Patents Assigned to Mizusawa Kagaku Kogyo Kabushiki Kaisha
  • Patent number: 4622166
    Abstract: Disclosed is a process for the preparation of a zeolite slurry being excellent in either the static stability or the dynamic stability and having a good flowability, which comprises neutralizing an aqueous cake or slurry containing water and zeolite in such a state that both are substantially inseparable from each other by filtration, with an inorganic or organic acid or an acid anydride or acidic salt thereof so that the pH value of the zeolite slurry at the time of completion of addition of said acid, acid anhydride or acidic salt is in the range of from 9.5 to 12 and the pH value of the zeolite slurry in the stationary state after addition of said acid, acid anhydride or acidic salt is in the range of from 11.3 to 12.7, adding a water-soluble or water-dispersible organic polymeric dispersant in an amount of at least 0.1% by weight based on the anhydrous zeolite to the neutralized zeolite slurry, and subjecting the resulting slurry to highly shearing stirring.
    Type: Grant
    Filed: July 5, 1984
    Date of Patent: November 11, 1986
    Assignee: Mizusawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Tadahisa Nakazawa, Koichi Usui, Masahide Ogawa, Kiyoshi Abe, Takashi Tokita
  • Patent number: 4476169
    Abstract: A multilayer glass structure constructed by joining the edge portions of a plurality of glass sheets by a sealant through spacers having an adsorbent filled therein. According to this invention, the adsorbent comprises a combination of a granular zeolite composed of a core of a synthetic zeolite/clay binder mixture containing the synthetic zeolite in an amount larger than its average content in the granular zeolite and a shell of a synthetic zeolite/clay binder mixture containing the clay in an amount larger than its average content in the granular zeolite, with granular activated carbon having on its surface 1 to 20% by weight, based on the activated carbon, of a coating of a synthetic resin latex. The adsorbent can effectively adsorb water vapor and the vapor of an organic solvent evaporated from the sealant, and prevent dew deposition on the glass surface. Moreover, it does not yield dust even when the glass structure is handled under severe conditions.
    Type: Grant
    Filed: June 22, 1982
    Date of Patent: October 9, 1984
    Assignees: Takeda Chemical Industries, Ltd., Mizusawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Hiroshi Nishino, Fumiichi Ogino, Tetsuo Masuko, Kunio Goto, Masao Takahashi
  • Patent number: 4450885
    Abstract: A process for the preparation of granules of low-melting-point metals which comprises spouting a melt of a low-melting-point metal in the form of fine streams in a gas phase under melt fracture-causing conditions and introducing the fine streams of the molten metal into a collecting liquid phase so that the speed of the molten metal fine streams just above the liquid face is 50 to 300 cm/sec is disclosed. According to this process, granules having a substantially spherical shape and being uniform in the size can be prepared very easily at high efficiency.
    Type: Grant
    Filed: November 7, 1978
    Date of Patent: May 29, 1984
    Assignee: Mizusawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yujiro Sugahara, Hiroyuki Naito, Akira Takahashi, Manshiro Hasegawa, Hisashi Tsuchida
  • Patent number: 4420419
    Abstract: Disclosed is an abrasion-resistant granular zeolite formed from a mixture of a synthetic zeolite and a clay binder, said granular zeolite comprising a core composed of a synthetic zeolite clay binder mixture containing the synthetic zeolite at a content higher than the average synthetic zeolite content in the granular zeolite and a shell composed of a synthetic zeolite-clay binder mixture containing the clay binder at a content higher than the average clay binder content in the granular zeolite.This granular zeolite is excellent in both the zeolitic characteristics such as adsorbability and ion exchange capacity and the mechanical strength characteristics such as abrasion resistance and compression strength.
