Patents Assigned to Mitsui Chemicals, Inc.
  • Patent number: 6159827
    Abstract: An object of the invention is to provide a preparation process of a semiconductor wafer, in which breakage of the wafer on grinding the back surface of the wafer and on peeling the adhesive tape is prevented, and the operation time can be reduced. The preparation process of a semiconductor wafer comprises the steps of: adhering an adhesive tape on a front surface of a semiconductor wafer; grinding a back surface of the semiconductor wafer by a grinding machine; peeling the adhesive tape; and cleaning the front surface of the semiconductor wafer, wherein an adhesive tape having heat shrinkability is used as the adhesive tape, and after grinding the back surface of the semiconductor wafer, warm water at a temperature of from 50 to 99.degree. C. is poured to peel the adhesive tape in a wafer cleaning machine, and the front surface of the semiconductor wafer is cleaned in the wafer cleaning machine.
    Type: Grant
    Filed: April 5, 1999
    Date of Patent: December 12, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Makoto Kataoka, Yasuhisa Fujii, Kentaro Hirai, Hideki Fukumoto, Masatoshi Kumagai
  • Patent number: 6156864
    Abstract: Propylene oxide is added to an active hydrogen compound in the presence of an alkali metal hydroxide catalyst in an amount of from 0.05 to 0.5 mole per mole of the active hydrogen compound at a reaction temperature of from 60 to 98.degree. C. at a reaction pressure less than or equal to 4 kg/cm.sup.2 to prepare a polyoxyalkylene polyol which has a hydroxyl value of from 10 to 35 mg KOH/g, a monool content less than or equal to 15 mol %, a Head-to-Tail bond selectivity greater than or equal to 96 percent, and low viscosity. A polymer polyol is prepared by polymerizing an ethylenically unsaturated monomer in the polyoxyalkylene polyol. A flexible polyurethane foam is prepared by reacting the polyoxyalkylene polyol or the polymer polyol with an organic polyisocyanate compound in the presence of a foaming agent, a catalyst, a surfactant, a crosslinking agent and other additives.
    Type: Grant
    Filed: October 30, 1997
    Date of Patent: December 5, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Kazuhiko Ohkubo, Tomoki Tsutsui, Yoshitsugu Sakaki, Tamotsu Kunihiro, Ariko Nishikawa, Tsukuru Izukawa
  • Patent number: 6156841
    Abstract: The present invention relates to 4-methyl-1-pentene polymer compositions. Specifically, the present invention relates to adhesive compositions comprising the 4-methyl-1-pentene polymers used in bonding a 4-methyl-1-pentene polymer layer and a polar-group-containing resin layer, and laminates obtained by using such compositions. The 4-methyl-1-pentene polymer compositions as these adhesive compositions comprise a 4-methyl-1-pentene polymer (A); and a modified polyolefin resin (B) comprising a mixture of an unsaturated carboxylic acid-modified .alpha.-olefin polymer (B-1) whose .alpha.-olefin is selected from a group of propylene, butene-1 and 4-methyl-1-pentene and an unsaturated carboxylic acid-modified ethylene/.alpha.-olefin copolymer (B-2). In these compositions, an unsaturated carboxylic acid-modified 4-methyl-1-pentene polymer (A') showing a particular modification rate and a particular melt flow rate may be used in place of (A) and (B-1).
    Type: Grant
    Filed: August 7, 1998
    Date of Patent: December 5, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Katsumi Noritomi, Toshimasa Takata
  • Patent number: 6156844
    Abstract: A propylene polymer composition is prepared by mixing a first propylene polymer prepared using an olefin polymerization catalyst containing a specific metallocene catalyst component of formula (I), e.g., rac-dimethylsilylene-bis{1-(2-ethyl-4-phenylindenyl)} zirconium dichloride, and an organoaluminum-oxy cocatalyst, with a second propylene polymer component. The compositions are excellent in heat resistance, mechanical strength, tensile elongation at break, and other properties and can be used to produce various structural materials, sheets and films.
