Abstract: Compositions are provided which comprises an active hydrogen-containing resin, a flexibilizer and at least one curing agent. The cured compositions possess enhanced flexibility while maintaining hardness, and are highly suitable for applications such as coatings, adhesives, sealants, gaskets, industrial rubber goods, and the like.
Type:
Grant
Filed:
June 19, 2017
Date of Patent:
February 13, 2018
Assignee:
Momentive Performance Materials Inc.
Inventors:
Constantine Kondos, Ping Jiang, Martin Wusik, Vikram Kumar
Abstract: A hydrophilic silicone polymer composition suitable for use in producing hydrogel polymer films disclosed. In one aspect, a hydrophilic silicone monomer is of the Formula 1: wAmBnw??(1) where A is a divalent block comprising a silicone-containing pendant group. In one embodiment, the silicone-containing pendant group comprises polyalkylene oxide groups. The structure of the polymer can be controlled and tuned to provide a material with excellent wettability and oxygen permeability. The polymers are suitable for use in a variety of applications including in providing a film for forming contact lenses.
Abstract: The present invention is directed to a selective and efficient process for the hydrosilylation of compounds containing terminally unsaturated 1,3-dienes using iron-based hydrosilylation catalysts. The resulting 1,2-addition products are useful as precursors for various silicone materials or silane- or silyl/silicone-functionalized polyolefins.
Type:
Grant
Filed:
May 6, 2014
Date of Patent:
February 13, 2018
Assignees:
MOMENTIVE PERFORMANCE MATERIALS INC., PRINCETON UNIVERSITY
Inventors:
Crisita Carmen Hojilla Atienza, Aroop Kumar Roy, Paul J. Chirik, Keith J. Weller, Johannes G. P. Delis, Tianning Diao
Abstract: A hydrophilic siloxane copolymer of siloxane and hydrophilic organic monomer/s The copolymers can be functionalized to make them capable of undergoing further polymerization by thermal or actinic radiations. The hydrophilicity of these polymers can be varied by varying the siloxane versus organic monomer ratio thereby going from water dispersible to soluble states. The siloxane content can be tuned accordingly in order to provide moderate to high oxygen permeability. These copolymers can be used as a single component curable composition which results in hydrogels to minimize the presence of leachable components thus by reducing the processing cost. The polymers may also find applications in personal care formulations as copolymers, film-formers, hydrogels, coating, emulsions/latex etc.
Abstract: The invention is directed to a personal care composition which contains an ionically-modified cross-linked silicone network which is formed by the polymerization of a silicone polymer containing hydrosilylation effective unsaturated moiety, silyl hydride moiety and ionic radicals.
Abstract: A curable composition comprises (a) a mercapto-functional siloxane; (b) a siloxane comprising unsaturated functional groups; (c) a photoinitiator; and (d) an antioxidant compound. In one embodiment, the antioxidant is chosen from a hindered phenolic compound. The curable compositions can be utilized to form a cured article, which may be useful in a variety of applications including, but not limited to, optical applications. The cured articles from the cured compositions may exhibit good physical properties including, for example, high refractive index. The articles may also exhibit good thermal stability.
Abstract: A continuous process for preparing a silylated polymer comprising a silylation step where a prepolymer having reactive functional groups, a first intermediate product, is reacted continuously with a silylating agent in an endcapping tubular reaction unit to form a second intermediate product, and where at least a portion of the second intermediate product is backmixed continuously with the first intermediate product to form the silylated polymer. The continuous process may further comprise a stabilization step, a quenching step or both a stabilization step and a quenching step.
Type:
Grant
Filed:
August 11, 2015
Date of Patent:
November 28, 2017
Assignee:
Momentive Performance Materials Inc.
Inventors:
John Banevicius, Misty Huang, Brendan O'Keefe, Vikram Kumar, Bruce Barbera
Abstract: The invention is directed to a personal care composition which contains a crosslinked ionic silicone network wherein the crosslinked ionic silicone network is formed by the ring-opening polymerization of oxirane moiety.
Type:
Grant
Filed:
December 16, 2014
Date of Patent:
October 31, 2017
Assignee:
Momentive Performance Materials Inc.
Inventors:
Alok Sarkar, Anubhav Saxena, Laxmi Samantara, Ning Lu
Abstract: A hydrophilic silicone macromer composition suitable for use in producing hydrogel polymer films from which biomedical devices such as contact lenses can be made. The hydrophilic silicone macromer comprises a polyether backbone comprising a silicone-containing pendant group. In one aspect, a hydrophilic silicone macromer is of the Formula 1: The hydrophilic silicone macromer can be used to form a polymer and a hydrogel film suitable for forming contact lenses.
