Patents Assigned to Mitsui Mining & Smelting Co.
  • Patent number: 12272828
    Abstract: An electrode catalyst layer for a fuel cell includes a catalyst/support composite including a support and a catalyst supported thereon. The support contains a titanium oxide. The surface of the catalyst/support composite has an oxide of at least one element selected from the group consisting of niobium, tantalum, zirconium, and silicon. The ratio A2/A1 is from 0.35 to 1.70, wherein A1 is the atomic ratio of titanium on a surface of the catalyst layer and A2 is the atomic ratio of a total of niobium, tantalum, zirconium, and silicon on the surface of the catalyst layer, A1 and A2 being measured by X-ray photoelectron spectroscopy. The titanium oxide preferably has a composition TiOX (0.5?x<2).
    Type: Grant
    Filed: February 12, 2021
    Date of Patent: April 8, 2025
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Takuya Kitabatake, Joji Miki, Haruka Watanabe
  • Patent number: 12263523
    Abstract: A method is provided for producing a bonding composition containing copper particles and a second liquid medium. In this production method, the copper particles are produced in a first liquid medium using a wet reduction method, and thus a dispersion of the copper particles is prepared. Subsequently, the first liquid medium in the dispersion is ultimately, finally or eventually replaced with the second liquid medium while the dispersion is kept wet. It is also preferable that the first liquid medium is replaced with another liquid medium one or more times, and the second liquid medium is used in the final replacement. The liquid media are preferably replaced at a temperature of lower than 100° C. The second liquid medium preferably includes one or more of water, alcohol, ketone, ester, ether, and hydrocarbon.
    Type: Grant
    Filed: March 12, 2021
    Date of Patent: April 1, 2025
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Kei Anai, Shinichi Yamauchi, Jung-Lae Jo
  • Patent number: 12233463
    Abstract: A composition for pressure bonding contains a metal powder and a solid reducing agent and has a compressibility of 10% to 90%, the compressibility being expressed by a relationship formula using the thickness A of a dried coating film formed by drying the composition in an air atmosphere at 110° C. under atmospheric pressure for 20 minutes and the thickness B of a sintered body formed by treating the dried coating film in a nitrogen atmosphere at 280° C. under a pressure of 6 MPa for 20 minutes. The solid reducing agent may be BIS-TRIS. Also provided is a bonded structure of conductors in which a bonding portion via which two conductors are bonded together is formed by treating, under pressure, the two conductors and a coating film formed of the composition for pressure bonding provided therebetween.
    Type: Grant
    Filed: March 25, 2020
    Date of Patent: February 25, 2025
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Kei Anai, Shinichi Yamauchi, Jung-Lae Jo
  • Patent number: 12139592
    Abstract: A resin composition is provided including: coated particles, each including a core containing a metal oxide and a coating layer containing an aluminum hydrous oxide and provided on a surface of the core; and a resin. The metal oxide is represented by MxOy, where M represents at least one element selected from the group consisting of Ba, Ti, Sr, Pb, Zr, La, Ta, Ca, and Bi, and x and y each represent a number determined from a stoichiometric ratio according to the valence of the metal element M. The resin composition has an atomic ratio Al/(M+Al) of 0.05 or more and 0.7 or less, as determined by XPS for the particles contained in the resin composition.
    Type: Grant
    Filed: September 14, 2021
    Date of Patent: November 12, 2024
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Toshihiro Hosoi, Yoshihiro Yoneda, Tetsuro Sato, Hitohiko Ide, Hiromi Matsuura, Kouichi Kawaratani
  • Patent number: 12083509
    Abstract: Provided is a beta zeolite satisfying P>76.79Q?29.514 in a range in which Q is less than 0.4011 nm, wherein, P represents an AB value that is an intensity ratio of A to B, A represents a diffraction intensity of a main peak of the beta zeolite observed by X-ray diffraction measurement, B represents a diffraction intensity of the (116) plane of ?-alumina obtained by X-ray diffraction measurement under the same conditions as those for the X-ray diffraction measurement on the beta zeolite, the ?-alumina being the standard substance 674a distributed by the American National Institute of Standards and Technology, and Q represents a lattice interplanar spacing of the main peak of the beta zeolite observed by X-ray diffraction measurement. It is preferable that the formula (1) above is satisfied in a range in which Q is from 0.3940 to 0.4000 nm.