    Type: Grant
    Filed: September 8, 1994
    Date of Patent: December 5, 2000
    Assignee: Mitsui Chemicals Inc
    Inventors: Mikio Hashimoto, Takasi Ueda, Masaaki Kawasaki, Satoru Moriya, Akira Mizuno, Daisuke Fukuoka, Junichi Imuta, Keiji Hirose, Junji Saito, Yoshihisa Kiso
  • Patent number: 6153807
    Abstract: A copolymer of ethylene and an alpha-olefin having an ethylene content of from 30 to 90 mole %, a number average molecular weight of from 300 to 30,000 and a molecular weight distribution defined by a Q value (the ratio of the weight average molecular weight to the number average molecular weight of not more than 3 and a Z value (the ratio of the maximum value of the molecular weight to the minimum value of the molecular weight when the molecular weight is measured by gel permeation chromatography) of from 15 to 200. The said copolymer can be produced by a process comprising copolymerizing ethylene with an alpha-olefin in the liquid phase in the presence of a polymerization catalyst composed of a combination of a soluble vanadium compound and an organoaluminum compound in the co-presence of hydrogen, characterized in that(a) the copolymerization is carried out in a continuous manner,(b) the concentration of the vanadium compound in the polymerization system is maintained at 0.
    Type: Grant
    Filed: July 14, 1993
    Date of Patent: November 28, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hidekuni Oda, Tatuo Kinoshita, Akiyoshi Shimizu
  • Patent number: 6153794
    Abstract: An organic compound which is basic and soluble in an organic solvent, does not have a problem in preparation or handling and exhibits catalytic activity as a basic compound, i.e., a phosphine sulfide represented by formula (1), and a manufacturing process therefor, i.e., manufacturing a phosphine sulfide represented by formula (1), by reacting one molecule of thiophosphoryl chloride with three molecules of a phosphorane represented by formula (2). The phosphine sulfide can be used in a process for effectively manufacturing a poly(alkylene oxide) by polymerizing an alkylene oxide in the presence of the phosphine sulfide or of the phosphine sulfide and an active hydrogen compound selected from water and organic compounds having a partial structure of --OH or --NH--; and 2) a process for manufacturing a 1,2-dioxyethane derivative from an epoxy compound, i.
    Type: Grant
    Filed: July 7, 1999
    Date of Patent: November 28, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Katsuhiko Funaki, Isao Hara, Takaomi Hayashi, Shinji Kiyono, Atsushi Shibahara, Kazumi Mizutani, Tadahito Nobori, Usaji Takaki
  • Patent number: 6150438
    Abstract: The invention provides a composite resin composition comprising aliphatic polyester resin (component A) having aliphatic hydroxycarboxylic acid units, one or more biomass material (component B) selected from the group consisting of cellulose, lignocellulose and starch and unsaturated carboxylic acid or a derivative thereof (component C), wherein the composite resin composition comprises a component obtained by covalently bonding a portion or the whole of component A and component B through component C. On processing into various formed items, the composite resin composition of the invention exhibits excellent tensile strength and other physical properties and processability and simultaneously has good biodegradability, and enable biomass materials of low added value to apply to high added value uses in a large amount.
    Type: Grant
    Filed: March 30, 2000
    Date of Patent: November 21, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Nobuo Shiraishi, Masanobu Ajioka
  • Patent number: 6149992
    Abstract: The present invention makes it possible to provide a pellicle having, on the inside of the pellicle frame, a tacky layer which exhibits excellent performance for holding foreign matters such as dust or dirt suspended in space defined by the pellicle and the mask, and resistance against light of short wavelengths such as excimer beam. The pellicle comprises a pellicle frame, a pellicle film stretched on one side of said pellicle frame, and a tacky layer formed on the inside of said pellicle frame and containing a greasy fluorine-contained resin.
