Patents Assigned to National Starch & Chemical Investment Holding Corporation
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Patent number: 5059656Abstract: The two-solution acrylic adhesive composition of this invention is composed of a solution A which has as its necessary ingredients (1) a chlorosulfonated polyethylene, (2) a (meth)acrylate monomer, and (3) an organic peroxide, and a solution B which has as its necessary ingredients (4) a butadiene-acrylonitrile copolymer elastomer (NBR), (5) a (meth)acrylate monomer, and (6) an aminealdehyde condensate.Type: GrantFiled: December 28, 1989Date of Patent: October 22, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventor: Hideoki Tsuji
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Patent number: 5059479Abstract: A pressure-sensitive adhesive emulsion composition, characterized in that it is a pressure-sensitive adhesive emulsion composition containing the ingredients (A) and (B) below; the content of ingredient (B) is set at 1-70 solid parts per 100 solid parts by weight of the emulsion composition.(A) A polymer derived from at least one compound selected from a group including alkyl acrylates, alkyl methacrylates, and vinyl compounds, and having a glass transition temperature in the range of -60.degree. C. to -30.degree. C.(B) A bituminous emulsifier with an average particle diameter of the emulsified particles of 0.5-3.0 .mu.m.Type: GrantFiled: December 29, 1989Date of Patent: October 22, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventors: Hajime Yuyama, Fumio Maekawa, Kazuo Umekage
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Patent number: 5057568Abstract: A solvented polyurethane adhesive composition comprising 20 to 40% by weight of diphenylmethane diisocyanate, 0.5 to 4.0% by weight of a caprolactone triol, 40 to 75% by weight of a neopentyl adipate ester diol, 0 to 10% by weight of at least one polypropylene oxide diol, and a functionally effective amount of a catalyst therefor.Type: GrantFiled: April 17, 1990Date of Patent: October 15, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventors: James Nowicki, Arthur Pruiksma
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Patent number: 5055503Abstract: A water resistant, starch-based alkaline corrugating adhesive which includes a polysaccharide graft copolymer containing a reactive aminoethyl halide group.Type: GrantFiled: June 26, 1989Date of Patent: October 8, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventors: Craig H. Leake, John J. Tsai, Eric A. Meier
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Patent number: 5049434Abstract: A pre-patterned device substrate device-attach transfer tape is described which allows a one step mounting of adhesive patterns on a device substrate in the desired configuration for later mount of surface mounted devices (e.g., semiconductor dies) thereon. The tape product contains the adhesive pattern in a mirror image to that desired on the exposed surface of the device substrate. The product of the present invention is utilized by bringing the tape product into contact with the device substrate so that the adhesive on the carrier film bonds to the desired surface of the device substrate thereby bringing the adhesive patterns into the desired configuration desired on the device substrate. The use of pressure and, possibly, heat preferentially bonds the adhesive to the device substrate and allows for later stripping of the support film from the support film/adhesive/device substrate composite.Type: GrantFiled: October 5, 1984Date of Patent: September 17, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventor: William M. Wasulko
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Patent number: 5049634Abstract: A derivatized graft polymer of a polysaccharide, a crosslinked graft polymer of a polysaccharide, and a derivatized and crosslinked graft polymer of a polysaccharide are prepared. The derivatized polymer has the structure Sacch-g-[(M--CH.dbd.N--Y).sub.x -g-[(M).sub.q ]; the crosslinked polymer has the structure Sacch-g-[(M--CH.dbd.N).sub.z -P].sub.w -g-[(M).sub.q ] or Sacch-g-[(M--CH.dbd.C).sub.z -P].sub.w -g-[(M).sub.q ]; the derivatized and crosslinked polymer has the structure Sacch-g-[(M--CH.dbd.N--Y).sub.x ]-g-[(M--CH.dbd.N)-P]-g-[(M).sub.q ] or Sacch-g-[(M--CH.dbd.N--Y).sub.x ]-g-[(M--CH.dbd.C).sub.z -P].sub.w -g-[(M).sub.q ]. Sacch represents a polysaccharide such as starch, gum, or cellulose; g-represents a graft; M represents one or more ethylenically or allylically unsaturated monomers, at least one of which contains an acetal or aldehyde; P represents a multivalen residue from a reagent containing more than one primary amine group or ketone group; --N.dbd.Type: GrantFiled: September 22, 1989Date of Patent: September 17, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventors: John J. Tsai, Patrick G. Jobe, Robert L. Billmers, Rama S. Chandran
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Patent number: 5047087Abstract: The invention provides cost effective cementiferous compositions having superior flow characteristics imparted by the incorporation therein of a copolymer of an ethylenically polymerizable carboxylic acid, an alkyl ester of a ethylenically polymerizable carboxylic acid and, optionally, a third ethylenically unsaturated comonomer.Type: GrantFiled: May 4, 1989Date of Patent: September 10, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventors: Peter G. Montague, Peter Bainbridge, John T. Hoarty
