Patents Assigned to Mitsui Petrochemical Industries, Inc.
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Patent number: 6063871Abstract: An ethylene type polymer composition comprising 20 to 90% by weight of an ethylene type polymer (A) and 80 to 10% by weight of an ethylene type polymer (B). The ethylene type polymer (A) is an ethylene polymer or a copolymer of ethylene and an .alpha.-olefin of 3 to 20 carbon atoms and has a density (d.sub.A) of 0.96 to 0.980 g/cm.sup.3 and an intrinsic viscosity (.eta.) of 0.5 to 3.0 dl/g. The ethylene type polymer (B) is an ethylene polymer or a copolymer of ethylene and an .alpha.-olefin of 3 to 20 carbon atoms and has a density (d.sub.B) of 0.91 to 0.965 g/cm.sup.3 and an intrinsic viscosity (.eta.) of 1.0 to 10 dl/g. At least one of the ethylene type polymers (A) and (B) is an ethylene type polymer prepared by the use of a metallocene catalyst. The ethylene type polymer composition has the properties: d.sub.A /d.sub.B is larger than 1; the density is 0.940 to 0.970 g/cm.sup.3 ; the MFR is of 0.005 to 20 g/10 min; the MFR and the melt tension (MT) satisfy the relation log(MT).gtoreq.-0.4 log(MFR)+0.Type: GrantFiled: March 24, 1997Date of Patent: May 16, 2000Assignee: Mitsui Petrochemical Industries, Inc.Inventors: Masahiro Kishine, Keiji Watanabe, Toshiyuki Tsutsui, Katsunori Yano
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Patent number: 5714273Abstract: A resin-coated steel sheet for drawn-and-ironed cans and a method of producing the resin-coated steel sheet. The resin-coated steel sheet has a steel sheet with a tin-coat on each side and a resin layer of a first crystalline thermoplastic polyester resin on one of the tin-coats and a second non-crystalline thermoplastic polyester resin on the first crystalline thermoplastic polyester resin. The first crystalline thermoplastic polyester resin has an alloying ratio of: 50.ltoreq.alloying ratio <100. The second non-crystalline thermoplastic polyester resin has an alloying ratio of 0<alloying ratio <50. The method includes thermal fusion of a mixture of 95-5 percent by weight of a crystalline polyester resin and 5-95 percent of a non-crystalline polyester resin to produce the first crystalline thermoplastic polyester resin and the second non-crystalline thermoplastic polyester resin.Type: GrantFiled: March 18, 1994Date of Patent: February 3, 1998Assignees: Nippon Steel Corporation, Mitsui Petrochemical Industries, Inc.Inventors: Ryousuke Wake, Ryoichi Yoshihara, Hiroji Niimi, Takashi Hiraoka
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Patent number: 5432279Abstract: The present invention relates to a process for the preparation, from e.g. anhydrovinblastine, of binary indole alkaloids effective as an anti-cancer drug, such as vinblastine, leurosidine, etc., wherein a trivalent iron source and hydride source are added in the presence of oxygen, thereby increasing a yield of an object compound. The yield of an object compound is improved still more by further addition, to the reaction system, of an oxalic acid ion source, malonic acid ion source, inorganic anion source, amino acid, etc.Type: GrantFiled: May 3, 1993Date of Patent: July 11, 1995Assignee: Mitsui Petrochemical Industries, Inc.Inventors: Naoya Sakamoto, Hiroaki Tan, Eiichirou Hata, Noriaki Kihara
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Patent number: 5126301Abstract: A solid catalyst for polymerizing an olefin is prepared from an organometallic compound, a fine-particle carrier, an aluminoxane, a compound of group IVB transition metal in periodic table, and an olefin polymer produced in a preliminary polymerization. The catalyst has a high polymerization activity and is capable of producing an olefin polymer having a narrow molecular- weight distribution. When the catalyst is used for producing an olefin copolymer, the resulting copolymer has both narrow molecular-weight distribution and composition distribution.Type: GrantFiled: March 12, 1990Date of Patent: June 30, 1992Assignee: Mitsui Petrochemical Industries, Inc.Inventors: Toshiyuki Tsutsui, Ken Yoshitsugu, Akinori Toyota, Norio Kashiwa
