Patents Assigned to Mitsui Toatsu Chemical, Inc.
  • Patent number: 5525682
    Abstract: A process for preparing a novel superabsorbent polymer which is readily hydrolyzed and conform to environment by reacting a polysuccinimide with a diamine in an aqueous solution or an organic solvent to partially crosslink the polysuccinimide, and subsequently or concurrently hydrolyzing the remaining imide ring with an alkali while controlling the pH; and the superabsorbent polymer thus obtained.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: June 11, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Akinori Nagatomo, Hiroaki Tamatani, Masanobu Ajioka, Akihiro Yamaguchi
  • Patent number: 5525704
    Abstract: Disclosed is an aromatic diamine compound represented by the formula (I) ##STR1## wherein R is H or CH.sub.3. Also disclosed is a bismaleimide compound represented by the formula (IV) ##STR2## wherein R is H or CH.sub.3, A resin forming composition comprising these compounds is also disclosed. The compounds are useful as raw materials for resins, and the resin forming composition and the resin can provide excellent heat resistance and impact resistance and low hygroscopicity.
    Type: Grant
    Filed: October 24, 1995
    Date of Patent: June 11, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Shoji Tamai, Norimasa Yamaya, Masahiro Ohta, Akihiro Yamaguchi
  • Patent number: 5525686
    Abstract: A process for preparing a polyvalent metal salt of a salicylic acid resin which comprises the steps of reacting salicylic acid or its derivative with styrene or its derivative at a temperature of -20.degree. C. or higher but lower than 40.degree. C. in the presence of sulfuric acid, and then reacting the resulting reaction product with a polyvalent metal compound; an aqueous dispersion in which the polyvalent metal salt of the resin is dispersed in water; and a developing sheet in which the polyvalent metal salt of the salicylic acid resin is used.
    Type: Grant
    Filed: December 13, 1994
    Date of Patent: June 11, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Yoshimitsu Tanabe, Jotaro Kida, Kiyoharu Hasegawa, Masakatsu Nakatsuka, Masayuki Furuya, Takeshi Nishimura
  • Patent number: 5525675
    Abstract: Described is a thermoplastic elastomer comprising (A) 10-90 wt. % of polypropylene having substantially a syndiotactic structure, and (B) 90-10 wt. % of an ethylene-propylene-nonconjugated diene copolymer rubber and/or ethylene-propylene copolymer rubber, said (B) having been partially crosslinked. The elastomer according to the present invention is useful for obtaining formed products, particularly automotive bumper fascias, automotive mud guards and automotive trim skin material, which are excellent not only in flexibility, rubber elasticity and mechanical strength but also in external appearance and touch, and are substantially free from bleeding and fogging.
    Type: Grant
    Filed: March 23, 1994
    Date of Patent: June 11, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Kazuhiko Masuda, Sachio Yokote, Masatoshi Kumagai
  • Patent number: 5525684
    Abstract: A phenolic resin composition comprises a mixture of 100 parts by weight of a phenol aralkyl resin and 5 to 60 parts by weight of a novolak type phenolic resin having a content of binuclear components of not more than 10% by area, and a content of trinuclear components of not less than 50% by area and a sum content of tri- and tetra-nuclear components of 75% by area based on the total novolak phenolic resin except for the binuclear components, and an epoxy-cured product obtained by curing an epoxy resin while using the phenolic resin composition as set forth in claim 1 as a curing agent. The phenolic resin composition has a low viscosity and, when it is used as a curing agent for epoxy resins, the resulting epoxy-cured product has a low water absorption rate, is excellent in resistance to moisture and has a high glass transition temperature as compared with the cured product obtained using a novolak type phenolic resin as a curing agent.
    Type: Grant
    Filed: January 20, 1995
    Date of Patent: June 11, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tomoyuki Kawabata, Shigeru Iimuro, Teruo Yuasa
  • Patent number: 5523467
    Abstract: A process is provided for the preparation of an aliphatic polyisocyanate. Upon reacting an aliphatic polyamine or its hydrochloride or carbonate with phosgene in an inert liquid medium, the reaction is conducted while charging an inert gas into a reaction system.
