Patents Assigned to Mitsubishi Chemical Industries, Limited
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Patent number: 4839207Abstract: Disclosed herein is an optical recording medium for recording informations by irradiating the optical recording medium with a laser beam to form a hole or a deformed part thereon, said optical recording medium comprising a substrate and a recording layer containing at least Te, Se and F in the amounts of from 35 to 94.9 atomic % of Te, from 5 to 25 atomic % of Se and from 0.1 to 40 atomic % of F, produced by a reactive sputtering, said Se being derived from selenium fluoride and a sputtering target of Te or a sputtering target comprising Te-Se-alloy, and a process for producing the same.Type: GrantFiled: February 16, 1988Date of Patent: June 13, 1989Assignee: Mitsubishi Chemical Industries LimitedInventors: Toshihiko Yoshitomi, Yoshimitsu Kobayashi, Yoshiyuki Kisaka, Hidemi Yoshida, Michikazu Horie, Takanori Tamura, Mitsuaki Ohgaki
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Patent number: 4839388Abstract: This invention relates to a novel prostacyclin represented by the formula: ##STR1## [wherein R.sup.1 represents --CO.sub.2 R.sup.5 group or --CONR.sup.6 R.sup.7 group; A is(i) --CH.dbd.CH--CH.sub.2 CH.sub.2 -- or(ii) --CH.sub.2 CH.sub.2 --O--CH.sub.2 --;B represents --C.tbd.C-- group; R.sup.2 represents an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, a phenyl group or a phenoxy group;R.sup.3 represents a hydrogen atom, a methyl group or a vinyl group; R.sup.4 represents a hydrogen atom, an acyl group, a tri(1 to 7 carbon atoms)hydrocarbyl-silyl group or a group forming an acetal bond with an oxygen atom of a hydroxy group; a double bond in the substituent represented by A is E or Z, or a mixture thereof; asymmetric center in the substituent represented by R.sup.Type: GrantFiled: May 18, 1987Date of Patent: June 13, 1989Assignees: Mitsubishi Chemical Industries Limited, Sagami Chemical Research CenterInventors: Masakatsu Sibasaki, Mikiko Sodeoka, Katsuhiko Iseki, Masaki Shinoda, Chiyoko Aoki, Yosio Hayasi, Toshiji Kanayama
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Patent number: 4837309Abstract: A monoazo dyestuff of the formula: ##STR1## wherein D represents substituted or unsubstituted phenyl, imidazolyl, pyridyl, thiazolyl, thiadiazolyl, thienyl, benzoisothiazolyl, pyridinoisothiazolyl, thienoisothiazolyl, thienothiazolyl or benzothiazolyl, R.sup.1 represents substituted or unsubstituted alkyl, cyclohexyl, alkenyl, aralkyl or aryl, R.sup.2 and R.sup.3 each represents hydrogen, alkyl optionally substituted by cyano, hydroxy, alkoxy or alkoxyalkoxy, alkenyl, cyclohexyl, aryl or aralkyl, or together represent a 5- or 6-membered nitrogen-containing heterocyclic ring formed by combining R.sup.2 and R.sup.3, A represents ##STR2## X represents fluorine or chlorine, and Y.sup.1 represents hydrogen, chlorine, methyl or acylamino. The monoazo dyestuff is especially useful in the dyeing of cellulose-containing fibers and exhibits good fastness properties including good wet color fastness and good light fastness.Type: GrantFiled: February 24, 1984Date of Patent: June 6, 1989Assignee: Mitsubishi Chemical Industries LimitedInventors: Toshio Niwa, Kiyoshi Himeno, Toshio Hihara, Yutaka Kurose, Yukiharu Shimizu
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Patent number: 4837337Abstract: Disclosed herein is a process for producing a pyrrolidone derivative represent by the general formula (I): ##STR1## wherein R is an organic residue obtained by removing hydroxy radical from a C.sub.1-10 primary alcohol, C.sub.1-10 secondary alcohol or derivative thereof, comprising (1) reacting 2-pyrrolidone with acetaldehyde in the presence of a catalyst, thereby obtaining N-(.alpha.-hydroxyethyl)pyrrolidone, and (2) reacting the thus obtained N-(.alpha.-hydroxyethyl)pyrrolidone with a primary alcohol, a secondary alcohol or a derivative thereof in the presence of an acidic catalyst to obtain the pyrrolidone derivative.Type: GrantFiled: February 3, 1988Date of Patent: June 6, 1989Assignee: Mitsubishi Chemical Industries LimitedInventors: Yoshikazu Murao, Masao Miyake
