Patents Assigned to Mitsui Petrochemicals Industries, Ltd.
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Patent number: 5310789Abstract: An adhesive composition for a vinyl halide resin is disclosed. This adhesive composition is formed by incorporating an aliphatic polyamine having a plurality or ether bonds, an alicyclic polyamine or an alkylene diamine into a blend of an epoxy resin and a vinyl chloride copolymer resin. This adhesive composition is effectively used in the solvent-free state for a molded body of a vinyl halide type resin such as a vinyl chloride resin or a vinylidene halide resin.Type: GrantFiled: April 12, 1993Date of Patent: May 10, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Toshikazu Furihata, Toru Tomoshige
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Patent number: 5310801Abstract: Disclosed herein is a process for the production of cycloolefin random copolymers comprising flash drying a solution of a cylcoolefin random copolymer in a hydrocarbon, said solution being obtained by copolymerization of ethylene and a specific cycloolefin in said hydrocarbon in the presence of a catalyst. Further proposed herein is a process for the production of cycloolefin random copolymers by copolymerization of ethylene with a specific cycloolefin of the in a hydrocarbon in the presence of a catalyst wherein said copolymerization is carried out in a polymerization reactor where a gas phase is not substantially present.Type: GrantFiled: April 27, 1993Date of Patent: May 10, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Takashi Hayashi, Shunyo Uesugi, Hiroo Wamura
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Patent number: 5310931Abstract: This invention is to provide a novel process for the isomerization of a cycloolefin having an endo form to a cycloolefin having an exo form. The resulting isomer mixture has a novel composition, and a random copolymer produced from the above compositionally novel isomer mixture and ethylene has an excellent heat resistance and mechanical strength.Type: GrantFiled: January 10, 1992Date of Patent: May 10, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Toshihiro Sagane, Hideaki Yamaguchi, Shuji Minami, Akira Mizuno, Hiroo Wamura
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Patent number: 5308573Abstract: A method of molding a fuel tank wherein two baffle plates mounted on a blow-in are inserted in a molten parison of a thermoplastic resin surrounded by a split metal mold. The split metal mold is closed around the parison and a pressurized fluid is fed through the blow-in into the molten parison to blow-mold the fuel tank. The baffle plates, during the blow-molding, are melt-adhered onto the inner wall of the fuel tank. A blow-molded fuel tank containing two baffle plates adhered to the inner wall of the fuel tank is obtained.Type: GrantFiled: August 5, 1992Date of Patent: May 3, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventor: Sadamu Hirakawa
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Patent number: 5308816Abstract: The present invention relates to a solid catalyst composed of a specific solid catalyst component [A-1], the catalyst containing the solid catalyst and the olefin polymerization process using the solid catalyst, in which the solid catalyst component [A-1] comprises; (a-1) a particulate carrier composed of a specific oxide of a metal; (a-2) an organoaluminum oxy compound; and (a-3) a specific transition metal compound containing a specific ligand, wherein the organoaluminum oxy compound (a-2) and the transition metal compound (a-3) are supported on the particulate carrier (a-1).The catalysts are applicable to a suspension polymerization and a vapor phase polymerization, and capable of preparing spherical olefin polymers excellent in particle characteristics at high polymerization activity.Type: GrantFiled: May 29, 1992Date of Patent: May 3, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Toshiyuki Tsutsui, Ken Yoshitsugu, Kunio Yamamoto
