Patents Assigned to Mitsui Chemicals
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Publication number: 20110034648Abstract: Provided are a solid titanium catalyst component for ethylene polymerization which can polymerize ethylene at a high activity and which can provide an ethylene polymer having an excellent particle property, an ethylene polymerization catalyst and an ethylene polymerization method in which the catalyst is used. The solid titanium catalyst component (I) for ethylene polymerization according to the present invention is obtained by bringing a liquid magnesium compound (A) including a magnesium compound, an electron donor (a) having 1 to 5 carbon atoms and an electron donor (b) having 6 to 30 carbon atoms into contact with a liquid titanium compound (C) under the presence of an electron donor (B) and includes titanium, magnesium and a halogen. The ethylene polymerization catalyst of the present invention includes the component (I) and an organic metal compound catalyst component (II).Type: ApplicationFiled: April 3, 2009Publication date: February 10, 2011Applicant: Mitsui ChemicalsInventors: Kazuhisa Matsunaga, Hideki Yamamoto, Kunio Yamamoto, Tetsunori Shinozaki, Kiyoshi Takahashi
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Patent number: 6319986Abstract: A semiaromatic polyamide resin composition comprising: (A) a polyamide copolymer in which a main constituent component unit is a polyamide formed of a recurring unit of a dicarboxylic acid component unit and a diamine component unit, at least not less than 45 mol % of said dicarboxylic acid component unit being a terephthalic acid component unit, and said diamine component unit comprising a straight-chain alkylenediamine component unit and/or an alkylenediamine component unit having a side-chain alkyl group; (B) an aliphatic polyamide containing, a unit derived from a lactam having 12 carbon atoms, a unit derived from an aminocarboxylic acid having 12 carbon atoms or a unit derived from a dodecanoic diacid and a diamine; and (C) a graft-modified product of a graft-modified ethylene/&agr;-olefin copolymer, a graft-modified product of an aromatic vinyl compound/conjugated diene copolymer, or a graft-modified product of a hydrogenated product of the aromatic vinyl compound/conjugated diene copolymer.Type: GrantFiled: July 1, 1999Date of Patent: November 20, 2001Assignee: Mitsui ChemicalsInventors: Yoshikatsu Amimoto, Yoshimasa Ogo, Masayuki Sakka
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Patent number: 6235818Abstract: A hot melt adhesive composition exhibiting excellent adhesive strength and which is useful as an adhesive for styrene resins contains (B) tackifier and (C) ethylene/C3-C20 &agr;-olefin/aromatic vinyl compound random copolymer and, in some embodiments also (A) base polymer, such as polyolefin, polar group-containing polymer and aromatic vinyl compound/conjugated diene copolymer. A low molecular weight polyolefin may also be included in all embodiments. The randon copolymer (C) may be prepared by polymerizing the &agr;-olefin and aromatic vinyl compound in the presence of a metallocene containing catalyst. In addition to excellent adhesive strength the hot melt adhesives have improved workability.Type: GrantFiled: July 29, 1999Date of Patent: May 22, 2001Assignee: Mitsui ChemicalsInventors: Kenichi Morizono, Keiji Okada, Suguru Tokita
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Patent number: 6231800Abstract: Disclosed is a method of injection-molding for epoxy resin moldings wherein an epoxy resin composition is used as starting material, a molding cycle is shortened, a continuous molding operation is possible and a waste portion after curing can be minimized as well as an injection-moldable epoxy resin composition excellent in thermal stability possessing latent-type curing characteristics capable of rapidly promoting curing reaction in a metal mold without being cured in an injection molding machine. The aforesaid method is carried out by charging an epoxy resin composition possessing the latent-type curing characteristics into a mini-sprue metal mold which is composed of a manifold part, a mini-sprue part and an ejector-plate part and wherein a metal mold temperature at the manifold part is so maintained that the epoxy resin composition is molten but curing of the composition is not promoted, and injection-molding the composition.Type: GrantFiled: July 6, 1999Date of Patent: May 15, 2001Assignee: Mitsui ChemicalsInventors: Eiki Togashi, Tsukasa Sakuraba
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Patent number: 6225410Abstract: Ethylene/C6-8 alpha-olefin copolymers are characterized by melt tension, flow activation energy and haze. The copolymers have excellent moldability and produce films of excellent transparency and mechanical strength.Type: GrantFiled: December 23, 1998Date of Patent: May 1, 2001Assignee: Mitsui ChemicalsInventors: Kenji Sugimura, Ken Yoshitsugu, Mamoru Takahashi, Takashi Nakagawa
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Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer
Patent number: 6214939Abstract: The present invention provides olefin polymerization catalysts and processes for preparing a polypropylene and a propylene block copolymer using the olefin polymerization catalysts. The olefin polymerization catalyst (1) of the invention is formed from: (I-1) a contact product obtained by contacting: (A) a solid titanium catalyst component, (B) an organometallic compound catalyst component, and (C) a specific organosilicon compound; (II-1) (D) a specific polyether compound; and optionally, (III) an organometallic compound catalyst component. The olefin polymerization catalyst (2) of the invention is formed from: (I-2) a contact product obtained by contacting: (A) a solid titanium catalyst component, (B) an organometallic compound catalyst component, and (D) a specific polyether compound; (II-2) (C) a specific organosilicon compound; and optionally, (III) an organometallic compound catalyst component.Type: GrantFiled: June 3, 1998Date of Patent: April 10, 2001Assignee: Mitsui ChemicalsInventors: Tetsunori Shinozaki, Mamoru Kioka -
