Patents Assigned to Neste Oil Oyj
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Publication number: 20110092724Abstract: A composition, which is suitable for the production of stilbene compounds, can be separated from tall oil. It contains esters of pinosylvin or pinosylvin derivatives and it is concentrated in relation to these. Preferably, the composition contains esters of pinosylvin monomethyl ethers, the acid part of which is formed of an inorganic acid or an organic acid, in particular an organic acid, which is present in the crude tall oil or which is generated from this oil during the process of refining it. Typically, such acids are fatty and resin acids and lower alkane acids. With the invention, it is possible to generate, at an industrial scale, product fractions, and the pinosylvin compounds which are separated from the fractions can be used as such or they can be further modified by means of different chemical methods.Type: ApplicationFiled: April 14, 2009Publication date: April 21, 2011Applicant: Neste Oil OyjInventor: Kosti Mokkila
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Publication number: 20110065940Abstract: The present invention relates to a method for the production of fat with a principal application as transportation biofuel or a component or raw material therefor. According to the method, cell masses, cell suspensions and/or liquid phases formed in the production of single cell oil, and/or biomass-containing side streams or microorganism cell masses for another purpose and/or originating from other sources, are contacted with a fat-production capable microorganism and the organism is allowed to produce fat. The resulting fat is recovered or the microorganism mass is passed to a single-cell oil production process. By means of the invention, the organic matter present in the cell mass and side streams of single-cell oil can be re-utilized for the production of the single-cell oil, thereby improving a total fat yield, as well as reducing an organic load of the side streams.Type: ApplicationFiled: June 24, 2010Publication date: March 17, 2011Applicant: Neste Oil OYJInventors: Heidi Kahelin, Simo Laakso, Ossi Pastinen, Miia Mujunen, Tarja Suomalainen
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Patent number: 7888542Abstract: The invention relates to a process for producing high-quality saturated base oil or a base oil component based on hydrocarbons. The process of the invention comprises two main steps, the oligomerization and deoxygenation. A biological starting material containing unsaturated carboxylic acids and/or esters of carboxylic acids is preferably used as the feedstock.Type: GrantFiled: December 12, 2006Date of Patent: February 15, 2011Assignee: Neste Oil OyjInventors: Eija Koivusalmi, Jukka Myllyoja, Jorma Matikainen
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Publication number: 20110015459Abstract: In the process of the invention, an aliphatic C2-C14 hydrocarbon product is prepared from natural fats or derivatives thereof. The process comprises the steps of: (i) providing a natural fat or derivative thereof, (ii) deoxygenating a natural fat or derivative thereof originating from step (i) to yield an aliphatic C9-C28 hydrocarbon, (iii) hydrocracking an aliphatic C9-C28 hydrocarbon originating from step (ii) to yield a product comprising an aliphatic C2-C14 hydrocarbon, (iv) isomerising an aliphatic C2-C14 hydrocarbon originating from step (iii) into an isomerised aliphatic C2-C14 hydrocarbon, and optionally (v) recovering an isomerised C2-C14 hydrocarbon originating from step (iv) as said C2-C14 hydrocarbon product. Pure and high quality light fuel is easily obtained in sufficient amounts.Type: ApplicationFiled: July 16, 2010Publication date: January 20, 2011Applicant: NESTE OIL OYJInventors: Pekka Aalto, Ville Alopaeus, Elina Harlin, Raimo Linnaila, Leena Rantanen-Kolehmainen
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Patent number: 7850841Abstract: The invention relates to a process for producing high-quality hydrocarbon base oil particularly of biological origin. The process of the invention comprises aldol condensation, hydrodeoxygenation, and isomerization steps. Aldehydes and/or ketones, preferably of biological origin are used as the feedstock.Type: GrantFiled: December 12, 2006Date of Patent: December 14, 2010Assignee: Neste Oil OyjInventors: Eija Koivusalmi, Ilkka Kilpeläinen, Pirkko Karhunen, Jorma Matikainen
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Publication number: 20100287821Abstract: The invention relates to a process for the manufacture of diesel range hydrocarbons wherein a feed comprising fresh feed is hydrotreated in a hydrotreating step and isomerised in an isomerisation step and the fresh feed contains at least 20% by weight triglyceride C12-C16 fatty acids or C12-C16 fatty acid esters or C12-C16 fatty acids or combinations of thereof and feed contains 50-20000 w-ppm sulphur calculated as elemental sulphur.Type: ApplicationFiled: June 30, 2006Publication date: November 18, 2010Applicant: Neste Oil OyjInventors: Jukka Myllyoja, Pekka Aalto, Elina Harlin
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Patent number: 7795484Abstract: A feedstock originating from renewable sources is converted to branched and saturated hydrocarbons without heteroatoms in the base oils distillation range by converting the fatty acids to olefins, which are subsequently oligomerised.Type: GrantFiled: June 14, 2007Date of Patent: September 14, 2010Assignee: Neste Oil OyjInventor: Eija Koivusalmi
