Abstract: Process for the polymerization of olefins comprising contacting an olefin, admixed with an oxygen-containing gas, with a supported organophosphoryl-chromium oxide catalyst.

Abstract: Novel high pore volume, high purity alumina gels and catalysts prepared therefrom are provided by a unique alumina gel preparation comprising hydrolyzing an aluminum alcoholate in a medium of a mixture of water and acetone aging the resultant product and thereafter washing with acetone. Processes for the polymerization of olefins utilizing the afore-described alumina gels are also included herein.

Abstract: An olefin polymerization catalyst comprising a silica xerogel support having a pore volume greater than about 2.0 cc/g, the major portion of which volume is provided by pores having pore diameters ranging from 300 to 600 A and a surface area ranging from 200 to 500 m.sup.2 /g, and having deposited thereon a metal-containing catalytic material, such as chromium oxide, or other metal oxide. A suitable hydrogel is treated with a water miscible organic liquid to substantially displace the aqueous phase and the resultant organogel with or without intermediate drying is then impregnated by a concentrated aqueous solution of a metal salt decomposable to the oxide on subsequent calcination. Also disclosed is a polymerization process utilizing such a catalyst for the preparation of polymers and copolymers of 1-olefins having a maximum of 8 carbon atoms in the chain and having no branching nearer the double bond than the 4-position, e.g., ethylene polymers.

Abstract: Olefin polymerization catalysts comprised of a supported adduct of a trialkyl-dialkylphosphato-titanate and chromium trioxide, processes for their preparation and polymerization processes employing the same.

Abstract: Olefin polymerization catalysts are prepared by depositing an organophosphoryl chromium product and an aluminum compound on an inorganic support material, and heating the support material in a non-reducing atmosphere at a temperature above about 300.degree. C. up to the decomposition temperature of the support material.

Abstract: Supported catalyst compositions incorporating preformed materials comprising the reaction product of organophosphorus compounds such as the organophosphates and organophosphites with chromium trioxide, wherein the organic moiety is a hydrocarbon radical, e.g., alkyl, aralkyl, aryl, cycloalkyl, or the like or combinations thereof. Typical supports constitute an inorganic material of high surface area, especially a high pore volume (>1.96 cc/g) silica xerogel. Catalytically promoted polymerizations of 1-olefins proceed efficiently to products of specially adapted utility for molding, and particularly the production of blow molded articles. The polymerization activity of the catalyst compositions is promoted by heating in a dry, oxygen containing atmosphere. The catalysts are utilized alone or in conjunction with other catalytic ingredients such as organometallic and/or organo non-metallic reducing agents.

Abstract: Olefin polymerization catalysts are prepared by depositing an organophosphoryl chromium product and an aluminum acetyl acetonate on an inorganic support material, and heating the support material in a non-reducing atmosphere at a temperature above about 300.degree. C. up to the decomposition temperature of the support material.

Abstract: Polymerization of 1-olefins is conducted with a supported catalyst consisting essentially of a polymeric hydrocarbon aluminate comprising at least one ##STR1## unit.

Abstract: Olefin polymerization catalysts are prepared by depositing an organophosphoryl chromium product and an aluminum compound on an inorganic support material, and heating the support material in a non-reducing atmosphere at a temperature above about 300.degree. C. up to the decomposition temperature of the support material.

Abstract: A continuously operated liquid-solids separator for separating a powdered resin material suspended in water forming a slurry by permitting the resin, which is of a lower specific gravity than the water, to float or be impelled upwardly within a separator vessel or upright tank from which it is withdrawn through an outlet orifice as a thickened slurry.

Abstract: A plug valve adapted to meter precise quantities of material passing therethrough in which a cylindrical valve plug is rotatably mounted in a cylindrically shaped aperture in a valve body. First and second sets of radially extending inlet and outlet passageways are connected to the valve body aperture, with each inlet passageway being radially opposite a corresponding outlet passageway. Two orthogonally oriented, nonintersecting valve ports extend through the valve plug perpendicular to its axis of rotation, the ports being closely spaced from each other along the axis and with the diameter of each valve port being approximately one-half the diameter of the passageways such that one valve port connects one set of inlet and outlet passageways while the orthogonally positioned second port simultaneously connects the second set of inlet and outlet passageways.

Abstract: Catalysts, especially for olefin polymerization are prepared by coating an aluminum compound on a selected high pore volume silica gel, and calcining the support at temperatures of from about 200.degree. to 2000.degree. F. The preferred catalyst is prepared with an inorganic support material as aforesaid, thereafter depositing an organophosphoryl chromium compound thereon, and activating the thus-treated support by heating in a non-reducing, preferably oxygen-containing, atmosphere at temperatures of from about 800.degree. to 2000.degree. F. The activated, supported catalyst composition may, but need not necessarily, be combined with a metallic and/or non-metallic reducing agent, to provide a catalyst system useful in the polymerization of 1-olefins.