Patent number: 6121393Abstract: A process for polymerizing an alpha-olefin using either a catalyst formed by contacting a highly active solid titanium catalyst component, an organo-metallic compound of a metal of Group 1 to 3 of the periodic table, an organic halogen compound or a transition metal compound, and an organosilicon compound or a sterically hindered amine in an inert medium in the absence of an alpha olefin, or a catalyst prepared by preliminarily polymerizing an alpha olefin in the presence of a catalyst comprising the above four catalyst components, provided that the last one is an optional component. This process achieves the industrially advantage that the catalysts are highly active, and give a polymer having excellent stereoregularity.Type: GrantFiled: April 7, 1995Date of Patent: September 19, 2000Assignee: Mitsui ChemicalsInventors: Mamoru Kioka, Norio Kashiwa, Tomohiko Kimura, Mitsuo Tomura, Toshiki Sotoyama
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Patent number: 6117942Abstract: A semiaromatic polyamide resin composition of the present invention contains a polyamide (A) in which a dicarboxylic acid component unit comprises a terephthalic acid component unit and a diamine component unit comprises a straight-chain alkylenediamine component unit and an alkylenediamine component unit having a side-chain alkyl group; and a modified ethylene/.alpha.-olefin copolymer (B) obtained by graft-modifying an ethylene/.alpha.-olefin copolymer having particular properties with an unsaturated carboxylic acid or a derivative thereof. A molded article obtained by using this composition exhibits excellent anti-creeping property under high-temperature and high-humidity conditions, and causes the metal mold to be little fouled during the molding operation.Type: GrantFiled: March 12, 1998Date of Patent: September 12, 2000Assignee: Mitsui ChemicalsInventors: Yoshimasa Ogo, Yoshikatsu Amimoto
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Patent number: 6111038Abstract: The present invention intends to provide a process for preparation of a solid titanium catalyst component for an olefin polymerization excellent in polymerization activity per unit catalyst, and a process for preparation of a polyolefin using a catalyst containing the catalyst component. The process according to the present invention is characterized by comprising the steps of contacting (A) a magnesium compound with (B) a solution titanium compound to obtain a solid titanium catalyst component composed of titanium, magnesium and a halogen as the essential components, wherein a titanium compound mixture liquid composed of 88 to 99% by weight of a titanium compound and 1 to 12% by weight of hydrocarbon containing halogen-containing hydrocarbon is used as (B) the solution titanium compound.Type: GrantFiled: April 9, 1998Date of Patent: August 29, 2000Assignee: Mitsui ChemicalsInventors: Mamoru Kioka, Shinichi Kojoh, Tsuneo Yashiki
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Patent number: 6106999Abstract: A visible light curable resin composition containing a photocurable resin, a photoreaction initiator and a photosensitizer having the formula (1). The composition has a very high sensitivity to a general-purpose visible light laser, so that a high-speed scanning exposure is possible by the laser, and an extremely fine high resolution can be obtained. In addition, the composition can be used for coating or printing under safelight irradiating conditions and under bright circumstantial conditions without any thickening of the composition, and hence the composition can exert excellent noticeable effects in points of safe operativity, operational efficiency and the stability of products. Formula (1) is as follows: ##STR1## wherein rings X.sub.1 and X.sub.2 are each an optionally substituted pyrrole ring; Y is H, CN, optionally substituted alkyl, aralkyl, aryl, heteroaryl or alkenyl group; and Z.sub.1 and Z.sub.Type: GrantFiled: August 10, 1998Date of Patent: August 22, 2000Assignees: Mitsui Chemicals, Kansai Paint Co., Ltd.Inventors: Akira Ogiso, Tsutami Misawa, Taizo Nishimoto, Hisashi Tsukahara, Keisuke Takuma, Kenichi Sugimoto, Takeshi Tsuda, Genji Imai, Hideo Kogure
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Patent number: 6063886Abstract: Disclosed is a cycloolefin copolymer which is obtained from (A) a straight-chain or branched .alpha.-olefin of 2 to 20 carbon atoms, (B) a specific cycloolefin and (C) an aromatic vinyl compound and has an intrinsic viscosity [.eta.] of 0.1 to 10 dl/g, wherein the content of constituent units derived from the cycloolefin (B) and the content of constituent units derived from the aromatic vinyl compound (C) satisfy a specific relation. The cycloolefin copolymer has high heat resistance, low moisture absorption and small birefringence.Type: GrantFiled: April 14, 1998Date of Patent: May 16, 2000Assignees: Mitsui Chemicals, Hoechst AktiengesellschaftInventors: Masayoshi Yamaguchi, Kazuyuki Takimoto
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Patent number: 6060416Abstract: A high-performance prepolymerized solid catalyst is prepared by polymerizing an olefin onto an olefin polymerization catalyst in a heterogeneous system under irradiation with an elastic wave, wherein the olefin is prepolymerized in an amount of not less than 0.1 g based on 1 mmol of a transition metal contained in the olefin polymerization catalyst. The elastic wave is preferably an ultrasonic wave. In a process for heterogeneous polymerization of an olefin, an olefin is subjected to slurry polymerization or gas phase polymerization in the presence of the prepolymerized solid catalyst. In a process for heterogeneous polymerization of an olefin, an olefin may be polymerized onto the olefin polymerization catalyst in a heterogeneous system under irradiation with an elastic wave to prepare polyolefin. Therefore, the heterogeneous polymerization of an olefin can be stably conducted and polyolefins of uniform property and high quality can be obtained.Type: GrantFiled: November 20, 1998Date of Patent: May 9, 2000Assignee: Mitsui ChemicalsInventors: Atsuo Kobata, Tetsuhiro Matsumoto