Abstract: Certain particulates of encapsulated treatment chemicals, and methods of and systems for their use in subterranean formations, are provided. In one embodiment, the methods comprise: providing a plurality of treatment particulates, at least one of which comprising a polymer matrix that comprises and/or encages at least one treatment chemical and a coating disposed around an outer surface of the polymer matrix; and introducing the treatment particulates into a well bore penetrating at least a portion of a subterranean formation.
Abstract: A method of controlling corrosion in a subsea pipeline is disclosed which includes supplying a low dose inhibitor stream (LDHI) comprised of a quaternary amine and drying with a desiccant.
Type:
Grant
Filed:
September 21, 2011
Date of Patent:
November 28, 2017
Assignee:
Multi-Chem Group, LLC
Inventors:
Danny Durham, James Russum, Nathan Davis, Curtis Conkle
Abstract: Composition for the removal or inactivation of hydrogen sulfide or soluble sulfide ion other species comprising ionizable sulfur (e.g., mercaptans, thiols, etc.) using compositions containing acrylate and/or derivatives thereof are provided. Methods for the removal or inactivation of hydrogen sulfide or other sulfur species in oilfield sites and other related applications using compositions containing acrylate and/or derivatives thereof are provided.
Type:
Application
Filed:
December 23, 2014
Publication date:
November 23, 2017
Applicant:
Multi-Chem Group, LLC
Inventors:
Liu Shi, Funian Zhao, Liangwei Qu, Michael Harless, Ron Hoppe
Abstract: Surfactant compositions for enhancing oil and/or gas production from certain subterranean formations (e.g., unconventional reservoirs), and related methods of use, are provided. In one embodiment, the methods comprise: providing a treatment fluid comprising a carrier fluid and a cationic surfactant comprising at least two hydrophobic heads that each comprise a quaternary cationic moiety; and introducing the treatment fluid into at least a portion of a subterranean formation.
Type:
Application
Filed:
December 22, 2014
Publication date:
November 16, 2017
Applicant:
Multi-Chem Group, LLC
Inventors:
Kai He, Funian Zhao, Liangwei Qu, Liang Xu
Abstract: Compounds comprising multiple hydrophilic heads and a lipophilic tail may be employed into fluids to inhibit agglomeration of hydrates, among other things. Suitable hydrophilic heads may include secondary, tertiary, and/or quaternary ammonium cation moieties, phosphonium cation moieties, and combinations thereof. Such LDHI compounds may provide enhanced interactivity with hydrate crystals and/or hydrate-forming molecules. These compounds may be employed in fluids in various environments, such as a conduit penetrating a subterranean formation, or a conduit carrying fluid in an industrial setting.
Abstract: Systems and methods for creating and/or using multi-functional surfactant complexes that may enhance surfactant treatments in subterranean formations are provided. In some embodiments, the methods comprise: providing a treatment fluid comprising an aqueous base fluid and one or more multi-functional surfactant complexes that comprise at least one surfactant and at least one polymeric additive, wherein the surfactant and the polymeric additive carry opposite charges; and introducing the treatment fluid into a well bore at a well site penetrating at least a portion of a subterranean formation.
Abstract: A slick water fracturing fluid including a brine, an inorganic nitrate, a nitrogen reducing bacteria, a scale inhibitor selected from the group consisting of a polyacrylate polymer, a polyacrylate copolymer, a polyacrylate terpolymer, and mixtures thereof, and a friction reducer, wherein the friction reducer is a polyacrylamide.
Abstract: Low-dosage hydrate inhibitor (“LDHI”) compounds comprising multiple lipophilic tails and a hydrophilic head may be employed into fluids to inhibit agglomeration of hydrates, among other things. Suitable hydrophilic heads may include quaternary or tertiary ammonium cation moieties, and combinations thereof. Such LDHI compounds in some embodiments may include reaction products of DETA and/or other amines, fatty acid(s), and, optionally, alkyl halide(s). Compounds according to some embodiments may be employed in fluids in various environments, such as a conduit penetrating a subterranean formation, or a conduit carrying fluid in an industrial setting.
Type:
Grant
Filed:
May 5, 2014
Date of Patent:
June 13, 2017
Assignee:
Multi-Chem Group, LLC
Inventors:
Funian Zhao, Yanqiu Sun, Liangwei Qu, Erick J. Acosta
Abstract: Systems and methods for creating surfactant-polyelectrolyte complexes at a well site are provided. In one embodiment, the methods comprise: providing a first solution comprising at least one surfactant and a second solution comprising at least one polyelectrolyte; using a stop-flow mixing apparatus at a well site to mix the first and second solutions to form one or more surfactant-polyelectrolyte complexes; using a low-dose pumping apparatus at the well site to transfer the one or more surfactant-polyelectrolyte complexes from the stop-flow mixing apparatus to a blending apparatus at the well site; using the blending apparatus to mix the one or more surfactant-polyelectrolyte complexes with an aqueous base fluid to form a treatment fluid; and introducing the treatment fluid into a well bore penetrating at least a portion of a subterranean formation at the well site.
