Abstract: The present invention relates to quinoline-4-carbonylguanidine derivative represented by formula (1) ##STR1## and pharmaceutically acceptable salt thereof, a process for producing the same, and a Na.sup.+ /H.sup.+ exchanger inhibitor containing the compound as an active ingredient. The compounds of the present invention are useful as an agent for treating or preventing various diseases by hyperfunction of the Na.sup.+ /H.sup.+ exchanger and as a diagnostic agent for these diseases.
Abstract: The present invention provides an aqueous gel comprising a polymer of (meth)acrylamide or particular (meth)acrylamide derivative(s), particulate metal oxide(s) and an aqueous medium, a process for producing said gel, and products utilizing said gel.This aqueous gel can be produced so as to have transparency, has fire resistance and can prevent the spreading of flames, and is highly elastic. The aqueous gel, when produced as a transparent gel, becomes cloudy when heated or cooled and is useful for the shielding of heat rays or cold radiation.
Abstract: A fiber excellent in strength and having an average size of 10,000-0.1 denier can be obtained by extruding a new material composed mainly of a polypropylene having a syndiotactic pentad fraction of 0.7 or more and optionally stretching the resulting extruded material. By using as the raw material a composition consisting of two kinds of polypropylenes each having an intrinsic viscosity .eta..sub.1 or .eta..sub.2, the log(.eta..sub.2 /.eta..sub.1) being more than 0.05 or less than -0.05, and a syndiotactic pentad traction of 0.7 or more at a weight ratio of 95:5-5:95 or a composition consisting of at least 50 parts by weight of a syndiotactic polypropylene having the intrinsic viscosity .eta..sub.1 and a syndiotactic pentad fraction of 0.7 or above and at most 50 parts by weight of an isotactic polypropylene having the intrinsic viscosity .eta..sub.2, the extrudability is improved and the fiber stretching conditions are broadened.
Abstract: Disclosed herein is a process for the preparation of alkylsilanes and alkenyl silanes by hydrosilylation of their corresponding silanes and unsaturated hydrocarbons in the presence or absence of a catalyst, a process for the preparation of polyalkenylsilanes (some of which are high molecular compounds) by the anionic coordination polymerization, radical polymerization or ionic polymerization of the alkenylsilanes, and a process for the production of silicon carbide by using these polyalkenylsilanes as prepolymers.
Abstract: An allyletherificated phenol aralkyl resin is obtained through the reaction of a phenol aralkyl resin with an allyl halide in the presence of a base in an organic solvent at room temperature to 100.degree. C. and changed into an allylated phenol aralkyl resin at 160.degree.-250.degree. C. through Claisen rearrangement. The two resins are low in melt viscosity. Epoxy resin compositions containing the allylated phenol aralkyl resin as the curing agent give cured products being excellent in heat and moisture resistances.
Abstract: The present invention is concerned with a novel azo compound represented by formula (1), (2) or (3), a water-soluble dye comprising this azo compound, and a polarizing film containing this azo compound. The obtained polarizing film has high hydrothermoresistance and a high polarization degree and is excellent in optical characteristics: ##STR1## wherein each of R.sub.1, R.sub.3 and R.sub.12 is independently a hydrogen atom, halogen atom, hydroxyl group, alkyl group having 1 or 2 carbon atoms, or alkoxy group having 1 or 2 carbon atoms; each of R.sub.2, R.sub.4, R.sub.8 and R.sub.9 is independently a hydrogen atom, hydroxyl group, alkyl group having 1 or 2 carbon atoms, alkoxy group having 1 or 2 carbon atoms, or acetylamino group; R.sub.5 is a hydroxyl group or amino group at the o-position or p-position to the azo group; each of R.sub.6 and R.sub.10 is a hydrogen atom, carboxyl group, or alkoxy group having 1 or 2 carbon atoms; each of R.sub.7 and R.sub.
Abstract: Disclosed are (1) a method for preparing an aromatic secondary amino compound which comprises reacting an N-cyclohexylideneamino compound in the presence of a hydrogen moving catalyst and a hydrogen acceptor by the use of a sulfur-free polar solvent and/or a cocatalyst, and(2) a method for preparing an aromatic secondary amino compound which comprises reacting cyclohexanone or a nucleus-substituted cyclohexanone, an amine and a nitro compound corresponding to the amine in a sulfur-free polar solvent in the presence of a hydrogen moving catalyst, a cocatalyst being added or not added. In a further aspect, a method is provided for the preparation of aminodiphenylamine by reacting phenylenediamine and cyclohexanone in the presence of a hydrogen transfer catalyst in a sulfur-free polar solvent while using nitroaniline as a hydrogen acceptor.
Abstract: A process for the continuous preparation of aniline by hydrogenating nitrobenzene with hydrogen is disclosed which comprises the steps of suspending, in an aniline solvent, a catalyst of palladium or palladium-platinum which is deposited on a lipophilic carbon having an oil absorbency of at least 100, and carrying out reaction at a temperature of from 150.degree. to 250.degree. C. substantially in the absence of water while aniline and water formed in said reaction are continuously distilled off as vapor from the reaction product, and the concentration of nitrobenzene in the reaction solution is maintained at 0.01% by weight or less, wherein a zinc compound is added to the reaction system as a promotor and carbon monoxide is added to the hydrogen at a concentration of 1-500 ppm.