    Type: Grant
    Filed: June 29, 2020
    Date of Patent: September 10, 2024
    Assignee: Mitsui Mining &Smelting Co., Ltd.
    Inventors: Yuichi Senoo, Katsuhiko Hayashi, Junki Tomita, Takahiro Kogawa, Akihiro Kanno
  • Patent number: 12070801
    Abstract: A bonding material includes: a copper foil; and a sinterable bonding film formed on one surface of the copper foil. The bonding film contains a copper powder and a solid reducing agent. The bonding material is used for bonding to a bonding target having, on its surface, at least one metal selected from the group consisting of gold, silver, copper, nickel, and aluminum. The bonding material is also used as a material for wire bonding. A bonded structure is also provided in which a bonding target having a metal layer formed on its surface and a copper foil are electrically connected to each other via a bonding layer formed of a sintered structure of a copper powder, wherein the metal layer contains at least one metal selected from the group consisting of gold, silver, copper, nickel, and aluminum.
    Type: Grant
    Filed: March 2, 2020
    Date of Patent: August 27, 2024
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Kei Anai, Jung-Lae Jo
  • Patent number: 12046572
    Abstract: A bonding sheet includes a copper foil and sinterable bonding films formed on both faces of the copper foil. The bonding films each contain copper particles and a solid reducing agent. The bonding sheet is used to bond to a target object to be bonded having at least one metal selected from gold, silver, copper, and nickel on a surface thereof. A bonded structure includes: a bonded object having at least one metal selected from gold, silver, copper, and nickel on a surface thereof; a copper foil; and a bonding layer including a sintered structure of copper particles; and the bonded object and the copper foil are electrically connected to each other via the bonding layer.
    Type: Grant
    Filed: March 12, 2021
    Date of Patent: July 23, 2024
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Kei Anai, Jung-Lae Jo
  • Patent number: 12030125
    Abstract: A bonded body is provided including: a bonding layer containing Cu; and a semiconductor element bonded to the bonding layer. The bonding layer includes an extending portion laterally extending from a peripheral edge of the semiconductor element. In a cross-sectional view in a thickness direction, the extending portion rises from a peripheral edge of a bottom of the semiconductor element or from the vicinity of the peripheral edge of the bottom of the semiconductor element, and includes a side wall substantially spaced apart from a side of the semiconductor element. Preferably, the extending portion does not include any portion where the side wall and the side of the semiconductor element are in contact with each other. A method for manufacturing a bonded body is also provided.
    Type: Grant
    Filed: March 2, 2020
    Date of Patent: July 9, 2024
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Kei Anai, Shinichi Yamauchi, Jung-Lae Jo, Takahiko Sakaue
  • Patent number: 12024435
    Abstract: Out of sintered metal carbides having an extremely high melting point, there is provided a sintered metal carbide which can be produced without having to perform sintering under high pressure such as hot pressing or HIP, having a high relative density and excellent mechanical strength. A sintered metal carbide of at least one metal selected from the group consisting of elements of Groups 4 and 5 of the periodic table, wherein the sintered metal carbide contains Si element of 0.1 wtppm or more and 10,000 wtppm or less.
    Type: Grant
    Filed: February 8, 2019
    Date of Patent: July 2, 2024
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Hitoshi Kajino, Shoji Imaura
  • Patent number: 11990583
    Abstract: Provided are a sulfide solid electrolyte having a small particle size and a low specific surface area; an electrode composite material, a slurry and a battery in each of which the sulfide solid electrolyte is used; and a method of producing the sulfide solid electrolyte. The sulfide solid electrolyte contains lithium (Li), phosphorus (P) and sulfur (S) elements and has: a median diameter D50 of 0.10 ?m or more and 2.0 ?m or less; and a value of the formula: (A×B)/C, wherein A represents a BET specific surface area (m2/g), B represents a true density (g/cm3), and C represents a CS value (m2/cm3), of 1.0 or more and 2.5 or less.
    Type: Grant
    Filed: December 25, 2020
    Date of Patent: May 21, 2024
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Yuki Nakayama, Takahiro Ito, Tsukasa Takahashi
  • Patent number: 11980935
    Abstract: Copper particles are provided that each include a core particle made of copper and a coating layer that coats the surface of the core particle, wherein the coating layer is made of a copper salt of an aliphatic organic acid. It is also preferable that the copper particles have an infrared absorption peak in a range of 1504 to 1514 cm?1 and no infrared absorption peak in a range of 1584 to 1596 cm?1. It is also preferable that, in thermogravimetric analysis of the copper particles, the temperature at which the ratio of the mass loss value to the mass loss value at 500° C. reaches 10% is from 150° C. to 220° C. A method is also provided for producing copper particles, the method including bringing core particles made of copper into contact with a solution containing a copper salt of an aliphatic organic acid to thereby coat the surface of the core particles.
