Patents Assigned to Mitsubishi Gas Chemical Co.
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Patent number: 9988269Abstract: The invention provides a method for producing a peroxymonosulfuric acid solution with high stability, including the steps of mixing 35 mass % or more of hydrogen peroxide and 70 mass % or more of sulfuric acid to react them, cooling the reaction solution to 80° C. or lower within five minutes after initiation of the mixing step, and diluting the reaction solution with water four times or more as much as the reaction solution by mass.Type: GrantFiled: October 1, 2015Date of Patent: June 5, 2018Assignee: MITSUBISHI GAS CHEMICAL CO., INC.Inventors: Kiyoshi Yoshida, Tetsuo Koshitsuka, Kaoru Tsuyuki, Wakana Uesugi
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Patent number: 9182666Abstract: A cyclic compound of the present invention has a molecular weight of 500 to 5000, and is represented by the following formula (1):Type: GrantFiled: November 14, 2012Date of Patent: November 10, 2015Assignee: MITSUBISHI GAS CHEMICAL CO., INC.Inventors: Masatoshi Echigo, Masako Yamakawa
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Patent number: 8173051Abstract: There are disclosed insulated ultrafine powder comprising electroconductive ultrafine powder which is in the form of sphere, spheroid or acicular each having a minor axis in the range of 1 to 100 nm and an insulating film applied thereto; a process for producing the same which is capable of covering the surfaces of the insulated ultrafine powder with the insulating film having a thickness in the range of 0.3 to 100 nm without causing any clearance or vacancy; and a resin composite material which uses the same. A high dielectric constant of the material is assured by adding a small amount of insulated ultrafine powder wherein an insulating film is applied to the electroconductive ultrafine powder, while maintaining the processability and moldability that are the characteristics inherent in a resin material.Type: GrantFiled: September 11, 2009Date of Patent: May 8, 2012Assignee: Mitsubishi Gas Chemical Co., Inc.Inventors: Takahiro Matsumoto, Toshiaki Yamada, Hirotaka Tsuruya
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Patent number: 8097315Abstract: The multilayer container of the present invention comprises an outermost layer, an innermost layer and at least one intermediate layer interposed between the outermost layer and the innermost layer. Each of the outermost and innermost layers is mainly made of a thermoplastic polyester resin A produced by polymerizing a dicarboxylic acid component comprising 80 mol % or higher of terephthalic acid with a diol component comprising 80 mol % or higher of ethylene glycol. At least one of the intermediate layers is mainly made of a mixed resin B of a polyamide resin C and a polyamide resin D in a mixing ratio of 99.5/0.5 to 80/20 by weight. The polyamide resin C is produced by polymerizing a diamine component comprising 70 mol % or higher of m-xylylenediamine with a dicarboxylic acid component comprising 70 mol % or higher of adipic acid.Type: GrantFiled: May 4, 2004Date of Patent: January 17, 2012Assignee: Mitsubishi Gas Chemical Co., Inc.Inventors: Katsuya Maruyama, Kazunobu Maruo, Hiroyuki Nanba
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Publication number: 20100261749Abstract: It is an object of the present invention to provide a safe and highly effective preventing or ameliorating agent for skin psoriasis. The present invention provides a preventing or ameliorating agent for skin psoriasis, containing, as an active ingredient, a compound represented by general formula (I) or a salt thereof: (wherein R1, R2, and R3 simultaneously or separately represent a lower alkyl, lower alkenyl, lower alkynyl, aralkyl, araryl, or phenyl group, or a hydrogen atom).Type: ApplicationFiled: November 12, 2008Publication date: October 14, 2010Applicants: KYOWA HAKKO BIO CO., LTD., MITSUBISHI GAS CHEMICAL CO., LTD.Inventors: Ayako Kamimura, Toshikazu Kamiya, Masahiko Nakano, Kazutoshi Kikkawa
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Publication number: 20090318730Abstract: [Problems] To provide a method for efficiently separating and collecting an optically active amino acid amide and an optically active amino acid which are highly important substances as intermediates in the production of various industrial chemicals, agricultural chemicals, and pharmaceuticals, from an aqueous solution containing the optically active amino acid amide and the optically active amino acid.Type: ApplicationFiled: April 21, 2006Publication date: December 24, 2009Applicant: MITSUBISHI GAS CHEMICAL CO., INC.Inventors: Masaki Sugita, Satoshi Nanba, Akinori Tanaka