    Type: Grant
    Filed: March 8, 1982
    Date of Patent: December 13, 1983
    Assignee: Mizusawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Masahide Ogawa, Tetsuo Masuko, Kunio Goto, Hideo Sugai, Masao Takahashi
  • Patent number: 4405371
    Abstract: A color developer for pressure-sensitive recording paper which is derived from a clay mineral having a layer-structure composed of regular tetrahedrons of silica and which shows(A) the diffraction pattern attributable to the crystals of layer-structure composed of regular tetrahedrons of silica when subjected to an electron diffraction analysis, but(B) substantially no diffraction pattern attributable to the crystals of said layer-structure when subjected to an X-ray diffraction analysis, and which(C) contains as the constituting elements besides oxygen, at least silicon, magnesium and/or aluminum.This color developer is produced by acid-treating a clay mineral having a layer-structure composed of regular tetrahedrons of silica until its SiO.sub.2 content reaches 82-96.5% by weight on dry basis (drying at 105.degree. C.
    Type: Grant
    Filed: June 30, 1981
    Date of Patent: September 20, 1983
    Assignee: Mizusawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yujiro Sugahara, deceased, Koichi Usui, Masahide Ogawa, Teiji Sato, Yasuo Mizoguchi, Seiji Kojima
  • Patent number: 4329182
    Abstract: Disclosed is a granular stabilizer for chlorine-containing polymers, which comprises porous spherical particles composed of randomly integrated needle crystals of a polybasic sulfuric acid/fatty acid lead salt having a chemical composition of 1 mole of SO.sub.3, 3.7 to 4.5 moles of PbO and 0.06 to 1.27 moles of a higher fatty acid and also having X-ray diffraction peaks at spacings d of 2.95 A and 3.27 A, wherein the fatty acid component is enrolled in the surfaces of the respective needle crystals without substantial phase separation in the surfaces of the spherical particles.
    Type: Grant
    Filed: October 14, 1980
    Date of Patent: May 11, 1982
    Assignee: Mizusawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yujiro Sugahara, Hiroyuki Naito, Mamoru Saito, Hisashi Tuchida
  • Patent number: 4265864
    Abstract: When an alkali such as an alkali metal bicarbonate or carbonate is intimately mixed with bauxite or other alumina-containing raw material at an Al.sub.2 O.sub.3 /Na.sub.2 O molar ratio of from 1/1 to 1/3 and the mixture is molded into granules, then calcined and extracted with an aqueous medium, the alumina component can be recovered in a high yield in the form of an aqueous solution of an alkali metal aluminate. The alkali component is not substantially contained in the residue left after recovery of this aqueous solution.
    Type: Grant
    Filed: February 12, 1979
    Date of Patent: May 5, 1981
    Assignee: Mizusawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yujiro Sugahara, Hiroyuki Naito, Kiyoshi Takai, Shigehisa Imafuku
  • Patent number: 4238346
    Abstract: A detergent builder consisting essentially of an inorganic fine powder composed mainly of an alkali metal aluminosilicate having an X-ray diffraction pattern substantially the same as that of zeolite of the type A and having a degree of crystallization in the range of from 35 to 75%, wherein the inorganic fine powder has a primary particle size smaller than 1.mu. and a secondary particle size smaller than 4.mu., the inorganic fine powder has a buffer capacity (S) of at least 132 ml/100 g of solids, the buffer capacity being expressed by an amount of hydrochloric acid necessary for lowering the pH of a 1% aqueous dispersion of said inorganic fine powder from 9.0 to 6.75 when the dispersion is titrated with 0.4 N hydrochloric acid at a rate of 20 to 50 ml/hr, and wherein the inorganic fine powder has a calcium ion binding property (C. I.) of at least 70 mg/g as expressed as CaO.