    Type: Grant
    Filed: October 19, 1998
    Date of Patent: November 21, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventor: Norio Nakayama
  • Patent number: 6146739
    Abstract: A glass run channel comprising a glass run channel body composed of a bottom wall and side walls extending from two opposite edges of the bottom wall, the glass run channel body having a substantially U-shaped section and provided with a groove, and tonguelike draining parts protruding from vicinities of distal edges of the side walls toward the bottom wall of the glass run channel body so as to become proximate to each other. Each of the tonguelike draining parts has a window glass contact part composed of a surface to be brought into contact with a window glass, which comprises a layer of a thermoplastic elastomer and a layer of an ultrahigh molecular weight polyolefin composition. The layer of ultrahigh molecular weight polyolefin composition is arranged so as to contact a window glass. The ultrahigh molecular weight polyolefin composition comprises at least a polyolefin (composition) having a specified intrinsic viscosity and an olefinic thermoplastic elastomer.
    Type: Grant
    Filed: February 20, 1998
    Date of Patent: November 14, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Yuichi Itoh, Masato Karaiwa, Kyoko Kobayashi, Akira Uchiyama
  • Patent number: 6147439
    Abstract: A piezoelectric substrate supporting structure for piezoelectric transformer is provided which, in the supporting and fixing of a piezoelectric substrate on a base plate or in an outer trim case, does not inhibit the vibration of the piezoelectric substrate, exhibits high impact resistance and enables stable supporting, is free from performance deterioration and enables simultaneously and easily performing an electrode takeoff from the piezoelectric substrate. Further, a piezoelectric transformer including the above piezoelectric substrate supporting structure is provided.
    Type: Grant
    Filed: June 23, 1998
    Date of Patent: November 14, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Shusaku Takagi, Masamitsu Tanaka, Sigeru Bando, Tadao Sunahara, Katsuo Kono, Mitsunobu Yoshida, Yasushi Iwata
  • Patent number: 6143433
    Abstract: In a first aspect, an organic electroluminescent device having an electroluminescent layer and/or a charge injecting/transporting layer formed out of a thin film of organic polymers of network structure which are excellent in heat resistance and durability, e.g., polyoxadiazoles is obtained by conducting a vapor deposition polymerization of a bifunctional monomer, a polyfunctional monomer of 3 or higher in functionality or a mixture of the polyfunctional monomer and bifunctional monomer and heating the resultant polymer in vacuum or an inert gas.
    Type: Grant
    Filed: September 11, 1995
    Date of Patent: November 7, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hideyuki Murata, Hideki Hirano
  • Patent number: 6143827
    Abstract: Disclosed is an olefin thermoplastic elastomer composition obtained by dynamically heat treating, in the presence of an organic peroxide, a blend comprising 10 to 60 parts by weight of a crystalline polyolefin resin (A) and 40 to 90 parts by weight of an unsaturated olefin copolymer (B) of at least one .alpha.-olefin of 2 to 20 carbon atoms, a conjugated diene monomer represented by the following formula (I), and optionally, an aromatic vinyl compound, the total amount of said components (A) and (B) being 100 parts by weight; ##STR1## wherein R.sup.1 and R.sup.2 are each independently a hydrogen atom, an alkyl group of 1 to 8 carbon atoms or an aryl group, and at least one of R.sup.1 and R.sup.2 is a hydrogen atom. The composition has excellent moldability and can provide a molded product having excellent elastomeric properties, tensile strength properties and appearance.