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Patent number: 7604794Abstract: The present invention relates to an active and selective zeolite catalyst having MTT structure that is useful in skeletal isomerisation of light olefins. The method for the manufacture of the zeolite catalyst having MTT structure comprises the steps of a) preparing of a gel mixture capable of forming crystalline material, and the mixture comprising sources of alkali or alkaline earth metal (M), of an oxide of a trivalent element (X), of an oxide of a tetravalent element (Y), water and a directing agent (R), and the mixture having a composition, in terms of molar ratios, within the given ranges; b) maintaining the mixture under sufficient conditions, including a temperature of from about 100° C. to about 250° C., under dynamic mode of stirring until crystals of the material are formed, recovering the material; and c) removing the directing agent (R) partly or totally with a calcination procedure.Type: GrantFiled: March 9, 2004Date of Patent: October 20, 2009Assignee: Neste Oil OyjInventors: Marja Tiitta, Elina Harlin, Jaana Makkonen, Narendra Kumar, Dmitry Yu Murzin, Tapio Salmi
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Patent number: 7601880Abstract: The present invention relates to a method for catalytic deoxygenation of process fluids of olefin dimerization processes. According to the invention at least one process fluid containing oxygenates is brought into contact with a deoxygenation catalyst at, at least one location in a column or connected to a column. The present invention relates also to a process for dimerization of olefins, wherein at least part of olefin feed is dimerized in at least one dimerization reaction zone to produce a first product stream comprising oxygenates, and separating in a distillation zone, comprising one or more distillation columns, the first product stream into a second product stream and a third product stream and at, at least one location of the distillation column or a vessel connected to the distillation column is located a deoxygenation catalyst for decomposing oxygenates.Type: GrantFiled: September 17, 2004Date of Patent: October 13, 2009Assignee: Neste Oil OyjInventor: Antti Pyhälahti
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Publication number: 20090014354Abstract: The invention relates to a process for producing base oils, comprisings the steps where feedstock selected from ketones, aldehydes, alcohols, carboxylic acids, esters of carboxylic acids and anhydrides of carboxylic acids, alpha olefins, metal salts of carboxylic acids and corresponding sulphur compounds, corresponding nitrogen compounds and combinations thereof, is subjected to a condensation step and subsequently subjected to a combined hydrodefunctionalization and isomerization step.Type: ApplicationFiled: June 11, 2008Publication date: January 15, 2009Applicant: Neste Oil OyjInventors: Pekka Knuuttila, Eija Koivusalmi, Pekka Aalto, Rami Piilola
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Patent number: 7473811Abstract: The present invention relates to a process for the hydrogenation of olefins. The process comprises hydrogenation of a feed stock comprising more than 90 wt-% of olefins, carried out in a hydrogenation reactor comprising at least two reaction stages, wherein the feed stock is hydrogenated in the first reaction stage equipped with a cooling circuit and comprising a first and an optional second catalyst bed, and the effluent from the first reaction stage is hydrogenated in the final reaction stage comprising one or more catalyst beds and optionally equipped with a cooling circuit, the process is operated in trickling or pulse flow mode in a three phase reactor with a fixed catalyst bed and at least one catalyst of same or different type is used in each stage, the catalyst having different particle size and/or optionally different shape in at least two stages.Type: GrantFiled: November 12, 2004Date of Patent: January 6, 2009Assignee: Neste Oil OyjInventors: Isto Eilos, Antti Pyhälahti, Matti Nurminen, Veli-Matti Purola
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Publication number: 20080302001Abstract: The invention relates to a process for producing saturated C5-C28 hydrocarbons, suitable as diesel fuels, kerosenes and gasolines, comprising the steps where feedstock derived from starting material of biological origin, is subjected to a condensation step and subsequently subjected to a combined hydrodefunctionalization and isomerization step.Type: ApplicationFiled: June 10, 2008Publication date: December 11, 2008Applicant: Neste Oil OyjInventors: Eija Koivusalmi, Rami Piilola, Pekka Aalto
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Patent number: 7459597Abstract: A feedstock originating from renewable sources is converted to branched and saturated hydrocarbons without heteroatoms in the diesel fuel distillation range by skeletal isomerisation and deoxygenation carried out by hydrodeoxygenation or alternatively by combined decarboxylation and decarbonylation reactions, whereby the consumption of hydrogen is decreased.Type: GrantFiled: December 12, 2006Date of Patent: December 2, 2008Assignee: Neste Oil OyjInventors: Eija Koivusalmi, Juha Jakkula
