Patents Assigned to Mitsui Toatsu Chemicals
  • Patent number: 5173162
    Abstract: A multi-layered electrostrictive effect element comprises films or thin plates of an electrostrictive material and inner electrodes alternatively arranged in layers, the inner electrodes being formed on the entire surface of the films or thin plates of the electrostrictive material, wherein the insulating layer which insulates the inner electrodes exposed on the side end faces of the element comprises a polyimide resin having repeating units represented by the following general formula (I): ##STR1## (wherein X represents a tetravalent group selected from the group consisting of tetravalent phenyl groups; tetravalent biphenyl groups; and tetravalent polyphenyl groups in which at least one of either the phenyl or bipheny groups are bonded through at least one member selected from the group consisting of O, CO, S, CH.sub.2, C(CH.sub.3).sub.2 and C(CF.sub.3).sub.
    Type: Grant
    Filed: January 4, 1991
    Date of Patent: December 22, 1992
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Atsushi Hagimura, Mutsuo Nakajima, Kunio Nishihara, Ikuo Inage
  • Patent number: 5171468
    Abstract: Disclosed herein are a polyiscoyanate comprising a mixture of aromatic polyisocyanates represented by the general formula: ##STR1## wherein A is a phenylene group, alkylene group, alkyl-substituted phenylene group, diphenylene group, diphenyl ether group or naphthylenyl group, R.sub.1 is a halogen atom, lower alkoxy group with a carbon number of 4 or less or lower alkyl group with a carbon number of 5 or less, R.sub.1 s may be the same or different from each other and may form a ring, l is 1 or 2, m is an integer of 0-3, and n is a integer of 0-300, and a production process thereof.
    Type: Grant
    Filed: October 11, 1991
    Date of Patent: December 15, 1992
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Kiyoshi Shikai, Ryuzi Haseyama, Kouzou Hayashi, Katsuyoshi Sasagawa, Akihiro Yamaguchi
  • Patent number: 5169823
    Abstract: Disclosed herein is a method for the stabilizing treatment of a catalyst comprising washing the catalyst with hot washing water following the preparation of the catalyst, the catalyst being composed principally of chromium oxide and used in the production of chlorine by the oxidation of hydrogen chloride with an oxygen-containing gas, thereby improving its catalytic activity and prolonging its life.
    Type: Grant
    Filed: July 1, 1991
    Date of Patent: December 8, 1992
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Yukihiro Yoshikawa, Tooru Hihara, Teruo Hirayama, Kunihiro Yamada, Shinji Takenaka
  • Patent number: 5169924
    Abstract: A copolymer of propylene and butene-1, the constituent monomer units of which comprise 20-63 wt. % of propylene and 37-80 wt. % of butene-1, and which exhibits 0.5 or more in the ratio of the sum of the intensities of absorptions observed at about 20.0-21.0 ppm to the sum of the intensities of total absorptions attributable to the methyl groups in the propylene units observed at about 19.0-22.0 ppm in the .sup.13 C-NMR spectrum measured in a 1,2,4-trichlorobenzene solution and 0.05 or more in the intrinsic viscosity measured at 135.degree. C. in a tetralin solution.
    Type: Grant
    Filed: July 25, 1990
    Date of Patent: December 8, 1992
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Tadashi Asanuma, Tetsunosuke Shiomura, Tateyo Sasaki, Tutomu Iwatani, Nobutaka Uchikawa
  • Patent number: 5169971
    Abstract: The present invention relates to the production of a norcamphane dicarbonitrile and is directed to solving the problems of low conversion from the starting material, low selectivity and uneconomical production.According to the present invention, a norcamphane dicarbonitrile is produced by hydrocyanation of bicyclo [2,2,1]-5-heptene-2-carbonitrile in the presence of a zero-valent nickel complex catalyst and a Lewis acid.