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Patent number: 4837063Abstract: An optical recording material comprising a recording layer containing a substance with its optical properties changeable by irradiation with light in which information is recorded by irradiating the recording layer with light, said substance being an ethylene derivative having at its 1- and 2-positions heterocyclic groups which are cyclizable by irradiation with light to form a cyclohexadiene ring and thereby change the optical properties, and the other 1- and 2-positions connected to each other to form a ring.Type: GrantFiled: March 11, 1988Date of Patent: June 6, 1989Assignee: Mitsubishi Chemical Industries LimitedInventor: Masahiro Irie
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Patent number: 4834944Abstract: An automatic analytical apparatus comprising a sample cassette for holding a plurality of cups each containing a sample, a pipette means for pipetting the sample contained in the cup into a reaction tube transferred to a predetermined position, a transport means for holding the reaction tube at predetermined spaces, a driving means for intermittently driving the transport means, a diluent pipetting means for pipetting a diluent into the reaction tube containing the sample at a predetermined position according to a measuring item, a pipette transfer means for measuring the sample and the diluent added thereto and for discharging them into a reaction tube held in a measuring turret, a reagent pipetting means for pipetting a reagent according to the measuring item into the sample and diluent in the reaction tube held in the measuring turret, a transfer means for transferring the reaction tube containing the sample, the diluent and the reagent to an absorptiometry position, and an optical measuring means for optiType: GrantFiled: April 20, 1987Date of Patent: May 30, 1989Assignee: Mitsubishi Chemical Industries LimitedInventor: Koichi Wakatake
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Patent number: 4829049Abstract: A transfer sheet for heat sensitive transfer recording is disclosed, comprising a base film having provided thereon a coloring layer containing a dye represented by formula ##STR2## wherein R.sup.1 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aralkyl group, or an allyl group; R.sup.2 and R.sup.3 each represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aralkyl group, or an allyl group; X and Y each represents a hydrogen atom, an alkoxy group, an alkyl group, or a halogen atom; and n represents 1 or 2. The transfer sheet provides a transferred image excellent in uniformity, color density, color reproduction, and preservability.Type: GrantFiled: January 28, 1987Date of Patent: May 9, 1989Assignee: Mitsubishi Chemical Industries LimitedInventors: Yukichi Murata, Shuichi Maeda
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Patent number: 4829047Abstract: A dye transfer sheet for heat-sensitive transfer recording which has an ink layer containing a sublimable dye formed on a base film, said sublimable dye being of the formula: ##STR1## wherein --B represents ##STR2## --Z.sup.1 and --Z.sup.2 each represents hydrogen, alkyl optionally substituted by fluorine, alkoxy, halogen or --NHB, K represents ##STR3## --R.sup.1, --R.sup.2, --R.sup.6 and --R.sup.7 each represents hydrogen, C.sub.1 -C.sub.8 substituted or unsubstituted alkyl, substituted or unsubstituted vinyl, allyl or aryl, --R.sup.3, --R.sup.4 and --R.sup.5 each represents hydrogen or methyl, --X represents hydrogen, alkyl optionally substituted by fluorine, alkoxy, formylamino, alkylcarbonylamino optionally substituted by fluorine, arylcarbonylamino or halogen, and --Y represents hydrogen, alkyl optionally substituted by fluorine, alkoxy or halogen.Type: GrantFiled: January 29, 1987Date of Patent: May 9, 1989Assignee: Mitsubishi Chemical Industries LimitedInventors: Toshio Niwa, Yukichi Murata, Shuichi Maeda
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Patent number: 4828720Abstract: A liquid separating agent consisting essentially of (A) a separating layer-forming material which is a polymeric oily substance selected from the group consisting of a copolymer of an .alpha.-olefin with an .alpha.,.beta.-unsaturated dicarboxylic acid diester and a copolymer of a styrene with an .alpha.,.beta. unsaturated dicarboxylic acid diester and (B) an organic gelling agent which is a condensation product of a benzaldehyde with a tetra- or higher hydric alcohol.Type: GrantFiled: February 11, 1987Date of Patent: May 9, 1989Assignee: Mitsubishi Chemical Industries LimitedInventors: Katsuhiko Kuroda, Hideki Yamanouchi
