Abstract: A molded foam article with an integral skin is produced by blow-molding a parison in a cavity of a metal mold to form a hollow member, filling the hollow member with pre-expanded thermoplastic resin besides before cooling and solidification of the hollow member, and heating the pre-expanded beads to cause the beads to expand further and fuse together. A filler for the pre-expanded thermoplastic resin beads is provided with a cutter for making a hole in the hollow member before introducing the resin beads into the hollow member.

Abstract: An aqueous dispersed resin composition comprising (A) an aqueous dispersion of carbonyl-containing resin particles having an inner layer and an outermost layer, which is obtained by emulsion polymerization of a monomer mixture comprising (a) not less than 0.5% by weight of a carbonyl-containing monomer containing at least one aldo group or keto group and one polymerizable unsaturated double bond in the molecule thereof, (b) not less than 0.5% by weight of an ethylenically unsaturated carboxylic acid, (c) not more than 99% by weight of a monomer having a water-solubility of not more than 8 g/100 ml at 20.degree. C.

Abstract: An aqueous dispersed resin composition is disclosed, comprising (A) an aqueous dispersion of carbonyl-containing resin particles having an inner layer and an outermost layer, which is obtained by emulsion polymerization of a monomer mixture comprising (a) not less than 0.5% by weight of a carbonyl-containing monomer containing at least one aldo group or keto group and one polymerizable unsaturated double bond in the molecule thereof, (b) not less than 0.5% by weight of an ethylenically unsaturated carboxylic acid, (c) not more than 99% by weight of a monomer having a water-solubility of not more than 8 g/100 ml at 20.degree. C.

Abstract: An aqueous crosslinking resin composition comprising (I) an aqueous resin dispersion obtained by emulsion polymerization of a monomer mixture consisting of (a) 2 to 50% by weight of an unsaturated carboxylic acid monomer, (b) 0.

Abstract: A mat or rug having a laminate structure is described composed of (A) a reverse side mat layer including (a) a laminated mat composed of (a.sup.1) base fabric and (a.sup.2) nonwoven fabric made of a thermoplastic resin fibrous binder, the base fabric (a.sup.1) and nonwoven fabric (a.sup.2) being united by needling, (b) cut piles made of a thermoplastic resin implanted from one side of the laminated mat (a), and (c) a resin adhesive layer formed by coating a liquid resin adhesive on the nonwoven fabric (a.sup.2) on the side opposite to the cut piles (b) and drying, (B) a thermoplastic resin adhesive layer, and (C) a surface mat layer, wherein the surface mat layer (C) is adhered via the thermoplastic resin adhesive layer (B) to the reverse side mat layer (A) on the side of reverse side mat layer (A) on which the liquid resin adhesive has been coated, wherein the cut piles (b) are implanted under the following conditions:Implanting density: 16 to 400 roots/in.sup.

Abstract: A process for producing expanded plastic with a skin and a molding apparatus therefor, the process including blowing a parison being held in a closed blow mold to obtain a hollow article, filling the hollow article with thermoplastic preexpanded resin beads before the hollow article is cooled to solidify, heating and fusing said beads, and cooling the expanded plastic. A hollow article and an expanded body are completely fused together, and improved productivity is obtained.

Abstract: A crosslinking aqueous pigment dispersion is disclosed, comprising (A) an aqueous resin dispersion, (B) a pigment, (C) a carbonyl-containing copolymer resin having an aldo group or a keto group, and (D) a hydrazine derivative having at least two hydrazino groups (--NHNH.sub.

Abstract: A process for producing a carpet is disclosed, comprising laminating a backing material composition comprising 100 parts by weight, on a resin solid basis, of an aqueous emulsion of a resin having a glass transition point of not higher than 5.degree. C., from 120 to 400 parts by weight of hydraulic inorganic cement, and up to 600 parts by weight of a non-hydraulic inorganic filler on a carpeting surface base material and heating the laminate to harden and dry the backing material composition. A carpet in which a carpeting surface base material and a backing material (and a carpeting back base material, if used) are firmly and integrally bonded can easily be obtained. The carpet has excellent properties, such as flexibility (softness), dimensional stability (resistance to shrinkage), fit to a floor, and workability, in a good balance.

