Patents Assigned to Mitsubishi Gas Chemical
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Publication number: 20100168464Abstract: The present invention provides an efficient production method suitable to industrial-scale production not requiring column purification for adamantyl (meth)acrylates having an adamantane skeleton and useful as monomers for use for resins excellent in optical properties, etc.Type: ApplicationFiled: December 16, 2009Publication date: July 1, 2010Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Kikuo Furukawa, Yoshihisa Arai
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Publication number: 20100168474Abstract: A method of producing xylylenediamine by the hydrogenation of dicyanobenzene obtained by the ammoxidation of xylene in a high yield while prolonging the catalyst life. In the method, a molten dicyanobenzene from which compounds having a boiling point lower than that of dicyanobenzene have been removed but compounds having a boiling point higher than that of dicyanobenzene are not removed is dissolved in a solvent containing liquid ammonia. By this dissolution, at least part of dicyanobenzene polymers precipitates as insolubles. The precipitates are removed by a solid-liquid separation. By subjecting the resulting solution containing the dicyanobenzene polymers in a reduced amount to hydrogenation, xylylenediamine is produced in a high yield and the life time of hydrogenation catalyst is prolonged.Type: ApplicationFiled: December 8, 2009Publication date: July 1, 2010Applicant: Mitsubishi Gas Chemical Company, IncInventors: Tatsuyuki KUMANO, Kenji Nakaya, Shinichi Nagao
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Publication number: 20100160494Abstract: The present invention provides an amine based epoxy resin curing agent containing an epoxy resin and an amine compound capable of imparting a high gas barrier performance and a long pot life, in addition to excellent performances which an epoxy resin conventionally possesses, and an epoxy resin composition with a high gas barrier performance and a long pot life, which contains the subject curing agent. Also, the present invention provides an adhesive for laminate with excellent adhesiveness to various polymers, papers, metals, etc., which contains, as a main component, an epoxy resin composition containing an amine based resin curing agent with a high gas barrier performance and a long pot life.Type: ApplicationFiled: May 20, 2008Publication date: June 24, 2010Applicant: Mitsubishi Gas Chemical Company Inc.Inventors: Shinichi Yonehama, Shigeyuki Hirose, Shinichi Ayuba, Eiichi Honda, Masayoshi Takahashi, Kana Kumamoto
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Patent number: 7736515Abstract: There is provided a method for highly treating distillation waste generated in the process of separating a distilled alcoholic material after alcoholic fermentation of starchy materials. The method includes the steps of adding sodium polyacrylate to the distillation waste from the starchy materials, then adding chitosan to treat the distillation waste, and further adding sodium polyacrylate to the waste. Furthermore, solid-liquid separation is then carried out. A liquid material thus separated is brought into contact with a reverse osmosis membrane.Type: GrantFiled: January 17, 2008Date of Patent: June 15, 2010Assignees: Mitsubishi Gas Chemical Company, Inc., Dia Aqua Solutions Co., Inc.Inventors: Hiroshi Takamiya, Shoichiro Kajiwara, Koji Hirukawa, Kimihisa Iwashiro
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Publication number: 20100144995Abstract: The invention relates to a method for producing a thermoplastic resin, comprising using a composition at least comprising a fluorene-containing dihydroxy compound represented by the following formula (1) and a fluorene-containing hydroxy compound represented by the following formula (2) in an amount of from 0.5 parts by weight to 1.5 parts by weight relative to 100 parts by weight of the fluorene-containing dihydroxy compound of formula (1).Type: ApplicationFiled: October 26, 2009Publication date: June 10, 2010Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Noriyuki KATO, Toshiaki Yamada, Shu Yoshida, Jun Hagiwara, Hiroki Furuhashi, Kazuaki Kaneko, Keiichi Kameyama
