Patents Assigned to Mitsubishi Kasei Corporation
-
Patent number: 5437716Abstract: A recording liquid comprising an aqueous medium and at least one dye selected from dyes, free acid forms of which are represented by formulae (I) and (II): ##STR1## The symbols in formulae (I) and (II) are defined in the specification.Type: GrantFiled: May 13, 1994Date of Patent: August 1, 1995Assignee: Mitsubishi Kasei CorporationInventors: Hideo Sano, Tomio Yoneyama, Yukichi Murata, Masahiro Yamada
-
Patent number: 5436145Abstract: 6-Hydroxy nitrogen-containing 6-membered ring compounds of the following general formula (II): ##STR1## wherein R.sup.1 represents carboxy group, carbamoyl group, cyano group, formyl group, C.sub.1 -C.sub.5 hydroxyalkyl group, C.sub.2 -C.sub.6 alkoxycarbonyl group, carboxyvinyl group, carboxymethyl group or oxime group, R.sup.2 represents hydrogen atom or carboxy group, and A represents carbon atom or nitrogen atom, can be prepared by reacting a nitrogen-containing 6-membered ring compounds of the following general formula (I): ##STR2## wherein R.sup.1, R.sup.2 and A are as defined in the general formula (II) above, with a microorganism or physico-chemically treated microorganism in an aqueous medium. Efficiency of the above reaction can be raised by conducting the reaction in the presence of phenazine methosulfate.Type: GrantFiled: May 20, 1994Date of Patent: July 25, 1995Assignee: Mitsubishi Kasei CorporationInventors: Mari Yasuda, Haruyuki Ohkishi, Katsutoshi Sato, Yuuki Morimoto, Toru Nagasawa
-
Patent number: 5436391Abstract: A synthetic gene encoding an insecticidal protein, the gene is provided having a base sequence which has been modified to bring the codon usage in conformity with the genes of gramineous plants particularly rice plants. A preferred gene sequence is shown in SEQ ID NO: 1. An expression vector containing said structural gene is provided. A method for producing recombinant gramineous plants is provided, which comprises transforming protoplasts derived from gramineous plants with the vector, incubating the protoplasts in a liquid medium in the presence of cultured cells of the plants to form colonies and regenerating plants from said colonies. Recombinant gramineous plants having resistance against insects are also provided.Type: GrantFiled: November 27, 1992Date of Patent: July 25, 1995Assignees: Mitsubishi Corporation, Mitsubishi Kasei CorporationInventors: Hideya Fujimoto, Kimiko Ito, Mikihiro Yamamoto, Ko Shimamoto
-
Patent number: 5432037Abstract: Disclosed herein are an image-forming process which comprises steps of:uniformly charging a latent image carrier by a charging member disposed in contact with or in close vicinity to the latent image carrier,forming a latent image pattern on the latent image carrier by exposure,developing the formed latent image pattern with a developer composed of image-developing particles and conductive particles having an average particle size of smaller than that of said image-developing particles, thereby transferring at least said image-developing particles in the developer to the latent image carrier, andtransferring the image-developing particles transferred to the latent image carrier, to a transfer material; a developer for use in the image-forming process; and an image-forming system.Type: GrantFiled: November 17, 1992Date of Patent: July 11, 1995Assignee: Mitsubishi Kasei CorporationInventors: Takuya Nishikiori, Hiromi Horiuchi, Masayuki Hiroi
-
Patent number: 5427887Abstract: Disclosed is a light-sensitive composition which comprises(A) a diazo resin and(B) an alkali-soluble and swellable polymer compound, said polymer compound being a vinyl copolymer containing, as a constitutional unit, 0.1 to 10 mole % of a structure derived from an ester of acrylic acid or methacrylic acid having an alkyl group with 8 or more carbon atoms.Type: GrantFiled: August 16, 1993Date of Patent: June 27, 1995Assignees: Konica Corporation, Mitsubishi Kasei CorporationInventors: Satoshi Konuma, Toshiyuki Matsumura, Akihisa Murata, Shigeo Tsuji
-