    Type: Grant
    Filed: April 17, 1978
    Date of Patent: December 9, 1980
    Assignee: Mizusawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yujiro Sugahara, Koichi Usui, Masahide Ogawa, Hideaki Kurosaki, Shigehisa Imafuku
  • Patent number: 4219535
    Abstract: A detergent builder consisting essentially of an inorganic fine powder composed mainly of an alkali metal aluminosilicate having an X-ray diffraction pattern substantially the same as that of zeolite of the type A and having a degree of crystallization in the range of from 35 to 75%, wherein the inorganic fine powder has a primary particle size smaller than 1.mu. and a secondary particle size smaller than 4.mu., the inorganic fine powder has a buffer capacity (S) of at least 132 ml/100 g of solids, the buffer capacity being expressed by an amount of hydrochloric acid necessary for lowering the pH of a 1% aqueous dispersion of said inorganic fine powder from 9.0 to 6.75 when the dispersion is titrated with 0.4 N hydrochloric acid at a rate of 20 to 50 ml/hr, and wherein the inorganic fine powder has a calcium ion binding property (C. I.) of at least 70 mg/g as expressed as CaO.
    Type: Grant
    Filed: January 26, 1978
    Date of Patent: August 26, 1980
    Assignee: Mizusawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yujiro Sugahara, Koichi Usui, Masahide Ogawa, Hideaki Kurosaki, Shigehisa Imafuku
  • Patent number: 4205054
    Abstract: A process for recovery of nitric acid comprising incorporating or absorbing waste nitric acid and/or a nitrate in an oil-absorbing inorganic carrier and forming a nitrate-carrier granule containing water in the form of a hydroxide, a hydrate or adsorption moisture in an amount sufficient to generate a vapor of nitric acid stably and being substantially non-sticky at a decomposition temperature of the nitrate; heating the formed granule while keeping the substantially non-sticky state in the granule to decompose the nitrate in the granule to a vapor of nitric acid; and recovering the generated vapor of nitric acid is disclosed. According to this process, nitric acid can be directly recovered from waste nitric acid or a nitrate in the form of a vapor of nitric acid without substantial generation of nitrogen oxide gases by using a cheap and easily available inorganic carrier.
    Type: Grant
    Filed: March 28, 1978
    Date of Patent: May 27, 1980
    Assignee: Mizusawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yujiro Sugahara, Hiroyuki Naito, Kiyoshi Takai, Tatuya Kondo
  • Patent number: 4188268
    Abstract: A lead battery comprising as an active material a formation product of a novel lead monoxide or a heat treatment product thereof is disclosed. This novel lead monoxide has a true density of 8.3 to 9.2 g/cc, an average particle size not larger than 0.2.mu., an infrared absorption peak at a wave number of 1400 to 1410 cm.sup.-1 and a chromic anhydride reactivity of at least 94%.This lead battery is excellent over lead batterys comprising active materials formed from known starting substances with respect to the active material utilization ratio and it has a very long life and stable capacities. In this lead battery, the active material utilization ratio can be maintained at a very high level over a long period.
    Type: Grant
    Filed: June 26, 1978
    Date of Patent: February 12, 1980
    Assignee: Mizusawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yujiro Sugahara, Yoshibumi Noshi, Hiroyuki Naito, Akira Takahashi, Masanori Ito, Hisashi Tuchida
  • Patent number: 4126599
    Abstract: A water-resistant shaped structure of gypsum comprising (A) calcium sulfate dihydrate formed by hardening of calcium sulfate capable of hydration reaction, (B) a calcium type filler for filling up spaces among crystalline particles of said calcium sulfate dihydrate and (C) a water-insoluble or hardly water-soluble salt of a polybasic acid having a second stage dissociation constant of 10.sup.-3 to 10.sup.-10, especially 10.sup.-4 to 10.sup.-9, as measured at 25.degree. C.
