Patents Assigned to Mitsui-Cyanamid Ltd.
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Patent number: 5250602Abstract: Disclosed are a polymer emulsion prepared by neutralizing a seed polymer with an acid or a salt or by quaternizing it with a quaternizing agent and a method of preparing the polymer emulsion. The surfaces of the emulsion grains are very densely cationated. The seed polymer is formed by polymerizing a monomer of formula (I) or a mixture of the monomer (I) and copolymerizable ethylenic unsaturated monomer(s) (II) and a seed latex of a carboxyl-modified synthetic rubber latex or synthetic resin emulsion. ##STR1## R.sub.1 is H or CH.sub.3 ; R.sub.2 is a 2-5C alkylene; R.sub.3 and R.sub.4 each are H or a 1-5C alkyl; A is--COO--or--CONH--; and R.sub.1, R.sub.3 and R.sub.4 are so selected that the monomer is hardly soluble or insoluble in water. As a consequence of being very densely cationated by post-modification, the cationic polymer emulsion is useful in various fields as binders, fixers or other additives.Type: GrantFiled: January 31, 1990Date of Patent: October 5, 1993Assignee: Mitsui-Cyanamid, Ltd.Inventors: Hiroshi Itoda, Naotaka Watanabe, Yoshio Hosoya
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Patent number: 5213166Abstract: A pile driving and pile removing method comprises the step of causing a water-in-oil type water swellable polymer particle emulsion to be present on the pile surface or in the vicinity thereof during driving or extraction. The presence of the emulsion reduces the frictional resistance between the pile and the ground, enabling smooth and easy driving and removing of the pile.Type: GrantFiled: February 10, 1992Date of Patent: May 25, 1993Assignee: Mitsui-Cyanamid, Ltd.Inventors: Naotaka Watanabe, Hiroshi Itoda, Akio Kitamura
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Patent number: 5180473Abstract: Disclosed is a paper-making process for preparing a paper from a paper stock suspension, which is characterized by adding water-swellable cationic polymer particles optionally together with an acrylamide polymer to the suspension as a retention-improving agent. In the process, the stability of the retention even under high shearing force in the paper-making step is improved, the load for recovery of white water and treatment of waste water drained is reduced and the abrasion of paper-making wires is reduced.Type: GrantFiled: May 15, 1991Date of Patent: January 19, 1993Assignee: Mitsui-Cyanamid, Ltd.Inventors: Kenichi Akune, Naotaka Watanabe, Yukihiro Inomiya, Hiroshi Itoda, Takeo Arai, Reiko Funato
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Patent number: 5132358Abstract: A polymer emulsion capable of becoming water swellable is provided by mixing a monomer represented by the general formula ##STR1## (wherein R.sub.1 indicates H or CH.sub.3, R.sub.2 and R.sub.3 indicate an alkyl radical represented by CnH.sub.2N+1 in which n is a positive integer, A indicates --O--CH.sub.2 -- or --NH--CH.sub.2 --CH.sub.2 --, and R.sub.1, R.sub.2 and R.sub.3 are selected within the range wherein the monomer exhibits sparing solubility or insolubility in water)with a crosslinking agent and optionally with another vinyl monomer capable of copolymerization therewith, and emulsion polymerizing the so-obtained mixture in water. The so obtained a polymer can be made water swellable by reaction with an acid, a salt or a quaternizing agent.Type: GrantFiled: July 10, 1991Date of Patent: July 21, 1992Assignee: Mitsui-Cyanamid, Ltd.Inventors: Naotaka Watanabe, Takeo Arai, Hitoshi Fujiyoshi, Masako Shirota
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Patent number: 5069721Abstract: Disclosed is a mortar.concrete composition comprising a polymer emulsion, a portland cement material and an aggregate, which is characterized in that the polymer emulsion is one prepared by neutralizing a seed polymer with an acid or a salt or by quaternizing it with a quaternizing agent, the surfaces of the emulsion grains being thereby highly densely cationated, where the seed polymer is formed by adding a monomer as represented by the following formula (I) or a mixture of the monomer (I) and copolymerizable ethylenic unsaturated monomer(s) to a seed latex of a carboxyl-modified synthetic rubber latex or synthetic resin emulsion and polymerizing them: ##STR1## The polymer of the invention may noticeably reinforce the strength of the shaped product even when the amount of the polymer added is small.Type: GrantFiled: March 22, 1990Date of Patent: December 3, 1991Assignee: Mitsui-Cyanamid, Ltd.Inventors: Akira Tamura, Naotaka Watanabe, Hitoshi Fujiyoshi, Masako Shirota