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Publication number: 20100143491Abstract: It is intended to provide an organic peracid polymer composition which is stable, odorless and has sufficient water solubility and is suitably used as a bactericide, a bleaching agent and a cleaning agent. By mixing and dissolving an organic acid polymer, hydrogen peroxide and an inorganic acid and maintaining the mixture for a period ranging from 1 hour to 1 month at a temperature ranging from 10 to 80° C., the organic peracid polymer-containing composition containing an organic peracid polymer (2 to 50% by weight) and, in some cases, the hydrogen peroxide (2 to 50% by weight) and the inorganic acid (0.1 to 10% by weight) is obtained.Type: ApplicationFiled: July 18, 2006Publication date: June 10, 2010Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Yasunari Kawabata, Yasushi Hiramatsu
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Patent number: 7723435Abstract: The single-layered structure of the invention comprises (A) 50 to 97% by weight of a polyolefin, (B) 2 to 45% by weight of a polyamide resin comprising a diamine component and a dicarboxylic acid component and (C) 1 to 45% by weight of a modified polyolefin and/or styrene copolymer. The polyamide resin B is dispersed in layers throughout the single-layered structure. With such a dispersion state of the polyamide resin B, the single-layered structure exhibits excellent fuel barrier properties.Type: GrantFiled: June 23, 2006Date of Patent: May 25, 2010Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Kazunobu Maruo, Kazunobu Sato, Masashi Kurokawa
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Patent number: 7714166Abstract: A process for producing carnitinamide which is an intermediate for production of L-carnitine is provided, which can hydrate carnitine nitrile to form carnitinamide with high selectivity, whereby highly-purified carnitinamide excellent as a substrate for stereoselective hydrolysis by optical resolution or a microorganism is produced in high yield. The process comprises hydrating carnitine nitrile to form carnitinamide using a catalyst containing a manganese oxide, and thus carnitinamide substantially free from by-produced carnitine is produced in high yield, so that carnitinamide of extremely high purity can be obtained through simple and easy crystallization operation.Type: GrantFiled: August 24, 2006Date of Patent: May 11, 2010Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Genki Nogami, Hideo Ikarashi, Shinyo Gayama
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Patent number: 7708831Abstract: A method for producing a ZnO single crystal by a liquid phase growth technique, comprising the steps of: mixing and melting ZnO as a solute and PbF2 and PbO as solvents; and putting a seed crystal or substrate into direct contact with the obtained melted solution, thereby growing a ZnO single crystal on the seed crystal or substrate.Type: GrantFiled: February 28, 2007Date of Patent: May 4, 2010Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Hideyuki Sekiwa, Jun Kobayashi, Miyuki Miyamoto
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Publication number: 20100106096Abstract: A prefilled syringe is provided that has high heat resistance, low adsorbability, low moisture permeability and low oxygen permeability. A prefilled syringe containing, as a resin constituting at least a barrel and a joint, a polyester resin that contains a diol unit having a cyclic acetal skeleton in an amount of from 1 to 30% by mol based on diol units and a dicarboxylic acid unit having a naphthalene skeleton in an amount of 70% by mol or more based on dicarboxylic acid units, and satisfies the following (i) to (iii): (i) a glass transition temperature of 110° C. or more measured with a differential scanning calorimeter, (ii) a moisture permeation coefficient of 1 g·mm/m2/day or less, and (iii) an oxygen permeation coefficient of 10 cc·mm/m2/day/atm or less.Type: ApplicationFiled: December 17, 2007Publication date: April 29, 2010Applicant: Mitsubishi Gas Chemical Company, Inc.Inventors: Takeshi Hirokane, Yoshio Aoki
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Publication number: 20100105111Abstract: An optically active amino acid is useful as food or feed, agrochemicals, chemical products for industrial use, intermediates for synthesis of cosmetics or medicines and the like and is also important as optical resolving agents or chiral building blocks for use in organic synthesis. Thus, the object is to provide an industrially practical method for producing the optically active amino acid simply and at low cost.Type: ApplicationFiled: February 28, 2008Publication date: April 29, 2010Applicant: Mitsubishi Gas Chemical Company, Inc.Inventors: Yasuhisa Asano, Akinori Tanaka, Ryuji Hasemi
