, and rare earth elements, all numbers being in atomic percent. The ribbon has a local structure having nanocrystals with average particle sizes of less than 40 nm dispersed in an amorphous matrix, the nanocrystals occupying more than 30 volume percent of the ribbon and has a radius of ribbon curvature of at least 200 mm.
    Type: Grant
    Filed: January 7, 2015
    Date of Patent: January 25, 2022
    Assignees: METGLAS, INC., HITACHI METALS, LTD.
    Inventors: Motoki Ohta, Naoki Ito
  • Publication number: 20210310097
    Abstract: A method of producing an amorphous alloy ribbon having a composition of Fe100-a-bBaSibCc (13.0 atom %?a?16.0 atom %, 2.5 atom %?b?5.0 atom %, 0.20 atom %?c?0.35 atom %, and 79.0 atom %?(100-a-b)?83.0 atom %) includes: preparing an alloy ribbon; and, in a state in which the alloy ribbon is tensioned with a tensile stress of from 5 MPa to 100 MPa, increasing a temperature of the alloy ribbon to from 410° C. to 480° C., at an average temperature increase rate of from 50° C./sec to less than 800° C./sec, and decreasing a temperature of the thus heated alloy ribbon to a temperature of a heat transfer medium for temperature-decreasing, at an average temperature decrease rate of from 120° C./sec to less than 600° C./sec, with performing the increase and decrease of temperature being performed by contacting the traveling alloy ribbon with a heat transfer medium.
    Type: Application
    Filed: July 3, 2018
    Publication date: October 7, 2021
    Applicants: HITACHI METALS, LTD., METGLAS INC.
    Inventors: Daichi AZUMA, Naoki ITO
  • Publication number: 20200216926
    Abstract: A method of producing an amorphous alloy having a composition of Fe100-a-bBaSibCc (13.0 atom %?a?16.0 atom %, 2.5 atom %?b?5.0 atom %, 0.20 atom %?c?0.35 atom %, and 79.0 atom %?(100?a?b)?83.0 atom %) includes: preparing an alloy ribbon; and, in a state in which the alloy ribbon is tensioned with a tensile stress of from 20 MPa to 80 MPa, increasing a temperature of the alloy ribbon to from 410° C. to 480° C., at an average temperature increase rate of from 50° C./sec to less than 800° C./sec, and decreasing a temperature of the thus heated alloy ribbon to a temperature of a heat transfer medium for temperature-decreasing, at an average temperature decrease rate of from 120° C./sec to less than 600° C./sec.
    Type: Application
    Filed: July 3, 2018
    Publication date: July 9, 2020
    Applicants: HITACHI METALS, LTD., METGLAS INC.
    Inventors: Naoki ITO, Daichi AZUMA
  • Patent number: 10566127
    Abstract: An Fe—Si—B—C-based amorphous alloy ribbon as thick as 20-30 ?m having a composition comprising 80.0-80.7 atomic % of Fe, 6.1-7.99 atomic % of Si, and 11.5-13.2 atomic % of B, the total amount of Fe, Si and B being 100 atomic %, and further comprising 0.2-0.45 atomic % of C per 100 atomic % of the total amount of Fe, Si and B, except for inevitable impurities has a stress relief degree of 92% or more.
    Type: Grant
    Filed: December 8, 2015
    Date of Patent: February 18, 2020
    Assignees: HITACHI METALS, LTD., METGLAS, INC.
    Inventors: Eric Theisen, Yuichi Ogawa, Daichi Azuma
  • Patent number: 10337081
    Abstract: An apparatus for annealing alloy ribbon, the apparatus comprising: an unwinder unwinding an alloy ribbon from a spool of the alloy ribbon; a heating member comprising a first flat surface, on which the alloy ribbon unwound by the unwinder runs while contacting the first flat surface, the heating member heating the alloy ribbon running while contacting the first flat surface through the first flat surface; a cooling member comprising a second flat surface, on which the alloy ribbon heated by the heating member runs while contacting the second flat surface, the cooling member cooling the alloy ribbon running while contacting the second flat surface through the second flat surface; and a winder winding the alloy ribbon cooled by the cooling member.
