Abstract: Apparatus for the manufacture of an ultra-high molecular weight polyethylene thin-wall pipe which is uniform in thickness and free from a folded mark. The ultra-high molecular weight polyethylene thin-wall pipe is manufactured by supplying ultra-high molecular weight polyethylene into and melting and kneading, continuously extruding the molten substance of the ultra-high molecular weight polyethylene from a die connected to a screw of the screw extruder to form a cylindrical roughly shaped article, and diametrically expanding the cylindrical roughly extruded article by a tapered core and taking up.
Abstract: There is disclosed a resin composition containing graft copolymer having at least one isocyanate group and 10,000 to 20,000 of number-average molecular weight or high-molecular-weight polymer having at least one isocyanate group and 10,000 to 200,000 of number-average molecular weight, and low-molecular-weight polymer having or not having an isocyanate group and 500 to 8,000 of number-average molecular weight is disclosed. This resin composition has tackiness at ordinary temperature, and long pot life. It can be used to reactive hot melt type adhesives (which can omit hot press process), reactive hot melt type pressure-sensitive adhesives, or coating material.
Abstract: This invention provides a superconducting magnetic shield and a magnetic shielding apparatus including the same, thereby accurately measuring an extremely weak magnetic field such an magnetoencephalographic waves by reducing the influence of magnetic field of the earth or magnetic noises.
Abstract: Herein disclosed are a tetravinylpyrazine compound which has high light-emitting efficiency and thermal stability and which is represented by the following general formula (1): ##STR1## wherein R represents an aromatic ring or a heterocyclic ring; X represents a hydrogen atom, an aliphatic hydrocarbon group, an alicyclic hydrocarbon group, an aromatic hydrocarbon group, a halogen atom, a hydroxyl group, an alkoxy group, a carboxyl group, an alkoxycarbonyl group, an acylamino group, a dialkylamino group, a nitro group, an acyloxy group or an acyloxycarbonyl group; a method for preparing the tetravinylpyrazine; and electroluminescent elements and non-linear optical materials using the pyrazine compound.
Abstract: High concentration-low viscosity polymer-polyols are prepared by polymerizing mixtures of acrylonitrile and styrene in polyols, which are free of any polymerizable carbon-carbon double bond, in the presence of alkyl-substituted tertiary amines. Without use, as a dispersion stabilizer, of organic compounds which have a polymerizable carbon-carbon double bond and terminal hydroxyl groups, there can be obtained polymer-polyols which have a concentration of the polymer of 33-60 wt % and a glass transition temperature of the polymer of 90.degree.-120.degree. C.
Abstract: A polymer composition substantially comprising(A) 5 to 40 weight parts of a 1-butenic polymer,(B) 95 to 60 weight parts of an inorganic filler,(C) a hydrocarbonic oil in an amount of 2 to 20 weight parts per 100 weight parts in total of the above (A) and (B), and(D) a thermoplastic resin other than 1-butenic polymers in an amount of 0 to 20 weight parts per 100 weight parts in total of the above (A) and (B).
Abstract: A polyolefin resin composition comprising (A) a polyolefin resin, (B) a graft-modified .alpha.-olefin copolymer grafted with an unsaturated carboxylic acid and its derivative, and (C) an amino group-containing compound, (D) said polyolefin resin composition containing a crosslinked structure between the amino group-containing compound (C) and the graft-modified .alpha.-olefin copolymer (B), and containing, based on 100 parts by weight of the polyolefin resin (A) and the graft-modified .alpha.-olefin copolymer (B) in total, 1 to 99 parts by weight of each of the polyolefin resin (A) and the graft-modified .alpha.-olefin copolymer (B) and 0.01 to 10 parts by weight of the amino group-containing compound (C). The polyolefin resin composition gives a crosslinked molded article having impact resistance at ordinary temperature and a low temperature.
