Abstract: Photovoltaic cells comprising an active layer comprising, as p-type material, conjugated polymers such as polythiophene and regioregular polythiophene, and as n-type material at least one fullerene derivative. The fullerene derivative can be C60, C70, or C84. The fullerene also can be functionalized with indene groups. Improved efficiency can be achieved.

Abstract: An in-situ method and system of collecting, in a liquid, non-agglomerated fullerenic material from a gaseous suspension is provided. The method and system collects non-agglomerated fullerenic material by contacting a gaseous suspension comprising fullerenic material with a suspension liquid, so as to capture the fullerenic material in the suspension liquid; and collecting the liquid suspension as a suspension liquid containing the fullerenic material. This method and system may be particularly useful for collecting fullerenes or nanotubes and maintaining them in solution in non-agglomerated states.

Abstract: Functionalized carbon nanotubes and dispersions containing functionalized carbon nanotubes are provided. Exemplary functionalized carbon nanotubes include optionally substituted indene-based moieties. Methods of making functionalized carbon nanotubes and dispersions containing functionalized carbon nanotubes are provided. Methods of making conductive carbon nanotube dispersions, including films, are provided. Such methods include heating carbon nanotubes in a solvent in the absence of externally applied energy, to obtain an adduct that includes the solvent moiety bound to the carbon nanotube. Where the solvent includes an indene-based compound, the carbon nanotube thus prepared includes optionally indene-based moieties bound to the carbon nanotubes.

Abstract: The invention relates to improved fullerene derivatives, to methods for their synthesis and any educts or intermediates used in such methods, to compositions and formulations containing fullerene derivatives, to the use of the fullerene derivatives, compositions and formulations in, or for the preparation of, organic electronic (OE) devices like for example organic photovoltaic (OPV) devices or organic photodetectors (OPD), and to OE, OPV and OPD devices comprising, or being prepared from, these fullerene derivatives, compositions or formulations.

Abstract: Photovoltaic cells comprising an active layer comprising, as p-type material, conjugated polymers such as polythiophene and regioregular polythiophene, and as n-type material at least one fullerene derivative. The fullerene derivative can be C60, C70, or C84. The fullerene also can be functionalized with indene groups. Improved efficiency can be achieved.

Abstract: A membrane stack that includes a first polymer layer, a second polymer layer, and a nanostructured carbon material layer between the first polymer layer and the second polymer layer. The nanostructured carbon material layer includes a plurality of nanostructured carbon material intercalated with one or more proton conducting material or coated with one or more solid superacid particles. The first polymer layer and the second polymer layer are capable of transporting protons. The membranes described herein can be used as polymer electrolyte membranes in fuel cells and electrolyzers.

Abstract: Photovoltaic cells comprising an active layer comprising, as p-type material, conjugated polymers such as polythiophene and regioregular polythiophene, and as n-type material at least one fullerene derivative. The fullerene derivative can be C60, C70, or C84. The fullerene also can be functionalized with indene groups. Improved efficiency can be achieved.

Abstract: Functionalized carbon nanotubes and dispersions containing functionalized carbon nanotubes are provided. Exemplary functionalized carbon nanotubes include optionally substituted indene-based moieties. Methods of making functionalized carbon nanotubes and dispersions containing functionalized carbon nanotubes are provided. Methods of making conductive carbon nanotube dispersions, including films, are provided. Such methods include heating carbon nanotubes in a solvent in the absence of externally applied energy, to obtain an adduct that includes the solvent moiety bound to the carbon nanotube. Where the solvent includes an indene-based compound, the carbon nanotube thus prepared includes optionally indene-based moieties bound to the carbon nanotubes.

Abstract: Embodiments of tunneling barriers and methods for same can embed molecules exhibiting a monodispersion characteristic into a dielectric layer (e.g., between first and second layers forming a dielectric layer). In one embodiment, by embedding C60 molecules inbetween first and second insulating layers forming a dielectric layer, a field sensitive tunneling barrier can be implemented. In one embodiment, the tunneling barrier can be between a floating gate and a channel in a semiconductor structure. In one embodiment, a tunneling film can be used in nonvolatile memory applications where C60 provides accessible energy levels to prompt resonant tunneling through the dielectric layer upon voltage application. Embodiments also contemplate engineered fullerene molecules incorporated within the context of at least one of a tunneling dielectric and a floating gate within a nonvolatile flash memory structure.

Abstract: Improved methods of fullerene derivative production including use of less solvent, or elimination of solvent, as well as use of shorter reaction times and higher reaction temperatures. Methods useful for production of bis-, tris-, tetra-, penta-, and hexa-fullerene derivatives. Indene is a preferred derivative. The derivatives used in active layers for solar cell applications.