    Type: Grant
    Filed: November 4, 2016
    Date of Patent: July 2, 2019
    Assignees: Metglas, Inc., HITACHI METALS, LTD.
    Inventors: Donald Robert Reed, Jr., Joseph Custis Boggs, Norman Eugene Fuller, Jr.
  • Patent number: 10316396
    Abstract: An iron-based soft magnetic alloy greater than 63.5 mm in width, a thickness between 13 and 20 microns and having a composition represented by the following formula: (Fe1-aMa)100-x-y-z-p-q-rCuxSiyBzM?pM?qXr wherein M is Co and/or Ni, M? is at least one element selected from the group consisting of Nb, W, Ta, Zr, Hf, Ti and Mo, M? is at least one element selected from the group consisting of V, Cr, Mn, Al, elements in the platinum group, Sc, Y, rare earth elements, Au, Zn, Sn and Re, X is at least one element selected from the group consisting of C, Ge, P, Ga, Sb, In, Be and As, and a, x, y, z, p, q and r respectively satisfy 0?a?0.5, 0.1?x?3, 0?y?30, 1?z?25, 5?y+z?30, 0.1?p?30, q?10 and r?10, the alloy being at least 50% crystalline with an average particle size of 100 nm or less. This alloy has low core loss, high permeability and low magnetostriction.
    Type: Grant
    Filed: September 16, 2015
    Date of Patent: June 11, 2019
    Assignee: Metglas, Inc.
    Inventors: Eric Alan Theisen, Naoki Ito, Ronald Joseph Martis, Donald Robert Reed, Jr., John Paul Webb
  • Patent number: 10046420
    Abstract: Disclosed is a semi-amorphous, ductile brazing foil with a composition consisting essentially of NibalFeaCrbPcSidBeMof with approximately 30 atomic percent ?a?approximately 70 atomic percent; approximately 0 atomic percent ?b?approximately 20 atomic percent; approximately 9 atomic percent ?c?approximately 16 atomic percent; approximately 0 atomic percent ?d?approximately 4 atomic percent; e?approximately 2 atomic percent; f?approximately 5 atomic percent; and the balance being Ni and other impurities; where c+d+e<approximately 16 atomic percent.
    Type: Grant
    Filed: March 12, 2015
    Date of Patent: August 14, 2018
    Assignee: Metglas, Inc
    Inventors: William Coughlan, Eric Theisen
  • Patent number: 10022824
    Abstract: Disclosed is a semi-amorphous, ductile brazing foil with a composition consisting essentially of NibalFeaCrbPcSidBeMof with approximately 30 atomic percent?a?approximately 38 atomic percent; approximately 10 atomic percent?b?approximately 20 atomic percent; approximately 7 atomic percent?c?approximately 20 atomic percent; approximately 2 atomic percent?d?approximately 4 atomic percent; e?approximately 2 atomic percent; f?approximately 5 atomic percent; and the balance being Ni and other impurities; where c+d+e<approximately 16 atomic percent.
    Type: Grant
    Filed: March 18, 2014
    Date of Patent: July 17, 2018
    Assignee: Metglas, Inc.
    Inventors: William Coughlan, Eric Theisen
  • Patent number: 9970089
    Abstract: Disclosed is the semi-amorphous, ductile brazing foil with composition consisting essentially of NibalCraBbPcSidMoeFef with approximately 24 atomic percent?a?approximately 31 atomic percent; b?approximately 3 atomic percent; approximately 9 atomic percent?c?approximately 11 atomic percent; approximately 2 atomic percent?d?approximately 4 atomic percent; e?approximately 2 atomic percent; f?approximately 1 atomic percent; and the balance being Ni and other impurities; where b+c+d<approximately 16 atomic percent.