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Patent number: 5045393Abstract: A method for providing a polyolefin resin substrate with an adhesive coating having high adhesiveness and thermal resistance comprising the following steps:1. coating the surface of said polyolefin substrate with a primer film having at least 2 hydroxy groups, and2. coating said primer film with a molten layer of moisture setting hot melt urethane adhesive composition comprising a urethane prepolymer containing at least 2 NCO radicals.Type: GrantFiled: August 16, 1989Date of Patent: September 3, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventors: Shuichi Kumanoya, Makoto Yamamoto, Katsumi Sasaki, Masahiko Nishimura
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Patent number: 5043196Abstract: A biodegradable shaped product comprising an expanded high amylose starch product having at least 45% by weight amylose content, said expanded product having a low density, closed cell structure with good resilience and compressibility.Another embodiment provides a biodegradable packaging material comprising an expanded, low density, closed cell starch product, the starch having at least 45% by weight amylose content and the expanded product having a bulk density of less than about 2.0 lb/ft.sup.3, a resiliency of at least about 50%, and a compressibility of from about 100 to 800 g/cm.sup.2.Type: GrantFiled: December 5, 1989Date of Patent: August 27, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventors: Norman L. Lacourse, Paul A. Altieri
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Patent number: 5037700Abstract: Flexible laminates are prepared using a room temperature curable, water-borne laminating adhesive. The adhesive consists essentially of a copolymer emulsion of an alkyl acrylate, alkyl methacrylate, styrene or vinyl ester, or mixtures thereof, and an ethylenically unsaturated carboxylic acid, and optional selected comonomers, combined with an epoxy resin emulsion and a polyfunctional amine. The flexible laminates are characterized by rapid room temperature curing, high bond strength, superior heat resistance and chemical and water resistance.Type: GrantFiled: January 19, 1981Date of Patent: August 6, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventor: Irwin J. Davis
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Patent number: 5035930Abstract: A biodegradable shaped product comprising an expanded high amylose starch product having at least 45% by weight amylose content, said expanded product having a low density, closed cell structure with good resilience and compressibility.Another embodiment provides a biodegradable packaging material comprising an expanded, low density, closed cell starch product, the starch having at least 45% by weight amylose content and the expanded product having a bulk density of less than about 2.0 lb/ft.sup.3, a resiliency of at least about 50%, and a compressibility of from about 100 to 800 g/cm.sup.2.Type: GrantFiled: February 9, 1990Date of Patent: July 30, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventors: Norman L. Lacourse, Paul A. Altieri
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Patent number: 5032295Abstract: A polymer for use as a deflocculant in drilling muds comprising at least one unsaturated carboxylic acid or its anhydride or salt, at least one unsaturated sulfonic acid or its salt, at least one unsaturated cationic-containing monomer, and optionally, one or more unsaturated non-ionic monomer and/or one mono or di phosphate ester of an unsaturated alcohol.Type: GrantFiled: April 25, 1989Date of Patent: July 16, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventors: Gary F. Matz, James C. Long
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Patent number: 5030388Abstract: Water dispersible, self-emulsifiable triglyceride compositions are provided. The compositions comprise the reaction product of a) a triglyceride oil/olefinic acid (or anhydride) addition product and b) a water soluble monofunctional polyalkylene oxide.Type: GrantFiled: November 17, 1989Date of Patent: July 9, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventors: Gary T. Martino, Martin M. Tessler
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Patent number: 5030507Abstract: Emulsion binders which do not generate formaldehyde during cure are prepared for use in nonwoven products by using a emulsion copolymer comprising by weight about 100 parts C.sub.1 -C.sub.8 alkyl acrylate or C.sub.1 -C.sub.8 alkyl acrylates in combination with styrene, acrylonitrile, vinyl acetate and combinations thereof, about 1 to 20 parts hydroxyalkyl acrylate or methacrylate, about 2 to 20 parts meta or para isopropenyl-.alpha.,.alpha.-dimenthyl benyl isocyanate and optionally 0.1 to 5 parts of a multifunctional monomer. The binders are useful in the formation of heat resistant flexible products for use in roofing, flooring and filtering materials, as well as for facings and other applications in general purpose nonwoven products.Type: GrantFiled: January 12, 1990Date of Patent: July 9, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventors: Paul Mudge, Sirisoma Wanigatunga