    Type: Grant
    Filed: February 22, 1977
    Date of Patent: November 21, 1978
    Assignees: Mizusawa Kagaku Kogyo Kabushiki Kaisha, Mitsubishi Corporation
    Inventors: Yujiro Sugahara, Hiroyuki Naito, Tokio Okubo, Nobuo Omori
  • Patent number: 4117104
    Abstract: A novel lead monoxide having a true density of 8.3 to 9.2 g/cc, a primary particle size not larger than 0.2 .mu., an infrared absorption peak at a wave number of 1400 to 1410 cm.sup.-1 and a chromic anhydride reactivity of at least 94%.This lead monoxide is of the ultrafine particulate form excellent in light resistance, hue stability and reactivity and is substantially free of metallic lead. Chrome yellow, tribasic lead sulfate, lead silicate, white lead and the like lead salts can be prepared from this lead monoxide without performing a particular washing operation or using a catalyst.
    Type: Grant
    Filed: May 30, 1977
    Date of Patent: September 26, 1978
    Assignee: Mizusawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yujiro Sugahara, Yoshibumi Noshi, Hiroyuki Naito, Mamoru Saito, Akira Takahashi, Hisashi Tuchida
  • Patent number: 4102977
    Abstract: A detergent builder consisting essentially of an inorganic fine powder composed mainly of an alkali metal aluminosilicate having an X-ray diffraction pattern substantially the same as that of zeolite of the type A and having a degree of crystallization in the range of from 35 to 75%, wherein the inorganic fine powder has a primary particle size smaller than 1 .mu. and a secondary particle size smaller than 4 .mu., the inorganic fine powder has a buffer capacity (S) of at least 132 ml/100 g of solids, the buffer capacity being expressed by an amount of hydrochloric acid necessary for lowering the pH of a 1% aqueous dispersion of said inorganic fine powder from 9.0 to 6.75 when the dispersion is titrated with 0.4N hydrochloric acid at a rate of 20 to 50 ml/hr, and wherein the inorganic fine powder has a calcium ion binding property (C. I.) of at least 70 mg/g as expressed as CaO.
    Type: Grant
    Filed: November 12, 1976
    Date of Patent: July 25, 1978
    Assignee: Mizusawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yujiro Sugahara, Koichi Usui, Masahide Ogawa, Hideaki Kurosaki, Shigehisa Imafuku
  • Patent number: 4069295
    Abstract: A method of treating raw materials containing components of metals of the group IVb of the Periodic Table, which comprises heat-treating a raw material of a component of a metal of the group IVb of the Periodic Table containing coloring poisonous metal components such as Mn, V and Cr components in the presence of a flux composed mainly of an alkali metal nitrate or an alkali metal peroxide which is a thermal decomposition product of the alkali metal nitrate in an amount 2 to 5 times the amount of the raw material on the weight basis in a non-reducing atmosphere to thereby effect fluxing reaction, and subjecting the resulting fluxing reaction product to a leaching treatment of at least one stage in an aqueous medium to separate the fluxing reaction product into said coloring metal components and a concentrate of the component of the group IVb of the Periodic Table which is acid-soluble and substantially free of said coloring poisonous metal components.
    Type: Grant
    Filed: April 30, 1976
    Date of Patent: January 17, 1978
    Assignee: Mizusawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yujiro Sugahara, Yoshibumi Noshi, Hiroyuki Naito, Kiyoshi Takai, Noboru Maruyama
  • Patent number: 4060508
    Abstract: A stabilizer composition for chlorine-containing polymers having a much reduced tendency to blow at the molding step, which comprises (A) an inorganic stabilizer having a power volume of at least 0.5 cc/g, said stabilizer (A) consisting essentially of at least one member selected from the group consisting of silicates of metals of Groups II and IV of the Periodic Table and composites of silicate acid with oxides, hydroxides and carbonates of said metals, and (B) an organic additive having a boiling point or decomposition point higher than a chlorine-containing polymer-processing temperature, said organic additive (B) being incorporated into the stabilizer (A) at a weight ratio (A) : (B) of 1 : at least 0.1 so that the pore volume ratio defined by the following formula: ##EQU1## WHEREIN PVc denotes the pore volume (cc/g) of the entire composition and PVa denotes the pore volume (cc/g) of said inorganic stabilizer (A),is not higher than 0.8.