    Type: Grant
    Filed: May 6, 1992
    Date of Patent: December 8, 1992
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masamitu Inomata, Naokazu Shiotani, Kazuo Koshizuka, Minato Karasawa
  • Patent number: 5168093
    Abstract: Disclosed are magenta anthraquinone dyestuffs for sublimation thermaltransfer printing of one of the formulas ##STR1## wherein R is a halogen atom, methyl or methoxy; wherein R.sub.1 is a hydrogen atom, hydroxyl, a halogen atom, alkyl of 1 to 4 carbon atoms or alkoxy of 1 to 4 carbon atoms; and wherein R.sub.2 is a hydrogen atom, a halogen atom, alkyl or 1 to 4 carbon atoms or alkoxy of 1 to 4 carbon atoms, with the proviso that in formula (3) either R.sub.1 or R.sub.2 is not a hydrogen atom.
    Type: Grant
    Filed: July 10, 1990
    Date of Patent: December 1, 1992
    Assignee: Mitsui Toatsu Chemicals Inc.
    Inventors: Keisuke Takuma, Tsukasa Ohyama, Tamio Mikoda, Isamu Ghoda, Hitoshi Koshida, Akitoshi Igata
  • Patent number: 5166271
    Abstract: A heat resistant polyvinyl chloride copolymer or a heat and impact resistant polyvinyl chloride copolymer is prepared by conducting graft copolymerization of N-substituted maleimide on a vinyl chloride resin or a rubber containing vinyl chloride resin.The graft copolymerization reaction is carried out in the presence of a radical polymerizable monomer which is (1) liquid at the polymerization temperature, (2) capable of dissolving the N-substituted maleimide at the temperature, (3) 70.degree. C. or more in glass transition temperature of the polymer thereof, and (4) used in an amount sufficient to dissolve the N-substituted maleimide.
    Type: Grant
    Filed: September 1, 1989
    Date of Patent: November 24, 1992
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Seiichi Masuko, Hideaki Takahara, Akira Yamamoto
  • Patent number: 5166068
    Abstract: Disclosed is a method of culturing protoplasts in a liquid medium. According to the method, the protoplasts are cultured in a liquid medium layer having a thickness of about 100 to about 400 .mu.m.
    Type: Grant
    Filed: May 21, 1986
    Date of Patent: November 24, 1992
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tatsuhito Fujimura, Motoi Sakurai
  • Patent number: 5166285
    Abstract: The present invention relates to a process for preparing a hard transparent resin comprising polymerizing a monomer (A) having both a functional group of the following formula (I): ##STR1## wherein X is selected from the group consisting of an oxygen atom and a sulfur atom,and a functional group selected from the group consisting of a functional group of the formula (II):CH.sub.2 CR--COO-- (II)wherein R is selected from the group consisting of hydrogen and methyl group,and a functional group of the formula (III): ##STR2## The invention also provides a process for preparing a transparent resin comprising copolymerizing monomer (A) with a monomer (B) having at least one functional group selected from the group consisting ofCH.sub.2 CH.dbd.COO--,CH.sub.2 .dbd.C(CH.sub.3)--COO--, and ##STR3## This resin can be suitably used as a glazing material, and in the manufacture of optical lenses, optical information recording medium substrates, etc.
    Type: Grant
    Filed: February 14, 1992
    Date of Patent: November 24, 1992
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Katsuyoshi Sasagawa, Yoshinobu Kanemura, Masao Imai, Toshiyuki Suzuki
  • Patent number: 5166225
    Abstract: A process for producing crosslinked polyolefins having improved physical properties is disclosed. The process comprises irradiating a copolymer of alkenylsilane and olefins, or a mixture of this copolymer and thereof with a polyolefin devoid of alkenylsilane segments.