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Patent number: 7704917Abstract: A process for producing a catalyst for cyanhydrin hydration, which comprises a manganese oxide as a main component and is excellent in both physical strength and reaction activity, is provided, as well as a catalyst for cyanhydrin hydration obtained by the production process. Specifically, a process for producing a catalyst which is useful for cyanhydrin hydration and contains a manganese oxide as a main component, potassium, and one or more elements selected from the group consisting of bismuth, vanadium and tin, in which the above compounds are mixed together in an aqueous system; the resulting slurry precipitate is subjected to solid-liquid separation; and the resulting hydrous cake is dried in at least two separate stages comprising a predrying and a main drying, is provided, as well as a catalyst for cyanhydrin hydration obtained by the production process.Type: GrantFiled: July 6, 2006Date of Patent: April 27, 2010Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Hideho Matsuda, Takako Uchiyama, Yoshikazu Shima, Masaki Takemoto
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Publication number: 20100092407Abstract: A tooth bleaching material that is safe and has good operability and high bleaching effect and a tooth bleaching method using the tooth bleaching material are provided by bleaching and removing colored sediments (colored or discolored deposits) on a tooth with a tooth bleaching material containing hydrogen peroxide and/or a compound generating hydrogen peroxide in an aqueous solution, and a dicarboxylic anhydride, and also containing a basic compound and a thickening agent, and a tooth bleaching method containing attaching the tooth bleaching material to a surface of a discolored tooth after dilution or without dilution irradiating with light.Type: ApplicationFiled: February 21, 2008Publication date: April 15, 2010Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Hiroshi Kurata, Yuki Kumagai, Kenichi Kimiduka, Yoshinori Kondo, Yasunari Kawabata
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Publication number: 20100093780Abstract: An object of the present invention is to provide a safe and highly effective insulin resistance improving agent or therapeutic agent for type II diabetes. According to the present invention, an insulin resistance improving agent or a therapeutic agent for type II diabetes comprising a compound represented by general formula (I) (wherein R1, R2, and R3 are the same as or different from each other, and each represents lower alkyl, lower alkenyl, lower alkynyl, aralkyl, araryl, phenyl, or a hydrogen atom) or a salt thereof as an active ingredient can be provided.Type: ApplicationFiled: September 19, 2007Publication date: April 15, 2010Applicants: KYOWA HAKKO BIO CO., LTD., MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Mika Sumi, Fumiko Ogino, Toshikazu Kamiya, Masahiko Nakano, Kazutoshi Kikkawa
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Patent number: 7691555Abstract: There are provided a photocurable composition capable of being readily cured by irradiation of ultraviolet rays and a cured product of the photocurable composition, as well as a coating composition and a coating film obtained from the coating composition. The cured product exhibits a high refractive index, a less discoloration and an excellent transparency. The present invention relates to a photocurable composition comprising (A) an episulfide compound containing a thiirane ring; and (B) a photo-base generator represented by the general formula (1): wherein Ar is phenyl, etc.; R is an alkyl group, etc.; —A+ is an ammonium ion; and X? is a borate anion, etc., and a coating composition comprising the photocurable composition and (C) a modified silicone oil, as well as a cured product and a coating film obtained from these compositions.Type: GrantFiled: August 4, 2004Date of Patent: April 6, 2010Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Hitoshi Okazaki, Junya Hayakawa, Motoharu Takeuchi, Masahiro Johno, Kenji Ishii
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Publication number: 20100075403Abstract: The present invention relates to a method for producing a dry yeast containing S-adenosyl-L-methionine using a yeast having production capability of S-adenosyl-L-methionine, the method containing: adding a cyclodextrin compound to a yeast concentrate obtained from a fungus culture liquid of the yeast; and then drying the concentrate, an SAMe-containing dry yeast obtained by the production method, and a composition formed by molding the dry yeast. According to the present invention, a dry yeast containing S-adenosyl-L-methionine, which is useful as an aqueous physiologically active substance, in a high concentration excellent in storage stability and a composition obtained by molding the dry yeast can be produced conveniently and economically and can be brought into the market.Type: ApplicationFiled: January 23, 2008Publication date: March 25, 2010Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Kentarou Takano, Shinyo Gayama