Abstract: Photovoltaic cells comprising an active layer comprising, as p-type material, conjugated polymers such as polythiophene and regioregular polythiophene, and as n-type material at least one fullerene derivative. The fullerene derivative can be C60, C70, or C84. The fullerene also can be functionalized with indene groups. Improved efficiency can be achieved.

Abstract: Core shell particles and bulk-heterojunction organic photovoltaic devices using the core shell particles are described. In particular, core shell particles having a core particle and a shell of a second material and bulk-heterojunction organic photovoltaic devices using the core-shell particles are described. The core-shell particles can have a core particle with an electron donating material or a core particle with an electron donating material. Formation of a hulk-heterojunction organic photovoltaic device using such an core-shell particles forming an interpenetrating network with the an electron donating or electron accepting phase is also described.

Abstract: Photovoltaic cells comprising an active layer comprising, as p-type material, conjugated polymers such as polythiophene and regioregular polythiophene, and as n-type material at least one fullerene derivative. The fullerene derivative can be C60, C70, or C84. The fullerene also can be functionalized with indene groups. Improved efficiency can be achieved.

Abstract: Core shell particles and bulk-heterojunction organic photovoltaic devices using the core shell particles are described. In particular, core shell particles having a core particle and a shell of a second material and bulk-heterojunction organic photovoltaic devices using the core-shell particles are described. The core-shell particles can have a core particle with an electron donating material or a core particle with an electron donating material. Formation of a hulk-heterojunction organic photovoltaic device using such an core-shell particles forming an interpenetrating network with the an electron donating or electron accepting phase is also described.

Abstract: A mode of combustion and multi-component reactor to accomplish this mode of combustion are disclosed which produces fullerenes and fullerenic material by combustion. This mode consists of de-coupling an oxidation region of a flame from a post-flame region, thus giving greater control over operating parameters, such as equivalence ratio, temperature, and pressure; allows conditions of the operating parameters of the combustion reaction to be attained which would not be easily attained by conventional methods; and offers the ability to more easily stabilize the combustion reactions to allow for higher throughputs of fuel and oxidant. Several embodiments of a primary zone of a multi-component reactor are also disclosed. Said primary zone serves as the oxidation region, operates on the principle of providing recycle to the reacting combustion mixture, and which may be operated as approximately a well-mixed reactor.

Abstract: Chemically functionalized fullerenes are useful in various applications as radical scavengers. These chemically functionalized fullerenes offer the advantages of preservation of the high innate radical scavenging efficiency of the fullerene cage and ease of synthesis of fullerene derivatives of desirably altered chemical and physical properties and single isomers. Further, they are based on a common intermediate chemistry and intermediates can be easily functionalized and tailored to various requirements.

Abstract: Purification methods for fullerene derivatives are described. The method comprises passing a solution of fullerene derivatives containing impurities such as other fullerene derivatives and polycyclic aromatic hydrocarbons through activated charcoals. Fullerene derivatives with high purity were obtained.

Abstract: A mode of combustion and multi-component reactor to accomplish this mode of combustion are disclosed which produces fullerenes and fullerenic material by combustion. This mode consists of de-coupling an oxidation region of a flame from a post-flame region, thus giving greater control over operating parameters, such as equivalence ratio, temperature, and pressure; allows conditions of the operating parameters of the combustion reaction to be attained which would not be easily attained by conventional methods; and offers the ability to more easily stabilize the combustion reactions to allow for higher throughputs of fuel and oxidant. Several embodiments of a primary zone of a multi-component reactor are also disclosed. Said primary zone serves as the oxidation region, operates on the principle of providing recycle to the reacting combustion mixture, and which may be operated as approximately a well-mixed reactor.

Abstract: An optically transparent, electrically conductive hybrid film includes a carbon nanotubes network deposited on a substrate, and a population of transparent conductive inorganic nanoparticles distributed throughout the carbon nanotubes network to provide a conductive transparent hybrid film.

Abstract: A mode of combustion and multi-component reactor to accomplish this mode of combustion are disclosed which produces fullerenes and fullerenic material by combustion. This mode consists of de-coupling an oxidation region of a flame from a post-flame region, thus giving greater control over operating parameters, such as equivalence ratio, temperature, and pressure; allows conditions of the operating parameters of the combustion reaction to be attained which would not be easily attained by conventional methods; and offers the ability to more easily stabilize the combustion reactions to allow for higher throughputs of fuel and oxidant. Several embodiments of a primary zone of a multi-component reactor are also disclosed. Said primary zone serves as the oxidation region, operates on the principle of providing recycle to the reacting combustion mixture, and which may be operated as approximately a well-mixed reactor.