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Patent number: 5306545Abstract: The invention provides a melt-blown non-woven fabric obtained by melt-blowing an ethylene-.alpha.-olefin copolymer having a density of smaller than 0.900 g/cm.sup.3 and a crystallinity of from 5 to 40% or by melt-blowing a resin composition which chiefly comprises said copolymer, a laminated non-woven fabric obtained by laminating as a unitary structure a dry-type non-woven fabric on the melt-blown fabric that is obtained by melt-blowing said copolymer or the resin composition which chiefly comprises said copolymer, and a cataplasm which comprises the non-woven fabric obtained by melt-blowing said copolymer or said resin composition which chiefly comprises said copolymer, a dry-type non-woven fabric laminated on said melt-blown non-woven fabric, and a medicine layer applied onto said dry-type non-woven fabric. The non-woven fabric or the laminated non-woven fabric has excellent elastic property, i.e.Type: GrantFiled: December 9, 1992Date of Patent: April 26, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Ryutaro Shirayanagi, Akimi Saeki, Kazuhiro Masumoto, Masaki Shimizu
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Patent number: 5306754Abstract: The resin composition of the invention comprises as resin components specific aromatic polyamide (A), a specific graft-modified polymer (B), an aliphatic polyamide (C), and plural antioxidants comprising a hindered phenol type antioxidant (D) having a molecular weight of not less than 500 and a TGA 10% weight loss temperature of not lower than 300.degree. C. and a sulfur type antioxidant (E) having a molecular weight of not less than 600 and a TGA 10% weight loss temperature of not lower than 280.degree. C. The connector of the invention has housing formed from the above-mentioned resin composition. The resin composition of the invention shows excellent heat resistance. The connector of the invention is lightweight and is excellent in heat resistance, water resistance and chemical resistance.Type: GrantFiled: March 17, 1993Date of Patent: April 26, 1994Assignees: Mitsui Petrochemical Industries, Ltd., Yazaki CorporationInventors: Sanehiro Yamamoto, Kazuto Sugiyama, Akinori Toyota, Yoshikatsu Amimoto, Fumitoshi Ikejiri, Tetsuo Kato, Masahiro Kanda
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Patent number: 5304606Abstract: A thermoplastic resin composition according to the present invention comprises a polymer comprising recurring units derived from a polycyclic (meth)acrylate represented by the following formula [I] and a soft polymer in the proportion by weight of the polymer to the soft polymer of 99:1 to 40:60 ##STR1## where m is 0 or a positive integer, n is 0 or 1, R is hydrogen or methyl, R.sup.1 -R.sup.18 are each independently an atom or a group selected from the group consisting of hydrogen, halogen and hydrocarbon groups, R.sup.15 -R.sup.18, linked together, may form a monocyclic or polycyclic group which may have a double bond, or an alkylidene group, p is 0 or 1, and R.sup.a and R.sup.b each independently represent a hydrogen atom or a hydrocarbon group when p is 1.Type: GrantFiled: March 15, 1993Date of Patent: April 19, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventor: Yohzoh Yamamoto
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Patent number: 5304227Abstract: An electret filter made of a resin whose angle of contact upon wetting with pure water is no smaller than 95 degrees, as well as an electret filter made of a resin whose angle of contact upon wetting with pure water has been adjusted to no smaller than 95 degrees by addition of silicone oil. Those electret filters have high trapping efficiency and their ability to trap particulates, especially cigarette smoke, will not deteriorate even if they are continuously used. Therefore, they can advantageously be used as filter media in many applications such as home and industrial air conditioners, air cleaners, fan heaters, vacuum cleaners, and air conditioning systems for common equipment.Type: GrantFiled: April 28, 1993Date of Patent: April 19, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Satoshi Matsuura, Tsuneo Kishiba, Yoshio Shinagawa
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Patent number: 5304555Abstract: This invention provides novel pyrimidines or their pharmaceutically acceptable salts thereof and process for preparation thereof. The novel compounds are useful for neurological diseases of the peripheral and central nervous systems of animals.Type: GrantFiled: October 19, 1990Date of Patent: April 19, 1994Assignees: Mitsui Petrochemical Industries, Ltd., Mitsui Pharmaceuticals, Inc.Inventors: Akira Awaya, Kazutoshi Horikomi, Tadayuki Sasaki, Hisashi Kobayashi, Akira Mizuchi, Takuo Nakano, Ikuo Tomino, Shintaro Araki, Mitsuyuki Takesue, Koji Kato, Keiichi Yokoyama