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Patent number: 5069754Abstract: A method of preparing a paper having a reinforced strength wherein a polymer latex is added to a paper stock in an amount of from 2.5 to 30% by weight. The polymer latex is prepared by neutralizing a seed polymer with an acid or a salt or by quaternizing it with a quaternizing agent. The surfaces of the emulsion grains are provided with a large number of cationic groups. The seed polymer is formed by adding a monomer represented by the following formula (I) or a mixture of the monomer (I) and copolymerizable ethylenic unsaturated monomer(s) (II) to a seed latex of a carboxyl-modified synthetic rubber latex or synthetic resin emulsion and polymerizing them: ##STR1## R.sub.1 represents H or CH.sub.3 ; R.sub.2 represents an alkylene group having from 2 to 5 carbon atoms;R.sub.3 and R.sub.4 each represents H or an alkyl group having from 1 to 5 carbon atoms;A represents ##STR2## and R.sub.1, R.sub.3 and R.sub.4 are so selected that the monomer is hardly soluble or insoluble in water.Type: GrantFiled: February 16, 1990Date of Patent: December 3, 1991Assignee: Mitsui-Cyanamid, Ltd.Inventors: Naotaka Watababe, Takao Arai, Hitoshi Fujiyoshi, Masako Shirota
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Patent number: 5022999Abstract: A method of treating starch-containing water comprises the step of adding water swellable, cationic polymerizate particles to the starch-containing water. The starch is soluble starch. The water-swellable cationic polymer particles are polymer particles of a crosslinking monomer and either a cationic vinyl monomer or a cationic vinyl monomer and a nonionic vinyl monomer.Type: GrantFiled: September 22, 1989Date of Patent: June 11, 1991Assignee: Mitsui-Cyanamid, Ltd.Inventors: Naotaka Watanabe, Hiroshi Itoda, Reiko Funato
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Patent number: 4977208Abstract: (A) Water-absorbent coating compositions comprising (1) a nonaqueous dispersion of a resin, or a solution of a resin, and (2) a water-in-oil type emulsion of a water-swellable polymer with an average particle size not greater than 10 .mu.m; and a process for coating the same which uses a proper primer. (B) Water-absorbent coating compositions which comprise 100 parts by weight (on dry basis) of a resinous solution and 10 to 150 parts by weight (on solid basis) of a dehydrated water-in-oil type emulsion of a water-swellable polymer with an average particle size not greater than 10 .mu.m and which gives coated film with an elongation not lower than 30%.Type: GrantFiled: May 16, 1989Date of Patent: December 11, 1990Assignee: Mitsui-Cyanamid, Ltd.Inventors: Yoshio Hosoya, Naotaka Watanabe, Isao Takagi, Atsuo Miyoshi
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Patent number: 4789707Abstract: There is disclosed a coating resin composition which contains as a crosslinking agent a melamine-formaldehyde resin which permits a paint to cure at low temperatures, permits a paint to form a coating film flexible enough for the fabrication of the coated substrate, gives off only a small amount of formaldehyde at the time of paint application, and makes it possible to increase the solids content in a paint. The melamine-formaldehyde resin is a mixed alkyl etherified methylol melamine resin, and the other composition-constituting component is an alkyd resin, polyester resin, or vinyl copolymer.Type: GrantFiled: March 2, 1987Date of Patent: December 6, 1988Assignees: Mitsui-Cyanamid Ltd., Nippon Paint Co., Ltd.Inventors: Tsutomu Nishimura, Yasuo Saito, Kenji Shindo, Kazutoshi Abe