Abstract: In one embodiment, a membrane electrode assembly of a fuel cell has an anode aspect and a cathode aspect. A fuel distribution structure is disposed adjacent to the anode aspect. The fuel distribution structure has a fuel feed port configured to receive and inject liquid fuel to a flow field plate. The flow field plate has flow channels formed therein that split and spread from the fuel feed port to exit ports. The flow channels are configured to convey heat to fuel passing there through to substantially convert the liquid fuel to vaporous fuel within the flow channels. The exit ports are configured to deliver the resulting vaporous fuel to the anode aspect to substantially uniformly distribute fuel across the anode aspect. Further, an enthalpy exchanger and heat spreader assembly is in thermal contact with the fuel distribution structure and configured to provide to it heat from fuel cell operation.

Abstract: A fuel cell system which includes a fuel distribution structure that uniformly distributes vaporizing fuel to a fuel cell is provided. As the fuel travels in a flow field channel in the fuel distribution structure, it is substantially converted to a vapor by the heat of the fuel cell operation in such a manner that the resulting vapor pressure works to substantially uniformly distribute fuel evenly outwardly across substantially the entire active area of the anode aspect of one or more membrane electrode assemblies in the system, and whereby localized, uneven “hot spots” of fuel at the anode aspects are substantially prevented. A pair of enthalpy exchanger and heat spreader assemblies include a cathode current collector element that also has a heat spreader plate that collects and redirects heat in the fuel cell system, the assembly acting to manage the heat, temperature and condensation in the fuel cell system.

Abstract: Fuel feed systems capable of providing substantially consistent flow of fuel to a fuel cell and also capable of tolerating varying pressures from a reservoir (also referred to as fuel supply or fuel cell cartridge) and the fuel cell while maintaining substantially consistent control flow to the fuel cell are disclosed.

Abstract: A spring loaded direct oxidation fuel cell assembly reduces the effects of precompression relaxation. A near flat spring and a distribution plate form a spring assembly that is disposed between a membrane electrode assembly and one of the current collectors in the fuel cell. The components are assembled into a fuel cell assembly and are precompressed, and a spring yielding process is performed. While precompression is being applied, a set of pins and a plastic frame are insert molded around the fuel cell assembly to hold the components in place. Subsequently, as the precompression relaxes, the spring assembly forces act to maintain an evenly distributed compression on the MEA, thereby compensating for the loss of precompression. A related method of manufacturing a fuel cell assembly is provided.

Abstract: A fuel cell system having internal pushback of water, with a compact, thermally integrated enthalpy exchanger enabling effective hydration control in a small fuel cell system is provided. The enthalpy exchanger provides for the moisture in the fuel cell effluent to be used to humidify the incoming air stream to allow the fuel cell to be operated at higher temperatures while avoiding dry out. The enthalpy exchanger includes a moisture permeable membrane which collects moisture from the exhaust flow and makes this moisture available to an incoming air stream, thus humidifying the incoming air stream. In addition, the waste heat from the fuel cell reactions is transferred to the incoming air stream. The exhaust stream from the anode can also be used to provide additional moisture and heat to the enthalpy exchanger to be added to the incoming air stream. A water separator is also provided in one embodiment.

Abstract: A power pack system for charging a set of isolated batteries is provided. In an illustrative embodiment of the invention, a single fuel cell, a single DC-DC converter and a single system controller device comprises the power-generation side of the power pack. A set of switches is used to connect the power-generation side of the Power pack to one of the isolated batteries in the power pack, thereby recharging that particular battery in the battery power pack set. A battery protection and powerpath control device communicates with the system controller to determine which switches are to be closed depending upon which battery requires recharging. During normal operation the switches will follow the direction from the system controller. If a fault is detected by the battery protection circuit, the protection circuit will take priority and turn off the appropriate switch(es).

Abstract: A heat spreader assembly that provides electrical, thermal and structural functions to the fuel cell. The heat spreader assembly comprises two bulk composite material layers, and a heat spreader element. The heat spreader element includes a copper layer sandwiched between two stainless steel layers. The stainless steel layers are bonded to the bulk composite layers by a conductive thermal set adhesive. The lamination applied to the stainless steel layers enables heat and electricity to flow from the cathode while maintaining low resistance among other layers of the fuel cell. The copper layer diffuses heat across the layer and functions as cathode current collector for a fuel cell. The bulk composite material layers function as a cold side of an enthalpy exchanger system and a cathode flow field. Further the composite material includes flow channels formed throughout the material to evenly distribute incoming air over the enthalpy exchanger membrane and to the cathode of the MEA.

Abstract: Fuel feed systems capable of providing substantially consistent flow of fuel to a fuel cell and also capable of tolerating varying pressures from a reservoir (also referred to as fuel supply or fuel cell cartridge) and the fuel cell while maintaining substantially consistent control flow to the fuel cell are disclosed.

Abstract: Embodiments of a valve are disclosed that allow for the control and adjustment of a fluid flow between a valve inlet port and a valve output port as a function of the pressure at the valve inlet port, a pressure at a first pressure input port, and a reference pressure.

Abstract: A system-to-reservoir connector is disclosed in which a system-side-sub-connector and a reservoir-side-sub-connector provide for a fluid connection that is resilient to external forces, is substantially leak-proof upon insertion and retraction, and is orientation independent.