    Type: Grant
    Filed: December 13, 2013
    Date of Patent: May 15, 2018
    Assignee: Metglas, Inc.
    Inventors: William Coughlan, Eric Theisen
  • Publication number: 20170365392
    Abstract: An Fe—Si—B—C-based amorphous alloy ribbon as thick as 20-30 ?m having a composition comprising 80.0-80.7 atomic % of Fe, 6.1-7.99 atomic % of Si, and 11.5-13.2 atomic % of B, the total amount of Fe, Si and B being 100 atomic %, and further comprising 0.2-0.45 atomic % of C per 100 atomic % of the total amount of Fe, Si and B, except for inevitable impurities has a stress relief degree of 92% or more.
    Type: Application
    Filed: December 8, 2015
    Publication date: December 21, 2017
    Applicants: METGLAS, INC., HITACHI METALS, LTD.
    Inventors: Eric THEISEN, Yuichi OGAWA, Daichi AZUMA
  • Publication number: 20160196907
    Abstract: A nanocrystalline alloy ribbon has an alloy composition represented by FeCuxBySizAaXb where 0.6?x<1.2, 10?y?20, 0<z?10, 10?(y+z)?24, 0?a?10, 0?b?5, with the balance being Fe and incidental impurities, where A is an optional inclusion of at least one element selected from Ni, Mn, Co, V, Cr, Ti, Zr, Nb, Mo, Hf, Ta and W, and X is an optional inclusion of at least one element selected from Re, Y, Zn, As, In, Sn, and rare earth elements, all numbers being in atomic percent. The ribbon has a local structure having nanocrystals with average particle sizes of less than 40 nm dispersed in an amorphous matrix, the nanocrystals occupying more than 30 volume percent of the ribbon and has a radius of ribbon curvature of at least 200 mm.
    Type: Application
    Filed: January 7, 2015
    Publication date: July 7, 2016
    Applicants: METGLAS, INC., HITACHI METALS, LTD.
    Inventors: Motoki OHTA, Naoki Ito
  • Publication number: 20160196908
    Abstract: A magnetic core includes a nanocrystalline alloy ribbon having a composition represented by FeCuxBySizAaXb, where 0.6?x<1.2, 10?y?20, 0?(y+z)?24, and 0?a?10, 0?b?5, all numbers being in atomic percent, with the balance being Fe and incidental impurities, and where A is an optional inclusion of at least one element selected from Ni, Mn, Co, V, Cr, Ti, Zr, Nb, Mo, Hf, Ta and W, and X is an optional inclusion of at least one element selected from Re, Y, Zn, As, In, Sn, and rare earth elements. The nanocrylstalline alloy ribbon has a local structure such that nanocrystals with average particle sizes of less than 40 nm are dispersed in an amorphous matrix and are occupying more than 30 volume percent of the ribbon.
    Type: Application
    Filed: January 7, 2015
    Publication date: July 7, 2016
    Applicants: METGLAS, INC., HITACHI METALS, LTD.
    Inventors: Motoki OHTA, Naoki ITO
  • Publication number: 20160172087
    Abstract: An Fe—Si—B—C-based amorphous alloy ribbon as thick as 20-30 ?m having a composition comprising 80.0-80.7 atomic % of Fe, 6.1-7.99 atomic % of Si, and 11.5-13.2 atomic % of B, the total amount of Fe, Si and B being 100 atomic %, and further comprising 0.2-0.45 atomic % of C per 100 atomic % of the total amount of Fe, Si and B, except for inevitable impurities has a stress relief degree of 92% or more.
    Type: Application
    Filed: December 11, 2014
    Publication date: June 16, 2016
    Applicants: METGLAS, INC., HITACHI METALS, LTD.