    Type: Grant
    Filed: November 14, 1975
    Date of Patent: November 29, 1977
    Assignee: Mizusawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yujiro Sugahara, Yoshibumi Noshi, Hiroyuki Naito, Seiichi Nakamura
  • Patent number: 4018616
    Abstract: Water glass composition comprising a water-soluble or water-dispersible silicate binder and an inorganic phosphate curing agent, wherein said inorganic phosphate curing agent is composed of an inorganic solid fine powder comprising as the main ingredient a silicon polyphosphate or its metal salt and said curing agent has an initial dissolution amount (B) of up to 200 mg and an average hydrolysis rate constant (A) of at least 0.2, said initial dissolution amount (B) and average hydrolysis rate constant (A) being defined by the following formula:Y = AX + Bwherein X stands for the lapse of time (minutes) of up to 120 minutes after 1 g of the curing agent has been added to 100 ml of a 4N sodium hydroxide aqueous solution, and Y stands for the integrated amount (mg/100 ml) of phosphoric acid dissolved out of the curing agent into said aqueous solution during the time X.
    Type: Grant
    Filed: September 11, 1975
    Date of Patent: April 19, 1977
    Assignee: Mizusawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yujiro Sugahara, Yoshibumi Noshi, Niroyuki Naito, Takashi Maruya
  • Patent number: 3956005
    Abstract: A coated pigment composition having improved resistance, especially to abrasion, is disclosed, said coated pigment composition consisting essentially of particles composed mainly of an inorganic color pigment and a continuous solid glass coating layer covering the surfaces of said pigment particles, said continuous solid glass coating layer being formed of a continuous phase composed mainly of an alkali polysilicate having the following mole compositionMO.sub.2 : SiO.sub.2 = from 1 : 5 to 1 : 2wherein M stands for an alkali metal component, in which the solid glass coating layer is present in an amount, as calculated as SiO.sub.2, of from 3 to 40 % by weight based on said pigment particles and the value of the specific surface area ratio, expressed by the following formulaR.sub.s = S.sub.c /S.sub.pwherein S stands for the specific surface area (m.sup.2 /g) of uncoated pigment particles, S.sub.c stands for the specific surface area (m.sup.2 /g) of coated pigment particles, and R.sub.
    Type: Grant
    Filed: May 22, 1974
    Date of Patent: May 11, 1976
    Assignee: Mizusawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yujiro Sugahara, Kaichiro Miyazawa, Okitsu Hidetika, Mamoru Saito
  • Patent number: 3956004
    Abstract: This invention relates to a process for manufacturing granular lead oxides such as granular lead monoxide (litharge) and granular red lead at high purities from lead suboxide without formation of harmful dusts or fumes. Furthermore, the invention concerns novel lead bearing additives for use in ceramic industry, for instance, for formation of lead glasses and ceramic glazes to be employed for the manufacture of various optical glasses, cut glasses, tube lamp glasses, etc., and a process for the manufacture of such lead bearing additives.
    Type: Grant
    Filed: February 27, 1973
    Date of Patent: May 11, 1976
    Assignee: Mizusawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yujiro Sugahara, Yoshibumi Noshi, Hiroyuki Naito, Katsuya Toki
  • Patent number: 3935298
    Abstract: When phosphate rock and sulfuric acid are mixed under such conditions that gypsum dihydrate is stably formed and sulfuric acid is added to the phosphate rock in an amount not exceeding the amount equivalent to a calcium component in the phosphate rock, small masses of the reaction product between the phosphate rock and sulfuric acid can be maintained in the non-disintegrable form throughout extraction of phosphoric acid from said reaction product, and phosphoric acid can be extracted from such reaction product at a high rate in a good yield.
    Type: Grant
    Filed: July 2, 1973
    Date of Patent: January 27, 1976
    Assignee: Mizusawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yujiro Sugahara, Yoshibumi Noshi, Hiroyuki Naito, Akira Takahashi, Shoji Shoji