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Patent number: 4824913Abstract: Disclosed herein is a process for preparing a water-soluble polymer, which comprises granulating a hydrous gel-like polymer obtained by polymerizing N-vinylformamide in the form of an aqueous solution of which a monomer concentration is 20 to 60% by weight, dispersing the formed polymer particles in methanol and contacting them with an aqueous solution of ammonium salt of a monovalent acid in an amount of 1 to 200% by mole based on the formamide groups in said polymer, thereby partially modifying the formamide groups in the polymer.Type: GrantFiled: May 6, 1987Date of Patent: April 25, 1989Assignee: Mitsubishi Chemical Industries LimitedInventors: Yoshikazu Murao, Shigeru Sawayama, Kohichi Satoh
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Patent number: 4824704Abstract: A 3-methylbutene-1 polymer composition comprising:(a) from 10 to 85% by weight of a 3-methylbutene-1 homopolymer or a copolymer of 3-methylbutene-1 with other .alpha.-olefin having from 2 to 18 carbon atoms, which has a heat of fusion of at least 7 cal/g as measured by a differential scanning calorimeter;(b) from 10 to 85% by weight of a copolymer of 3-methylbutene-1 with other .alpha.-olefin having from 2 to 18 carbon atoms, which has a heat of fusion of more than 1 cal/g and less than 7 cal/g as measured by a differential scanning calorimeter; and(c) from 3 to 40% by weight of an elastomeric copolymer of 3-methylbutene-1 with other .alpha.-olefin having from 2 to 18 carbon atoms or an elastomeric copolymer of at least two other olefins having from 2 to 18 carbon atoms, which shows no peak in fusion as measured by a differential scanning calorimeter.Type: GrantFiled: March 25, 1988Date of Patent: April 25, 1989Assignee: Mitsubishi Chemical Industries LimitedInventors: Yoshinori Suga, Eiji Tanaka, Nobuo Enokido, Hidehito Kato, Katsuji Shibata
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Patent number: 4822917Abstract: A process for the hydroformylation of an olefin, which comprises hydroformylating an olefinic compound by reacting it with carbon monoxide and hydrogen in a hydroformylation reaction zone in the presence of a catalyst solution containing rhodium and an oxide of an organic trivalent phosphorus compound to form an aldehyde having a carbon number larger by one than that of the olefinic compound; adding an organic trivalent phosphorus compound to the reaction mixture, followed by distillation to separate a distillate containing the aldehyde from a high-boiling residue containing rhodium; oxidizing the high-boiling residue at the same time as or subsequent to the distillation to convert the organic trivalent phosphorus compound to its oxide; and recycling the oxidized residue to the hydroformylation reaction zone as a recycling catalyst solution, wherein the hydroformylation reaction is conducted under a condition such that the proportion of an alcohol content supplied as contained in the recycling catalyst solutiType: GrantFiled: December 16, 1987Date of Patent: April 18, 1989Assignee: Mitsubishi Chemical Industries LimitedInventors: Chihiro Miyazawa, Hiroshi Mikami, Akio Tsuboi, Katsuhide Hamano
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Patent number: 4822797Abstract: Pyridazinone derivatives represented by the following general formula (I): ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 represent a hydrogen atom, hydroxy group or alkoxy group of not more than 5 carbon atoms, or two of R.sub.1, R.sub.2 and R.sub.3 may be combined together to form a group of --O--CH.sub.2 --O-- or --O--CH.sub.2 --CH.sub.2 --O--, R.sub.4 represents an alkyl group, n represents an integer of 0 to 4 and the dotted line represents a single or double bond, or salts thereof.Type: GrantFiled: March 31, 1987Date of Patent: April 18, 1989Assignee: Mitsubishi Chemical Industries LimitedInventors: Hiromi Okushima, Akihiro Narimatsu, Makio Kobayashi, Rikizo Furuya, Yoshimi Kitada
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Patent number: 4818612Abstract: A carbon fiber having a cross-sectional crystal structure of substantially uniform mesh form orientation as observed by a polarizing microscope.Type: GrantFiled: April 20, 1987Date of Patent: April 4, 1989Assignee: Mitsubishi Chemical Industries LimitedInventors: Ryuichi Hara, Masami Kagizaki, Tsuyoshi Takakura, Shigeki Tomono