Abstract: Methods for increasing the durability of direct oxidation fuel cells are disclosed. In one instance, the method for increasing durability of a vapor fed direct oxidation fuel cell includes reducing fluctuations in output power, provided by the vapor fed direct oxidation fuel cell, to a load. The reduction of the fluctuations in output power can include, in one instance, utilizing a mass flow controller or an electro-osmotive pump to supply fuel to the vapor fed direct oxidation fuel cell.

Abstract: A simplified direct oxidation fuel cell system is provided. The fuel cell is constructed in such a manner that fuel is added to the cell anode as it is consumed and water is evaporated off at cell cathode so that there is no need for recirculation of unreacted fuel at the cell anode or water at the cell cathode. In addition, carbon dioxide generated from the anodic reaction is passively vented out of the system by using a CO2 gas permeable membrane material integrated as part of the anode chamber construction. It is thus possible that, the CO2 separation from the anode fluid occurs without the recirculation of the anode fluid outside the anode chamber. The passive system in which fuel is added as it is consumed and CO2 separated, both without pumping, ultimately will increase net power provided to the load due to low parasitic losses.

Abstract: Passive water management techniques are provided in an air-breathing direct oxidation fuel cell system. A highly hydrophobic component with sub-micrometer wide pores is laminated to the catalyzed membrane electrolyte on the cathode side. This component blocks liquid water from traveling out of the cathode and instead causes the water to be driven through the polymer membrane electrolyte to the cell anode. The air-breathing direct oxidation fuel cell also includes a layer of cathode backing and additional cathode filter components on an exterior aspect of the cell cathode which lessen the water vapor escape rate from the cell cathode. The combination of the well laminated hydrophobic microporous layer, the thicker backing and the added filter layer, together defines a cathode structure of unique water management capacity, that enables to operate a DMFC with direct, controlled rate supply of neat (100%) methanol, without the need for any external supply or pumping of water.

Abstract: The present invention provides a viscous fuel, which includes a fuel substance held in a polymeric structure, where the viscous fuel has benefits over previous fuels, including performance enhancements and desirable physical characteristics. One embodiment of the formulation includes neat methanol, to which a thickening substance, such as that sold commercially under the trade name Carbopol®, is added to impart viscosity, as well as stabilizing and suspending properties. In addition to the thickening substance, a further substance can be added to balance the pH of the viscous fuel when needed.

Abstract: A conformable fuel cell is provided which includes a basic structure that provides flexibility while providing a high compression along the active surface of the fuel cell's membrane electrode assembly, which can be achieved by an injection-molded frame. A suitable fuel is delivered to the anode aspect of the fuel cell. Effective water management could also be provided by appropriate diffusion layers. The fuel cell can be contour-molded to a desired shape, or can be constructed of an array of flexibly connected individual fuel cells that overall have a curvilinear shape, or can be constructed as a pliable fuel cell that can be incorporated into an application device or an article of clothing.

Abstract: A fuel reservoir having a reticulated material, generally a felt or a foam, disposed therein is provided. The addition of this reticulated material, either alone or in combination with a viscous fuel, assists the prevention of undesired flow of the fuel, the minimization of undesired leakages, and assists in orientation independence and uniform distribution of the fuel in the reservoir. The reticulated material enables the use of a viscous liquid fuel that has fuel diffusion rates and fuel utilization characteristics that approach those of neat liquid methanol. The material also helps create a greater surface area for evaporation, thus allowing a highly concentrated, vaporous fuel substance to be delivered to an associated fuel cell.

Abstract: Apparatus and methods for the generation of water in a direct oxidation fuel cell. Water, in addition to carbon dioxide and heat, is produced when carbonaceous fuel or fuel solution is oxidized in the presence of air and a suitable catalyst. This oxidation reaction is performed on a surface that allows for the introduction of oxygen in the presence of a catalyst. Water produced can then be directly added to the fuel solution thereby diluting the fuel solution to a desired concentration, or may be separately and then later added to fuel solution for the normal fuel cell operations depending on the permeability of the membrane to water.

Abstract: A passive direct oxidation fuel cell system, which uses a high concentration fuel such as neat methanol as a direct feed to an anode aspect of the fuel cell, is provided. The fuel cell includes a passive water management capability, achieved by the combined functions of controlled fuel dosing, effective push back of liquid water from the cathode through the membrane electrolyte by a hydrophobic microporous layer well bonded to the cathode catalyst and the use of a thin ionomeric membrane. The rate of fuel delivery is controlled by a passive fuel transport barrier. Carbon dioxide management techniques are also provided.

Abstract: The present invention provides a fuel efficient membrane electrode assembly that substantially resists methanol from “crossing over” by sealing the anode diffusion layer and catalyst layer, and by preventing fluids from passing across at least a portion of the membrane electrolyte. The efficiency of the fuel cell is maintained because essentially all of the fuel is reacted on the catalyst layers creating electricity, which is transferred to the fuel cell load. The temperature of the fuel cell is also maintained as the uncatalyzed reaction that produces heat is prevented.

Abstract: A method and system for dynamically controlling and managing a fuel cell system is provided. The method and system ensures that predetermined operating parameters and conditions are met. This is achieved using programmable on-board hardware that is already available in the fuel cell system and does not require additional components. More specifically, operating characteristics are measured such as the voltage of the weakest cell, the stack output voltage, the stack output current, the current of a battery being charged by the stack and/or the power of the stack. When each of these measurements is taken, a determination is made to find the load change that should be made in order to adjust the stack voltage to achieve a desired goal. In particular, the load on the fuel cell system can be varied by adjusting the duty cycle of the switches within a DC-DC converter that is being operated by an associated microcontroller.