Patents Assigned to Mitsui Mining & Smelting Company, Ltd.
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Patent number: 7455931Abstract: An anode for a nonaqueous secondary battery comprising a current collector having formed thereon a first covering layer containing tin, a tin alloy, aluminum or an aluminum alloy and a second covering layer containing a metal having low capability of forming a lithium compound in that order. The anode may have an additional first covering layer formed on the second covering layer. A covering layer containing a copper etc. may be formed as an uppermost layer. Each layer can be formed by heat treating to get desired property. As heat treatment can be done in a short time, it has a great cost merit.Type: GrantFiled: April 21, 2003Date of Patent: November 25, 2008Assignee: Mitsui Mining & Smelting Company, Ltd.Inventors: Kiyotaka Yasuda, Yoshiki Sakaguchi, Kazuko Taniguchi, Makoto Dobashi
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Patent number: 7147796Abstract: Iron oxide particles having the surface thereof coated with a layer of a complex iron oxide containing Al and Mg are disclosed. The total content of Al and Mg in the complex iron oxide layer is 0.1 to 2.5% by weight based on the whole iron oxide particles. The Mg content in the complex iron oxide layer is 0.05 to 1% by weight based on the whole iron oxide particles. The Al content in the complex iron oxide layer is 0.05 to 1.7% by weight based on the whole iron oxide particles. The Mg content in the complex iron oxide layer is 20% or more based on the total Mg content of the whole iron oxide particles.Type: GrantFiled: October 15, 2002Date of Patent: December 12, 2006Assignee: Mitsui Mining & Smelting Company, Ltd.Inventors: Hiroyuki Shimamura, Masahiro Miwa
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Patent number: 6821678Abstract: Manganese dioxide for lithium primary batteries which is obtained by soda neutralization and heat treatment of electrolytic manganese dioxide and has a sodium content of 0.05 to 0.2% by weight and a process for producing the same.Type: GrantFiled: January 3, 2001Date of Patent: November 23, 2004Assignee: Mitsui Mining & Smelting Company, Ltd.Inventors: Hiroshi Sumida, Kiyoteru Enomoto, Masaki Sato
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Patent number: 6798048Abstract: A 2-metal layer TAB and a both-sided CSP.BGA tape having an insulating substrate and a wiring layer provided on at least both sides of the substrate, the substrate having evenly spaced sprocket holes on both width direction edges in the longitudinal direction thereof and also having through-holes formed with a punching press, and the through-holes being filled with a conductor by means of a punching press such that the conductor and the wiring layers are electrically connected, which is characterized by having round pilot holes between the sprocket holes formed in the longitudinal direction thereof; and a process of producing the same.Type: GrantFiled: May 13, 2002Date of Patent: September 28, 2004Assignees: Mitsui Mining & Smelting Company, Ltd., Suzuki Co., Ltd.Inventors: Akira Ichiryu, Tatsuo Kataoka, Hirokazu Kawamura, Katsuhiko Hayashi, Masahito Ishii
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Patent number: 6773667Abstract: A hydrogen storage material which is an AB5 type hydrogen storage alloy having a CaCu5 type crystal structure represented by general formula: MmNiaMnbAlcCod wherein Mm is a misch metal, 4.1<a≦4.3, 0.4<b≦0.6, 0.2≦c≦0.4, 0.1≦d≦0.4, and 5.2≦a+b+c+d≦5.45, or general formula: MmNiaMnbAlcCodXe wherein Mm is a misch metal, X is Cu and/or Fe, 4.1<a≦4.3, 0.4<b≦0.6, 0.2≦c≦0.4, 0.1≦d≦0.4, 0<e≦0.1, and 5.2≦a+b+c+d+e≦5.45, characterized in that the lattice length on the c-axis is 406.2 pm or more, and a process of producing the same.Type: GrantFiled: December 27, 2001Date of Patent: August 10, 2004Assignee: Mitsui Mining & Smelting Company, Ltd.Inventors: Kiyotaka Yasuda, Yoshiki Sakaguchi, Shingo Kikugawa
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Patent number: 6746509Abstract: A process of producing a zinc or zinc alloy powder (4) for batteries which comprises dropping molten zinc or a molten zinc alloy to form a molten metal droplets stream (1) and striking an atomizing medium jet (3) emitted from a nozzle (2) against the molten metal stream (1) at right angles to atomize the molten zinc or the molten zinc alloy, wherein two or more the nozzles are arranged in parallel to each other, the orifice of each of the nozzles has a V-shaped, U-shaped, X-shaped or arc-shaped cross-section, the atomizing medium is air or an inert gas, two or more the molten metal streams have at least two different flow rates selected from a range 0.04 to 0.25 kg/sec, and two or more the atomizing medium jets have at least two different atomizing pressures selected from a range 4 to 9 kg/cm2.Type: GrantFiled: September 11, 2002Date of Patent: June 8, 2004Assignees: Mitsui Mining & Smelting Company, Ltd., Matsushita Electric Industrial Co., Ltd.Inventors: Akira Oyama, Tadayoshi Odahara, Seiji Fuchino, Mitsuo Shinoda, Hisaji Shimomura