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Patent number: 5030308Abstract: The bonding of semiconductor chips to a substrate is described wherein the first step involves the bonding of a tacky, curable and partially cured chip bonding adhesive, which is releasably supported on a support film, to the surface of the chip intended to be bonded to the substrate. The second step involves the further partial heat curing of the adhesive to convert it to a non-tacky state so that the adhesive will not undesirably stick during handling and storage operations. Thereafter, the chip with its adherent adhesive can be mounted to a substrate at elevated temperature to convert the adhesive to a more tacky state. The final step involves the curing of the adhesive after it has been used to bond the chip to the substrate.Type: GrantFiled: July 28, 1988Date of Patent: July 9, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventors: Gregory M. Sheyon, Joseph A. Aurichio
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Patent number: 5026765Abstract: Carpet coating compositions are disclosed which comprise 40 to 80 percent by weight filler and 20 to 60 percent by weight of a latex binder, the binder comprising an emulsion polymer ofa) 40 to 80% by weight of a vinyl ester of an alkomoic acid, the acid having from 1 to 13 carbon atoms;b) 5 to 25% by weight of a copolymerizable comonomer having a Tg of at least 50.degree. C.; and;c) 10 to 30% ethylene.Type: GrantFiled: December 15, 1989Date of Patent: June 25, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventors: Howard G. Katz, David Lunsford, Paul R. Mudge
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Patent number: 5026761Abstract: The present invention relates to an elastic paint composition, having a substantially uniform mixture comprising:(A) a water-based polymer emulsion; containing at least one monomer selected from the group consisting of acrylic esters and methacrylic esters having a glass transition temperature of 30.degree. to -60.degree. C., and(B) (1) a reactive compound dissolved in an organic solvent, selected from the group consisting of a compound having at least three methacryloyl radicals and a molecular weight of at least 200 that becomes hardened by the reaction of their methacryloyl radicals with ultraviolet rays, and(2) a compound having at least one double bond and a molecular weight of at least 300 that becomes hardened by the oxidation reaction at the double bond, wherein the amount of said organic solvent is in the range of 5 to 50 percent, based on the weight of water in said mixture.Type: GrantFiled: August 1, 1989Date of Patent: June 25, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventors: Motoyuki Takagi, Takuji Yoshimura, Yoshihiro Yamano
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Patent number: 5023368Abstract: Aminophosphonate-containing polymers of the formula:--B].sub.m [A].sub.nwhereinA represents repeating units from one or more ethylenically unsaturated comonomers;B is ##STR1## wherein R is hydrogen or methyl,X is hydrogen or an alkali metal,Z is CH.sub.2 --P(O)(OX).sub.2 or C.sub.1 -C.sub.6 alkyl, aryl, cyclohexyl or alkaryl, m/n is 0.01 to 0.5.The novel polymers of the present invention may be used as dispersants for concentrated aqueous particulate slurries, and as corrosion inhibitors and scale inhibitors in water treatment.Type: GrantFiled: June 8, 1989Date of Patent: June 11, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventors: John C. Leighton, Carmine P. Iovine
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Patent number: 5021507Abstract: The addition to urethane prepolymers of low molecular weight polymers formed from ethylenically unsaturated monomers which do not contain active hydrogen provides a hot melt adhesive which can be readily coated at a viscosity of 3000 to 50,000 cps. at 120.degree.C. without the need for additional tackifiers or plasticizers and which has improved initial cohesive strength as well as improved strength after aging of the cured bond. In a preferred embodiment of the invention, the ethylenically unsaturated monomers are polymerized in the non-isocyanate containing components of the isocyanate terminated prepolymer.Type: GrantFiled: May 27, 1988Date of Patent: June 4, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventors: Henry Stanley, Irwin Davis, Wen B. Chiao
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Patent number: 5021525Abstract: A process for the preparation of polymers containing at least one hydrophilic monomeric component and at least one hydrophobic monomeric component comprising the step of polymerizing the monomers in the presence of free radical polymerization initiators in an aqueous medium consisting of water and a cosolvent, wherein the amount of cosolvent is monitored so as to maintain the ratio of water to cosolvent equal or greater than unity during the reaction, thereby keeping the polymer as it forms in a sufficiently mobile condition and preventing homopolymerization and precipitation of the polymer from the hydrophobic monomer; thereby producing a polymer as a relatively high solids, low viscosity, opaque or semi-opaque product which is stable and slightly cloudy, opaque or semi-opaque, which exhibits no gelling, coagulation or product separation on standing and which, upon dilution to 0.25% solids content w/w, has a turbidity of at least 10 Nephelometric Turbidity units.Type: GrantFiled: June 12, 1989Date of Patent: June 4, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventors: Peter G. Montague, Philip A. Lagar, Peter Bainbridge