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Patent number: 4816435Abstract: A transfer sheet for thermal transfer recording system having a color material layer containing sublimable dyes on one surface of a base film, and said color material layer is a black color material layer containing sublimable dyes represented by following formulae (I), (II) and (III); ##STR1## in the above formulae, X and Y represent a hydrogen atom or a methyl group; --A-- represents --CO--, --COO--, or --SO.sub.2 --; and R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, and R.sup.7 represent a hydrogen atom or a substituted or unsubstituted alkyl group.Type: GrantFiled: May 27, 1987Date of Patent: March 28, 1989Assignee: Mitsubishi Chemical Industries LimitedInventors: Yukichi Murata, Shuichi Maeda
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Patent number: 4814366Abstract: Disclosed herein is a thermoplastic polyester resin composition comprising a thermoplastic polyester resin and an amount effective in ultraviolet screening of at least one of naphthalenetetracarboxylic acids, acid anhydrides thereof, imides thereof and esters thereof.Type: GrantFiled: October 5, 1987Date of Patent: March 21, 1989Assignee: Mitsubishi Chemical Industries LimitedInventors: Takuji Hirahara, Takashi Nakamura, Yoshiko Aoyama, Shuichi Maeda
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Patent number: 4814507Abstract: A novel sulfone compound represented by the general formula (I) ##STR1## wherein R.sup.1 is cyclohexyl, phenyl; or a phenyl substituted with a group selected from nitro, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy and halogen; R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are respectively hydrogen, halogen, cyano or carbonyl, wherein R.sup.1 and R.sup.2 may form an o-phenylene or an o-phenylene substituted with at least one group selected from nitro C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy and halogen; X is oxygen or methylkene; Y is -(CH.sub.2).sub.n --, wherein n is an integer of 0, 5 or 6, or ##STR2## wherein m is an integer 1-3; R.sup.6 is hydrogen, C.sub.1 -C.sub.3 alkyl, .omega.-alkylaminoalkyl, wherein each alkyl has 1-3 carbon atoms, or .omega.-dialkylaminoalkyl, wherein each alkyl has 1-3 carbon atoms; R.sup.7 is hydrogen or C.sub.1 -C.sub.3 alkyl; and R.sup.6 and R.sup.7 may form a ring together with N, or ##STR3## wherein R.sup.8 is hydrogen, C.sub.1 -C.sub.Type: GrantFiled: September 14, 1987Date of Patent: March 21, 1989Assignee: Mitsubishi Chemical Industries, LimitedInventors: Akihiro Tobe, Shinichiro Fujimori, Tomoshi Yamazaki, Mamoru Sugano, Ryoji Kikumoto, Issei Nitta
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Patent number: 4812698Abstract: A piezoelectric actuator comprising a longitudinal effect-type laminated piezoelectric element composed of piezoelectric ceramic sheets laminated in their thickness direction, and a supporting member fixed to one side in the longitudinal direction of the element and being bending and capable of constraining expansion of the element.Type: GrantFiled: September 29, 1987Date of Patent: March 14, 1989Assignee: Mitsubishi Chemical Industries LimitedInventors: Yukio Chida, Tetsunhiko Nishimura, Yasuo Oguri
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Patent number: 4812692Abstract: A motor comprises magnetic poles constituted by a permanent magnet magnetized in its radial direction and a core having salient poles placed inside or outside the magnetic poles wherein the magnetic flux distribution of the permanent magnet is controlled so that the cogging torque characteristic of the motor is rendered to be a specified condition.Type: GrantFiled: January 29, 1988Date of Patent: March 14, 1989Assignees: Mitsubishi Chemical Industries Limited, Mitsubishi Steel MFG Co., Ltd.Inventor: Yoji Arita
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Patent number: 4810805Abstract: There are disclosed a (2-chloro-3-oxo-1-alkenyl)-bicyclo[3.3.0 octene derivative represented by the formula: ##STR1## wherein R.sup.1 represents --CH.sub.2 CH.sub.2 CH.sub.2 COOR.sup.5, --CH.sub.2 CH.sub.2 --O--CH.sub.2 COOR.sup.5, --CH.dbd.CHCH.sub.2 COOR.sup.5 or --CH.sub.2 CH.sub.2 C.tbd.C--COOR.sup.5 group where R.sup.5 in the groups represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; R.sup.2 represents a hydrogen atom, an acyl group having 1 to 7 carbon atoms, a tri(1 to 7 carbon atoms)-hydrocarbylsilyl group or a group forming an acetal bonding with an oxygen atom of a hydroxy group; R.sup.Type: GrantFiled: December 19, 1986Date of Patent: March 7, 1989Assignee: Mitsubishi Chemical Industries LimitedInventors: Masakatsu Shibasaki, Katsuhiko Iseki, Masaki Shinoda, Chiyoko Aoki, Yoshio Hayashi