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Patent number: 6706444Abstract: To electrolydeposited manganese dioxide of which pH being adjusted to a range higher than 2 with either a sodium compound or a potassium compound, a raw lithium material and a compound containing any element selected from a group consisting of aluminum, magnesium, calcium, titanium, vanadium, chromium, iron, cobalt, nickel, copper and zinc to substitute a part of the manganese contained in the electrodeposited manganese dioxide with at least one element selected from the group described above, admixed and then burned.Type: GrantFiled: May 19, 2000Date of Patent: March 16, 2004Assignee: Mitsui Mining & Smelting Company, Ltd.Inventors: Koichi Numata, Tsuneyoshi Kamada
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Patent number: 6689233Abstract: A hydrogen storage material which is characterized by having, as a cast alloy, a flaky or similar shape with a thickness of 50 to 500 &mgr;m and showing such crystallite orientation that the X-ray diffraction pattern has an intensity ratio of plane indices (002)/(200) of 2 to 10 as measured with the cooled surface of the flaky cast alloy being in parallel with a mount, and a process of producing the same.Type: GrantFiled: December 10, 2001Date of Patent: February 10, 2004Assignee: Mitsui Mining & Smelting Company Ltd.Inventors: Kiyotaka Yasuda, Daisuke Mukai, Minoru Sakai, Shigeo Hirayama, Kazuhito Komatsu, Shinya Kagei
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Patent number: 6673134Abstract: A fine flaky copper powder having an average major axis diameter of 4 to 10 &mgr;m and a flakiness of 2 to 20, has a bulk density of 2 to 4 g/cm3 and a BET specific surface area of 0.4 to 1.5 m2/g; A process for producing the copper powder includes introducing a copper slurry into a medium type agitation mill and flattening the powder.Type: GrantFiled: December 31, 2001Date of Patent: January 6, 2004Assignee: Mitsui Mining & Smelting Company, Ltd.Inventors: Kenzo Hanawa, Kazuaki Takahashi
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Patent number: 6465130Abstract: The anode material to be used for non-aqueous electrolyte secondary batteries according to the present invention is composed of a Li-Mn type complex oxide having a spinel structure, either or both of the occupancy rate (gc) value of cations in an unit lattice of the material to be determined based on the composition, the lattice constant and the density or/and the ocupancy rate (ga) value of anions in an unit lattice of the material to be determined based on the composition, the lattice constant and the density is/are adjusted to a value of 0.985 or less. The actions of the complex are partially substituted with aluminum or magnesium.Type: GrantFiled: November 22, 1999Date of Patent: October 15, 2002Assignee: Mitsui Mining & Smelting Company, Ltd.Inventors: Koichi Numata, Shintarou Ishida
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Patent number: 6428932Abstract: Zinc alloy powder for alkaline batteries containing Bi at a rate of 0.01-0.1% by weight, In at a rate of 0.01-0.1% by weight, Mg at a rate of 0.0005-0.03 % by weight and unavoidable impurities, such as Pb, Cd and Cu, capable of improving high-rate performance and being suitable for using as a cathode active substance for alkaline batteries is provided.Type: GrantFiled: May 19, 2000Date of Patent: August 6, 2002Assignee: Mitsui Mining & Smelting Company, Ltd.Inventors: Mitsuo Shinoda, Keiichi Kagawa, Seiji Fuchino, Kouji Morita, Yoshiaki Tanino, Makoto Matsuo, Akira Oyama
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Patent number: 6403875Abstract: A process for producing a thermoelectric material comprising mixing at least two of bismuth, tellurium, selenium, and antimony and, if desired, a dopant, melting the mixture, grinding the resulting alloy ingot, forming the powder, and sintering the green body under normal pressure, or hot pressing the powder, wherein the grinding and the normal sintering or hot pressing are carried out in the presence of a solvent represented by CnH2n+1OH or CnH2n+2CO (wherein n is 1, 2 or 3).Type: GrantFiled: February 23, 2001Date of Patent: June 11, 2002Assignee: Mitsui Mining & Smelting Company, Ltd.Inventors: Shinji Karino, Ryouma Tsukuda, Yuichi Anno, Isamu Yashima, Hitoshi Kajino
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Publication number: 20010024752Abstract: Manganese dioxide for lithium primary batteries which is obtained by soda neutralization and heat treatment of electrolytic manganese dioxide and has a sodium content of 0.05 to 0.2% by weight and a process for producing the same.Type: ApplicationFiled: January 3, 2001Publication date: September 27, 2001Applicant: Mitsui Mining & Smelting Company, Ltd.,Inventors: Hiroshi Sumida, Kiyoteru Enomoto, Masaki Sato
