Abstract: A system and method for capturing and separating carbon dioxide from mixed gas streams. The gas stream is processed in a structure including a compression module comprising a plurality of compressors, intercoolers and inter-stage condensate separators. The flow path from the compression module includes a plurality of flow separators, gas stream splitters, heat exchangers and at least a first mixer and a first expander. The gas stream is sequentially compressed and cooled to form process condensate and separate it from the compressed gas stream. The gas stream is further dried and cooled to liquefy carbon dioxide and separate it from the non-condensable portion. Selective expansion of liquid carbon dioxide streams provides cooling for the system, and further energy efficiency is achieved by selective recycling of portions of gas streams, allowing for compact equipment and economical operation, while providing for high purity product streams of carbon dioxide.

Abstract: An apparatus protected by corrosion resistance coating, said apparatus comprises an enclosure and heat exchanging elements contained therein wherein the heat exchange element and the enclosure are coated with fluoropolymer composites filled with thermally conductive and thermally insulating fillers, respectively. The composites contain: i) at least one fluoropolymer, and in a preferred embodiment the fluoropolymer is perfluoroalkoxy (PFA), and ii) at least one thermally conductive or insulating filler, and in a preferred embodiment the thermally conductive filler is graphite and the thermally insulating filler is carbon black. The thermally conductive filler is added to the coating for heat exchange elements, e.g. tubes, plates, fins, etc., to enhance heat transfer, while the thermally insulating filler is added to the coating for enclosures, e.g. shell, tube sheets, etc., to reduce the heat transfer to the environment.

Abstract: A method of chromite reduction using cryolite (Na3AlF6) as an additive. The cryolite used may be pure cryolite or an impure mixture containing cryolite, such as the bath material produced as waste or as a by-product of aluminum smelting processes. In one embodiment, the reduction product is re-melted at a higher temperature to form larger metallic particles. In another embodiment, the chromite ore is granulated with cryolite particles and carbon reductant particles before being reduced.

Abstract: Disclosed are methods and apparatuses for analysis of synthetic ropes, cords, slings, cables and belts (collectively termed “ropes”) including but not limited to ropes for bearing loads as well as fiber optic cables. The ropes are provided with one or more elements for magnetic detection, wherein the magnetic detection elements each comprise a metal fiber or an appropriately treated synthetic fiber. The methods and apparatuses encompass detection of induced or residual magnetism or magnetic flux in the magnetic detection element(s), to sense for example lay length and/or damage, breakage or wear of the magnetic detection element(s), indicative of the condition of the rope.

Abstract: A method and apparatus for direct contact steam generation for a variety of industrial processes including heavy oil recovery, power generation and pulp and paper applications. The steam generation system consists of a combustor and steam generator and is constructed to be operable at elevated pressures. The fuel, at least one oxidant and a fluid supply including water are supplied at pressure to the combustor. Flue gas from the combustor is delivered to the direct contact steam generator at pressure, and upon direct contact with water produces a flue gas stream consisting primarily of steam. This product stream can then be cleansed and used for industrial application. The combustor can be operated with low grade fuel and low quality water with high solids and hydrocarbon contents. The apparatus and method reduce the environmental footprint by reducing air emission, concentrating CO2 to enable capture and reducing clean water requirements.

Abstract: Provided is a process for recovering metals from solid radioactive waste, preferably uranium, cesium, mercury, thorium, rare earths or combinations thereof. The process comprises a leaching step and a separation step. The leaching step comprises contacting the solid radioactive waste with an aqueous inorganic acid and a leaching salt to produce a mixture of a metal-rich leachate and a metal-poor waste, which are separated in the separation step. Also provided is a process for recovering metals from solid radioactive waste comprising an attrition step, a leaching step, a washing step, a combination step and a recovery step.

Abstract: A system for producing free-flowing powder with a narrow particle size distribution from liquid compositions comprising in combination: a feeding reservoir comprising said liquid compositions: a pumping device to pump said liquid composition into at least one atomizing device: said at least one atomizing device composed of at least one fluid nozzle to distribute an upward gaseous drying medium over said nozzle: two lateral streamlined tube-like devices for supplying said liquid composition and pressurized gas to said at least one nozzle from two opposite directions: a cylindrical plenum chamber wherein the fluid nozzle is located: an accelerating zone of a drying medium consisting of a cylindrical pipe located at the bottom of the cylindrical plenum: a conical-cylindrical drying chamber equipped with a manhole, a multi-nozzle manifold and insulation panels: and an intermediate drying medium consisting of a single bed or multi-beds of inert carriers within the drying chamber.