    Inventors: Eric THEISEN, Yuichi OGAWA, Daichi AZUMA
  • Publication number: 20150266139
    Abstract: Disclosed is a semi-amorphous, ductile brazing foil with a composition consisting essentially of NibalFeaCrbPcSidBeMof with approximately 30 atomic percent?a?approximately 38 atomic percent; approximately 10 atomic percent?b?approximately 20 atomic percent; approximately 7 atomic percent?c?approximately 20 atomic percent; approximately 2 atomic percent?d?approximately 4 atomic percent; e?approximately 2 atomic percent; f?approximately 5 atomic percent; and the balance being Ni and other impurities; where c+d+e<approximately 16 atomic percent.
    Type: Application
    Filed: March 18, 2014
    Publication date: September 24, 2015
    Applicant: Metglas, Inc.
    Inventors: William COUGHLAN, Eric THEISEN
  • Publication number: 20150168088
    Abstract: Disclosed is the semi-amorphous, ductile brazing foil with composition consisting essentially of NibalCraBbPcSidMoeFef with approximately 24 atomic percent?a?approximately 31 atomic percent; b?approximately 3 atomic percent; approximately 9 atomic percent?c?approximately 11 atomic percent; approximately 2 atomic percent?d?approximately 4 atomic percent; e?approximately 2 atomic percent; f?approximately 1 atomic percent; and the balance being Ni and other impurities; where b+c+d<approximately 16 atomic percent.
    Type: Application
    Filed: December 13, 2013
    Publication date: June 18, 2015
    Applicant: Metglas, Inc.
    Inventors: William COUGHLAN, Eric Theisen
  • Patent number: 8974609
    Abstract: A ferromagnetic amorphous alloy ribbon includes an alloy having a composition represented by FeaSibBcCd where 80.5?a?83 at. %, 0.5?b?6 at. %, 12?c?16.5 at. %, 0.01?d?1 at. % with a+b+c+d=100 and incidental impurities, the defect length along a direction of the ribbon's length being between 5 mm and 200 mm, the defect depth being less than 0.4×t ?m and the defect occurrence frequency being less than 0.05×w times within 1.5 m of ribbon length, where t and w are ribbon thickness and ribbon width, respectively, and the ribbon in its annealed state and straight strip form of the ribbon, has a saturation magnetic induction exceeding 1.60 T, and exhibits a magnetic core loss of less than 0.14 W/kg when measured at 60 Hz and at 1.3 T induction level. The ribbon is suitable for use in transformer cores, rotational machines, electrical chokes, magnetic sensors and pulse power devices.
    Type: Grant
    Filed: August 31, 2010
    Date of Patent: March 10, 2015
    Assignees: Metglas, Inc., Hitachi Metals, Ltd.
    Inventors: Yuichi Ogawa, Eric A. Theisen, Yuji Matsumoto, James Perrozi, Ryusuke Hasegawa
  • Patent number: 8968489
    Abstract: A ferromagnetic amorphous alloy ribbon, a method of fabricating a ribbon and a wound transformer core are provided. The ribbon includes an alloy of FeaSibBcCd where 80.5?a?83 at. %, 0.5?b?6 at. %, 12?c?16.5 at. %, 0.01?d?1 at. % with a+b+c+d=100, and is cast from a molten state of the alloy, having a-surface tension of greater than or equal to 1.1 N/mi,. A defect length along a direction of the ribbon's length is between 5 mm and 200 mm, a defect depth less than 0.4 ×t ?m and a defect occurrence frequency less than 0.05 ×w times within 1.5 m of ribbon length, where t is the ribbon thickness and w is the ribbon width in mm. The ribbon has a saturation magnetic induction exceeding 1.60 T and a magnetic core loss of less than 0.14 W/kg when measured at 60 Hz and at 1.3 T induction level in an annealed straight strip form, and a core magnetic loss of less than 0.3 W/kg and an exciting power of less than 0.
    Type: Grant
    Filed: August 31, 2010
    Date of Patent: March 3, 2015
    Assignees: Metglas, Inc., Hitachi Metals, Ltd.
    Inventors: Daichi Azuma, Ryusuke Hasegawa, Yuichi Ogawa, Eric A. Theisen, Yuji Matsumoto