    Type: Grant
    Filed: July 20, 1998
    Date of Patent: November 7, 2000
    Assignee: Mitsui Chemicals Inc
    Inventors: Kenichi Morizono, Keiji Okada, Masayoshi Yamaguchi
  • Patent number: 6143925
    Abstract: A process for producing aromatic carboxylic acids efficiently by operating a distillation column for separating the vaporized reaction solvent and other useful ingredients from an oxidation reactor while permitting efficient energy recovery without causing any obstruction to turbine and without causing any clogging of the distillation column, said process comprising oxidizing an alkyl aromatic compound in a liquid reaction solvent comprising an aliphatic carboxylic acid with a molecular oxygen-containing gas in the presence of an oxidation catalyst in the said oxidation reactor to form an aromatic carboxylic acid, guiding the oxidation reactor exhaust gas into the distillation column to subject it to a distillation, passing the distilltion overhead gas to a condenser to form a condensate, which is returned to the distillation column, and to generate a steam on the shell side, which is guided to a steam turbine for energy recovery, and burning the condenser exit gas in order to drive a gas turbine for energy r
    Type: Grant
    Filed: June 4, 1999
    Date of Patent: November 7, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tadashi Tomitaka, Michio Umeda, Hideaki Iwata, Fujimasa Nakao
  • Patent number: 6140077
    Abstract: A method for producing phytase using a Candida boidinii transformant, by which phytase is secreted to liquid medium without substantially increasing the number of the transformant cells is disclosed. In this method, cells of a Candida boidinii transformant which is transformed with a recombinant vector comprising a promoter inducible with methanol and a gene located downstream of said promoter and operably linked to said promoter, which gene encodes a polypeptide having phytase activity, are cultured in a liquid culture medium containing phosphoric acid or a phosphate compound in an amount effective of restricting proliferation of said cells of Candida boidinii transformant such that the amount of said cells of Candida boidinii transformant is not substantially increased, while adding methanol to the culture medium, so as to make said cells secrete said phytase.
    Type: Grant
    Filed: January 28, 1998
    Date of Patent: October 31, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Takeshi Nakamura, Tadashi Suzuki, Junko Tokuda, Nobuo Kato, Yasuyoshi Sakai, Daisuke Mochizuki, Hitoshi Takahashi
  • Patent number: 6139948
    Abstract: A membrane formed by coating an aqueous coating liquid comprising an antistatic agent or anticlouding agent on one or both surfaces of an aliphatic polyester film comprising a specific amount of a lubricant or an antiblocking agent, can remarkably improve adhesion of the membrane (antistatic layer or anticlouding layer) to the aliphatic polyester film, and thus the effect of the membrane (antistatic effect or anticlouding effect) can be continuously exhibited for a long period.
    Type: Grant
    Filed: November 24, 1998
    Date of Patent: October 31, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Naoki Kobayashi, Shuhei Ikado, Akira Kawano, Takayuki Kuroki, Hirotaka Wanibe
  • Patent number: 6140458
    Abstract: The invention provides a process for producing high-molecular aliphatic polyesters capable of being substitutes for general-purpose resins that are required to have high toughness, in a simplified manner and at a high volume efficiency. Specifically, in the process, used as the starting material is an easily-available, low-molecular aliphatic polyester prepolymer to be prepared through polycondensation of inexpensive materials of an aliphatic hydroxycarboxylic acid such as lactic acid, glycolic acid or the like, an aliphatic polyalcohol such as butanediol or the like, and an aliphatic polycarboxylic acid such as succinic acid or the like, and the starting prepolymer is crystallized and thereafter polycondensed in a solid phase in the presence of a catalyst to give the intended, tough and high-molecular aliphatic polyester.