    Type: Grant
    Filed: December 15, 2020
    Date of Patent: May 14, 2024
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Mizuki Akizawa, Takafumi Sasaki
  • Patent number: 11978850
    Abstract: A sulfide solid electrolyte that can suppress the generation of hydrogen sulfide gas while maintaining the lithium ion conductivity; and an electrode composite material, a slurry and a battery, in each of which the sulfide solid electrolyte is used, are provided. The sulfide solid electrolyte contains lithium (Li), phosphorus (P) and sulfur (S) elements; at least one halogen (X) element; and at least one metal (M) element having a first ionization energy of more than 520.2 KJ/mol and less than 1007.3 KJ/mol, wherein, in an X-ray diffraction pattern measured with CuK?1 radiation, peaks are present at positions of 2?=25.19°±1.00° and 29.62°±1.00°.
    Type: Grant
    Filed: December 11, 2020
    Date of Patent: May 7, 2024
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Yuki Nakayama, Takahiro Ito, Tsukasa Takahashi
  • Patent number: 11970395
    Abstract: A rare earth phosphate particle containing a rare earth element A, where A is Sc, Y, La, Eu, Gd, Dy, Yb, or Lu, and a rare earth element B different from the element A, where B is Sc, Y, La, Eu, Gd, Dy, Yb, or Lu. The phosphate of the element A is preferably crystalline, with at least part of the element B dissolved in the phosphate of the element A in a solid state. The phosphate of the element A preferably has a xenotime or monazite crystal structure.
    Type: Grant
    Filed: December 5, 2018
    Date of Patent: April 30, 2024
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Yoshihiro Yoneda, Kazuhiko Kato
  • Patent number: 11945974
    Abstract: A temporary fixing composition is provided that is used to temporarily fix a first bonding target material and a second bonding target material to each other before the two bonding target materials are bonded to each other. The temporary fixing composition contains a first organic component having a viscosity of less than 70 mPa·s at 25° C. and a boiling point of 200° C. or lower and a second organic component having a viscosity of 70 mPa·s or greater at 25° C. and a boiling point of 210° C. or higher. It is preferable that, when thermogravimetry-differential thermal analysis is performed under the conditions at a temperature increase rate of 10° C./min in a nitrogen atmosphere with a sample mass of 30 mg, the 95% mass reduction temperature is lower than 300° C.
    Type: Grant
    Filed: March 12, 2021
    Date of Patent: April 2, 2024
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Kei Anai, Jung-Lae Jo, Kengo Tashiro
  • Patent number: 11913367
    Abstract: There is provided an exhaust gas purifying catalyst including a substrate and catalyst portions. The substrate includes an inflow-side cells, outflow-side cells, and porous partition walls, each partition wall separating the inflow-side cell from the outflow-side cell. The catalyst portion includes: (group A) first catalyst portions, each first catalyst portion being provided on a surface of the partition wall that faces the inflow-side cell on an upstream side in an exhaust gas flow direction; and (group B) second catalyst portions being provided on a surface of the partition wall that faces the outflow-side cell on a downstream side in the exhaust gas flow direction. Each catalyst portion of one of group A and group B includes at least one oxidizing catalyst layer and at least one reducing catalyst layer, and each catalyst portion of the other of group A and group B includes at least one oxidizing catalyst layer and/or at least one reducing catalyst layer.
    Type: Grant
    Filed: April 17, 2019
    Date of Patent: February 27, 2024
    Assignees: Mitsui Mining & Smelting Co., Ltd., HONDA MOTOR CO., LTD.