    Type: Grant
    Filed: June 8, 1989
    Date of Patent: November 24, 1992
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Tadashi Asanuma, Kazuhiko Yamamoto
  • Patent number: 5166318
    Abstract: Modified HV1-type hirudinin which valine at the N-terminal end of the HV1-type hirudin and aspartic acid at the 5th residue of the N-terminal end were replaced with alanine and glutamic acid, respectively. A secretion plasmid into which a DNA sequence coding for a precursor with an addition of a secretion signal of neutral protease of Bacillus amyloliquefaciens at the N-terminal end of this modified HV1-type hirudin is integrated is introduced into bacteria of the genus Bacillus and the precursor is expressed intracellularly. The modified HV1-type hirudin can be efficiently secreted extracellularly while maintaining its high thrombin inhibiting activity.
    Type: Grant
    Filed: June 4, 1990
    Date of Patent: November 24, 1992
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Yoshio Furutani, Masaru Honjo, Akira Nakayama, Koichi Kawamura, Kazunori Ando, Michiko Hori, Keiko Fukazawa
  • Patent number: 5158703
    Abstract: Disclosed is a resin composition for ultraviolet luminescent screen comprising one or more of luminescent compound represented by the formula (I): ##STR1## wherein X is ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are individually a hydrogen atom, halogen atom, alkyl, alkoxy, amino, alkylamino, dialkylamino, anyl or aralkyl, and Y is perfluoroalkyl, and A.sup.+ is a cation represented by the formula (II): ##STR3## wherein R.sub.5, R.sub.6, R.sub.7 and R.sub.8 are individually a hydrogen atom, alkyl or aralkyl and may be combined with each other to form a ring, or a pyridium cation which may have a substituent, or a phosphonium cation.
    Type: Grant
    Filed: September 27, 1991
    Date of Patent: October 27, 1992
    Assignees: Mitsui Toatsu Chemicals Inc., Pioneer Electronic Corporation
    Inventors: Keisuke Takuma, Kimitoshi Kato, Shizuo Kuroda, Fumio Matsui
  • Patent number: 5159045
    Abstract: Polyisocyanato-isocyanurate and mixture of the same obtained by trimerizing straight chain aliphatic diisocyanate represented by the formula:OCN--R.sub.4 --NCOwherein R.sub.4 is an alkylene group having 2-12 carbon atoms and polycyclo-aliphatic diisocyanate represented by the formula: ##STR1## wherein k is an integer of 0 to 2, j and m are integers of 1 to 5, and h is an integer of 0 to 2; powder-paint curing agent which contains blocked isocyanate obtained by reacting the above raw materials with a blocking agent having at least one active hydrogen in a molecule; non-yellowing urathane paint resin prepared from the above raw materials and compound having at least two active hydrogen in a molecule; and paint composition comprising the curing agent and the resin; is disclosed.
    Type: Grant
    Filed: May 16, 1991
    Date of Patent: October 27, 1992
    Assignees: Mitsui Toatsu Chemicals, Inc., Shimizu Seiko Kabushiki Gaisha
    Inventors: Ryuji Haseyama, Kouzou Hayashi, Kazuyuki Kuroda, Taisaku Kano, Takayoshi Sekido, Hiroshi Nomura, Kiyoshi Shikai
  • Patent number: 5158882
    Abstract: Separation of tPA and undesired proteins is securely and effectivity accomplished by using a cation-exchanger in the two step procedure for selective elution of undesired proteins from the cation-exchanger on which tPA and undesired proteins are adsorbed: undesired proteins having the pI equivalent to or lower than that of tPA was eluted out in the first step and then undesired proteins having the pI equivalent to or higher than were eluted in the second step.