Abstract: A mini-reservoir device may be used to screen or otherwise determine a composition of one or more treatment fluids, additives, and other fluids. Such fluids may be for use in a subterranean formation. Methods of determining a composition may include visual analysis of each of two or more fluids, each from a plurality of candidate fluids, flowed through a mini-reservoir device, and selection of one of the plurality of candidate fluids based at least in part upon that visual analysis. Certain methods may include determining an oil recovery factor for each of one or more fluids flowed through a mini-reservoir device. In particular methods, multiple treatment fluids and/or additives, such as surfactants, may be selected based at least in part upon visual analysis of the fluids' flow through a mini-reservoir device.
Abstract: Provided are acidic treatment fluids comprising a weakly emulsifying surfactant, an aqueous base fluid, and an acid. In some embodiments, the treatment fluids are capable of forming short-lived oil-in-acid emulsions due, at least in part, to the interaction of at least a portion of the weakly emulsifying surfactant with one or more oil or gas molecules within a subterranean formation.
Abstract: A method of determining the suitability of a surfactant for use in a formation can include sampling water in the formation, providing at least two surfactants, and mixing each of the surfactants with the formation water to form surfactant/water samples. The method can further include determining the solubility of each surfactant with the formation water, comparing the solubility of each surfactant with the other surfactant, and assigning a solubility performance value for each surfactant based on its solubility in the formation water sample compared to the other surfactant.
Abstract: A method of inhibiting gas hydrate formation in petroleum and natural gas production systems through the use of low dosage hydrate inhibitors which include reaction products of non-halide-containing inorganic acids, organic acids, and organic amines. The use of these non-halide-containing reaction products rather than chloride containing acids or alkylating agents avoids corrosion and stress cracking caused by residual inorganic chloride and other inorganic, halide-containing acids. The anti-agglomerate compositions can be administered continuously to effectively inhibit gas hydrate formation. In preferred embodiments, the anti-agglomerate compositions are mixtures of reaction products of non-halide-containing organic acids and organic amines.
Type:
Grant
Filed:
September 26, 2011
Date of Patent:
November 24, 2015
Assignee:
Multi-Chem Group, LLC
Inventors:
Danny Durham, Curtis Conkle, James Russum
Abstract: An apparatus and method for remotely monitoring the temperature of acrolein in a storage tank has a temperature sensor in communication with the acrolein in the tank and with a temperature transmitter. A global positioning receiver/transmitter communicates with the temperature transmitter and sends the temperature data to a remote base station via a linking satellite while also providing location data about the storage tank. At the base station, the temperature data related to the actual temperature of the acrolein in the tank is compared to predetermined temperature set points. These predetermined set points correlate to polymerization reaction of the acrolein. When the set points are reached, a response processor initiates a response to control the polymerization reaction of the acrolein in the storage tank.
Abstract: A slick water fracturing fluid including a brine, an inorganic nitrate, a nitrogen reducing bacteria, a scale inhibitor selected from the group consisting of a polyacrylate polymer, a polyacrylate copolymer, a polyacrylate terpolymer, and mixtures thereof, and a friction reducer, wherein the friction reducer is a polyacrylamide.
Abstract: A method of controlling sulfides in a fluid including determining selected conditions of the fluid and selecting a nitrogen reducing bacteria (NRB) based on those conditions. The method further includes injecting an NRB into the fluid and injecting an inorganic nitrate into the fluid.
Abstract: A method of controlling a deleterious bacteria in a fluid including injecting a nitrite or nitrate into the fluid, identifying a phage capable of infecting the deleterious bacteria, and injecting the phage into the fluid.
Abstract: A method of controlling a deleterious bacteria in oil and gas production, oil and gas completion fluids or other industrial fluids is described which includes identifying a phage capable of infecting the deleterious bacteria, identifying a biocide compatible with the phage and effective against the deleterious bacteria and injecting the biocide and the phage into the oil and gas production, oil and gas completion or other industrial fluid.
Abstract: A method for scavenging hydrogen sulfide from geothermal steam in a condenser under vacuum. A fine curtain of atomized acrolein-water droplets may be sprayed into geothermal steam condensers in an amount of approximately 2:1 molar ratio of acrolein to H2S based on hydrogen sulfide in the incoming steam from the turbine. The range being approximately 0.1 ppm to 500 ppm of sulfide. The acrolein is allowed to react with the gas phase H2S to form non-volatile aldehyde byproducts which partition into the water phase, are returned to the cooling tower and ultimately removed by normal cooling-tower blow down.
Abstract: A method of determining the suitability of a surfactant for use in a formation can include sampling water in the formation, providing at least two surfactants, and mixing each of the surfactants with the formation water to form surfactant/water samples. The method can further include determining the solubility of each surfactant with the formation water, comparing the solubility of each surfactant with the other surfactant, and assigning a solubility performance value for each surfactant based on its solubility in the formation water sample compared to the other surfactant.