Patents Assigned to Multi-Chem Group, LLC
  • Publication number: 20170349821
    Abstract: Certain particulates of encapsulated treatment chemicals, and methods of and systems for their use in subterranean formations, are provided. In one embodiment, the methods comprise: providing a plurality of treatment particulates, at least one of which comprising a polymer matrix that comprises and/or encages at least one treatment chemical and a coating disposed around an outer surface of the polymer matrix; and introducing the treatment particulates into a well bore penetrating at least a portion of a subterranean formation.
    Type: Application
    Filed: December 3, 2014
    Publication date: December 7, 2017
    Applicant: Multi-Chem Group, LLC
    Inventors: Fang Wei, Pushkala Krishnamurthy, Ying Cong Jiang, Erick J. Acosta
  • Patent number: 9828834
    Abstract: A method of controlling corrosion in a subsea pipeline is disclosed which includes supplying a low dose inhibitor stream (LDHI) comprised of a quaternary amine and drying with a desiccant.
    Type: Grant
    Filed: September 21, 2011
    Date of Patent: November 28, 2017
    Assignee: Multi-Chem Group, LLC
    Inventors: Danny Durham, James Russum, Nathan Davis, Curtis Conkle
  • Publication number: 20170335188
    Abstract: Composition for the removal or inactivation of hydrogen sulfide or soluble sulfide ion other species comprising ionizable sulfur (e.g., mercaptans, thiols, etc.) using compositions containing acrylate and/or derivatives thereof are provided. Methods for the removal or inactivation of hydrogen sulfide or other sulfur species in oilfield sites and other related applications using compositions containing acrylate and/or derivatives thereof are provided.
    Type: Application
    Filed: December 23, 2014
    Publication date: November 23, 2017
    Applicant: Multi-Chem Group, LLC
    Inventors: Liu Shi, Funian Zhao, Liangwei Qu, Michael Harless, Ron Hoppe
  • Publication number: 20170327732
    Abstract: Surfactant compositions for enhancing oil and/or gas production from certain subterranean formations (e.g., unconventional reservoirs), and related methods of use, are provided. In one embodiment, the methods comprise: providing a treatment fluid comprising a carrier fluid and a cationic surfactant comprising at least two hydrophobic heads that each comprise a quaternary cationic moiety; and introducing the treatment fluid into at least a portion of a subterranean formation.
    Type: Application
    Filed: December 22, 2014
    Publication date: November 16, 2017
    Applicant: Multi-Chem Group, LLC
    Inventors: Kai He, Funian Zhao, Liangwei Qu, Liang Xu
  • Patent number: 9796906
    Abstract: Compounds comprising multiple hydrophilic heads and a lipophilic tail may be employed into fluids to inhibit agglomeration of hydrates, among other things. Suitable hydrophilic heads may include secondary, tertiary, and/or quaternary ammonium cation moieties, phosphonium cation moieties, and combinations thereof. Such LDHI compounds may provide enhanced interactivity with hydrate crystals and/or hydrate-forming molecules. These compounds may be employed in fluids in various environments, such as a conduit penetrating a subterranean formation, or a conduit carrying fluid in an industrial setting.
    Type: Grant
    Filed: May 5, 2014
    Date of Patent: October 24, 2017
    Assignee: Multi-Chem Group, LLC
    Inventors: Liangwei Qu, Yangqiu Sun, Funian Zhao, Curtis Conkle, Erick J. Acosta
  • Patent number: 9725986
    Abstract: Systems and methods for creating and/or using multi-functional surfactant complexes that may enhance surfactant treatments in subterranean formations are provided. In some embodiments, the methods comprise: providing a treatment fluid comprising an aqueous base fluid and one or more multi-functional surfactant complexes that comprise at least one surfactant and at least one polymeric additive, wherein the surfactant and the polymeric additive carry opposite charges; and introducing the treatment fluid into a well bore at a well site penetrating at least a portion of a subterranean formation.
    Type: Grant
    Filed: December 1, 2015
    Date of Patent: August 8, 2017
    Assignee: Multi-Chem Group, LLC
    Inventors: Liang Xu, Jayant Rane, Kai He
  • Patent number: 9683433
    Abstract: A slick water fracturing fluid including a brine, an inorganic nitrate, a nitrogen reducing bacteria, a scale inhibitor selected from the group consisting of a polyacrylate polymer, a polyacrylate copolymer, a polyacrylate terpolymer, and mixtures thereof, and a friction reducer, wherein the friction reducer is a polyacrylamide.