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Patent number: 7367158Abstract: A fixing agent in the form of an oil/water type, lamellar emulsion or suspension in which the aqueous phase is the principal component, the aqueous phase containing water and a byproduct of agriculture or fermentation and the oil phase containing oil and emulsifiers. The emulsion or suspension is prepared by adding an aqueous solution to the oil phase in order to produce a water/oil type emulsion or suspension, by adding a portion of the aqueous phase in order to produce an inverse oil/water type emulsion or suspension, and by thereafter mixing the oil/water type emulsion or suspension with the remainder of the aqueous phase.Type: GrantFiled: February 13, 2002Date of Patent: May 6, 2008Assignees: Neste Oil Oyj, Kemira Growhow OyjInventors: Marja-Riitta Hakala, Pekka Lukkarinen, Jari Peltonen, Heikki Hero
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Patent number: 7344632Abstract: A process for producing alkyl ethers, by etherification of tertiary C4-7 olefins with an alkanol, comprising carrying out the etherification in reactor train system primarily configured for dimerization of isoolefins. In the etherification, the ratio of alkanol-to-olefin is 0.5 to 2, calculated from the amount of tertiary C4-7 olefins of the fresh feedstock. The invention makes it possible to change the product of the process from dimer to ether and vice versa merely by adjusting specific flows within the process. The present kind of process is therefore readily adaptable to fluctuating market demands for various gasoline octane-boosters (isooctane or MTBE).Type: GrantFiled: September 28, 2004Date of Patent: March 18, 2008Assignee: Neste Oil OYJInventors: Matti Koskinen, Petri Lindqvist, Harri Jarvelin
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Patent number: 7329788Abstract: Process for producing gasoline components. The process comprises feeding a fresh olefinic hydrocarbon feedstock to a reaction zone, in which its structure is first isomerized. The isomerized hydrocarbon is drawn out of the first reaction zone and conducted to a second reaction zone, where the isomerized hydrocarbon is dimerized. The dimerized reaction product is drawn out of the second reaction zone and separated from the flow in a separation zone. Because there are more isoolefins present in the dimerization unit feed, more isoolefin dimers useful as fuel components can be produced.Type: GrantFiled: December 22, 2003Date of Patent: February 12, 2008Assignee: Neste Oil OyjInventors: Marja Tiitta, Elina Harlin, Antti Pyhälahti
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Publication number: 20070299291Abstract: A feedstock originating from renewable sources is converted to branched and saturated hydrocarbons without heteroatoms in the base oils distillation range by converting the fatty acids to olefins, which are subsequently oligomerised.Type: ApplicationFiled: June 14, 2007Publication date: December 27, 2007Applicant: Neste Oil OyjInventor: Eija Koivusalmi
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Publication number: 20070293712Abstract: The present invention relates to a process for producing polyolefins wherein a feedstock comprising n-olefin or a mixture of n-olefins is dimerized in the presence of a solid acidic catalyst by passing the feedstock to a catalytic distillation apparatus comprising either a) a combination of a distillation column and a reactor comprising at least one catalyst bed, or b) a distillation column connected to one or more side reactors comprising at least one catalyst layer, recovering the unreacted n-olefin from the distillation column or the combination of the distillation column and the reactor at the upper part thereof as a side-stream to be combined with the feedstock, and the reaction product from the dimerization is hydrogenated.Type: ApplicationFiled: June 13, 2007Publication date: December 20, 2007Applicant: Neste Oil OyjInventors: Marja Tiitta, Anna-Mari Illikainen, Kari Kulmala, Vesa-Matti Lehtinen, Fredrik Nissfolk
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Patent number: 7304196Abstract: A method for dimerizing isobutene, wherein, in dimerizing conditions, the isobutene is brought into contact with a porous cation exchange resin comprising a styrene polymer, which is cross-linked with divinyl benzene, and any sulphonic acid groups adhering to the polymer. The harmful deactivation of this catalyst, which is caused by the accumulation of the oligomers and polymers of isobutene and other C4-olefins in the cation exchange resin catalyst, is essentially decreased by selecting the cation exchange resin from a group including cation exchange resins, the acid,capacity of which is 4.7 equivalents/kg at a minimum, and the portion of divinyl benzene units of which is 5% by weight at a minimum and smaller than 20% by weight.Type: GrantFiled: October 29, 2004Date of Patent: December 4, 2007Assignee: Neste Oil OYJInventors: Veli-Matti Purola, Sami Toppinen, Antti Pyhalahti, Marina Lindblad, Johan Gronqvist, Pirjo Siira
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Publication number: 20070191662Abstract: A process for dimerizing olefins in the presence of a catalyst, a hydrocarbon feedstock containing C4 to C6 isoolefins is subjected to dimerization. The process comprises the steps of contacting the C4 to C6 isoolefins at conditions conducive to dimerization with a catalytic material comprising an acidic mesoporous molecular sieve, the catalytic material being thermally stable at a temperature of at least 900° C., and carrying out the contacting step essentially in the absence of butadiene and water in the feedstock. By means of the invention, the dimerization process can be operated over extended periods of time with prolonged maintenance intervals.Type: ApplicationFiled: October 26, 2006Publication date: August 16, 2007Applicant: Neste Oil OyjInventors: Niilo Oikarinen, Kari Keskinen, Antti Pyhalahti, Veli-Matti Purola