Patents Assigned to Mitsubishi Chemical Industries, Limited
  • Patent number: 4645832
    Abstract: Reactive azo dyes represented by the general formula (I) or (II): ##STR1## wherein M is a hydrogen atom or an alkali metal, R.sup.1 is a hydrogen atom, a chlorine atom, a lower alkyl group, a lower alkoxy group, a nitro group or a carboxyl group, R.sup.2 and R.sup.8 are a lower alkyl group, a lower alkoxy group or a sulfonic acid group, R.sup.3, R.sup.7 and R.sup.9 are a hydrogen atom, a lower alkyl group, a lower alkoxy group, an acetylamino group or a sulfonic acid group, R.sup.4 and R.sup.5 are a hydrogen atom, a methyl group, a methoxy group or a sulfonic acid group, R.sup.6 is a hydrogen atom, a lower alkyl group, a lower alkoxy group or a sulfonic acid group, Z.sup.1 is a chlorine atom, a fluorine atom, an aliphatic or an aromatic amino residual group, a methoxy group or a phenoxy group, Z.sup.2 is the same one as Z.sup.1 when Z.sup.3 is ##STR2## Z.sup.2 is a chlorine atom or a fluorine atom when Z.sup.
    Type: Grant
    Filed: April 9, 1985
    Date of Patent: February 24, 1987
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Toshio Niwa, Yoshiaki Kato
  • Patent number: 4646309
    Abstract: There is herein, disclosed a dye laser including a container for a dye solution and a pumping energy source coupled thereto, said dye solution containing a perimidone dye formula (I): ##STR1## wherein R.sup.1 is a hydrogen atom, an alkyl group, a trifluoromethyl group, an alkoxycarbonyl group, an alkoxycarbonylalkyl group, an aralkyl group or a phenyl group; R.sup.2 is an optionally substituted alkoxycarbonyl group, a cyclohexyloxycarbonyl group, tetrahydrofurfuryloxycarbonyl group, an aryloxycarbonyl group, a benzyloxycarbonyl group, an acyl group, a cyano group or an optionally substituted carbamoyl group; R.sup.3 and R.sup.4 which may be the same or different are each a hydrogen atom, an alkyl group, an alkoxyalkyl group, an aralkyl group or an aryl group.
    Type: Grant
    Filed: October 7, 1983
    Date of Patent: February 24, 1987
    Assignees: Japan Atomic Energy Research Institute, Mitsubishi Chemical Industries Limited
    Inventors: Takashi Arisawa, Yoichiro Maruyama, Koreyuki Shiba, Toshio Niwa, Masaharu Kaneko, Hitoshi Ono
  • Patent number: 4626590
    Abstract: Reactive pyridone azo dyestuffs of the general formula [I]: ##STR1## wherein D represents ##STR2## represents phenylene optionally substituted by lower alkyl, lower alkoxy, trifluoromethyl or halogen, ##STR3## represents phenylene optionally substituted by lower alkyl, lower alkoxy, halogen or acetylamino,--A--represents --CH.sub.2 --, --C.sub.2 H.sub.4 --, --OC.sub.2 H.sub.4 --, ##STR4## --SO.sub.2 NHC.sub.2 H.sub.4 --or --SO.sub.2 C.sub.2 H.sub.4 --, --X represents hydrogen, lower alkyl, lower alkoxy, nitro, trifluoromethyl or halogen,--Y represents alkyl, aryl or aralkyl optionally substituted by lower alkoxy or phenoxy,--Z--represents a connecting group of --O--or --S--,--V represents --CN or --CONH.sub.2,--W represents a 6-membered nitrogen-containing heterocyclic ring having at least one active halogen atom, andn represents 0 or 1.These reactive pyridone azo distuffs give dyeings which are yellowish to reddish orange in color which have excellent light fastness.