    Type: Grant
    Filed: March 10, 1995
    Date of Patent: June 4, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Koju Okazaki, Yoshinobu Kanemura, Teruyuki Nagata
  • Patent number: 5521085
    Abstract: The present invention relates to human monoclonal antibodies capable of plurally binding with O-antigens of Pseudomonas aeruginosa, relates to novel parent cell lines for producing human hybridomas derived from human immunoglobulin synthesizing cells, which cell lines themselves incapable of producing human immunoglobulin and capable of fusing with human antibody-producing cells, relates to human-human hybridomas which can secrete monoclonal antibodies capable of binding with at least one of serotypes of Pseudomonas aeruginosa, relates to pharmaceutical compositions for prophylaxis or therapy of Pseudomonas aeruginosa infectious diseases, and relates to prophylactic or therapeutic methods for Pseudomonas aeruginosa infectious diseases.
    Type: Grant
    Filed: April 1, 1993
    Date of Patent: May 28, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tamotsu Fukuda, Yasushi Ono, Shiro Shigeta, Yasuyuki Kuriowa, Hisayoshi Ooka
  • Patent number: 5516837
    Abstract: A molding resin composition comprising 99.9 to 50% by weight of polyimide represented by the formula: ##STR1## and 0.1 to 50% by weight of polyether ketone resin and/or polyester resin, and more particularly comprising the polyester resin capable of forming an anisotropical molten phase at a temperature of 420.degree. C. or less, and a polyimide-based molding resin composition which comprises the said resins and other additives such as phenolic resin, fluororesin, graphite, carbon fibers, aromatic polyamide fibers, potassium titanate fibers and a crystallization accelerator, and is excellent in thermal resistance, chemical resistance, mechanical strength and processability.
    Type: Grant
    Filed: March 2, 1994
    Date of Patent: May 14, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Toshihiko Tsutsumi, Toshiyuki Nakakura, Toshiaki Takahashi, Atsushi Morita, Yoshihisa Gotoh, Hiroyasu Oochi
  • Patent number: 5514793
    Abstract: The present invention relates to 1,3,6-Trialkylhexahydro-1,3,6-triazocine-2-on represented by the formula (1): ##STR1## wherein R is a C.sub.1 .about.C.sub.8 alkyl group and a preparation process of the compound comprising reacting N,N',N"-trialkyldiethylenetriamine represented by the formula (2): ##STR2## wherein R is a C.sub.1 .about.C.sub.8 alkyl group, with urea, phosgene or carbon dioxide.
    Type: Grant
    Filed: February 17, 1995
    Date of Patent: May 7, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Hiroshi Naruse, Hideki Mizuta, Shinichi Umeda, Teruyuki Nagata
  • Patent number: 5514448
    Abstract: A molding obtained by laminating resinous plates of 0.05 to 1 mm thick, prepared by impregnating 20% by volume or more of a reinforcing fiber with a thermoplastic resin, and molding the resultant laminate, wherein sections where deviation or deformation is caused by an external force, or preferably nonjoining parts having an area of 5 to 60% based on the area of the location where impact is absorbed, are provided between the laminated layers constituting the molding, or the laminated layer surface where the impact is absorbed is formed with a shape having a curvature of 5 to 20 mm in radius. The molding absorbs impact force significantly and prevents efficiently human body, etc. from the shock upon striking.
