Abstract: A method of producing nanoparticles comprises effecting conversion of a molecular cluster compound to the material of the nanoparticles. The molecular cluster compound comprises a first ion and a second ion to be incorporated into the growing nanoparticles. The conversion can be effected in the presence of a second molecular cluster compound comprising a third ion and a fourth ion to be incorporated into the growing nanoparticles, under conditions permitting seeding and growth of the nanoparticles via consumption of a first molecular cluster compound.

Abstract: Methods of synthesizing transition metal dichalcogenide nanoparticles include forming a metal-amine complex, combining the metal-amine complex with a chalcogen source in at least one solvent to form a solution, heating the solution to a first temperature for a first period of time, and heating the solution to a second temperature that is higher than the first temperature for a second period of time.

Abstract: LED devices emitting white light comprise a blue-emitting LED, green-emitting quantum dots (QDs) and red-emitting K2SiF6:Mn4+ (KSF) phosphor. A backlight unit (BLU) for a liquid crystal display (LCD) comprises one or more blue-emitting LEDs and a polymer film containing green-emitting QDs and KSF phosphor. The QDs and/or KSF phosphor may be encapsulated in beads that provide protection from oxygen and/or moisture.

Abstract: Organically capped quantum dots are made by functionalizing the surfaces of QDs of various architectures with a combination of 6-mercaptohexanol (MCH) and 2-[2-(2-methoxyethoxy)-ethoxy]-acetic acid (MEEAA). Such MCH/MEEAA-capped QDs exhibit improved compatibility with solvents used in the fabrication of QD-containing films of light emitting devices, such as liquid crystal displays.

Abstract: Highly stable films containing semiconductor nanoparticles (“quantum dots”) are prepared from resins containing a fast-curing inner phase having a high glass transition temperature (Tg) and certain inner phase/outer phase combinations. The resins may comprise an inner phase and outer phase (but may appear to be a single phase due to their homogeneous appearance when viewed using an optical microscope). The method provides a highly scalable and cost-effective procedure for preparing films that are resistant to light, elevated temperatures, moisture, and oxygen.

Abstract: Quantum dot semiconductor nanoparticle compositions that incorporate ions such as zinc, aluminum, calcium, or magnesium into the quantum dot core have been found to be more stable to Ostwald ripening. A core-shell quantum dot may have a core of a semiconductor material that includes indium, magnesium, and phosphorus ions. Ions such as zinc, calcium, and/or aluminum may be included in addition to, or in place of, magnesium. The core may further include other ions, such as selenium, and/or sulfur. The core may be coated with one (or more) shells of semiconductor material. Example shell semiconductor materials include semiconductors containing zinc, sulfur, selenium, iron and/or oxygen ions.

Abstract: A core/shell semiconductor nanoparticle structure comprises a core comprising a halide perovskite semiconductor and a shell comprising a semiconductor material that is not a halide perovskite (and that is substantially free of halide perovskites). The halide perovskite semiconductor core may be of the form AMX3, wherein: A is an organic ammonium such as CH3NH3+, (C8H17)2(CH3NH3)+, PhC2H4NH3+, C6H11CH2NH3+ or 1-adamantyl methyl ammonium, an amidinium such as CH(NH2)2+, or an alkali metal cation such as Li+, Na+, K+, Rb+ or Cs+; M is a divalent metal cation such as Mg2+, Mn2+, Ni2+, Co2+, Pb2+, Sn2+, Zn2+, Ge2+, Eu2+, Cu2+ or Cd2+; and X is a halide anion (F?, Cl?, Br?, I?) or a combination of halide anions.

Abstract: Organically capped quantum dots are made by functionalizing the surfaces of QDs of various architectures with a combination of 6-mercaptohexanol (MCH) and 2-[2-(2-methoxyethoxy)-ethoxy]-acetic acid (MEEAA). Such MCH/MEEAA-capped QDs exhibit improved compatibility with solvents used in the fabrication of QD-containing films of light emitting devices, such as liquid crystal displays.

Abstract: A phototherapy device comprises a face mask having a rigid (or semi-rigid) shell contoured to the human face. A flexible array of LEDs is affixed to the inner surface of the mask. A flexible, quantum dot-containing film is situated over the flexible array of LEDs. The quantum dots in the QD-containing film are selected to photo-luminesce at one or more particular wavelengths in response to photoexcitation by the light emitted from the LEDs. The LEDs emit “primary light” and the quantum dots down-convert at least a portion of the primary light to “secondary light.” The flexible, quantum dot-containing film may be interchangeable such that the wavelength(s) of the secondary light may be tailored to various phototherapy treatment regimes.

Abstract: An illuminated sign comprises a source of blue light; a quantum dot-containing film that produces green light when illuminated by the source of blue light; and, a patterned blue cutoff filter in optical communication with the quantum dot-containing film configured to allow a mixture of excess blue light from the source of blue light and green light from the quantum dot-containing film to pass through the pattern. The mixture of blue light and green light produces a pseudo white light. The illuminated sign may thus comprise pseudo white letters and/or graphics on a luminous green background.