    Type: Grant
    Filed: November 6, 1984
    Date of Patent: December 2, 1986
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Toshio Niwa, Kiyoshi Himeno, Toshio Hihara, Yukiharu Shimizu
  • Patent number: 4623719
    Abstract: This invention relates to disazo dyestuffs for cellulose or cellulose-containing fibers represented by the formula: ##STR1## wherein R.sup.1 represents a hydrogen atom, a nitro group, a halogen atom, an alkyl group of 1 or 2 carbon atoms or an acetylamino group; R.sup.2 and R.sup.3 each represents a hydrogen atom, an alkyl group of 1 or 2 carbon atoms, and alkoxy group or an acetylamino group; Y.sup.1 and Y.sup.2 each represents a hydrogen atom or an alkyl group, and alkenyl group, a cyclohexyl group, an aryl group or an aralkyl group which group ma optionally be substituted by cyano, hydroxyl, lower alkoxy or dialkylamino, or NY.sup.1 Y.sup.2 represents a 5-membered or 6-membered nitrogen-containing heretocyclic ring formed by combination of Y.sup.1 and Y.sup.2, and the total carbon atoms in Y.sup.1 and Y.sup.2 is 18 or less.
    Type: Grant
    Filed: March 24, 1986
    Date of Patent: November 18, 1986
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Toshio Niwa, Kiyoshi Himeno, Toshio Hihara
  • Patent number: 4621129
    Abstract: A process for producing a melting-anisotropic copolymerized polyester containing an alkylene terephthalate component, which comprises reacting a starting polyester composed of a dicarboxylic acid and a diol with an oxyaromatic carboxylic acid to form a copolymerized oligomer, then conducting acylating reaction by the addition of an acylating agent and further conducting polycondensating reduction thereby producing a melting-anisotropic, copolymerized polyester having a logarithmic viscosity of at least 0.2 dl/g. According to this process, a polyester of excellent physical property can be obtained at a good production efficiency.
    Type: Grant
    Filed: October 31, 1985
    Date of Patent: November 4, 1986
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Tamotsu Yoshimura, Masahiko Nakamura, Ken Honma
  • Patent number: 4614521
    Abstract: The transfer recording method which comprises heating a transfer sheet having a color material layer containing a sublimable dye on a base according to the image information received, thereby subliming said sublimable dye and transfer recording it on an image receiving layer of a recording sheet, a transfer recording method which is characterized by that the image receiving layer of the recording sheet contains a compound capable of reacting with the sublimable dye contained in the color material layer of the transfer sheet.
    Type: Grant
    Filed: May 10, 1985
    Date of Patent: September 30, 1986
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Toshio Niwa, Yukichi Murata, Shuichi Maeda
  • Patent number: 4613700
    Abstract: An improved process for catalytic hydrogenation of aromatic carboxylic acids to produce aromatic aldehydes is described, using a catalyst comprising zirconium oxide containing as an essential component at least one element selected from the group consisting of chromium, manganese, iron, cobalt, zinc, bismuth, lead, rhenium and the elements of Group III of periods 3 to 6 of the periodic table; the process results in improved catalyst activity and produces the desired aromatic aldehydes in high yield.
    Type: Grant
    Filed: January 18, 1985
    Date of Patent: September 23, 1986
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Takao Maki, Toshiharu Yokoyama
  • Patent number: 4613598
    Abstract: A piperazine derivative according to the present invention has the following general formula [I]: ##STR1## wherein R.sup.1 is --OH, --OR.sup.3, --SR.sup.3, --SOR.sup.3 or --SO.sub.2 R.sup.3 wherein R.sup.3 is alkyl group having 1 to 3 carbon atoms;R.sup.2 is --SO.sub.2 NH.sub.2, --SO.sub.2 NHR.sup.4, --SO.sub.2 NR.sup.4 R.sup.5, --COOH, --COOR.sup.4, --CONH.sub.2, --CONHR.sup.4, --CONR.sup.4 R.sup.5, --NHCONH.sub.2, --NHCSNH.sub.2, --NHCONHR.sup.4, --NHCOR.sup.4 or --NHSO.sub.2 R.sup.4 wherein R.sup.4 and R.sup.5 are independently alkyl group having 1 to 3 carbon atoms; orR.sup.1 and R.sup.2 together with carbon atoms to which they are attached form ##STR2## Z is --CO-- or --CH(OH)--; Ar is pyridyl or substituted or unsubstituted phenyl; andn is an integer of 3 to 5.An acid addition salt of the piperazine derivative having the above formula [I] is included in the present invention.