Abstract: The catalyst for olefin polymerization of the present invention contains R.sub.k.sup.1 R.sub.l.sup.2 R.sub.m.sup.3 M(SO.sub.3 R.sup.4) (M=Zr, Ti or Hf; R.sup.1-3 =a group having a cyclopentadienyl skeleton) as a catalyst component of a transition metal compound. According to the catalyst of the invention, an olefin polymer having excellent particle properties can be prepared with high polymerization activities, and further a copolymer having a narrow composition distribution can be prepared when two or more monomers are copolymerized. Of the above-mentioned transition metal compounds, a compound represented by the following formula is a novel compound unknown so far and shows excellent catalytic properties. ##STR1## (Cp=a group having a cyclopentadienyl skeleton, X=SO.sub.3 R, a halogen atom, R, OR, NR.sub.n, S(O).sub.q R, SiR.sub.3 or P (O).sub.q R.sub.
Abstract: The propylene polymer composition of the invention comprises, as its essential components, a specific propylene polymer [A] described below and a propylene block copolymer [B]. In addition to the propylene polymer [A] and the propylene block copolymer [A], the propylene polymer composition may contain a thermoplastic elastomer [C] selected from polystyrene.polyethylene/poybutylene.polystyrene block copolymers and ethylene/.alpha.-olefin random copolymers, or may further contain an inorganic filler [D]. The propylene polymer [A] used in the invention has the following characteristic properties:(1) a boiling heptane-insoluble component is contained in said polymer in an amount of not less than 96% by weight,(2) a pentad isotacticity [M.sub.5 ] of the boiling heptane-insoluble component obtained from the following formula (1) using a .sup.13 C-NMR spectrum is in the range of 0.970 to 0.995: ##EQU1## (3) a pentad tacticity [M.sub.
Abstract: In the preparation of polyester by conducting ring-opening polymerization of a cyclic ester compound in the presence of a hydroxyl compound as a molecular weight regulator in the reaction system, the molecular weight of polyester can be accurately controlled in the desired range by previously estimating the amount of free carboxylic acid contained in the cyclic ester compound and controlling the amount of the hydroxyl compound on the basis of the estimated amount.
Abstract: A multi-shell emulsion particle of dry state structure having one or more of penetrating pore(s) connecting the surface layer of the particle with the interior of the particle and having a particle diameter of from 0.1 to 5.0.mu. preferably from 0.1 to 1.2.mu..
Abstract: The improved nonwoven fabric in an electret state is composed of monofilaments with an average fiber diameter of 0.5-100 .mu.m that are formed of a polymer composition containing no more than 1 mol % of polar groups; the fabric has a weight of 5-100 g/m.sup.2, a bulk density of 0.05-0.40 g/cm.sup.3 and an average surface charge density of at least 0.1.times.10.sup.-9 C/cm.sup.2. This nonwoven fabric is capable of efficient dust collection and its trapping ability is retained for a prolonged time even in a hot and humid condition. Also disclosed are a process for producing this nonwoven fabric, as well as a filtering and an air masking material which are composed of that nonwoven fabric.
Abstract: This invention is to offer a copper powder for solderable and conductive paints which have an improved solderability, excellent adhesion and conductivity.A copper powder for solderable and conductive paints comprising particles of green caterpillar shape is obtained by crushing particulate dendritic copper powder, and has an oil absorption value (JIS K5101) of up to 20 ml/100 g, a maximum particle diameter of up to 44 .mu.m, an average particle diameter of up to 10 .mu.m, and a hydrogen-reduction loss of up to 0.5%. A process for producing this copper powder for solderable and conductive paints comprises: preparing a copper powder comprising particles of a green caterpillar shape having an average particle diameter of up to 10 .mu.m by crushing dendritic copper powder having a maximum diameter of up to 44 .mu.
Abstract: A herbicidal composition is here disclosed which exerts an excellent herbicidal activity and which is harmless to paddy rice.A 1-[1-methyl-1-(substituted phenyl)ethyl]-4,5-dimethyl-3-(substituted phenyl)-3-pyrroline-2-one derivative represented by the formula (I) ##STR1## (wherein X is a chlorine atom, fluorine atom or bromine atom; Y is a hydrogen atom, fluorine atom, chlorine atom or methoxy group; Z is a hydrogen atom, fluorine atom, bromine atom or chlorine atom; and Q is a hydrogen atom or fluorine atom)is a novel compound, and the herbicidal composition containing this compound as a herbicidally active ingredient has the strong activity and high selectivity as the herbicidal composition for paddy fields.