    Type: Grant
    Filed: June 30, 2015
    Date of Patent: June 20, 2017
    Assignee: Multi-Chem Group, LLC
    Inventors: Danny K. Durham, Michael L. Harless
  • Patent number: 9676991
    Abstract: Low-dosage hydrate inhibitor (“LDHI”) compounds comprising multiple lipophilic tails and a hydrophilic head may be employed into fluids to inhibit agglomeration of hydrates, among other things. Suitable hydrophilic heads may include quaternary or tertiary ammonium cation moieties, and combinations thereof. Such LDHI compounds in some embodiments may include reaction products of DETA and/or other amines, fatty acid(s), and, optionally, alkyl halide(s). Compounds according to some embodiments may be employed in fluids in various environments, such as a conduit penetrating a subterranean formation, or a conduit carrying fluid in an industrial setting.
    Type: Grant
    Filed: May 5, 2014
    Date of Patent: June 13, 2017
    Assignee: Multi-Chem Group, LLC
    Inventors: Funian Zhao, Yanqiu Sun, Liangwei Qu, Erick J. Acosta
  • Publication number: 20170130121
    Abstract: Systems and methods for creating surfactant-polyelectrolyte complexes at a well site are provided. In one embodiment, the methods comprise: providing a first solution comprising at least one surfactant and a second solution comprising at least one polyelectrolyte; using a stop-flow mixing apparatus at a well site to mix the first and second solutions to form one or more surfactant-polyelectrolyte complexes; using a low-dose pumping apparatus at the well site to transfer the one or more surfactant-polyelectrolyte complexes from the stop-flow mixing apparatus to a blending apparatus at the well site; using the blending apparatus to mix the one or more surfactant-polyelectrolyte complexes with an aqueous base fluid to form a treatment fluid; and introducing the treatment fluid into a well bore penetrating at least a portion of a subterranean formation at the well site.
    Type: Application
    Filed: August 1, 2014
    Publication date: May 11, 2017
    Applicant: Multi-Chem Group, LLC
    Inventors: Liang Xu, Jayant Rane, Kai He
  • Patent number: 9488586
    Abstract: A mini-reservoir device may be used to screen or otherwise determine a composition of one or more treatment fluids, additives, and other fluids. Such fluids may be for use in a subterranean formation. Methods of determining a composition may include visual analysis of each of two or more fluids, each from a plurality of candidate fluids, flowed through a mini-reservoir device, and selection of one of the plurality of candidate fluids based at least in part upon that visual analysis. Certain methods may include determining an oil recovery factor for each of one or more fluids flowed through a mini-reservoir device. In particular methods, multiple treatment fluids and/or additives, such as surfactants, may be selected based at least in part upon visual analysis of the fluids' flow through a mini-reservoir device.
    Type: Grant
    Filed: April 4, 2014
    Date of Patent: November 8, 2016
    Assignee: Multi-Chem Group, LLC
    Inventors: Kai He, Liang Xu
  • Publication number: 20160280986
    Abstract: Provided are acidic treatment fluids comprising a weakly emulsifying surfactant, an aqueous base fluid, and an acid. In some embodiments, the treatment fluids are capable of forming short-lived oil-in-acid emulsions due, at least in part, to the interaction of at least a portion of the weakly emulsifying surfactant with one or more oil or gas molecules within a subterranean formation.
    Type: Application
    Filed: April 11, 2014
    Publication date: September 29, 2016
    Applicant: MULTI-CHEM GROUP, LLC
    Inventor: Liang Xu
  • Patent number: 9422470
    Abstract: A method of determining the suitability of a surfactant for use in a formation can include sampling water in the formation, providing at least two surfactants, and mixing each of the surfactants with the formation water to form surfactant/water samples. The method can further include determining the solubility of each surfactant with the formation water, comparing the solubility of each surfactant with the other surfactant, and assigning a solubility performance value for each surfactant based on its solubility in the formation water sample compared to the other surfactant.
    Type: Grant
    Filed: September 12, 2012
    Date of Patent: August 23, 2016
    Assignee: Multi-Chem Group, LLC
    Inventors: Liang Xu, Qiang Fu
  • Patent number: 9193671
    Abstract: A method of inhibiting gas hydrate formation in petroleum and natural gas production systems through the use of low dosage hydrate inhibitors which include reaction products of non-halide-containing inorganic acids, organic acids, and organic amines. The use of these non-halide-containing reaction products rather than chloride containing acids or alkylating agents avoids corrosion and stress cracking caused by residual inorganic chloride and other inorganic, halide-containing acids. The anti-agglomerate compositions can be administered continuously to effectively inhibit gas hydrate formation. In preferred embodiments, the anti-agglomerate compositions are mixtures of reaction products of non-halide-containing organic acids and organic amines.