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Publication number: 20090233367Abstract: There is provided a method by which multiple types of substances desired to be transferred into cells can be continuously transferred into multiple types of cells by a convenient procedure, a cell in which the substance desired to be transferred into cells has been taken up by this method, and an apparatus for transferring a substance into cells by this method. The foregoing objects can be achieved by electrospraying cells with a liquid free from the substance to be transferred into cells while the cells are kept in contact with the substance to be transferred into cells, or first electrospraying cells with a liquid free from the substance to be transferred into cells and then bringing the cells into contact with the substance to be transferred into cells.Type: ApplicationFiled: May 16, 2007Publication date: September 17, 2009Applicants: MITSUBISHI GAS CHEMICAL CO., INC., SAITAMA UNIVERSITYInventors: Kazuto Ikemoto, Yusuke Okubo, Kanako Koike, Sayaka Aizawa, Ichiro Sakata, Takafumi Sakai
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Publication number: 20090136933Abstract: A method and kit for electrochemically simply determining with excellent precision the amount of double-stranded DNA does not require an expensive measurement electrode, such as an immobilized enzyme electrode or any high level electrode production technique which can retain uniform surface area accuracy. A method and kit are provided for electrochemically determining the amount of double-stranded DNA in a sample solution based on a residual amount of a substance capable of binding to the double-stranded DNA which is added to the solution in excess amount, in which a buffering substance is added to a sample solution, the buffering substance being capable of allowing an oxidation wave potential of the potential-current curve for the substance capable of binding to the double-stranded-DNA determined in a solution containing the buffering substance to change depending on the concentration of the free substance capable of binding to the double-stranded DNA in the solution.Type: ApplicationFiled: November 16, 2006Publication date: May 28, 2009Applicant: Mitsubishi Gas Chemical Co., Ltd.Inventor: Hitoshi Sakamoto
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Patent number: 7534493Abstract: Provided is a gas-barriering coated film obtained by coating a gas barriering layer on at least one face of a flexible film or an inorganic-deposited polymer film, wherein the above gas-barriering layer is a polyurethane resin-cured material formed from a composition comprising an active hydrogen-containing compound (A) and an organic polyisocyanate compound (B), and 20% by weight or more of a skeletal structure represented by Formula (1) is contained in the above resin-cured material. The gas-barriering coated film of the present invention is excellent in various performances such as a layer-to-layer adhesive property, a gas barriering property at a high humidity, a bending resistance and a retort treating resistance in addition to a high gas barriering property, and therefore it is applied to various uses including packing materials for food and medicines to which a high gas barriering property is required.Type: GrantFiled: June 19, 2006Date of Patent: May 19, 2009Assignee: Mitsubishi Gas Chemical Co., LtdInventors: Takeshi Nomura, Takeshi Koyama
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Publication number: 20090036301Abstract: A process for producing a catalyst for cyanhydrin hydration, which comprises a manganese oxide as a main component and is excellent in both physical strength and reaction activity, is provided, as well as a catalyst for cyanhydrin hydration obtained by the production process. Specifically, a process for producing a catalyst which is useful for cyanhydrin hydration and contains a manganese oxide as a main component, potassium, and one or more elements selected from the group consisting of bismuth, vanadium and tin, in which the above compounds are mixed together in an aqueous system; the resulting slurry precipitate is subjected to solid-liquid separation; and the resulting hydrous cake is dried in at least two separate stages comprising a predrying and a main drying, is provided, as well as a catalyst for cyanhydrin hydration obtained by the production process.Type: ApplicationFiled: July 6, 2006Publication date: February 5, 2009Applicant: MITSUBISHI GAS CHEMICAL CO., INC.Inventors: Hideho Matsuda, Takako Uchiyama, Yoshikazu Shima, Masaki Takemoto