Abstract: Foamed particles of a propylene resin are described which comprises, as a base resin, a random copolymer of propylene and 1-butene, said random copolymer having a 1-butene content of from 3 to 12% by weight.A foamed mold article is also described which is composed of a random copolymer of propylene and 1-butene, and having a density of from 0.015 to 0.09 g/cm.sup.3.A bumper core material for use in automobile bumpers is also described which is composed of a foamed mold article of a random copolymer of propylene and 1-butene, said random copolymer having a 1-butene content of from 3 to 12% by weight, said foamed mold article having a density of from 0.02 to 0.08 g/cm.sup.3, a compression stress at 50% compression as measured at 20.degree. C. of 2.5 to 10 kg/cm.sup.2, and an energy absorption efficiency as measured at 20.degree. C. of 60 to 90%, the ratio (E.sub.80 /E.sub.20) of the amount of the energy absorption of said foamed mold article as measured at 80.degree. C. (E.sub.

Abstract: A process for producing an aqueous copolymer dispersion is disclosed, which comprises emulsion polymerizing 100 parts by weight of a vinyl monomer mixture comprising (A) from 60 to 99.8% by weight of an acrylic ester of an aliphatic saturated alcohol having from 4 to 8 carbon atoms, (B) from 0.2 to 10% by weight of a monomer selected from the group consisting of an .alpha.,.beta.-unsaturated carboxylic acid, an .alpha.,.beta.-unsaturated carboxylic acid anhydride, a 2-hydroxyalkyl acrylate, a 2-hydroxyalkyl methacrylate, acrylamide, methacrylamide, methylolacrylamide, and methylolmethacrylamide, and (C) up to 30% by weight of a vinyl monomer other than the monomers (A) and (B) in the presence of from 0.01 to 10 parts by weight of a compound having an allyl hydrogen atom, with a total amount of the monomers (A), (B) and (C) being 100% by weight.

Abstract: A process for producing a composite laminate comprising a insert part and an injection-molded resin part by coating the insert part with a primer comprising a copolymer aqueous emulsion having a glass transition point of not higher than 20.degree. C. which is obtained by emulsion polymerization of a monomer mixture consisting mainly of (a) from 35 to 75% by weight of an alkyl acrylate having from 1 to 8 carbon atoms in the alkyl moiety thereof, (b) from 10 to 50% by weight of an alkyl methacrylate having from 1 to 4 carbon atoms in the alkyl moiety thereof, (c) up to 15% by weight of styrene and/or acrylonitrile, the sum of the (b) and (c) components ranging from 15 to 55% by weight, (d) up to 5% by weight of a vinyl monomer selected from the group consisting of an .alpha.,.beta.

Abstract: Foamed particles of a propylene resin are described which comprises, as a base resin, a random copolymer of propylene and 1-butene, said random copolymer having a 1-butene content of from 3 to 12% by weight.A foamed mold article is also described which is composed of a random copolymer of propylene and 1-butene, and having a density of from 0.015 to 0.09 g/cm.sup.3.A bumper core material for use in automobile bumpers is also discribed which is composed of a foamed mold article of a random copolymer of propylene and 1-butene, said random copolymer having a 1-butene content of from 3 to 12% by weight, said foamed mold article having a density of from 0.02 to 0.08 g/cm.sup.3, a compression stress at 50% compression as measured at 20.degree. C. of 2.5 to 10 kg/cm.sup.2, and an energy absorption efficiency as measured at 20.degree. C. of 60 to 90% the ratio (E.sub.80 /E.sub.20) of the amount of the energy absorption of said foamed mold article as measured at 80.degree. C. (E.sub.

Abstract: A process for producing a moldable non-woven fabric is disclosed, which comprises coating or impregnating a mat made of non-woven fabrics with an aqueous emulsion of a thermoplastic resin having a moldable temperature range of from 80.degree. to 180.degree. C. in such an amount that the resin solids content of the emulsion is 15 to 300 wt % based on the weight of the mat, removing the moisture from the mat by heating, and pressing the mat to adjust the apparent density of the mat to 0.15 to 0.5 g/cm.sup.3. This fabric is useful as an interior material for use in an automobile, for example.