Patent number: 5428110Abstract: A process for producing a copolymer of propylene and other .alpha.-olefins in the presence of a catalyst comprising a titanium-containing solid catalyst component and an organoaluminum compound is disclosed. The process comprises (1) a first step in which propylene is homopolymerized or propylene and a minor proportion of other .alpha.-olefin are copolymerized to prepare polymer particles having a pore volume of from 0.15 to 0.30 cm.sup.3 /g, and (2) a second step in which propylene and other .alpha.-olefin are copolymerized in the presence of said polymer particles. The resulting propylene copolymer particles have improved fluidity and high bulk density.Type: GrantFiled: December 21, 1993Date of Patent: June 27, 1995Assignee: Mitsubishi Kasei CorporationInventors: Yumito Uehara, Hideshige Kato, Hidehito Kato, Kouzou Kitayama
-
Patent number: 5426238Abstract: A method for producing an aldehyde, which comprises reacting an olefin with carbon monoxide and hydrogen in a hydroformylation reaction zone in the presence of a rhodium catalyst having an organophosphorus compound as a ligand, wherein a reaction solution withdrawn from the hydroformylation reaction zone, which contains an unreacted olefin, an aldehyde product and the catalyst, is countercurrently contacted with carbon monoxide and hydrogen in a contact tower to separate and recover the unreacted olefin without substantially deactivating the rhodium catalyst and supplying the recovered unreacted olefin together with the carbon monoxide and the hydrogen to the hydroformylation reaction zone.Type: GrantFiled: May 26, 1994Date of Patent: June 20, 1995Assignee: Mitsubishi Kasei CorporationInventors: Tomoyuki Mori, Akio Ueda, Kouichi Fujita
-
Patent number: 5424325Abstract: Aminoketone derivatives according to the present invention strongly inhibit thiol protease such as calpain, papain, cathepsin B, cathepsin H, cathepsin L or the like and have excellent properties concerning absorbance on oral administration, tissue distribution and cell membrane permeability. The aminoketone derivatives cart thus be used as therapeutic agents for treating muscular dystrophy, cataract, cardiac infarction, stroke, Alzheimer's disease, amyotrophy, osteoporosis and hypercalcemia and so on. It may also be used as therapeutic agents for preventing metastasis of cancer. In addition, the present derivatives are also applicable as intermediates for the preparation of ketone derivatives, which have inhibitory activity against thiol protease.Type: GrantFiled: December 22, 1993Date of Patent: June 13, 1995Assignee: Mitsubishi Kasei CorporationInventors: Ryoichi Ando, Naoko Ando, Hirokazu Masuda, Toshiro Sasaki, Yasuhiro Morinaka, Chizuko Takahashi, Yoshikuni Tamao, Akihiro Tobe
-
Patent number: 5422359Abstract: Alpha-aminoketone derivatives of the present invention strongly inhibit thiol protease such as papain, cathepsin B, cathepsin H, cathepsin L and calpain or the like and have excellent properties in absorbance on oral administration, tissue distribution and cell membrane permeability. The alpha-aminoketone derivatives can thus be used as therapeutic agents for treating muscular dystrophy, amyotrophy, cardiac infarction, stroke, Alzheimer's disease, disturbance of consciousness or dyskinesia caused upon brain trauma, multiple sclerosis, peripheral nervous neuropathy, cataract, inflammation, allergosis, fulminant hepatitis, osteoporosis, hypercalcemia, breast carcinoma, prostatic carcinoma or prostatomegaly. They may also be used as therapeutic agents for suppressing growth of cancer cells, preventing metastasis of cancer or suppressing aggregation of plaques.Type: GrantFiled: December 22, 1993Date of Patent: June 6, 1995Assignee: Mitsubishi Kasei CorporationInventors: Ryoichi Ando, Toshiro Sakaki, Yasuhiro Morinaka, Chizuko Takahashi, Yoshikuni Tamao
-
Patent number: 5422328Abstract: A process for preparing a catalyst useful for producing a nitrile by a gas phase catalytic oxidation reaction of an alkane with ammonia, which comprises drying a solution or slurry containing molybdenum, vanadium and tellurium by a spray drying method or a freeze-drying method and heat-treating the resulting dried product.Type: GrantFiled: December 27, 1993Date of Patent: June 6, 1995Assignee: Mitsubishi Kasei CorporationInventors: Takashi Ushikubo, Itaru Sawaki, Kazunori Oshima, Kei Inumaru, Satoshi Kobayakawa, Ken-ichi Kiyono
-
Patent number: 5416117Abstract: A novel cyclopropenone derivative (I) which possesses a potent inhibitory activity against thiol protease such as papain, cathepsin B, cathepsin H, cathepsin L, calpain or the like with excellent properties regarding oral absorbance, tissue transference and cell membrane permeability, and are clinically useful in the treatment of various diseases such as muscular dystrophy, amyotrophy. Also provided are a process for producing the compound (I) and a pharmaceutical composition containing the same.Type: GrantFiled: February 28, 1994Date of Patent: May 16, 1995Assignee: Mitsubishi Kasei CorporationInventors: Ryoichi Ando, Yasuhiro Morinaka, Chizuko Takahashi, Yoshikuni Tamao, Akihiro Tobe