    Type: Grant
    Filed: March 6, 1985
    Date of Patent: September 23, 1986
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Harukazu Fukami, Shinya Inoue, Issei Nitta, Kenichiro Nakao, Ryoji Kikumoto
  • Patent number: 4609720
    Abstract: Disclosed herein is a wholly aromatic polyester comprising a structural unit represented by the formula (A): ##STR1## (i) a structural unit represented by the formulae (B), (C) and (D): ##STR2## or (ii) a structural unit represented by the formulae (E), (F) and (G): ##STR3## wherein X represents a C.sub.1 to C.sub.5 -hydrocarbon group, a halogen atom or an alkoxy group, and ##STR4## wherein Y represents an oxygen atom, a sulfur atom, a SO.sub.2 group, a carbonyl group, an alkylene group or an alkylidene group, or a single bond directly connecting the two benzene rings and R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.
    Type: Grant
    Filed: December 19, 1984
    Date of Patent: September 2, 1986
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Tamotsu Yoshimura, Masahiko Nakamura
  • Patent number: 4604483
    Abstract: In a method of separating phenylalanine and cinnamic acid from a mixed solution containing phenylalanine and cinnamic acid, a method of separating phenylalanine and cinnamic acid which comprises subjecting said mixed solution to chromatographic development using a synthetic adsorbent, such as Diaion, Amberlite etc., in the presence of a salt, such as ammonium halides, ammonium sulfate, alkali metal nitrates, ammonium and alkali metal salts of fatty acids, at a concentration in the range where the salting-out effect on cinnamic acid is greater than that on phenylalanine and also both phenylalanine and cinnamic acid can be dissolved, for example, in the range of 0.2-5N.
    Type: Grant
    Filed: February 7, 1985
    Date of Patent: August 5, 1986
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Tomohiko Kitsukawa, Hiroshi Kusano, Eiji Miyata, Toyokazu Sugawara
  • Patent number: 4593122
    Abstract: A process for producing terephthalic acid from p-xylene continuously, wherein p-xylene is oxidized to terephthalic acid by air in the presence of a catalyst containing cobalt, manganese and bromine at a temperature of 180.degree. to 230.degree. C. in a water containing acetic acid solvent in which the concentration of oxygen gas contained in an exhaust gas obtained from the reaction vessel used for oxidizing p-xylene is 2 to 8% by volume, said process comprising, (a) preparing an oxidation exhaust gas by condensing a gas withdrawn from said reaction vessel for removing condensates from said gas, (b) dividing the prepared oxidation exhaust gas into a discharged gas and a recycled gas, in which the volume ratio of said recycled gas to said discharged gas is 0.
    Type: Grant
    Filed: July 27, 1984
    Date of Patent: June 3, 1986
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Hiroshi Hashizume, Yoshiaki Izumisawa
  • Patent number: 4578507
    Abstract: A process for the production of cinnamic acid esters which is characterized by reacting a styrene with an aliphatic alcohol of 1-4 carbon atoms, carbon monoxide and oxygen in the presence of a catalyst comprising (a) a palladium metal or a compound thereof, (b) a salt of copper or iron, (c) a salt of an alkali metal or an alkaline earth metal, (d) an organic acid and (e) a halogen compound.
    Type: Grant
    Filed: January 24, 1985
    Date of Patent: March 25, 1986
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Keisuke Wada, Yoshimitsu Kobayashi, Yukio Kasori
  • Patent number: 4567300
    Abstract: Disclosed herein is a process for producing N-substituted formamide represented by the formula: ##STR1## wherein R represents a hydrogen atom or a residual radical of a primary or secondary alcohol, comprising the steps of reacting formamide with acetaldehyde in the presence of a basic catalyst and if required, further reacting the thus formed product, N-(.alpha.-hydroxyethyl)formamide, with a primary or secondary alcohol in the presence of an acid catalyst.