    Type: Grant
    Filed: April 27, 1999
    Date of Patent: October 31, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Yuji Terado, Hiroshi Suizu, Masatoshi Takagi, Masanobu Ajioka, Shoji Hiraoka, Masayuki Sakai, Hiroyuki Suzuki, Ryo Shinagawa, Shinji Ogawa, Yasushi Kotaki
  • Patent number: 6140441
    Abstract: A process for preparing an ethylene/.alpha.-olefin/norbornene nonconjugated polyene random copolymer, comprising preparing an ethylene random copolymer simultaneously meeting the following requirements (1) to (5):(1) the molar ratio of ethylene (a) to an .alpha.-olefin (b) having 3 to 20 carbon atoms ranges from 40:60 to 95:5;(2) a given amount of non conjugated polyene (c) has a norbornene skeleton;(3) the available network chain density .nu. is not less than 1.5.times.10.sup.20 /cm.sup.3 after press cross-linking of the copolymer using a dicumyl peroxyde;(4) the ratio of the rate .gamma.1 of shear showing a shearing stress of 0.4.times.10.sup.6 dyn/cm.sup.2 as determined from the melt flow curve at 100.degree. C. and the rate .gamma.2 of shear showing a shearing stress of 2.4.times.10.sup.6 dyn/cm.sup.2, that is .gamma.2/.gamma.1 and the available network chain density .nu. has a relationship represented by the following general formula: 0.04.times.10.sup.-19 .ltoreq.Log(.gamma.2/.gamma.1)/.nu..ltoreq.0.20.
    Type: Grant
    Filed: March 30, 1998
    Date of Patent: October 31, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Takashi Hakuta, Mikio Hosoya, Tetsuo Tojo, Masaaki Kawasaki
  • Patent number: 6136879
    Abstract: A soft polyurethane foam which has a rebound resilience percentage of not higher than 30% and whose temperature dependency of a compression force deflection that is represented by a difference between a 25%-compression force deflection value at -20.degree. C. and a 25%-compression force deflection value at +20.degree. C. is not larger than 0.030 kg/cm.sup.2.
    Type: Grant
    Filed: October 23, 1998
    Date of Patent: October 24, 2000
    Assignees: Tokai Rubber Industries, Ltd., Mitsui Chemicals, Inc.
    Inventors: Kiyomi Nishida, Shuichi Takahashi, Kunio Sasaoka, Masashi Obata
  • Patent number: 6136743
    Abstract: The invention provides catalysts which have a high polymerization activity, enable the obtaining of olefin polymers of wide molecular weight distribution, and which comprise (a)(a-1) a metallocene compound or (a-2) a titanium catalyst component containing magnesium, titanium, and halogen, (b) a compound of a transition metal from Groups 8 to 10 of the periodic table and is of the general formula shown below, and a cocatalyst component. ##STR1## The invention also provides olefin polymer compositions excellent in rigidity and impact resistance which can be produced using a catalyst comprising the transition metal compound (b) and which comprises a non-crystalline olefin polymer having a specific intrinsic viscosity, glass transition temperature and density, and another known olefin polymer.
    Type: Grant
    Filed: October 7, 1998
    Date of Patent: October 24, 2000
    Assignee: Mitsui Chemicals, INC.
    Inventors: Kenji Sugimura, Kiyotaka Yorozu, Yasuhiko Suzuki, Tetsuo Hayashi, Shin-ya Matsunaga
  • Patent number: 6136905
    Abstract: A lactic acid polymer composition comprising formulating 100 parts by weight of a mixture consisting of 80-95% by weight of an L-lactic acid polymer having an L-lactic acid proportion of 75% or more and 5-20% by weight of a plasticizer selected from the group consisting of a polyhydric alcohol ester and a hydroxypolycarboxylic acid ester, 0.1-5 parts by weight of an anti-blocking agent having a SiO.sub.2 content of 90% or more and an average particle size of 7-50 nm, and 0.1-2 parts by weight of a slip agent; a molded product and film obtained from the composition; and a preparation process of the same are disclosed. The molded product and film are excellent in processability, transparency, flexibility, anti-blocking property and slip, and can be degraded into harmless water and carbon dioxide under natural environment, when abandoned.
    Type: Grant
    Filed: December 22, 1997
    Date of Patent: October 24, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Kazuhiko Suzuki, Takayuki Watanabe, Yasuhiro Kitahara, Masanobu Ajioka, Shuhei Ikado