    Type: Grant
    Filed: July 19, 1993
    Date of Patent: May 7, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Satoru Kishi, Toshiyuki Nakakura, Hiroshi Tanabe, Hideo Sakai
  • Patent number: 5514748
    Abstract: A molding resin composition comprising 99.9 to 50% by weight of polyimide represented by the formula: ##STR1## and 0.1 to 50% by weight of polyether ketone resin and/or polyester resin, and more particularly comprising the polyester resin capable of forming an anisotropical molten phase at a temperature of 420.degree. C. or less, and a polyimide-based molding resin composition which comprises the said resins and other additives such as phenolic resin, fluororesin, graphite, carbon fibers, aromatic polyamide fibers, potassium titanate fibers and a crystallization accelerator, and is excellent in thermal resistance, chemical resistance, mechanical strength and processability.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 7, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Toshihiko Isutsumi, Toshiyuki Nakakura, Shuichi Morikawa, Katsunori Shimamura, Toshiaki Takahashi, Atsushi Morita, Nobuhito Koga, Akihiro Yamaguchi, Masahiro Ohta, Yoshihisa Gotoh, Masaki Amano, Hiroyasu Oochi, Kayako Ito
  • Patent number: 5512653
    Abstract: A preparation process of polyhydroxycarboxylic acid having an inherent viscosity of 0.3 dl/g or more by dehydrating polycondensation of lactic acid containing hydroxycarboxylic acid in an organic solvent in the presence or absence of a catalyst, comprising using a hydroxycarboxylic acid raw material which comprises one or more impurities selected from the group consisting of methanol, ethanol, acetic acid, pyruvic acid, fumaric acid, methyl lactate, ethyl lactate and butyl lactate in a total amount of 0.3% by mole or less for the amount of said hydroxycarboxylic acid raw material.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 30, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masahiro Ohta, Shoji Obuchi, Yasunori Yoshida
  • Patent number: 5508377
    Abstract: This invention relates to a novel polyimide or polyimide copolymer having excellent heat resistance and greatly improved processability, and has a novel aromatic diamino compound used for the polyimide, a preparation process thereof, a polyimide-based resin composition comprising the polyimide or polyimide copolymer and a fibrous reinforcement, a process for preparing the resin composition, an injection molded article of the resin composition.The polyimide comprise a requisite structural unit having one or more recurring structural units of the formula: ##STR1## wherein L is an oxygen atom, carbonyl, isopropylidene or hexafluoroisopropylidene, and X is ##STR2## and Ar is a tetravalent radical having 6 to 27 carbon atoms and being selected from the group consisting of a monoaromatic radical, condensed polyaromatic radical and noncondensed polyaromatic radical having aromatic radicals connected to each other with a direct bond or a bridge member.
    Type: Grant
    Filed: December 13, 1994
    Date of Patent: April 16, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Wataru Yamashita, Yuichi Okawa, Shoji Tamai, Akihiro Yamaguchi
  • Patent number: 5506291
    Abstract: A fatigue-resistant polyimide resin composition comprising 100 parts by weight of polyimide having from 0.5 (exclusive) to 1.0 (inclusive) mole ratio of recurring structural units represented by the formula (1) and from 0 (inclusive) to 0.5 (exclusive) mole ratio of recurring structural units represented by the formula (2): ##STR1## wherein X is ##STR2## in the formulas (1) and (2), and having an inherent viscosity of 0.45 dl/g or more; and 5.about.65 parts by weight of a carbon fiber, glass fiber, aromatic polyamide fiber and/or potassium titanate fiber, and an injection molded article having a high fatigue resistance.
    Type: Grant
    Filed: October 12, 1994
    Date of Patent: April 9, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Yuichi Okawa, Yoshihiro Sakata, Wataru Yamashita, Katsuaki Iiyama, Shoji Tamai, Akihiro Yamaguchi
  • Patent number: 5506304
    Abstract: A process for continuously preparing rubber modified styrene resins from styrene monomers and acrylonitryle monomers in the presence of a rubbery polymer in accordance with a continuous mass and/or solution polymerization method by the use of serial polymerization device comprising two or more reactors; said process comprising(1) a first step of feeding a polymeric materials to the first reactor to carry out the polymerization of monomers in a condition where the rubbery polymer is not inverted to the dispersed phase, and a second step of adding a polymeric materials to second reactors to carry out the polymerization of the monomers and to thus invert the rubbery polymer to the dispersed phase,(2) a ratio of the added materials to the materials used in the first step being in the range of from 10 to 220% by weight,whereby impact resistance and surface gloss can be remarkably improved.