-
Patent number: 5414160Abstract: A method for dimerizing an n-butene wherein a catalyst system is used which is produced in situ from an organonickel compound having no nickel-halogen bond, a triarylphosphine and/or a monoalkyldiarylphosphine, an organoaluminum compound and hydrogen. The resulting octenes are excellent as a raw material of alcohols for a plasticizer, and an excellent plasticizer can be obtained from alcohols having 9 carbon atoms produced by using the octenes.Type: GrantFiled: June 16, 1994Date of Patent: May 9, 1995Assignee: Mitsubishi Kasei CorporationInventors: Keiichi Sato, Yuuji Kawaragi, Yasuko Higashino
-
Patent number: 5407619Abstract: A spinning nozzle for dry spinning a spinning solution containing a metal compound and an organic polymer compound by a blowing method. In the spinning nozzle, an air nozzle 6 is provided having a rectangular-prism-like slit which is formed by opposing inner surfaces, extending in parallel to each other. The opposing inner surfaces each include a projecting portion, which are formed at the front side of a pair of cover plates 1,1, with each of the projecting portions having a knife edge portion at its free end. Spinning solution supplying nozzles are composed of a plurality of linear pipes and are arranged in the air nozzle 6 in such a manner that they are in parallel to the parallel surfaces of the cover plates and project from the edges of the parallel surfaces. Air fed through a gas feeding port 5 and blown out as an air stream from the air nozzle 6, and streams of the spinning solution extruded from the spinning solution supplying nozzles form parallel streams.Type: GrantFiled: October 6, 1993Date of Patent: April 18, 1995Assignee: Mitsubishi Kasei CorporationInventors: Hiroshi Maeda, Mamoru Shoji
-
Patent number: 5407902Abstract: A methoxyiminoacetic acid derivative represented by the following formula (I): ##STR1## wherein X represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 4 carbon atoms or an alkoxy group having 1 to 4 carbon atoms; A represents a methoxy group or a methylamino group; when A is a methoxy group, B represents --O--CO-- or --N=C(R.sup.1)-- and when A is a methylamino group, B represents --O--CR.sup.1 R.sup.2 --, wherein R.sup.1 and R.sup.2 independently represent a hydrogen atom, an alkyl group having 1 to 4 carbon atoms or a trifluoromethyl group; and Ar represents an optionally substituted aryl group or an optionally substituted heteroaryl group, and an agricultural/horticultural fungicide containing the same as an active ingredient.Type: GrantFiled: October 1, 1993Date of Patent: April 18, 1995Assignee: Mitsubishi Kasei CorporationInventors: Masatsugu Oda, Manabu Katsurada, Hirofumi Tomita
-
Patent number: 5405828Abstract: A tetrahydrofuran derivative represented by the following general formula [I]: ##STR1## [wherein A represents direct bonding or a group represented by --B--CHR.sup.1 -- (wherein B represents oxygen atom, sulfur atom or imino group; R.sup.1 represents hydrogen atom or an alkyl group); R represents hydrogen atom, halogen atom, hydroxyl group, an alkoxy group, benzyloxy group, an alkylsulfonyloxy group or a group represented by --O--COR.sup.2 (wherein R.sup.2 represents an alkyl group, a haloalkyl group, an alkenyl group, a cycloalkyl group, phenyl group, benzyl group, an alkoxy group, an alkylamino group or a dialkylamino group; X represents halogen atom; Y represents hydrogen atom or halogen atom) and the herbicide containing the same as the effective ingredient. The compounds of the present invention have exceedingly high herbicidal activity, and furthermore, the compounds are superior to the known similar compounds in terms of safety on crops. Thus, the compounds are useful as herbicides.Type: GrantFiled: January 25, 1994Date of Patent: April 11, 1995Assignee: Mitsubishi Kasei CorporationInventors: Natsume Bunji, Kyomura Nobuo, Suzuki Seiichi, Takahashi Yoji, Jikihara Tetsuo
-