    Inventors: Hiroki Kurihara, Yusuke Nagai, Shingo Akita, Yoshinori Endo, Takeshi Mori, Takayuki Watanabe, Tomoko Tsuyama
  • Patent number: 11831007
    Abstract: A Si-based negative electrode active material that is capable of improving cycle characteristics, reducing or eliminating a plateau region in the discharge profile, and further improving high-rate characteristics. The Si-based negative electrode active material contains Si and a compound containing Si and a semimetal/metal element M, wherein the content of Si in the negative electrode active material is more than 50 wt %; the content of oxygen atoms (O) is less than 30 wt %; the content of the semimetal/metal element M is more than 10 wt % and less than 50 wt %, wherein in an X-ray diffraction pattern as measured by a powder X-ray diffraction (XRD) device using Cu-K?1 rays, the full width at half maximum of the peak of the (111) plane of Si is 0.25° or more; and wherein the peak intensity of the peak of the (111) plane of Si is less than 20,000 cps; and the true density is 2.5 g/cm3 or more.
    Type: Grant
    Filed: August 10, 2018
    Date of Patent: November 28, 2023
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventor: Tetsuya Mitsumoto
  • Patent number: 11824188
    Abstract: A positive electrode active material for an all-solid-state lithium secondary battery, which is capable of improving the rate characteristics, the cycle characteristics, and the initial charge and discharge efficiency even in the case where a sulfide-based solid electrolyte is used, wherein the surface of a lithium-containing composite oxide, referred to as present core particles, is coated with a compound, referred to as, LiAO compound, containing Li, A, where A represents one or more elements selected from the group consisting of Ti, Zr, Ta, Nb, Zn, W, and Al, and O; and a halogen is present on the surface of the present core particles.
    Type: Grant
    Filed: August 10, 2018
    Date of Patent: November 21, 2023
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Daisuke Washida, Hitohiko Ide
  • Patent number: 11799079
    Abstract: Provided is a 5 V class spinel type lithium nickel manganese-containing composite oxide having an operating potential of 4.5 V or more with respect to a metal Li reference potential, wherein the composite oxide is able to improve cycle characteristics while suppressing the amount of gas generated under high temperature environments and, moreover, to improve output characteristics while suppressing a shoulder on discharge at around 4.1 V in a charge and discharge curve. The spinel type lithium nickel manganese-containing composite oxide is represented by a general formula [Li(LiaNiyMnxTibMgzM?)O4-?] (where 0<a, 0<b, 0.30?y<0.60, 0<z, 0??, x=2?a?b?y?z??<1.7, 3?b/a?8, 0.11<b+z+?, 0<z/b<1, 0???0.2, and M represents one or two or more elements selected from the group consisting of Fe, Co, Ba, Cr, W, Mo, Y, Zr, Nb, P, and Ce).
    Type: Grant
    Filed: February 28, 2018
    Date of Patent: October 24, 2023
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventor: Tetsuya Mitsumoto
  • Patent number: 11745172
    Abstract: A substrate (11) of an exhaust gas purification catalyst (10) includes inflow-side cells (21), outflow-side cells (22), and porous partition walls (23), each separating the inflow-side cell and the outflow-side cell. Catalyst portions (14, 15) are provided on the surfaces of the partition walls that each face the inflow-side cell and/or the surfaces of the partition walls that each face the outflow-side cell. In a cross section vertical to an exhaust gas flow direction, the percentage of the total area of voids, each void satisfying the expression L/{2(?S)1/2}?1.1 (wherein L is the perimeter of the void in the cross section, and S is the area of the void in the cross section), is greater than 10% to 30% or less based on the apparent area of the catalyst portion present on the partition wall. The content of zirconium element in terms of oxide (amount of ZrO2) in the catalyst portions is from 35 mass % to 85 mass %.
    Type: Grant
    Filed: March 9, 2020
    Date of Patent: September 5, 2023
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Yusuke Nagai, Shingo Akita, Hiroki Kurihara, Yoshinori Endo
  • Patent number: 11699809
    Abstract: Provided is a sulfide-based solid electrolyte which is capable of suppressing the generation of hydrogen sulfide caused by reaction with moisture even when in contact with dry air in a dry room or the like, and capable of maintaining lithium ion conductivity. Proposed is a sulfide-based solid electrolyte for a lithium secondary battery, wherein the surface of a compound containing lithium, phosphorus, sulfur, and halogen, and having a cubic argyrodite-type crystal structure is coated with a compound containing lithium, phosphorus, and sulfur, and having a non-argyrodite-type crystal structure.
    Type: Grant
    Filed: May 16, 2017
    Date of Patent: July 11, 2023
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Hideo Uesugi, Norihiko Miyashita, Hitohiko Ide, Takahiro Ito, Takashi Chikumoto, Takashi Muranaka