Abstract: A process for producing a silane-crosslinked polyolefin which comprises exposing a polyolefin containing at least one [1,3,2]-dioxasilinane ring structure to moisture in the presence of an organic carboxylic acid, which is used as a hydrolysis and condensation catalyst and does not contain tin, thereby producing the silane-crosslinked polyolefin, wherein the polyolefin containing at least one [1,3,2]-dioxasilinane ring structure is made by the process of grafting an olefinically unsaturated [1,3,2]-dioxasilinane to a polyolefin in the presence of a free radical initiator. There is also provided the resulting silane-crosslinked polyolefin and the graftable silane composition used in the process.
Abstract: In one aspect, a self-lubricating component is provided for a pharmaceutical packaging assembly. The self-lubricating component comprises a polymer composition and an effective amount of a lubricating additive such as, for example, boron nitride. In another aspect, a pharmaceutical packaging assembly may be provided having a surface thereof coated with a lubricating composition comprising boron nitride. The pharmaceutical packaging composition may be, for example, a pre-filled syringe comprising a body (barrel) and a plunger assembly.
Type:
Grant
Filed:
August 16, 2013
Date of Patent:
October 10, 2017
Assignee:
Momentive Performance Materials Inc.
Inventors:
Samuel Conzone, David M. Rusinko, Chandrashekar Raman, Indumathi Ramakrishnan, Anantharaman Dhanabalan, Mayank Kumar Dubey, Markus Bley, Hans Rafael Winkelbach
Abstract: Disclosed herein is the use of manganese, iron, cobalt, or nickel complexes containing tridentate pyridine di-imine ligands as hydrosilylation catalysts. These complexes are effective for efficiently catalyzing hydrosilylation reactions, as well as offering improved selectivity and yield over existing catalyst systems.
Type:
Grant
Filed:
December 14, 2011
Date of Patent:
October 10, 2017
Assignees:
MOMENTIVE PERFORMANCE MATERIALS INC., PRINCETON UNIVERSITY
Inventors:
Keith James Weller, Crisita Carmen H. Atienza, Julie Boyer, Paul Chirik, Johannes G. P. Delis, Kenrick Lewis, Susan A. Nye
Abstract: There is provided herein a curable polysiloxane composition comprising a reactive polysiloxane having the general structural formula (I): as described herein. There is provided a method of making the polysiloxane. In addition there is provided a curable composition including the polysiloxane.
Abstract: There is described a release composition including a polyorganosiloxane polymer and a release modifier. The release modifier includes comprising an alkenyl silsesquioxane an organo functional siloxane of the formula MDxM, wherein M represents R3SiO1/2, D represents R2SiO2/2, wherein R is alkyl or alkenyl of 1 to 40 carbon atoms, or hydrogen wherein the organo functional siloxane has a viscosity of from about 5 centipoises to about 80 centipoises and x is from about 5 to about 80, and an optionally a reactive diluent. The release composition includes at least one siloxane cross-linking agent, an inhibitor; and a hydrosilation catalyst.
Abstract: The present invention relates to oil-in-water emulsion-forming compositions having reduced whitening effect when applied on wet substrates. The oil-in-water emulsion compositions are suitable for use in personal care products, textile treatments, polishing products, gloss enhancements and water resistance treatments.
Type:
Grant
Filed:
December 9, 2014
Date of Patent:
September 5, 2017
Assignee:
Momentive Performance Materials Inc.
Inventors:
Anne Dussaud, Sigfredo Gonzalez, Bhavna Rana
Abstract: The present technology provides compositions, methods, and processes to form polysiloxanes. In one aspect, the present technology provides a process for the ring opening polymerization of a cyclosiloxane comprising contacting a cyclosiloxane with a N-trialkylsilyl-bis(perfluoroalkylsulfonyl)imide compound.
Abstract: A transport puck vertically aligns a caulking cartridge, nozzle-down. The puck includes (i) a substantially solid lower plug portion, having a lead face and a bottom face and an center passageway that is at least partially inverted frustum-shaped that forms a side contact face that tapers from a wider lead face opening to a narrower bottom face opening; and or to a tubular sleeve from the side contact face to the bottom face opening; (ii) an upper sleeve, shaped to receive the caulking cartridge in a desired vertical alignment to the lower plug portion; and (iii) at least one funnel-shaped bore into the bottom face with an inserted connector comprising a head and stem, the head spaced within the bore to define a spacing that has been determined to identify bottom face wear.