    Type: Grant
    Filed: September 26, 2011
    Date of Patent: November 24, 2015
    Assignee: Multi-Chem Group, LLC
    Inventors: Danny Durham, Curtis Conkle, James Russum
  • Patent number: 9127986
    Abstract: An apparatus and method for remotely monitoring the temperature of acrolein in a storage tank has a temperature sensor in communication with the acrolein in the tank and with a temperature transmitter. A global positioning receiver/transmitter communicates with the temperature transmitter and sends the temperature data to a remote base station via a linking satellite while also providing location data about the storage tank. At the base station, the temperature data related to the actual temperature of the acrolein in the tank is compared to predetermined temperature set points. These predetermined set points correlate to polymerization reaction of the acrolein. When the set points are reached, a response processor initiates a response to control the polymerization reaction of the acrolein in the storage tank.
    Type: Grant
    Filed: February 16, 2010
    Date of Patent: September 8, 2015
    Assignee: Multi-Chem Group, LLC
    Inventor: Michael L. Harless
  • Patent number: 9096789
    Abstract: A slick water fracturing fluid including a brine, an inorganic nitrate, a nitrogen reducing bacteria, a scale inhibitor selected from the group consisting of a polyacrylate polymer, a polyacrylate copolymer, a polyacrylate terpolymer, and mixtures thereof, and a friction reducer, wherein the friction reducer is a polyacrylamide.
    Type: Grant
    Filed: August 19, 2011
    Date of Patent: August 4, 2015
    Assignee: Multi-Chem Group, LLC
    Inventors: Daniel K. Durham, Michael L. Harless
  • Publication number: 20140299314
    Abstract: A method of controlling sulfides in a fluid including determining selected conditions of the fluid and selecting a nitrogen reducing bacteria (NRB) based on those conditions. The method further includes injecting an NRB into the fluid and injecting an inorganic nitrate into the fluid.
    Type: Application
    Filed: April 5, 2013
    Publication date: October 9, 2014
    Applicant: MULTI-CHEM GROUP, LLC
    Inventors: Edward Corrin, Michael Harless
  • Publication number: 20140301984
    Abstract: A method of controlling a deleterious bacteria in a fluid including injecting a nitrite or nitrate into the fluid, identifying a phage capable of infecting the deleterious bacteria, and injecting the phage into the fluid.
    Type: Application
    Filed: April 5, 2013
    Publication date: October 9, 2014
    Applicant: MULTI-CHEM GROUP, LLC
    Inventors: Edward Corrin, Michael Harless
  • Publication number: 20140199271
    Abstract: A method of controlling a deleterious bacteria in oil and gas production, oil and gas completion fluids or other industrial fluids is described which includes identifying a phage capable of infecting the deleterious bacteria, identifying a biocide compatible with the phage and effective against the deleterious bacteria and injecting the biocide and the phage into the oil and gas production, oil and gas completion or other industrial fluid.
    Type: Application
    Filed: January 14, 2013
    Publication date: July 17, 2014
    Applicant: Multi-Chem Group, LLC
    Inventor: Edward Corrin
  • Publication number: 20130101473
    Abstract: A method for scavenging hydrogen sulfide from geothermal steam in a condenser under vacuum. A fine curtain of atomized acrolein-water droplets may be sprayed into geothermal steam condensers in an amount of approximately 2:1 molar ratio of acrolein to H2S based on hydrogen sulfide in the incoming steam from the turbine. The range being approximately 0.1 ppm to 500 ppm of sulfide. The acrolein is allowed to react with the gas phase H2S to form non-volatile aldehyde byproducts which partition into the water phase, are returned to the cooling tower and ultimately removed by normal cooling-tower blow down.
    Type: Application
    Filed: December 12, 2012
    Publication date: April 25, 2013
    Applicant: MULTI-CHEM GROUP, LLC
    Inventor: MULTI-CHEM GROUP, LLC
  • Publication number: 20130067999
    Abstract: A method of determining the suitability of a surfactant for use in a formation can include sampling water in the formation, providing at least two surfactants, and mixing each of the surfactants with the formation water to form surfactant/water samples. The method can further include determining the solubility of each surfactant with the formation water, comparing the solubility of each surfactant with the other surfactant, and assigning a solubility performance value for each surfactant based on its solubility in the formation water sample compared to the other surfactant.
    Type: Application
    Filed: September 12, 2012
    Publication date: March 21, 2013
    Applicant: Multi-Chem Group, LLC
    Inventors: Liang Xu, Qiang Fu