Abstract: An absorbent composition for purifying gases which contain acidic components. The composition contains at least one compound of formula (I), wherein n is 2-6, p is 1-3, the R1 groups may be the same or different and represent hydrogen or C1-3 alkyl, and R2 is hydrogen, C1-3 alkyl or a group of formula (II). The composition is an aqueous solution of 20-60 w/w %.
Type:
Grant
Filed:
March 21, 2000
Date of Patent:
July 31, 2001
Assignees:
Huntsman Corporation Hungary Vegyipari Termelo-Fejleszto
Reszvenytarsasag, Mol Magyar Olaj-Es Gazipari Rt., Alkoto-Pannon Muszaki Fejleszto es Szolgaltato KFT
Inventors:
Istvan Gemes, Tamas Drozda, Gyorgy Borsi, Peter Aranyi, Miklos Nyari, Katalin Novotnik, Arpad Vago, Laszlo Beliczay, Karoly Olah, Gyorgy Csoor, Levente Kotsis, Zoltan Nagy, Ervin Vertesi
Abstract: The invention relates to improved manufacture of methylene bis-(dibutyl-dithiocarbamate) with ASTM coulour less than 2, by reacting aqueous solutions of dibutyl amine and sodium hydroxide with carbon disulfide, treating the obtained reaction product with methylene dichloride, followed by vacuum stripping, phase separation and filtration of the precipitated sodium chloride. According to the invention, during reaction with carbon disulfide the temperature of the mixture is kept at or below 15.degree. C. and the vacuum stripping is performed in two steps, first between 45.degree. C. and 100.degree. C. and at a pressure of 5-50 kPa, then phase separation is carried out at a temperature between 35.degree. C. and 50.degree. C., followed by stripping the separated organic phase in vacuum also at a temperature between 45.degree. C. and 100.degree. C. and at a pressure of 5-50 kPa.
Type:
Grant
Filed:
February 2, 1996
Date of Patent:
April 28, 1998
Assignee:
MOL Magyar Olaj- es Gazipari Rt.
Inventors:
Bela Jover, Janos Forstner, Jozsef Petro, Szabolcs Szoboszlay, Imre Fekete, Karoly Csergo, Gyula Sztreharszki, Gyula Raksi, Janos Kiss, Ferenc Miko, Jeno Baladincz, Jozsef Toth