Abstract: A measuring section of a stereolithography device measures a temperature of a photocurable resin liquid by a temperature sensor. A setting section sets an integrated light amount on the basis of temperature information obtained from a measured temperature and curing information stored in a storage section. An illuminating section controls a projector such that light, by which the set integrated light amount is obtained, is illuminated onto the photocurable resin liquid. Due thereto, light, which is such that there becomes an integrated light amount corresponding to the temperature of the photocurable resin liquid, is illuminated onto the photocurable resin liquid, and therefore, a molded object can be molded with high accuracy.
Abstract: The present invention provides a crosslinked molded article having a lower compression set; and a method for producing a crosslinked molded article by injection molding, the method enabling shortening of one cycle in injection molding, the method being suitable for obtaining a crosslinked molded article having a lower compression set. The present invention relates to a method for producing a crosslinked molded article, comprising melt-kneading a polymer composition containing a polymer having a terminal double bond, a hydrosilyl group-containing compound (Y) having at least two hydrosilyl groups per molecule, a platinum-based catalyst (Z) for hydrosilicon crosslinking, and a reaction inhibitor (D), subjecting the polymer composition to injection molding in a mold, performing primary crosslinking in the mold, removing the primary-crosslinked molded article from the mold, and then performing secondary crosslinking in a heat medium.
Abstract: A 4-methyl-1-pentene polymer (X) wherein a content of a constitutional unit derived from 4-methyl-1-pentene is 90 to 100% by mol; a content of a constitutional unit derived from at least one olefin selected from ethylene and an ?-olefin, other than 4-methyl-1-pentene, having 3 to 20 carbon atoms is 0 to 10% by mol; and the 4-methyl-1-pentene polymer satisfies certain requirements (a) to (f): (a) a meso diad fraction (m) measured by 13C-NMR falling within a certain range; (b) a ratio of weight-average molecular weight Mw within a certain range; (c) a melt flow rate (MFR) within a certain range; (d) a cumulative weight fraction within a certain range; (e) a proportion of a polymer having a molecular weight of a certain range; and (f) a heat of fusion and a melting point of the 4-methyl-1-pentene polymer within certain ranges.
Abstract: Disclosed is a polyamide resin composition including 50% to 99% by mass of a polyamide (P) and 1% to 50% by mass of an acid-modified polyolefin (Q) satisfying the following requirements (1) to (3). (1) A melt flow rate (MFR) as measured at 230° C. under a load of 2.16 kg is 50 to 200 (g/10 min). (2) An acid modification amount is 0.1% to 2.0% by mass. (3) The acid-modified polyolefin (Q) includes a modified product (q1) of an elastomer including 10% to 95% by mole of an ethylene-derived skeleton unit, 0% to 80% by mole of a propylene-derived skeleton unit, and 3% to 40% by mole of a skeleton unit derived from an ?-olefin having 4 to 8 carbon atoms (with a total amount of the ethylene-derived skeleton unit, the propylene-derived skeleton unit, and the skeleton unit derived from an ?-olefin being 100% by mole), the elastomer being modified by maleic acid or an anhydride thereof.
Abstract: The present invention relates to a composition, a laminate, a packaging material, a battery case packaging material, and a battery, and the composition includes: a modified olefin polymer (A) that is a modified olefin polymer, the modified olefin polymer being a polymer (a) of a C2 to C20 ?-olefin modified by a monomer (b) having a functional group reactive with an epoxy group or an oxazoline group; a crosslinking agent (B) including at least one of an epoxy compound and an oxazoline compound; and a catalyst (C) having a pKa of 11 or more, the modified olefin polymer (A) satisfying the following requirements (i) and (ii): Requirement (i): the polymer (a) contains a structural unit derived from a C4 to C20 ?-olefin, and Requirement (ii): a heat of fusion of the polymer (A), as measured according to JIS K7122, is 0 to 50 J/g.