Abstract: The advent of graphene and related 2D materials has recently led to a new technology: heterostructures based on these atomically thin crystals. The paradigm proved itself extremely versatile and led to rapid demonstration of tunnelling diodes with negative differential resistance, tunnelling transistors, photovoltaic devices and so on. In the present invention, the complexity and functionality of such van der Waals heterostructures is taken to the next level by introducing quantum wells (QWs) engineered with one atomic plane precision. We describe light-emitting diodes (LEDs) made by stacking metallic graphene, insulating hexagonal boron nitride and various semiconducting monolayers into complex but carefully designed sequences.

Abstract: A template-assisted method for the synthesis of 2D nanosheets comprises growing a 2D material on the surface of a nanoparticle substrate that acts as a template for nanosheet growth. The 2D nanosheets may then be released from the template surface, e.g. via chemical intercalation and exfoliation, purified, and the templates may be reused.

Abstract: A lighting fixture for promoting the development of animals comprises a backlight, such as an LED or an array of LEDs, and a series of one or more retractable, rotatable or interchangeable lenses comprising quantum dots, such that the color and/or color temperature of the light emitted by the lighting fixture can be altered and optimized during animal development. A lighting fixture adapted for use on an aquarium may be in the form factor of a standard fluorescent tube and comprise one or more LEDs and a quantum dot-containing film for down-converting at least a portion of the light emitted by the LEDs so as to provide optimum wavelengths for photosynthesis by aquarium plants while simultaneously providing attractive display lighting for the aquarium fish.

Abstract: Compositions and methods are described for delivery of drugs to desired tissues via soluble quantum dots.

Abstract: Quantum dot semiconductor nanoparticle compositions that incorporate ions such as zinc, aluminum, calcium, or magnesium into the quantum dot core have been found to be more stable to Ostwald ripening. A core-shell quantum dot may have a core of a semiconductor material that includes indium, magnesium, and phosphorus ions. Ions such as zinc, calcium, and/or aluminum may be included in addition to, or in place of, magnesium. The core may further include other ions, such as selenium, and/or sulfur. The core may be coated with one (or more) shells of semiconductor material. Example shell semiconductor materials include semiconductors containing zinc, sulfur, selenium, iron and/or oxygen ions.

Abstract: Certain dithio-compounds have been found to be superior capping ligands for quantum dot (QD) nanoparticles. Example dithio-ligands include dithiocarbamate ligands. These strongly binding ligands are capable of coordinating to both positive and negative atoms on the surface of the nanoparticle. The ligands are bi-dentate and thus their approach to the QD surface is not as sterically hindered as is the approach of mono-dentate ligands. These ligands can therefore completely saturate the QD surface.

Abstract: A molded nanoparticle phosphor for light emitting applications is fabricated by converting a suspension of nanoparticles in a matrix material precursor into a molded nanoparticle phosphor. The matrix material can be any material in which the nanoparticles are dispersible and which is moldable. The molded nanoparticle phosphor can be formed from the matrix material precursor/nanoparticle suspension using any molding technique, such as polymerization molding, contact molding, extrusion molding, injection molding, for example. Once molded, the molded nanoparticle phosphor can be coated with a gas barrier material, for example, a polymer, metal oxide, metal nitride or a glass. The barrier-coated molded nanoparticle phosphor can be utilized in a light-emitting device, such as an LED. For example, the phosphor can be incorporated into the packaging of a standard solid state LED and used to down-convert a portion of the emission of the solid state LED emitter.

Abstract: Surface-modified nanoparticles are produced by associating ligand interactive agents with the surface of a nanoparticle. The ligand interactive agents are bound to surface modifying ligands that are tailored to impart particular solubility and/or compatibility properties. The ligand interactive agents are crosslinked via a linking/crosslinking agent, such as hexamethoxymethylmelamine or a derivative thereof. The linking/crosslinking agent may provide a binding site for binding the surface modifying ligands to the ligand interactive agents.

Abstract: A scalable method for the manufacture of narrow, bright, monodisperse, photo-luminescent quantum dots prepared in the presence of a Group II-VI molecular seeding cluster fabricated in situ from a zinc salt and a thiol or selenol compound. Exemplary quantum dots have a core containing indium, phosphorus, zinc and either sulfur or selenium.

Abstract: The surfaces of nanoparticles (QDs) are modified with amphiphilic macromolecules, for example, amphiphilic copolymers. The surface modification renders the QDs more compatible with oxygen-excluding matrices, such as epoxy resin, polyurethane resin, polyester resins or any hydrophilic inorganic/organic hybrid resin such as (meth)acrylate-functionalized polyhedral oligomeric silsesquioxane (POSS).