Abstract: A system using hybrid Rankine cycles is provided. The system includes a first Rankine cycle system using a first working fluid, the first system producing exergy loss and residual energy from at least one of turbine extraction, turbine condensation and boiler flue gas; and a second Rankine cycle system using a second working fluid to recover the exergy loss and residual energy. The second working fluid comprises a first stream and a second stream, wherein the first stream exchanges heat with the first system via at least one first heat exchanger, and the second stream exchanges heat with the first system via the at least one first heat exchanger and at least one second heat exchanger. A turbine of the first system is configured to allow the first working fluid to exit at a sufficiently high pressure and temperature to provide heat to the second system instead of expanding to a low pressure and temperature and discharging heat to ambient using a condenser.

Abstract: A combustion system for operational connection to an energy conversion system and a method of providing thermal energy to the energy conversion system. The system comprises a combustor to be oxy-fired at above atmospheric pressure, using solid, liquid or gaseous fuels, with a supply of oxygen and supercritical carbon dioxide. The combustion gases from the combustor are delivered to a heat exchanger which interfaces with the energy conversion system. Temperatures in the combustor, and the delivery temperature to the heat exchanger, are controlled by selective recirculation of at least part of the combustion gases to the combustor, and by modulating the supply of oxygen and fuel to the combustor. Any combustion gases which are not recirculated are processed to separate carbon dioxide for use or sequestration. The system and method substantially eliminate emissions of carbon dioxide, while providing a highly efficient supply of thermal energy to the energy conversion system.

Abstract: A method and apparatus for direct contact steam generation for a variety of industrial processes including heavy oil recovery, power generation and pulp and paper applications. The steam generation system consists of a combustor (10) and a steam generator (70) and is constructed to be operable at elevated pressures. The fuel, at least one oxidant and a fluid supply including water are supplied at pressure to the combustor. Flue gas from the combustor (10) is delivered to the direct contact steam generator (70) at pressure, and upon direct contact with water, produces a flue gas stream consisting primarily of steam. This product stream can then be cleansed and used for industrial applications. The combustor (10) can be operated with low grade fuel and low quality water with high solids and hydrocarbon contents. The apparatus and method reduce the environmental footprint by reducing air emission, concentrating CO2 to enable capture and reducing clean water requirements.

Abstract: The invention relates to a method and apparatus for measuring lay length of a wire rope having a number or external strands to form a rope having spiral grooves in the surface between the strands. A magnetic flux circuit is generated, part of which is formed within a region of the advancing wire rope. Variations of magnetic field around the region of the rope or variations of magnetic flux entering or leaving the rope are sensed by at least two sensors arranged around the rope. Signals from the sensors are subtractively combined to eliminate variations due to off-axis movements of the rope, and the combined signals reveal an oscillating pattern due to the undulating surface of the rope. Linking the oscillating pattern to distance along the rope reveals the lay length, which corresponds to a number of oscillations which is the same as the number of strands at the surface.

Abstract: A method and system for improving high excess air combustion system efficiency, including induration furnaces, using a re-routing of flue gas within the system by gas recirculation. Flue gas is drawn from hot system zones including zones near the stack, for re-introduction into the process whereby the heat recovery partially replaces fuel input. At least one pre-combustion drying zone, at least one combustion zone, and at least a first cooling zone exist in these furnaces. At least one exhaust gas outlet is provided to each pre-combustion drying and combustion zone. At least part of the gaseous flow from each system zone exhaust outlet is selectively delivered to an overall system exhaust, the remaining flow being selectively delivered via recirculation to cooling zones. Recirculation flow is adjusted to meet required system temperatures and pressures. The method and system provide efficiency improvements, reducing fuel requirements and greenhouse gas emissions.

Abstract: The present invention relates to the bioupgrading of crude oil is directed to a process for decreasing the acidity of an acidic crude oil, comprising contacting an acidic crude oil with a mixture nitrogen containing compounds selected from the group comprising ammonia, ammonia hydroxide, amines and the salts thereof, and in the presence of lipase enzyme, under conditions of suitable temperature and pressure sufficient to form the corresponding amide. The resulting naphthenic acid derived amides can then be processed normally in a refinery using such processes as cracking or hydrotreating and converted to hydrocarbon, ammonia and carbon dioxide without causing damage to the refinery infrastructure. This enzyme process is done at reduced temperatures (40-60° C.) and pressures requiring less energy.