Abstract: The polymerizable composition for an optical material includes an allyl carbonate compound (A) including two or more allyloxycarbonyl groups which is represented by General Formula (1); a (meth)acrylate compound (B) including two or more (meth)acryl groups which is represented by General Formula (2); at least one kind of compound (C), selected from compounds represented by General Formulas (3) to (6) and specified dyes; and a polymerization initiator (D) including at least a radical polymerization initiator (D1) and a radical polymerization initiator (D2).
Abstract: Provided is a curable composition that has a sufficient pot life and does not cause a significant delay in curing time even after long-term storage at room temperature or higher. A separately packed curable composition includes: (A) a first pack containing: (a1) a polymerizable monomer having no acidic group, (b) a polymerizable monomer having an acidic group, and (c) a transition metal compound; and (B) a second pack containing: (a2) a polymerizable monomer having no acidic group, (d) an aromatic amine compound, and (e) at least one compound selected from sulfinic acid and a salt thereof.
Abstract: Provided are monomers useful for dental materials that include a compound in which a core and a specific terminal group are bonded to each other directly or via a linking group, wherein the core is a C1-200 polyvalent organic group having a valence of not less than 3 containing an oxygen atom or a nitrogen atom in which an atom bonded to the terminal group or the linking group is the oxygen atom or the nitrogen atom; the terminal group is a specific (meth)acryloyl group-containing group, a (meth)acryloyl group, a C1-20 hydrocarbon group or a hydrogen atom, and the terminal group needs to meet specific requirements; and the linking group is a specific divalent group, and when the compound contains a plurality of linking groups, the linking groups may be the same as or different from each other. Compositions, dental materials and kits are also provided.
Abstract: A metal/resin composite structure (106) of the invention is formed by bonding a metal member (103) and a resin member (105) to each other. A concavo-convex shape satisfying the following characteristics (i) and (ii) is formed on a bonding surface (104) of the metal member (103) to be bonded to the resin member (105). (i) A mean width of the profile elements (RSm) is equal to or greater than 150 ?m and equal to or smaller than 1500 ?m and a maximum height roughness (Rz) is equal to or greater than 170 ?m and equal to or smaller than 800 ?m (ii) A mean width of the profile elements (RSm) is equal to or greater than 100 nm and equal to or smaller than 10000 nm and a maximum height roughness (Rz) is equal to or greater than 100 nm and equal to or smaller than 10000 nm.
Abstract: A tackifier (B) according to the present invention comprises a copolymer (C) that comprises a structural unit derived from ?-methylstyrene or isopropenyltoluene and a structural unit derived from styrene, and the copolymer (C) satisfies the following (i) to (iii): (i) a content of the structural unit derived from ?-methylstyrene or isopropenyltoluene is in the range of 30 to 70 mol %, (ii) a softening temperature (Tm) measured by the ring-and-ball method according to JIS K 2207 is in the range of 110° C. to 170° C., and (iii) a content of a fraction having molecular weight of not more than 350, as determine by gel permeation chromatography (GPC) and calculated from polystyrene standard, is less than 1.5 mass %.
Type:
Application
Filed:
April 10, 2019
Publication date:
May 27, 2021
Applicant:
MITSUI CHEMICALS, INC.
Inventors:
Hirotaka KANAYA, Yosuke TAKAHASHI, Koji MATSUNAGA, Kuniaki KAWABE
Abstract: An object of the present invention is to provide a highly heat resistant and highly rigid propylene-based polymer having unprecedentedly high stereoregularity. The propylene-based polymer of the present invention satisfies requirements (1) to (4) and preferably requirement (5): (1) an average meso chain length is 800 to 100,000; (2) a MFR is 0.5 to 1,000 g/10 minutes; (3) a ratio of Mw to Mn, Mw/Mn, as measured by GPC is 4.2 to 20; (4) when the ratio of a component which elutes at a temperature of 122° C. or more as measured by temperature rising elution fractionation (TREF) is A % by weight and the melt flow rate of the requirement (2) is B g/10 minutes, 100?A?20*EXP(?0.01*B); (5) an amount of a component soluble in n-decane at 23° C. is 0.01 to 2% by weight.
Type:
Application
Filed:
June 29, 2018
Publication date:
May 20, 2021
Applicants:
MITSUI CHEMICALS, INC., PRIME POLYMER CO., LTD.