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Publication number: 20100048943Abstract: The invention provides a method for producing isophthalic acid, characterized by including subjecting a m-phenylene compound to liquid-phase oxidation reaction by use of a molecular-oxygen-containing gas in the presence of a catalyst at least containing a heavy metal compound and a bromine compound, and hydrous acetic acid having a water content of 1 to 15 mass %, to thereby yield a slurry; regulating the temperature of the slurry to 35 to 140° C., to thereby cause isophthalic acid to precipitate; removing the isophthalic acid through to solid-liquid separation to thereby recover a mother liquor; and recovering the catalyst from the mother liquor through a series of the following steps (1) to (4) for reusing at least a portion of the catalyst in the liquid-phase oxidation reaction: (1) an adsorption step including regulating the ratio “amount by mole of bromide ions in the mother liquor/total amount by mole of heavy metal ions in the mother liquor” to 0.Type: ApplicationFiled: December 7, 2007Publication date: February 25, 2010Applicant: Mitsubishi Gas Chemical Company Inc.Inventors: Fumiya Zaima, Nobuo Namiki, Hideaki Fujita
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Publication number: 20100047704Abstract: A long-life electrophotographic photosensitive body having excellent wear resistance and crack resistance can be obtained by using a polycarbonate resin composition, which is obtained by blending 0.01-5 parts by weight of a silicone-modified polyurethane per 100 parts by weight of a polycarbonate resin, as a binder for photosensitive layer (or in case when the photosensitive layer is of multilayer type, for at least an electron transport layer) of the electrophotographic photosensitive body. The silicone-modified polyurethane is obtained by reacting a diol component (a) represented by the general formula (I) below, an active hydrogen-containing polysiloxane compound (b), a polyisocyanate component (c) and, if necessary, a chain extender (d).Type: ApplicationFiled: July 25, 2007Publication date: February 25, 2010Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Jun Tajima, Takahiro Adachi
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Patent number: 7666509Abstract: A resin composition excellent in heat resistance after moisture absorption, lead-free solder reflow properties, dimensional stability and electrical characteristics for high-multilayer and high-frequency-capable printed wiring boards, which composition comprises a bisphenol A type epoxy resin (a) having at least two epoxy groups per molecule and a secondary hydroxyl group amount of 0.4 meq/g or less, a novolak type epoxy resin (b) at least two epoxy groups per molecule, a cyanate ester resin (c) having at least two cyanate groups per molecule and spherical silica having an average particle diameter of 4 ?m or less, wherein the equivalent ratio of cyanate groups/epoxy groups in the resin composition is in the range of 0.7 to 1.45, and a prepreg and a metal-foil-clad laminate each of which comprises the resin composition.Type: GrantFiled: February 23, 2007Date of Patent: February 23, 2010Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Kenichi Mori, Takaki Tsuchida
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Publication number: 20100041854Abstract: Provided are a method of bonding resin materials for bonding a resin material (X) containing an oxymethylene-based polymer (A) and a resin material (Y), and a structure obtained by the bonding method. The method includes the steps of: preparing as the resin material (Y) an oxymethylene-based polymer composition (B) satisfying the following conditions (1) and (2); or preparing as the resin material (Y) the resin material (X) or another resin material and providing the oxymethylene-based polymer composition (B) between the resin material (Y) and the resin material (X); and heating the resin materials: (1) the oxymethylene-based polymer composition (B) has a melting point lower than that of the oxymethylene-based polymer (A), and a difference in melting point between the composition and the polymer is smaller than 5° C.Type: ApplicationFiled: December 3, 2007Publication date: February 18, 2010Applicant: Mitsubishi Gas Chemical Company, Inc.Inventors: Akira Okamura, Satoshi Nagai