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Patent number: 5115010Abstract: A composition comprising (I) a thermally stable polyamide such as an aromatic polyamide, (II) a halogenated polystyrene or a halogenated polyphenylene oxide, and (III) sodium antimonate has excellent fire retardancy and excellent thermal stability during molding. The thermal stability of the composition is further enhanced by including (IV) a hydrotalcite-type complex hydroxide or (V) magnesium oxide and/or zinc oxide.Type: GrantFiled: April 15, 1991Date of Patent: May 19, 1992Assignee: Mitsui Petrochemical Industries, Inc.Inventors: Hideki Sakai, Kazuo Ishiwatari, Fumitoshi Ikejiri
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Patent number: 5061597Abstract: The optical recording media disclosed herein comprises a substrate and a recording layer formed thereon, wherein the recording layer is irradiated with beam of energy to form thereon bits corresponding to given pieces of information and thereby record the pieces of information. The recording layer comprises Te, Cr, C and H, the proportion of Cr contained in said recording layer, based on all atoms constituting the recording layer, is 0.1-40 atom % and that of C contained in said recording layer is 0.1-40 atom %. In another aspect, the proportion of Cr contained in said recording layer, based on the sum total of Te and Cr atoms present in said recording layer, is 0.1-60 atom %, and the proportion, based on the sum total of Te, Cr and C atoms present in said recording layer, of C is 0.1-40 atom %.Type: GrantFiled: August 13, 1990Date of Patent: October 29, 1991Assignee: Mitsui Petrochemical Industries, Inc.Inventors: Hisaharu Toibana, Mitsuyuki Kuroiwa, Akira Todo, Takeshi Minoda
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Patent number: 5015786Abstract: In a first form, a process is provided for preparing phenol by converting acetone by-produced by the cumene process into isopropanol, and alkylating benzene with the isopropanol and optional propylene, thereby forming phenol without acetone by-product. And cumene is prepared by alkylating benzene in the presence of a zeolite catalyst using isopropanol or a mixture of isopropanol and propylene as an alkylating agent. Further provided is the continuous alkylation of benzene with isopropanol wherein a reaction mixture is divided into first and second portions, with the first portion being recycled to the reactor and the second portion being taken out as a reaction product.Type: GrantFiled: November 27, 1989Date of Patent: May 14, 1991Assignee: Mitsui Petrochemical Industries Inc.Inventors: Shintaro Araki, Fujihisa Matsunaga, Hiroshi Fukuhara
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Patent number: 4970258Abstract: When a hydrophobic thermoplastic resin such as an olefin resin and a water-insoluble or non-water-swelling polymer containing a carboxylic acid salt group are melt-kneaded in the presence of water, phase inversion of forming a dispersion comprising water as the dispersion medium phase and resin particles as the dispersed phase is caused even if the amount of water is very small. If an anionic surfactant, optionally together with a solvent or oil, is made present in the composition to be melt-kneaded, the size of dispersed particles can be greatly reduced in the formed aqueous dispersion even if a resin having a very high molecular weight or a high melt viscosity is used.Type: GrantFiled: August 10, 1988Date of Patent: November 13, 1990Assignee: Mitsui Petrochemical Industries, Inc.Inventors: Shiro Homma, Masatoshi Kashiwagi, Mitsuhiro Tanaka
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Patent number: 4937118Abstract: An active energy ray-curable composition substantially comprising at least one of (meth)acrylates and oligomers thereof represented by the following general formula (I) ##STR1## wherein R represents a hydrogen atom or a methyl group,X represents an alkylene group in which at least one hydrogen atom may be replaced by a hydroxyl group,m is 0 or an integer of 1 to 4,Y represents a hydrocarbon group having a cyclic hydrocarbon moiety therein, andn is 1 or 2.The composition is useful as an adhesive, particularly as one in the production of optical discs.Type: GrantFiled: July 14, 1989Date of Patent: June 26, 1990Assignee: Mitsui Petrochemical Industries, Inc.Inventors: Hajime Inagaki, Kenji Yamane
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Patent number: 4933507Abstract: Phenol is produced by dehydrogenating cyclohexenone through a vapor-phase reaction in the presence hydrogen using a solid-phase catalyst having platinum and alkali metal carried on a support.Type: GrantFiled: November 29, 1988Date of Patent: June 12, 1990Assignee: Mitsui Petrochemical Industries, Inc.Inventors: Satoshi Inoki, Yasushi Nakashima, Fujihisa Matsunaga