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Patent number: 5304596Abstract: Polyolefin resin compositions having a sea and island structure wherein cycloolefin resin, graft modified cycloolefin resin and graft modified elastomer components are finely dispersed in polyamide by melt kneading the cycloolefin resin, graft modified cycloolefin resin, graft modified elastomer and polyamide. Molded products formed by using the polyolefin resin compositions of the present invention are high in impact strength and surface characteristics, particularly less in surface delamination, and also excellent in surface glossiness. The molded products are low in water absorption properties and also excellent in oil resistance.Type: GrantFiled: May 23, 1991Date of Patent: April 19, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Satoru Moriya, Akio Ishimoto, Mamoru Takahashi
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Patent number: 5302463Abstract: According to the present invention, there is provided a thermoplastic elastomer laminate which comprisesa layer comprising a thermoplastic elastomer (A) composed of a crystalline polyolefin and a rubber, anda layer comprising an ultra-high molecular weight polyolefin (B) or an ultra-high molecular weight polyolefin composition.In addition, a glass run channel composed of the thermoplastic elastomer laminate is also provided in the invention.Type: GrantFiled: April 22, 1992Date of Patent: April 12, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Kazuhiko Murata, Norishige Murakami, Kyooji Muraoka, Noboru Sakamaki
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Patent number: 5302453Abstract: In accordance with the present invention, there are provided high molecular weight polyethylene molecular orientation molded articles formed from high molecular weight polyethylenes having a weight average molecular weight of 300,000-600,000, said molecular orientation molded articles having a fineness of not more than 15 deniers, a tensile strength of more than at least 1.7 GPa and satisfying the tensile strength S (GPa)-weight average molecular weight M. (g/mol)-fineness D (denier) relationship represented by the formula [I] ##EQU1## and processes for preparing the same. Further in accordance with the present invention, there are also provided high molecular weight polyethylene molecular orientation molded articles formed from high molecular weight polyethylene having a weight average molecular weight of exceeding 600,000 and satisfying the relationship represented by the formula [II].Type: GrantFiled: May 28, 1993Date of Patent: April 12, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Yasuo Kouno, Yuichi Itoh, Kazuo Yagi
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Patent number: 5300352Abstract: The laminate of the invention comprises a substrate and a resin surface layer having a glossiness of not less than 60% when measured at an incidence angle of 60.degree. laminated on at least one side surface of the substrate, and the substrate is formed from at least one cycloolefin polymer (A) selected from the group consisting of a random copolymer (a-1) of specific cycloolefin and ethylene, a ring opening polymer (a-2) of specific cycloolefin, a ring opening copolymer (a-3) of specific cycloolefin and a hydrogenation product (a-4) of the ring opening polymer or the ring opening copolymer, or formed from a cycloolefin resin composition (B) comprising the cycloolefin polymer (A) and crystalline polyolefin and/or an .alpha.-olefin elastomeric copolymer. The substrate shows excellent resistance to flon gas, so that the resin surface layer is effectively prevented from occurrence of cracks caused by influence of flon gas.Type: GrantFiled: June 11, 1992Date of Patent: April 5, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventor: Shiro Honma
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Patent number: 5300558Abstract: A curable resin composition comprising:(A) a compound having at least one curable acrylic radical, methacrylic radical or vinyl radial, or a mixture thereof;(B) an organic solvent containing an alcoholic organic solvent with an amount of not less than 40% by weight;(C) a compound having at least one pentavalent P with phosphoryl bonding; and(D) a polymerization initiator whichwhen coated on the surface of molded inorganic or organic materials, the coating shows superiority in curing under atmosphere and the cured composition has excellent adhesion, surface hardness, resistance to scratch, resistance to abrasion, surface luster, transparency and antistatic property.Type: GrantFiled: April 3, 1992Date of Patent: April 5, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Masayoshi Kurisu, Koji Utaka, Hajime Inagaki, Suguru Tokita, Kazuyuki Miyamoto, Yukari Hattori, Noriyuki Murakoshi, Tsutomu Saito