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Patent number: 6132639Abstract: A manganese-nickel mixed hydroxide for battery active material comprising a manganese-containing mixed hydroxide having a coated layer composed of a mixed-oxide of nickel and cobalt, to provide an excellent discharging property and allows one to achieve an improvement in the discharge utilization when it is used as an electrode material for secondary batteries.Type: GrantFiled: March 3, 1999Date of Patent: October 17, 2000Assignee: Mitsui Mining & Smelting Company, Ltd.Inventors: Kazuhito Komatsu, Sumihiko Makizoe, Tsuneyoshi Kamada, Yasuhiro Ochi, Takashi Okito
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Patent number: 6123911Abstract: A process for producing a lithium manganate for lithium secondary batteries comprising mixing a manganese compound and a lithium compound, firing the mixture at 1000 to 1500.degree. C., mixing the resulting complex oxide with a lithium compound, and firing the mixture at 600 to 800.degree. C.Type: GrantFiled: September 10, 1998Date of Patent: September 26, 2000Assignee: Mitsui Mining & Smelting Company, Ltd.Inventors: Munetoshi Yamaguchi, Koichi Numata
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Patent number: 6083476Abstract: Black ultrafine magnetite particles of this invention have an FeO content of 31 to 35% and a particle size of 0.1 .mu.m or less. A process for producing the black ultrafine magnetite particles comprises dispersing ultrafine magnetite particles with a particle size of 0.1 .mu.m or less in water containing ferrous hydroxide, aging the dispersion of 90 to 200.degree. C. at a free alkali concentration of 1 mol/liter (M/l) or more, then adding 0.2 to 5%, based on the magnetite particles, of sodium oleate or potassium oleate, and adjusting the pH to 5 to 6 to adhere oleic acid to magnetite.Type: GrantFiled: January 29, 1998Date of Patent: July 4, 2000Assignee: Mitsui Mining & Smelting Company, Ltd.Inventors: Naoyoshi Mochizuki, Kenzo Hanawa
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Patent number: 6059988Abstract: Magnetite particles continuously contain a total amount of 0.2 to 1.2 wt. %, based on magnetite, of a silicon component and an aluminum component expressed as silicon and aluminum, in a region ranging from the center to the surface of the particle, a total amount of 0.01 to 0.5 wt. % of the silicon component and the aluminum component, expressed as silicon and aluminum, being exposed on the surface of the particle, and an outer shell of the particle being coated with a metal compound comprising at least one metal component bound to the silicon component and the aluminum component, the metal component being selected from the group consisting of Zn, Mn, Cu, Ni, Co, Cr, Cd, Zr, Sn, Mg, Ti, Ce, W and Mo and a process for their preparation.Type: GrantFiled: December 21, 1998Date of Patent: May 9, 2000Assignee: Mitsui Mining & Smelting Company, Ltd.Inventors: Masachika Hashiuchi, Takeshi Miyazono, Masahiro Miwa
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Patent number: 6056834Abstract: A sample is taken out of a molten magnesium alloy, the cooling curve of the sample during solidification is measured, the content of the aluminum component in the sample is determined by the use of the crystallization temperature of a phase appearing in the cooling curve, together with cooling curves, and if the results of bath analysis show the components to deviate from the standard values and target values, an aluminum-manganese master alloy, aluminum or magnesium is added to the molten magnesium alloy to adjust the components to an appropriate amount of aluminum or an appropriate iron/manganese ratio, whereby a magnesium alloy is produced.Type: GrantFiled: June 30, 1998Date of Patent: May 2, 2000Assignee: Mitsui Mining & Smelting Company, Ltd.Inventors: Kohei Kubota, Takashi Ogami, Tsutomu Sato, Koichi Sato, Mitsuharu Hoshiya, Yoichi Nosaka
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Patent number: 6013193Abstract: Magnetite particles continuously containing 0.2 to 1.0 wt. %, based on magnetite, of a silicon component expressed as silicon, in a region ranging from the center to the surface of the particle; 0.01 to 0.3 wt. % of the silicon component being exposed on the surface of the particle; and an outer shell of the particle being coated with a metal compound comprising at least one metal component bound to the silicon component, the metal component being selected from the group consisting of Zn, Mn, Cu, Ni, Co, Cr, Cd, Al, Sn, Mg, Ti and Ce, and a process for preparing the particles.Type: GrantFiled: September 22, 1998Date of Patent: January 11, 2000Assignee: Mitsui Mining & Smelting Company, Ltd.Inventors: Masachika Hashiuchi, Takeshi Miyazono, Masahiro Miwa
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Patent number: 5972074Abstract: A method for reducing Carbon contained in hydrogen storage alloys recovered from negative electrodes of nickel/hydrogen storage alloy secondary batteries of misch metal and alloys thereof as raw materials of hydrogen storage alloys for negative electrodes of nickel/hydrogen secondary batteries by adding titanium or zirconium or oxides of these elements, and melting in an inert gas atmosphere or in vacuum.Type: GrantFiled: July 8, 1997Date of Patent: October 26, 1999Assignee: Mitsui Mining & Smelting Company, Ltd.Inventors: Hiroshi Sumida, Yoshiyuki Komatsu, Masao Hidaka