    Type: Grant
    Filed: June 24, 1994
    Date of Patent: April 9, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Shiro Otsuzuki, Mune Iwamoto, Akihiko Nakajima, Masato Takaku, Hisao Morita, Takao Kobayashi, Toshihiko Ando
  • Patent number: 5506311
    Abstract: In one aspect, the present invention relates to polyimides having excellent thermal resistance and process for preparing the same comprising carrying out condensation of 4,4'-bis(3-aminophenoxy)biphenyl with pyromellitic dianhydride in the presence of a different diamine compound and optionally with a different tetracarboxylic acid dianhydride.In a second aspect, the present invention relates to a heat resistant resin composition consisting essentially of an aromatic polyetherimide and a defined polyimide.In a third aspect, the present invention relates to a polyimide resin composition comprised on a defined polyimide and a separate high-temperature engineering polymer.In a fourth aspect, the present invention relates to a resin composition comprised of a defined polyimide and an aromatic polyamideimide.
    Type: Grant
    Filed: November 3, 1994
    Date of Patent: April 9, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Shoji Tamai, Masahiro Ohta, Saburo Kawashima, Katsuaki Iiyama, Hideaki Oikawa, Akihiro Yamaguchi
  • Patent number: 5506269
    Abstract: The present invention discloses a parasiticide comprising, as the active ingredient, at least one natural or synthetic pyrethroid type compound.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: April 9, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Kazutomi Ohnuma, Masahiko Nakamura, Takashi Fujita, Takatoshi Udagawa
  • Patent number: 5496923
    Abstract: A purification process of an aliphatic polyester prepared in the presence of a catalyst from a hydroxycarboxylic acid or a cyclic ester of a hydroxycarboxylic acid, or a combination of an aliphatic polyhydric alcohol with an aliphatic polybasic acid, or a mixture of these compounds, comprising deactivating the catalyst while maintaining the aliphatic polyester in a molten or dissolved state, or insolubilizing and separating the catalyst and successively removing low molecular compounds. The process can provide aliphatic polyester which has a low content of unreacted monomers and low molecular weight compounds and is excellent in heat resistance and weatherability.
    Type: Grant
    Filed: September 14, 1994
    Date of Patent: March 5, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Hiroshi Suizu, Masatoshi Takagi, Masanobu Ajioka, Akihiro Yamaguchi
  • Patent number: 5496713
    Abstract: A human growth hormone having a molecular weight of 20,000 daltons can be effectively secreted and produced in the periplasm of Escherichia coli by constructing a human growth hormone secretion plasmid comprising a vector DNA replicable in E. coli and a DNA fragment including a promoter, a ribosome binding site, a secretion signal coding region, which are all those of the neutral protease gene of B. amyloliquefaciens and a gene encoding 20 kD hGH placed just downstream from the secretion signal coding region; introducing the said plasmid into E. coli; and culturing the resultant transformed cells.
    Type: Grant
    Filed: September 9, 1993
    Date of Patent: March 5, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masaru Honjo, Setsuo Yoshino, Akira Nakayama, Naokazu Naito
  • Patent number: 5494737
    Abstract: A ceiling material for vehicles, said ceiling material comprises:a core material (11) composed of a resin foamed article;a protective layer (12) comprising a thermoplastic resin blended with fibers in a range of not less than 40% and not more than 80% in volume content;said protective layer (12) being provided on at least one surface of the core material (11);and a thin sheet-shaped surface material (14) provided on the surface of the protective layer (12).
    Type: Grant
    Filed: December 22, 1993
    Date of Patent: February 27, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Hideo Sakai, Kojiro Motai, Satoru Kishi, Katsuyuki Morita, Hiroshi Tanabe