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Publication number: 20090030163Abstract: An efficient process for producing glycidyl 2-hydroxyisobutyrate useful as a reactive diluent is provided. When glycidyl 2-hydroxyisobutyrate is produced by reacting allyl 2-hydroxyisobutyrate with hydrogen peroxide, a solution in which allyl 2-hydroxyisobutyrate is dissolved in an aliphatic ester as a solvent is reacted with hydrogen peroxide in the presence of a crystalline titanosilicate catalyst. Thus, a production process of glycidyl 2-hydroxyisobutyrate, which is small in degradation of purity and yield due to generation of peroxides or the like, and products thereof are provided.Type: ApplicationFiled: June 30, 2006Publication date: January 29, 2009Applicant: Mitsubishi Gas Chemical Co. Inc.Inventors: Rieko Nakano, Masaki Takemoto, Yoshikazu Shima
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Patent number: 7309794Abstract: Episulfide compounds useful as starting materials of optical materials are stably stored for a long period of time at a temperature ranging from their solidifying points to 20° C., preventing the production or precipitation of polymers and the yellowing.Type: GrantFiled: November 7, 2000Date of Patent: December 18, 2007Assignee: Mitsubishi Gas Chemical Co., Inc.Inventors: Akikazu Amagai, Yuichi Yoshimura, Motoharu Takeuchi, Atsuki Niimi, Hiroshi Horikoshi, Masanori Shimuta, Nobuyuki Uemura
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Patent number: 7192994Abstract: Disclosed is a method of producing a powdery coating material by using: a curable polyester resin (A) having a hydroxyl group and/or a carboxyl group at the terminals thereof, and further having a number average molecular weight of from 1,000 to 30,000, a glass transition temperature of from 30 to 100° C.; a curing agent (B) which is solid at normal temperature and is capable of being reacted with the hydroxyl group or the carboxyl group of the curable polyester resin (A); and a solvent (C) having a boiling point under normal pressure of from 50 to 130° C.; and comprising a step of kneading the curable polyester resin (A), the curing agent (B) and the solvent (C) under condition in which at 50 to 130° C., not less than 20% by weight of the curing agent (B) is dissolved in the solvent and, then, vapor-removing the solvent (C) under a reduced pressure.Type: GrantFiled: October 12, 2004Date of Patent: March 20, 2007Assignee: Mitsubishi Gas Chemical Co., Inc.Inventors: Nobuyuki Koike, Shojiro Kuwahara
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Patent number: 7186844Abstract: A method for producing a cyclic carbamate ester produces the cyclic carbamate ester by reacting an organic compound having at least two halogen atoms per molecule, an amine having at least two hydrogen atoms on a nitrogen atom, and carbon dioxide.Type: GrantFiled: January 3, 2005Date of Patent: March 6, 2007Assignee: Mitsubishi Gas Chemical Co., Inc.Inventor: Kazuto Ikemoto
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Patent number: 7119230Abstract: In the process of the present invention, xylylenediamine and/or cyanobenzylamine is produced by a catalytic liquid-phase hydrogenation of a phthalonitrile compound. The liquid-phase hydrogenation is performed by controlling the concentration of a benzamide compound to a specific level or lower. In a preferred embodiment, the concentration of a benzoic acid compound is further controlled to a specific level or lower. By the process, xylylenediamine and/or cyanobenzylamine is produced at high yields and the catalyst life is prolonged.Type: GrantFiled: June 30, 2003Date of Patent: October 10, 2006Assignee: Mitsubishi Gas Chemical Co., Inc.Inventors: Kazuhiko Amakawa, Takuji Shitara