    Type: Grant
    Filed: February 28, 1992
    Date of Patent: October 27, 1992
    Assignee: Mitsui Toatsu Chemical Incorporated
    Inventors: Mitsuyoshi Morii, Nobuhiro Kawashima, Kunizo Mori, Masaharu Ohoka
  • Patent number: 5157165
    Abstract: Herein provided are a method for preparing 1,1,2,2-tetrakis(4-hydroxy-3,5-dimethylphenyl)ethane (TKXE) comprising subjecting two molecules of bis(3,5-dimethyl-4-hydroxyphenyl) methane to dehydration-condensation under oxidizing conditions, an epoxy resin prepared by epoxidating TKXE obtained by the method and an epoxy resin composition comprising TKXE obtained by the method as a hardener and an epoxy resin as well as methods for preparing the resin and composition. The method makes it possible to prepare highly pure TKXE in the form of crystals. Moreover, the epoxy resin and the epoxy resin composition can provide hardened products excellent in physical properties such as heat resistance and mechanical strength.
    Type: Grant
    Filed: November 22, 1991
    Date of Patent: October 20, 1992
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Naru Koike, Shigeru Iimuro, Mizuo Ito
  • Patent number: 5157085
    Abstract: This invention relates to molding resin compositions, and more particularly relates to polyimide resin compositions having markedly improved molding ability in addition to excellent high temperature stability, chemical resistance and mechanical strength.The polyimide resin compositions of this invention comprises 99.9 to 50.0% by weight of the polyimide and 0.1 to 50.0% by weight of polyphenylene sulfide and/or aromatic polysulfone and/or aromatic polyetherimide high-temperature engineering polymer.
    Type: Grant
    Filed: March 9, 1989
    Date of Patent: October 20, 1992
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Masahiro Ohta, Saburo Kawashima, Katsuaki Iiyama, Shoji Tamai, Hideaki Oikawa, Akihiro Yamaguchi
  • Patent number: 5157097
    Abstract: Melt moldable polyamide-imide resins are disclosed which have a glass transition temperature ranging from 120.degree. to 300.degree. C. and have molecule ends blocked with an unsubstituted aromatic group or an aromatic group having a substituent not reactive with amines, isocyanates, carboxylic acids and dicarboxylic acid anhydrides.
    Type: Grant
    Filed: August 19, 1991
    Date of Patent: October 20, 1992
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Hiroshi Takayanagi, Hirotoshi Katsuoka, Hiromi Nakano, Masumi Ookita, Akihiro Yamaguchi, Masahiko Asano
  • Patent number: 5157130
    Abstract: A monochloro-substituted aliphatic alcohol containing 3-8 carbon atoms, a copper compound and a zinc compound are added to maleic anhydride to prevent discoloration of the maleic anhydride. Deterioration of the quality of the maleic anhydride can be inhibited when it is stored for a long period of time or heat-melted.
    Type: Grant
    Filed: June 20, 1990
    Date of Patent: October 20, 1992
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Harusige Sugawara, Takasi Ohkawa
  • Patent number: 5157092
    Abstract: A polymer of 4-methylpentene-1 having a substantially syndiotactic structure, which polymer contains 0 to 30 mol % of the .alpha.-olefin unit other than the 4-methylpentene-1 unit and has excellent physical properties.
    Type: Grant
    Filed: June 11, 1990
    Date of Patent: October 20, 1992
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Tadashi Asanuma, Tetsunosuke Shiomura, Nobutaka Uchikawa, Yukari Tamai, Tateyo Sasaki, Tutomu Iwatani
  • Patent number: 5155191
    Abstract: By dispersing and polymerizing at least one N-alkyl-or N-alkylene-substituted (meth)acrylamide or a mixture of at least one N-alkyl- or N-alkylene-substituted (meth)acrylamide and other copolymerizable monomer is an aqueous inorganic salt solution having inorganic particulates suspended, there is provided a preparation process of granular polymers containing no impurities such as polymer stabilizers, surface active agents, etc. The granular polymers are useful as concentrating agents, slow releasing base materials, etc.
    Type: Grant
    Filed: February 14, 1992
    Date of Patent: October 13, 1992
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Hiroshi Itoh, Takashi Abe, Kouji Ohkoshi, Atsuhiko Nitta