    Type: Grant
    Filed: January 10, 1985
    Date of Patent: January 28, 1986
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Yoshikazu Murao, Shigeru Sawayama, Kohichi Satoh
  • Patent number: 4564690
    Abstract: A macrocyclic compound represented by the following general formula: ##STR1## and a process for preparing thereof which comprises reacting an .alpha.,.omega.-dihalogenated hydrocarbon and an active methylene compound with a base in a solvent to obtain a macrocyclic compound represented by the following general formula (II): ##STR2## and then inducing the functional group of Y.sup.1, Y.sup.3 and Y.sup.5 by means of a hydrolysis, oxidation or such, and an uranyl ion capturing agent comprising a polymer chemically bonded to a functional group in a macrocyclic compound and preparation thereof.
    Type: Grant
    Filed: December 6, 1982
    Date of Patent: January 14, 1986
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Iwao Tabushi, Yoshiaki Kobuke
  • Patent number: 4562285
    Abstract: There is disclosed a process for producing terephthalic acid in which the mother liquor of the terephthalic acid slurry resulting from the oxidation of para-xylene, from which terephthalic acid has been separated is subjected to distillation to recover at least a portion of methyl acetate present therein, the recovered methyl acetate being circulated into the reactor.
    Type: Grant
    Filed: January 22, 1985
    Date of Patent: December 31, 1985
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Hiroshi Hashizume, Yoshiaki Izumisawa
  • Patent number: 4560793
    Abstract: There is disclosed a process for the production of terephthalic acid by oxidizing para-xylene with molecular oxygen in which substantially all of the methyl acetate present in the vapor evolved from the reactor is recovered and circulated into the reactor.
    Type: Grant
    Filed: September 29, 1981
    Date of Patent: December 24, 1985
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Hiroshi Hashizume, Yoshiaki Izumisawa
  • Patent number: 4556751
    Abstract: Catalytic isomerization of 10 types of dimethylnaphthalenes, which are classified into four groups, can be carried out by using as a catalyst a zeolite defining the main pore opening consists of a ten-membered oxygen ring.
    Type: Grant
    Filed: February 14, 1984
    Date of Patent: December 3, 1985
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Takao Maki, Tetsuo Masuyama, Yoshio Asahi
  • Patent number: 4551575
    Abstract: A substrate for an amorphous silicon semiconductor material characterized in that a metal or alloy film is formed on the surface of a metal substrate by means of an electroplating treatment.
    Type: Grant
    Filed: September 26, 1983
    Date of Patent: November 5, 1985
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Kiyoshi Takahashi, Makoto Konagai, Toshihiko Yoshitomi, Takeshi Omori
  • Patent number: 4537855
    Abstract: A photopolymerizable photosensitive composition characterized by comprising a photopolymerizable photosensitive resin having polyfunctional ethylenically unsaturated groups in the side chains or end groups thereof, and a photopolymerization initiator.
    Type: Grant
    Filed: October 11, 1983
    Date of Patent: August 27, 1985
    Assignee: Mitsubishi Chemical Industries Limited
    Inventor: Hiroshi Ide
  • Patent number: 4528113
    Abstract: An anthraquinone dye and a liquid crystal composition containing the dye are disclosed.The liquid crystal composition is preferably used in an electro-optic cell which enables a good color display utilizing the guest-host effect of the liquid crystal.
    Type: Grant
    Filed: March 27, 1984
    Date of Patent: July 9, 1985
    Assignees: Mitsubishi Chemical Industries Limited, Hitachi Limited
    Inventors: Shuji Imazeki, Akio Mukoh, Mikio Sato, Masaharu Kaneko, Tetsuo Ozawa, Tomio Yoneyama