Patent number: 5401756Abstract: Benzamide platelet activating factor antagonists of the following formula (I): ##STR1## wherein ##STR2## B, D: hydrogen atom, etc. E: pyridyl group, etc.n: integer from 0 to 2R.sup.2 : R.sup.3 R.sup.4 N-- etc.(R.sup.3, R.sup.4 : optionally substituted C.sub.6 -C.sub.12 aryl group, etc.) ##STR3## optical antipodes thereof or pharmaceutically acceptable salts thereof, show excellent PAF antagonism and are effective for therapy and prophylaxis of diseases caused by PAF (bronchial asthma, nephritis, shocks, cardiac infarction, cerebral hemorrhage, ulcer, DIC, autoimmune diseases, thrombosis, etc.).Type: GrantFiled: February 2, 1994Date of Patent: March 28, 1995Assignee: Mitsubishi Kasei CorporationInventors: Akihiro Yamamoto, Shuji Morita, Yoshio Hayashi, Noboru Yamada, Toshihito Kitamura
-
Patent number: 5399724Abstract: Novel acyclic terpene compounds useful as intermediates for producing sarcophytol A which have an anti-carcinogenic promotor activity and anti-tumor activity, which compounds are shown by the following general formula (I): ##STR1## [wherein R.sup.1 is a hydrogen atom, 1-alkoxyalkyl group, tetrahydrofuryl group, tetrahydropyranyl group or acyl group; R.sup.2 is a group of formula: --CHO, --CH.sub.2 OR.sup.3 or ##STR2## (wherein R.sup.3 is a hydrogen atom, 1-alkoxyalkyl group, tetrahydrofuryl group, tetrahydropyranyl group or acyl group; and R.sup.4 is C.sub.1 to C.sub.4 alkyl group) with the proviso that R.sup.1 and R.sup.3 do not represent the same substituents simultaneously; when R.sup.1 is a hydrogen atom, R.sup.3 is not acetyl group or tetrahydropyranyl group; and when R.sup.2 is a group of formula: ##STR3## R.sup.1 is not a hydrogen atom).Type: GrantFiled: September 28, 1993Date of Patent: March 21, 1995Assignee: Mitsubishi Kasei CorporationInventors: Hisao Takayanagi, Yasunori Kitano, Yasuhiro Morinaka
-
Patent number: 5398784Abstract: The present invention discloses a disc brake for a vehicle having a disc which is rotatable integrally with the wheels and pads which are brought into friction engagement with the disc. The disc is prepared by impregnating a reinforcing material into a carbon fiber reinforced carbon composite obtained by dispersing bundles of multiple single short carbon fibers with primarily a pitch, a combination of a pyrolytic carbon and a pitch or a combination of a pyrolytic carbon and a thermosetting resin, followed by baking; whereas the pads are prepared by impregnating a reinforcing material into a carbon fiber reinforced carbon composite obtained by dispersing bundles of multiple single short carbon fibers with primarily a combination of a pyrolytic carbon and a thermosetting resin or a combination of a pitch and a thermosetting resin, followed by baking.Type: GrantFiled: October 27, 1992Date of Patent: March 21, 1995Assignees: Nissin Kogyo Co., Ltd., Mitsubishi Kasei CorporationInventors: Ichiro Haneda, Tatsuyoshi Sakurai, Mashiro Yanagisawa, Kohei Okuyama, Kazuo Niwa, Toshihiro Fukagawa
-
Patent number: 5399196Abstract: A die coater comprising a die composed of upper and lower mold-pieces which form a manifold and a slit extending from the manifold, a first paint supply pipe communicating with one end portion of the manifold, a second paint supply pipe communicating with another end portion of the manifold and a flow channel closing member disposed in the manifold in a fluid sealing state, the member being movable along the manifold.Type: GrantFiled: July 29, 1993Date of Patent: March 21, 1995Assignee: Mitsubishi Kasei CorporationInventors: Kunihiko Ichikawa, Takefumi Yoshikawa
-
Patent number: RE34903Abstract: Disclosed herein is a vinylamine copolymer having the structural units represented by the following formulas (I), (II), (III).[.,.]. .Iadd.and .Iaddend.(IV) .[.and (VI).].: ##STR1## wherein x.crclbar. represents an anion or hydroxyl ion R represents a hydrogen atom or a methyl group, M.sym. represents a hydrogen ion or a monovalent cation, in which the molar fraction of the structural unit (I) is 5 to 85% by mole, the molar fraction of the structural unit (II) is 2 to 85% by mole, the molar fraction of the structural unit (III) is 5 to 80% by mole,.[.the molar fraction of the structural unit (IV) is 0 to 40% by mole,.]. all of said molar fractions being based on the vinylamine copolymer, and the molar fraction of the structural unit .[.(V).]. (.Iadd.IV) is 0 to 8% by mole which is based on the total content of the structural units (III).[.,.]. .Iadd.and .Iaddend.(IV), .[.and (V),.].Type: GrantFiled: November 8, 1993Date of Patent: April 11, 1995Assignee: Mitsubishi Kasei CorporationInventors: Takaharu Itagaki, Mitsuaki Shiraga, Shigeru Sawayama, Kohichi Satoh