Abstract: A purification process for polyhydroxycarboxylic acids which comprises dissolving polyhydroxycarboxylic acid in an water-immiscible phenol or an organic solvent containing said water-immiscible phenol, successively bringing the resulting solution into contact with water which contains an acidic material, separating the organic layer from an aqueous layer, and isolating polyhydroxycarboxylic acid from the organic layer. The process can efficiently remove a catalyst contained in the polyhydroxycarboxylic acid prepared in the presence of the catalyst, does not require polyhydroxycarboxylic acid to be in the form of a solid, and can treat polyhydroxycarboxylic acid in a higher concentration as compared with using chlorinated hydrocarbon as a solvent.
Abstract: A tetrahydrofuran-compound is disclosed herein which is represented by the formula (1) ##STR1## wherein each of X.sub.1 and X.sub.2 is a hydrogen atom or a methyl group, Y is a hydrogen atom or a carbonyl group substituted by a lower alkyl group (Y') having 1 to 4 carbon atoms, i.e., an acyl group (--COY'), andn is 2 or 3,and an insecticide containing the tetrahydrofuran-compound as an effective component.
Abstract: There is provided a process for reacting water and olefin such as ethylene or propylene under mild conditions in the presence of a polyorganosiloxane contaminating sulfonic acid groups to produce alcohol corresponding to the olefin with high yield and selectivity.
Abstract: A novel polythiol having four or more functional groups, a process for producing the polythiol comprising reacting thiourea with a specific compound, a sulfur-containing urethane-based resin prepared from the polythiol and a lens made of the resin. The resin has a high refractive index, and low dispersion of refractive index, is lightweight, colorless and transparent, has no optical distortion, and has excellent characteristics in weatherability, dye-affinity, heat resistance, impact resistance and machinability.
Type:
Grant
Filed:
January 17, 1995
Date of Patent:
March 4, 1997
Assignee:
Mitsui Toatsu Chemicals, Inc.
Inventors:
Koju Okazaki, Yoshinobu Kanemura, Teruyuki Nagata
Abstract: Upon subjecting trimethylamine with ammonia and optionally, a methylamine to a disproportioning reaction to reduce the proportion of the trimethylamine, use of a zeolite as a catalyst, said zeolite being mordenite, clinoptilolite or the like at least 80% of whose ion-exchangeable cations being in the form of hydrogen ions, makes it possible to efficiently conduct the reaction at a low reaction temperatures and also to suppress by-production of impurities such as acetonitrile.
Abstract: Described is a detection method of a pyrethroid compound which comprises providing a first antibody against the pyrethroid compound, said first antibody having been obtained by immunizing a responder with an immunogen which is a first conjugate between a first carrier and a first haptenic compound represented by the following formula (1) or (2): ##STR1## mixing the first antibody with the sample solution, causing any unreacted portion of the first antibody to be bound on a second conjugate as a coated antigen, said second conjugate being formed of a second carrier and a second haptenic compound and having been coated on a surface of a solid phase carrier, whereby an antigen-antibody conjugate is obtained; andreacting the antigen-antibody conjugate with a second antibody against the first antibody, said second antibody having a labelled enzyme linked therewith.
Abstract: Aminoketone derivative compounds containing a heterocyclic ring bonded to an aminoketone moiety and useful as effective ingredients of centrally acting muscle relaxants and pollakiurea curing agents.(+)3-phenyl-5-[2-(1-pyrrolidinylmethyl)butyryl] isoxazole, which has a more remarkable central muscle relaxant action as compared with its racemic modification, can be effectively separated from the racemic modification using optically active 10-camphorsulfonic acid as the agent for the optical resolution.
Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
Abstract: A process for the preparation of alkylsilanes and alkenyl silanes by hydrosilylation of their corresponding silanes and unsaturated hydrocarbons in the presence or absence of a catalyst. A process for the preparation of polyalkenylsilanes (some of which are novel high molecular compounds) by the anionic coordination polymerization, radical polymerization or ionic polymerization of the alkenylsilanes. A process for the production of silicon carbide by using these polyalkenylsilanes as prepolymers.
Abstract: One aspect of the present invention relates to a process for preparing plastic lenses having a high-refractive index comprising forming a mixture containing one or more polyisocyanate compounds; one or more active hydrogen compounds selected from the group consisting of a polyol compound having no sulfur atom, a polyol compound having at least one sulfur atom, and a polythiol compound having at least one sulfur atom in addition to the sulfur atom contained in mercapto group and at least one internal releasing agent and then casting and polymerizing the mixture.
Abstract: A holding container which is made of a polyether ether ketone resin and is suitable for use in holding one or more substrates upon fabrication of the corresponding number of thin-film semiconductor substrates useful in driving a planar display, for example, a liquid crystal display.
Abstract: A novel bis-urea compound, preparation process of the compound, and preparation process of 1,3-dialkyl-2-imidazolidinone are disclosed and the disclosure provides a novel preparation process of 1,3-dialkyl-2-imidazolidinone and simultaneously enables effective utilization of N,N',N"-trialkyldiethylentriamine which lacks a large amount use and is desired to develop new application.