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Patent number: 5300581Abstract: A process for producing a thermoplastic elastomer having excellent elasticity even with a small rubber content and being excellent in strength, coatability and thermal adhesion to different materials such as various resins, metals or the like, which comprises melting and kneading a material mixture containing (A) particles of a polymer composed of a crystalline olefin polymer portion and a noncrystalline olefin polymer portion, (B) a graft-modifier and (C) a radical initiator to form a graft-modified and crosslinked thermoplastic elastomer having a cyclohexane-insoluble content of at least 40% by weight; and a thermoplastic elastomer obtained by the above method.Type: GrantFiled: October 18, 1991Date of Patent: April 5, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Yasuhiko Otawa, Katsuo Okamoto, Mamoru Kioka, Takashi Ueda
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Patent number: 5301183Abstract: Information recording discs comprise a disc substrate having a recording layer on one side thereof, one hub having an insertion portion to be inserted into a center hole of the disc substrate and a flange portion to cover the disc substrate in the vicinity of the center hole, at least an apex of the insertion portion being composed of a magnetic material, the hub being inserted into the center hole so that the flange portion is positioned on the recording layer side of the disc substrate, and an adhesive layer is provided between the flange portion and the disc substrate. By this construction, a portion of the hub which protrudes from the back surface of the disc substrate, facing toward the spindle of a turn table can be altered in dimension and/or the diameter of the protrusion portion of the hub can be made smaller than that of the center hole of the disc substrate.Type: GrantFiled: December 31, 1992Date of Patent: April 5, 1994Assignee: Mitsui Petrochemical Industries Ltd.Inventors: Takeshi Minoda, Masayoshi Kurisu
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Patent number: 5298551Abstract: The present invention provides a vinyl chloride resin composition having an elevated heat distortion temperature, comprising]I[ [A] a vinyl chloride resin, and[II] [B] cycloolefin ring opening polymer or copolymer formed by ring opening polymerization of a cycloolefin represented by the formula [I], or a hydrogenated product thereof, and/or[C] a cycloolefin random copolymer of ethylene and a cycloolefin represented by the formula [I], said copolymer having an intrinsic viscosity [.eta.], as measured in decalin at 135.degree. C., of 0.05 to 10 dl/g and a glass transition temperature Tg of at least 70.degree. C., ##STR1## wherein n is 0 or 1, and m is 0 or a positive integer.Type: GrantFiled: April 28, 1992Date of Patent: March 29, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventor: Youzo Yamamoto
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Patent number: 5296580Abstract: A film for stretch packaging comprising as a substrate a film of a linear low density polyethylene having a melt flow rate (190.degree. C.), as measured by an ASTM-D-1238E method, of 0.3 to 8 g/10 min., a density, as measured by an ASTM-D-1505 method, of 0.900 to 0.918 g/cm.sup.3, a molecular weight distribution (Mw/Mn) of 2 to 6, two or more melting points existing as measured by a differential scanning calorimeter, a maximum melting point Tm.sub.1 of 118.degree. to 125.degree. C. and a ratio of the height Tm.sub.1 H of the peak of the highest melting point Tm.sub.1 to the height Tm.sub.1 H of the melting point Tm.sub.2 adjacent thereto (i.e., Tm.sub.1 H/Tm.sub.2 H), of 1.3 or less.Type: GrantFiled: July 28, 1993Date of Patent: March 22, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Takashi Matsunaga, Keiichi Miura
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Patent number: 5296565Abstract: A solid catalyst for olefin polymerization comprising[A] a particulate carrier composed of (i) an oxide of at least one element selected from among those belonging to the groups of II, III and IV of the periodic table, and containing (ii) at least 1.0 % by weight of water,[B] an organoaluminum oxy compound, and[C] a transition metal compound of a metal belonging to the group IV B of the periodic table containing a ligand having a cyclopentadienyl skeleton,wherein the organoaluminum oxy compound [B] and the transition metal compound [C] are supported on the particulate carrier [A].Type: GrantFiled: April 2, 1993Date of Patent: March 22, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Takashi Ueda, Okawa Kazunori