Abstract: A polyimide comprising a requisite structural unit having one or more recurring structural units of the formula: ##STR1## such as the structural units of the formula ##STR2## Further, the present invention relates to a novel aromatic diamine which has a perfluoro radical and can be used as a raw material monomer of the polyimide, and a process for preparing the same.The polyimide can have an extremely low dielectric constant and is colorless, transparent and excellent in processability and heat resistance.
Abstract: A degradable container which is excellent in transparency and impact strength and can be decomposed into nontoxic water and carbon dioxide in the natural environment within a relatively short period can be obtained by using the process for molding a container of an arbitrary shape from a thermoplastic composition having polylactic acid of lactic acids or a copolymer of lactic acids and other hydroxycarboxylic acids as a main component, preforming the composition and thereafter molding the container in a temperature range from Tg to Tg+60.degree. C. on the basis of the glass transition temperature Tg of the thermoplastic polymer composition and under the condition of a draw ratio of 6 times or less.
Abstract: The catalyst for olefin polymerization of the present invention contains R.sup.1.sub.k R.sup.2.sub.l R.sup.3.sub.m M(SO.sub.3 R.sup.4) (M=Zr, Ti or Hf; R.sup.1-3 =a group having a cyclopentadienyl skeleton) as a catalyst component of a transition metal compound. According to the catalyst of the invention, an olefin polymer having excellent particle properties can be prepared with high polymerization activities, and further a copolymer having a narrow composition distribution can be prepared when two or more monomers are copolymerized. Of the above-mentioned transition metal compounds, a compound represented by the following formula is a novel compound unknown so far and shows excellent catalytic properties. ##STR1## (Cp=a group having a cyclopentadienyl skeleton, X=SO.sub.3 R, a halogen atom, R, OR, NR.sub.n, S(O).sub.q R, SiR.sub.3 or P(O).sub.q R.sub.
Abstract: Near infrared absorbers which have a molecular extinction coefficient of 200,000 or more and are represented by the formula (I) ##STR1## wherein each of Y.sup.1, Y.sup.2, Y.sup.3, Y.sup.4, Y.sup.5, Y.sup.6, Y.sup.7 and Y.sup.8 is hydrogen, an alkyl group, alkoxyl group or alkylthio group; each of A.sup.1, A.sup.2, A.sup.3, A.sup.4, A.sup.5, A.sup.6, A.sup.7 and A.sup.8 is hydrogen, halogen, a nitro group, alkyl group, aralkyl group, alkenyl group, alkynyl group, alkoxyl group, aryloxy group, alkylthio group or arylthio group; and Met represents two hydrogen atoms or a metal, are useful for the production of optical display and recording materials.
Abstract: A thermal fixing-type developer material for electrophotography comprising a propylene-.alpha.-olefin copolymer wax (A) having a number average molecular weight (Mn) in the range of from 7,000 to 12,000; a binder (B); and a colorant (C).There is provided a thermal fixing-type developer material for electrophotography which, when used as a main component for an electrostatic toner, would provide a reprographic image which exhibits good release properties upon thermal fixing, a reduced adhesion to the heated roller or the photoreceptor, no offset or contamination, and a good fixing of the fixed image, and prevent the heated roll and the photoreceptor from undergoing contamination.
Abstract: A lubricant oil for refrigerators, industrial gears, automotive engines, automotive gear oil, fibers and as a rolling lubricant oil, comprising a glycol ether carbonate represented by the general formula [I] ##STR1## wherein R.sub.1 and R.sub.2 are each independently an aliphatic group, an alicyclic group, an aromatic group and an aromatic-substituted aliphatic group each having not greater than 20 carbon atoms. R.sub.3 and R.sub.4 are each independently an ethylene group or an isopropylene group, and m and n are each independently an integer of 2 to 100, and optionally containing ozone layer-nondestructive Freon such as Freon R-134a.