Abstract: Exemplary embodiments of the invention provide a process of increasing the cetane number rating of a diesel oil feedstock. The process involves reacting a diesel fuel feedstock in liquid form with ozone in gaseous form in the presence of an alcohol having two or more carbon atoms and at least one polar solvent different from the alcohol, thereby forming an ozonated diesel oil containing oxidized byproducts, wherein the alcohol and said polar solvent are employed in amounts totaling no more than about 10 vol. % of the feedstock. The oxidized byproducts are then separated from the ozontated diesel oil to produce a hydrocarbon product of increased cetane number rating relative to the feedstock oil. The product can be used as a diesel fuel or as a diesel fuel extender mixed with conventional diesel fuel of low cetane number.

Abstract: The invention disclosed relates to a novel composition and use thereof, for the attraction and detection of emerald ash borer, Agrilus planipennis Fairmaire. The composition comprises (3Z)-dodecen-12-olide and ash foliar or cortical volatiles (green leaf volatiles) associated with a prism trap of a color in the green range of the visible light spectrum. A significant increase in the capture of male A. planipennis is achieved when traps were deployed in the upper tree canopy. This invention is the first demonstration of increased attraction with a combination of a pheromone and a green leaf volatile in a Buprestid species.

Abstract: The invention relates to modifications of a non-ammoniacal thiosulfate process of leaching precious metals (e.g. gold or silver) from precious metal-containing ores. The process involves leaching the ore with an aqueous lixiviant containing a soluble thiosulfate other than ammonium thiosulfate, a copper compound and an organic compound that serves as a copper ligand (i.e. a ligand-forming compound). Four modifications of this process are effective for increasing the amount of precious metal that can be extracted, reducing the consumption of materials, or for improving the rate of extraction. These four process, which may be used singly or in any combination, include (a) additions of soluble lead (e.g. as lead nitrate), (b) additions of thiourea, (c) increases in dissolved oxygen, and (d) increases of temperature at ambient pressure. This avoids the use environmentally harmful chemicals and allows for extraction from a variety of ores, e.g., containing substantial amounts of sulfides and/or quartz.

Abstract: A method and system for improving high excess air combustion system efficiency, including induration furnaces, using a re-routing of flue gas within the system by gas recirculation. Flue gas is drawn from hot system zones including zones near the stack, for re-introduction into the process whereby the heat recovery partially replaces fuel input. At least one pre-combustion drying zone, at least one combustion zone, and at least a first cooling zone exist in these furnaces. At least one exhaust gas outlet is provided to each pre-combustion drying and combustion zone. At least part of the gaseous flow from each system zone exhaust outlet is selectively delivered to an overall system exhaust, the remaining flow being selectively delivered via recirculation to cooling zones. Recirculation flow is adjusted to meet required system temperatures and pressures. The method and system provide efficiency improvements, reducing fuel requirements and greenhouse gas emissions.

Abstract: The invention disclosed relates to a novel composition and use thereof, for the attraction and detection of emerald ash borer, Agrilus planipennis Fairmaire. The composition comprises (3Z)-dodecen-12-olide and ash foliar or cortical volatiles (green leaf volatiles) associated with a prism trap of a color in the green range of the visible light spectrum. A significant increase in the capture of male A. planipennis is achieved when traps were deployed in the upper tree canopy. This invention is the first demonstration of increased attraction with a combination of a pheromone and a green leaf volatile in a Buprestid species.

Abstract: The present invention relates to the use of microorganisms (biocatalysts), or catalysts derived from these organisms (enzymes), to improve the quality of crude oil and bitumen as an attractive alternative to current upgrading methods. The invention identifies and characterizes the microorganism species, in particular, N. muscorum (UTEX 2209) and Kocuria rhizophilia (ATCC533), that have the capability to biochemically convert organic acids into chemical species that do not possess corrosive properties.

Abstract: The invention relates to modifications of a non-ammoniacal thiosulfate process of leaching precious metals (e.g. gold or silver) from precious metal-containing ores. The process involves leaching the ore with an aqueous lixiviant containing a soluble thiosulfate other than ammonium thiosulfate, a copper compound and an organic compound that serves as a copper ligand (i.e. a ligand-forming compound). Four modifications of this process are effective for increasing the amount of precious metal that can be extracted, reducing the consumption of materials, or for improving the rate of extraction. These four process, which may be used singly or in any combination, include (a) additions of soluble lead (e.g. as lead nitrate), (b) additions of thiourea, (c) increases in dissolved oxygen, and (d) increases of temperature at ambient pressure. This avoids the use environmentally harmful chemicals and allows for extraction from a variety of ores, e.g., containing substantial amounts of sulfides and/or quartz.