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Patent number: 4923959Abstract: A polyaminobisimide resin composed of an unsaturated bisimide and a diamine which employs 1,3-bis and/or 1,4-bis(2-p-anilinopropylidene) benzene as a diamine component, when cured and used in a laminate, exhibit improved ply separation strength and water absorption.Type: GrantFiled: November 8, 1988Date of Patent: May 8, 1990Assignee: Mitsui Petrochemical Industries, Inc.Inventors: Kojiro Kan, Isao Kaneko
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Patent number: 4874647Abstract: A transparent, heat resistant polyester composition having improved mechanical strength is provided, which comprises (A) 20 to 80% by weight of a polyalkylene terephthalate predominantly comprising ethylene terephthalate and having an intrinsic viscosity of from 0.6 to 1.2 dl/g, and (B) 20 to 80% by weight of a bisphenol-A polycarbonate having an intrinsic viscosity of from 0.6 to 1.2 dl/g, the composition having an intrinsic viscosity of from 0.6 to 1.2 dl/g and a single glass transition temperature of from 80.degree. to 130.degree. C. A polyester laminate may be molded as comprising a layer of the polyester composition and a layer of alkylene terephthalate. The molded polyester laminate can take any form including films and containers.Type: GrantFiled: November 28, 1988Date of Patent: October 17, 1989Assignee: Mitsui Petrochemical Industries, Inc.Inventors: Tadao Yatsu, Yoshinori Akana
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Patent number: 4584348Abstract: A polymer composition comprising(A) 81 to 99 parts by weight of a copolymer containing olefin units and unsaturated carboxylic acid compound units and having an intrinsic viscosity [.eta.] of 0.5 to 10 dl/g and a crystallinity of at least 20%, and(B) 19 to 1 part by weight of a thermoplastic elastomer having an initial modulus of not more than 100 kg/cm.sup.2, a glass transition temperature of not more than 0.degree. C. and a weight average molecular weight (Mw) of at least 400,000.The above composition is useful as an adhesive.Type: GrantFiled: September 19, 1984Date of Patent: April 22, 1986Assignee: Mitsui Petrochemical Industries, Inc.Inventor: Riichiro Nagano
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Patent number: 4159889Abstract: A method of treating the outer surface of a pipe of a thermoplastic resinous material produced by extrusion by extruding molten resin from an extruder and sizing the same by a sizing die, and supplying a lubricant to a front end portion of the sizing die along the front end portion which is disposed in spaced juxtaposed relationship with the extruder.An apparatus for treating the outer surface of a pipe of a thermoplastic resinous material produced by extrusion including a sizing die for sizing the pipe extruded from an extruder for extruding a thermoplastic resin in tubular form, and lubricant supply means disposed at a front end portion of the sizing die in spaced juxtaposed relationship with the extruder for supplying a lubricant along the front end portion of the sizing die.Type: GrantFiled: February 24, 1977Date of Patent: July 3, 1979Assignee: Mitsui Petrochemical Industries, Inc.Inventors: Kazuo Yagi, Kazuhiro Masumoto
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Patent number: 3939131Abstract: A copolymer of 2,4-dimethyl-4-vinyl-1-cyclohexene and at least one member of the group consisting of 2,6- and 3,6-dimethyl-1,3,6-octatrienes, which copolymer is suitable for use as a tackifier, said copolymer consisting essentially of (A) structural units derived from 2,4-dimethyl-4-vinyl-1-cyclohexene and (B) structural units derived from at least one member selected from the group consisting of 2,6- and 3,6-dimethyl-1,3,6-octatriene in proportions of 100 moles of (A) to 1 to 400 moles of (B) and characterized by containing not more than seven unsaturated double bonds per 100 carbon atoms contained in its molecule and having a softening point of 85.degree.-160.degree.C. and an average molecular weight of 450-1850 is disclosed.Type: GrantFiled: August 19, 1974Date of Patent: February 17, 1976Assignee: Mitsui Petrochemical Industries, Inc.Inventors: Hiroyuki Morikawa, Tosio Sugimoto, Kazuo Sato