Abstract: A 4-methyl-1-pentene polymer (X) wherein a content of a constitutional unit derived from 4-methyl-1-pentene is 90 to 100% by mol; a content of a constitutional unit derived from at least one olefin selected from ethylene and an ?-olefin, other than 4-methyl-1-pentene, having 3 to 20 carbon atoms is 0 to 10% by mol; and the 4-methyl-1-pentene polymer satisfies certain requirements (a) to (f): (a) a meso diad fraction (m) measured by 13C-NMR falling within a certain range; (b) a ratio of weight-average molecular weight Mw within a certain range; (c) a melt flow rate (MFR) within a certain range; (d) a cumulative weight fraction within a certain range; (e) a proportion of a polymer having a molecular weight of a certain range; and (f) a heat of fusion and a melting point of the 4-methyl-1-pentene polymer within certain ranges.
Abstract: A control unit controls a position of a carrier and an irradiation unit to form a modeled object obtained by curing a photocurable composition. Here, the control unit irradiates the photocurable composition) with light from the irradiation unit to form the modeled object and a support portion which connects the carrier) and the modeled object. In addition, the control unit controls a modeling condition to make a modeling condition when modeling a joint portion of the support portion with the carrier be a condition in which the photocurable composition is easily cured rather than a modeling condition when modeling a first region, in which an area of a cross section parallel to the surface of the light transmission portion is the largest, in the modeled object.
Abstract: A control unit controls a position of a carrier and an irradiation unit to form a modeled object obtained by curing a photocurable composition. In addition, the control unit controls the position of the carrier and the irradiation unit to form at least a part of a flow channel connected to an outside of a container by curing the photocurable composition in a region irradiated with light, and controls the position of the carrier and the irradiation unit to at least temporarily provide at least one of an enlarged diameter portion and an opening portion.
Abstract: An antiredeposition agent includes a polyaspartic acid alkali metal having a polydispersity, represented by the ratio (Mw/Mn) of the weight-average molecular weight (Mw) to the number-average molecular weight (Mn), of 1.4 or more and being selected from the group consisting of lithium polyaspartate, potassium polyaspartate, and sodium polyaspartate.
Abstract: Provided is a polymerization initiator, which has an excellent curing rate and is an alternative to a polymerization initiator system using a benzoyl peroxide-aromatic amine compound, a curable composition containing the polymerization initiator, a dental material and dental filler material containing the composition, and a kit for preparing the curable composition. The polymerization initiator contains one or more compounds (A) selected from the group consisting of a pyrazolidinedione compound and/or pyrazolidine(di)thione compound (A1), a salt (A2) of the compound (A1), and a malonate compound (A3).
Abstract: A lubricating oil composition includes an ethylene/?-olefin copolymer (A) having 70 to 90 mole % of structural units derived from ethylene and an intrinsic viscosity [?] of 0.3 to 1.0 dl/g.
Abstract: The purpose of the present invention is to obtain an ethylene??-olefin?non-conjugated polyene copolymer that has a low permanent compression set at low temperatures, is flexible, and has an excellent balance of rubber elasticity at low temperatures and tensile strength at normal temperatures. This ethylene-based polymer is an ethylene??-olefin?non-conjugated polyene copolymer that includes units derived from ethylene (A), units derived from an ?-olefin (B) containing 4-20 carbon atoms, and units derived from a non-conjugated polyene (C) and satisfies (1)-(4). (1) The molar ratio of (A) to (B) is 40/60-90/10, (2) the contained amount of the units derived from (C) is 0.1-6.0 mol %, (3) ML(1+4) 125° C. is 5-100, and (4) the B value is 1.20 or more.
Abstract: Provided is a nonaqueous electrolyte solution for batteries, which contains an additive A that is composed of a boron compound represented by formula (1), and an additive B that has a lower reductive decomposition potential than the Additive A, in which n represents an integer from 1 to 5, M+ represents an Li+ ion or an H+ ion, and when n is an integer from 2 to 5, more than one M+ may be the same as or different from each other.