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Patent number: 7101513Abstract: A fuel supplying apparatus for maintaining a stable supply of a mixed water-methanol solution while preventing water from freezing in a cold climate, and for immediately supplying a mixed water-methanol gas that has a composition which is outside of the high-rate reaction region during the starting/stopping operation of the reformer when the control tends to be unstable. The methanol reforming apparatus that generates a hydrogen-rich gas by reacting a mixed gas of water, methanol and air on a catalyst is supplied with the fuel from a fuel supplying apparatus comprising a mixed water-methanol solution tank wherein the molar ratio of water and methanol used for reforming is controlled to a predetermined value, a mixed water-methanol solution tank wherein the molar ratio of water and methanol is controlled to 4.6 or higher, and a switching means that switches the mixed water-methanol solution tank used as a fuel source according to the conditions of operation of the methanol reforming apparatus.Type: GrantFiled: July 26, 2001Date of Patent: September 5, 2006Assignees: Honda Giken Kogyo Kabushiki Kaisha, Mitsubishi Gas Chemical Co., Inc.Inventors: Takahiro Naka, Hideaki Sumi, Masataka Furuyama, Shoji Isobe, Yasushi Hiramatsu, Mikio Yoneoka
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Patent number: 7074946Abstract: A method of stably producing glycidyl 2-hydroxyisobutyrate at high purity and high yield is provided. A reactive diluent is provided for an epoxy resin including the above-mentioned glycidyl 2-hydroxyisobutyrate, and an epoxy resin composition.Type: GrantFiled: December 1, 2004Date of Patent: July 11, 2006Assignee: Mitsubishi Gas Chemical Co., Ltd.Inventors: Takatoshi Shida, Syu Suzuki
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Patent number: 7056984Abstract: Disclosed is an acrylic syrup containing a vinyl monomer (A) of methyl methacrylate and a polymerized solid component (B) which is a high polymer of said vinyl monomer and has a weight average molecular weight of from 30,000 to 2,000,000 as measured by the GPC and a viscosity at 25° C. of from 0.1 to 50 Pa·s, wherein at least part of said polymerized solid component (B) is a grafted rubber obtained by graft-polymerizing said vinyl monomer with a rubbery polymer, and said grafted rubber has a large branching coefficient. The acrylic resin molded articles obtained from the acrylic syrup exhibit excellent impact resistance.Type: GrantFiled: May 15, 2002Date of Patent: June 6, 2006Assignee: Mitsubishi Gas Chemical Co., Inc.Inventors: Tadashi Kawabata, Shojiro Kuwahara, Masahiro Kurokawa
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Patent number: 7053172Abstract: The fuel-barrier polyamide resin of the present invention is a product of the polycondensation of a diamine component comprising 70 mol % or higher of m-xylylenediamine and a dicarboxylic acid component comprising 70 mol % or higher of a mixed dicarboxylic acid which comprises a C4 to C20 ?,?-linear aliphatic dicarboxylic acid and at least one dicarboxylic acid selected from the group consisting of isophthalic acid and naphthalenedicarboxylic acid in a molar ratio of 30:70 to 95:5. The polyamide resin is excellent in not only fuel-barrier property and heat resistance, but also moldability and recyclability, and therefore suitably used as a barrier material of fuel containers.Type: GrantFiled: May 4, 2004Date of Patent: May 30, 2006Assignee: Mitsubishi Gas Chemical Co., Inc.Inventors: Kazunobu Sato, Kazunobu Maruo, Jun Mitadera, Masashi Kurokawa
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Patent number: 7053143Abstract: The polyester-based resin composition of the present invention comprises a polyamide resin, a polyester resin containing an antimony compound and a compound selected from the group consisting of inorganic acid salts and hydroxides of group-1 or -2 metals of the periodic table and transition metals. In the polyester-based resin composition, the phosphorus atom concentration, the antimony atom concentration, and the blending ratio of the inorganic acid salt or hydroxide to the phosphorus compound are regulated so as to satisfy the specific relationships to effectively prevent the darkening due to the deposition of antimony metal, thereby providing the polyester-based resin composition having excellent gas barrier properties and a good appearance with minimized darkening.Type: GrantFiled: September 12, 2003Date of Patent: May 30, 2006Assignee: Mitsubishi Gas Chemical Co., Inc.Inventors: Akira Mori, Koji Yamamoto