Abstract: An olefin polymerization catalyst is prepared by depositing a poly (di-.mu.-dihydrocarbylphosphinatohydroxyaquochromium (III)) compound or the corresponding anhydrous compound upon an inorganic support material and calcining the impregnated support material in a non-reducing atmosphere above 300.degree. C. up to the decomposition temperature of the support material to provide an activated catalyst. The catalyst exhibits high productivity and produces polymers having high melt indices.

Abstract: Catalysts, especially for olefin polymerization are prepared by coating an aluminum compound on a selected high pore volume silica gel, and calcining the support at temperatures of from about 200.degree. to 2000.degree. F. The preferred catalyst is prepared with an inorganic support material as aforesaid, thereafter depositing an organophosphoryl chromium compound thereon, and activating the thus-treated support by heating in a non-reducing, preferably oxygen-containing, atmosphere at temperatures of from about 800.degree. to 2000.degree. F. The activated, supported catalyst composition may, but need not necessarily, be combined with a metallic and/or non-metallic reducing agent, to provide a catalyst system useful in the polymerization of 1-olefins.BACKGROUND OF THE INVENTIONThe modification of silica gels for catalytic activity is known as discussed in Burwell, Chemtech, pp. 370-377 (1974).The use of chromium compounds in the polymerization of olefins is well-known. U.S. Pat. Nos.

Abstract: Silica xerogels having pore volumes greater than about 2.0 cc/g., the major portion of which volumes are provided by pores having pore diameters ranging from 300 to 600 A, and surface areas ranging from 200 to 500 m.sup.2 /g. Xerogels having such cumulative pore volume, pore diameter distribution, and surface area characteristics are useful as supports for stereospecific catalysts for particle form olefin polymerization reactions effecting the production of low molecular weight, high melt index polyolefins.

Abstract: Olefin polymerization catalysts are prepared by depositing a chromium compound and an aluminum compound on an inorganic support material and heating the support material in a non-reducing atmosphere at a temperature above about 300.degree. C up to the decomposition temperature of the support material. The supported chromium and aluminum compound is then combined with a metallic and/or non-metallic reducing agent, to provide a catalyst system useful in the polymerization of 1-olefins.

Abstract: Supported catalyst compositions made by incorporating preformed materials comprising the reaction product of organophosphorus compounds such as the organophosphates and organophosphites with chromium trioxide, wherein the organic moiety is a hydrocarbon radical, e.g., alkyl, aralkyl, aryl, cycloalkyl, or the like or combinations thereof. Typical supports constitute an inorganic material of high surface area, especially a high pore volume (>1.96 cc/g) silica xerogel. The catalysts are activated by heating in a dry, oxygen containing atmosphere. The catalysts are utilized alone or in conjunction with other catalytic ingredients such as organometallic and/or organo non-metallic reducing agents. Polymerizations of 1-olefins promoted with the subject catalysts proceed efficiently to products of specially adapted utility for molding, particularly to resins useful for the production of blow molded articles.

Abstract: Olefin polymerization catalysts are prepared by depositing a chromium compound and an aluminum compound on an inorganic support material and heating the support material in a non-reducing atmosphere at a temperature above about 300.degree.C up to the decomposition temperature of the support material. The supported chromium and aluminum compound is then combined with a metallic and/or non-metallic reducing agent, to provide a catalyst system useful in the polymerization of 1-olefins.

Abstract: An olefin polymerization catalyst comprising a silica xerogel support having a pore volume greater than about 2.0 cc/g, the major portion of which volume is provided by pores having pore diameters ranging from 300 to 600 A and a surface area ranging from 200 to 500 m.sup.2 /g, and having deposited thereon a metal-containing catalytic material, such as chromium oxide, or other metal oxide. Further, a polymerization process utilizing such a catalyst for the preparation of polyolefins having relatively low molecular weights and high melt indexes without loss of catalyst activity, especially a process for the preparation of polymers and copolymers of 1-olefins having a maximum of 8 carbon atoms in the chain and having no branching nearer the double bond than the 4-position, e.g., ethylene polymers.

Abstract: A plug valve adapted to meter precise quantities of material passing therethrough in which a cylindrical valve plug is rotatably mounted in a cylindrically shaped aperture in a valve body. First and second sets of radially extending inlet and outlet passageways are connected to the valve body aperture, with each inlet passageway being radially opposite a corresponding outlet passageway. Two orthogonally oriented, nonintersecting valve ports extend through the valve plug perpendicular to its axis of rotation, the ports being closely spaced from each other along the axis and with the diameter of each valve port being approximately one-half the diameter of the passageways such that one valve port connects one set of inlet and outlet passageways while the orthogonally positioned second port simultaneously connects the second set of inlet and outlet passageways.