Abstract: A manufacturing method for a laminated sheet comprises:coating a backing coating material on a base fabric (A) which is made of a material having a thermal deformation temperature of at least 150.degree. C., the backing coating material comprising(a) a resin aqueous emulsion and(b) 150-170 parts by weight of expandable styrene resin particles per 100 parts by weight of solids of the resin aqueous emulsion (a);stacking a base fabric (B) which is made of a material having a thermal deformation temperature of at least 150.degree. C.

Abstract: A method of molding pre-foamed synthetic resin particles is described, which comprises increasing the pressure in a mold cavity with a pressurized gas, charging the mold cavity with pre-foamed synthetic resin particles as they are compressed with a gas pressurized to a pressure higher than the pressure in the mold cavity and heating the charged pre-foamed synthetic resin particles with steam so that they are fused together or expanded and fused together to form a foamed molded article, wherein a pressure detector is provided in a conduit for conveying the pre-foamed synthetic resin particles into the mold cavity as they are carried by the pressurized gas or at an inlet portion of a charging port leading to the mold cavity, and the supply of pre-foamed synthetic resin particles into the mold cavity is stopped when the pressure detected by the detector exceeds the pressure in the mold cavity by a predetermined amount.

Abstract: A process for producing expanded particles of a styrene-acrylonitrile-butadiene copolymer is disclosed, comprising dispersing styrene-acrylonitride-butadiene copolymer particles in water in a closed vessel, feeding a volatile blowing agent to the aqueous dispersion in the closed vessel, heating the aqueous dispersion to a temperature higher than a glass transition point of the copolymer particles by at least 20.degree. C. to impregnate the volatile blowing agent into the copolymer particles, and opening one end of the closed vessel to release the aqueous dispersion containing the expandable copolymer particles into a low pressure zone having a pressure lower than the inner pressure of the closed vessel. The resulting expanded particles have a degree of expansion of from 10 to 50.

Abstract: A process for producing expandable styrene-based polymer beads is disclosed, which comprises adding a low temperature polymerization initiator that is decomposable to the half at a temperature of from 50.degree. to 80.degree. C. for a period of 10 hours to an aqueous medium having suspended therein blowing agent-containing expandable styrene-based polymer small particles whose particle sizes have been adjusted so as to have a particle size distribution falling within a mean particle size .+-.

Abstract: A method of producing a polypropylene resin molded product from foamed polypropylene particles is disclosed, which comprises introducing a pressurizing gas into foamed polypropylene particles having closed cells so that the particles have an internal gas pressure of from 0.3 to 2.5 Kg/cm.sup.2 G, charging the particles in a mold cavity while compressing the particles with a pressurizing inorganic gas until the initial apparent volume of the particles is reduced to 50 to 99%, removing the gas from the mold cavity while keeping the foamed particles in a compressed state, and introducing steam in the cavity to cause adhesion of the compressed foamed particles. The method produces a molded product having satisfactory appearance and excellent adhesion among particles in a shortened molding cycle.

Abstract: A process for producing propylene random copolymer resin foamed particles is disclosed. The process comprises dispersing propylene-ethylene random copolymer resin particles having an ethylene content of from 1 to 12% by weight in water in a closed vessel, feeding an inorganic gas into the closed vessel to raise the pressure within the closed vessel to at least 5 Kg/cm.sup.2 G, heating the dispersion to a temperature above the melting point of said copolymer resin particles but not higher than that by 25.degree. C. or more, opening a discharge port provided in the closed vessel below the water surface, and releasing the copolymer resin particles together with water as a dispersing medium into an atmosphere having a lower pressure than in the closed vessel. A foamed product produced by molding the foamed particles has firm bondage among the particles and excellent mechanical strength.

Abstract: A process for producing a cushioning laminate is described, comprising melting a laminated sheet comprising (a) a thermoplastic resin substrate sheet and (b) a thermoplastic resin adhesive layer having a heat distortion temperature at least 25.degree. C. lower than that of the thermoplastic resin which constitutes the substrate sheet (a); moving the laminated sheet below an upper mold in such a manner that the substrate sheet (a) faces the upper mold; vacuum molding the laminated sheet using the upper mold to produce a molded article having a desired irregular surface; and then bonding a plate-shaped member, such as a cardboard plate, a metallic or plastic plate, to the adhesive layer (b) of the laminated sheet while the above-molded article is brought into close contact with the upper mold, thereby producing the cushioning laminate having enclosed air pockets. This cushioning laminate is useful as a cushioning material for wrapping.