Patents Assigned to Nippon A & L Inc.
  • Patent number: 11845825
    Abstract: A method for manufacturing a rubber-reinforced styrenic resin powder comprising 40% by mass or more of a rubbery polymer, satisfying the following conditions (1) to (4): (1) at least first and second coagulation baths are provided; (2) the first and second coagulation baths are connected; (3) an emulsified dispersion of fatty acid amide is supplied to the connecting part in an amount of 0.2 parts by mass to 2.0 parts by mass (solid content) with respect to 100 parts by mass (solid content) of a slurry; and (4) a temperature in the second coagulation bath is equal to or higher than a temperature in the first coagulation bath.
    Type: Grant
    Filed: March 26, 2019
    Date of Patent: December 19, 2023
    Assignee: NIPPON A&L INC.
    Inventor: Takashi Saito
  • Publication number: 20220251271
    Abstract: To provide a resin composition for plating and a plated molded article which are excellent in impact resistance and fluidity and which satisfy plating adhesion strength, plating deposition rate and thermal cycle resistance in a well-balanced manner.
    Type: Application
    Filed: April 22, 2022
    Publication date: August 11, 2022
    Applicant: NIPPON A&L INC.
    Inventors: Takayoshi FUJIWARA, Nana MATSUMOTO
  • Patent number: 10865266
    Abstract: The present invention provides a thermoplastic resin composition comprising 10 to 60 mass % of a graft copolymer (A), 1 to 20 mass % of a copolymer (B), 10 to 88 mass % of a copolymer (C), and 1 to 10 mass % of a copolymer (D). The contents of (A) to (D) are each relative to the total amount thereof. Copolymers (A), (B), (C), and (D) are as described in the specification.
    Type: Grant
    Filed: December 7, 2016
    Date of Patent: December 15, 2020
    Assignee: NIPPON A&L INC.
    Inventors: Taka Ikeda, Takayoshi Fujiwara
  • Patent number: 10723826
    Abstract: Provided is a modifier for polycarbonate, comprising: a graft polymer (A) having 30 to 80 parts by mass of a main chain composed of an ethylene-based polymer (a) and 70 to 20 parts by mass of a graft chain composed of a structural unit derived from a vinyl-based monomer (b), with a total amount of the main chain and the graft chain of 100 parts by mass; and a graft polymer (B) prepared by graft polymerization of a vinyl-based monomer to a rubbery polymer, at a mass ratio (A):(B)=9 to 98:91 to 2, wherein the vinyl-based monomer (b) comprises a specific aromatic vinyl monomer and vinyl cyanide monomer.
    Type: Grant
    Filed: March 22, 2018
    Date of Patent: July 28, 2020
    Assignee: NIPPON A&L INC.
    Inventors: Taisuke Yukawa, Kazuhiro Ishigaki
  • Patent number: 10538611
    Abstract: Provided is a graft copolymer (A) obtainable by graft-polymerizing, in the presence of 30 to 80 parts by mass of an ethylene-based polymer (a), an aromatic vinyl-based monomer (b) and, if necessary, another vinyl-based monomer (c) copolymerizable with the aromatic vinyl-based monomer (b) in a total amount of 20 to 70 parts by mass (provided that the sum of the components (a), (b) and (c) is 100 parts by mass), in which the ethylene-based polymer (a) has a density of 0.900 g/cm3 or more and less than 0.966 g/cm3, a number average molecular weight of 10,000 to 50,000, and a molecular weight distribution of 5 to 15, and the proportion of the ethylene-based polymer (a) molecules having a molecular weight of 10,000 or less is 5.5% or more.
    Type: Grant
    Filed: April 17, 2015
    Date of Patent: January 21, 2020
    Assignee: NIPPON A&L INC.
    Inventors: Kazuhiro Ishigaki, Kiyoshi Ikawa, Taisuke Yukawa
  • Patent number: 10508167
    Abstract: Provided is a graft copolymer (A) obtainable by graft-polymerizing, in the presence of 30 to 80 parts by mass of an ethylene-based polymer (a), an aromatic vinyl-based monomer (b) and, if necessary, another vinyl-based monomer (c) copolymerizable with the aromatic vinyl-based monomer (b) in a total amount of 20 to 70 parts by mass (provided that the sum of the components (a), (b) and (c) is 100 parts by mass), in which the ethylene-based polymer (a) has a density of 0.900 g/cm3 or more and less than 0.966 g/cm3, a number average molecular weight of 10,000 to 50,000, and a molecular weight distribution of 5 to 15, and the proportion of the ethylene-based polymer (a) molecules having a molecular weight of 10,000 or less is 5.5% or more.
    Type: Grant
    Filed: April 17, 2015
    Date of Patent: December 17, 2019
    Assignee: NIPPON A&L INC.
    Inventors: Kazuhiro Ishigaki, Kiyoshi Ikawa, Taisuke Yukawa
  • Publication number: 20190322786
    Abstract: To provide a resin composition for plating and a plated molded article which are excellent in impact resistance and fluidity and which satisfy plating adhesion strength, plating deposition rate and thermal cycle resistance in a well-balanced manner.
    Type: Application
    Filed: July 5, 2017
    Publication date: October 24, 2019
    Applicant: NIPPON A&L INC.
    Inventors: Takayoshi FUJIWARA, Nana MATSUMOTO
  • Patent number: 10118982
    Abstract: Provided is a graft copolymer (A) obtainable by graft-polymerizing, in the presence of 30 to 80 parts by mass of an ethylene-based polymer (a), an aromatic vinyl-based monomer (b) and, if necessary, another vinyl-based monomer (c) copolymerizable with the aromatic vinyl-based monomer (b) in a total amount of 20 to 70 parts by mass (provided that the sum of the components (a), (b) and (c) is 100 parts by mass), in which the ethylene-based polymer (a) has a density of 0.900 g/cm3 or more and less than 0.966 g/cm3, a number average molecular weight of 10,000 to 50,000, and a molecular weight distribution of 5 to 15, and the proportion of the ethylene-based polymer (a) molecules having a molecular weight of 10,000 or less is 5.5% or more.
    Type: Grant
    Filed: April 17, 2015
    Date of Patent: November 6, 2018
    Assignee: NIPPON A&L INC.
    Inventors: Kazuhiro Ishigaki, Kiyoshi Ikawa, Taisuke Yukawa
  • Publication number: 20170037175
    Abstract: Provided is a graft copolymer (A) obtainable by graft-polymerizing, in the presence of 30 to 80 parts by mass of an ethylene-based polymer (a), an aromatic vinyl-based monomer (b) and, if necessary, another vinyl-based monomer (c) copolymerizable with the aromatic vinyl-based monomer (b) in a total amount of 20 to 70 parts by mass (provided that the sum of the components (a), (b) and (c) is 100 parts by mass), in which the ethylene-based polymer (a) has a density of 0.900 g/cm3 or more and less than 0.966 g/cm3, a number average molecular weight of 10,000 to 50,000, and a molecular weight distribution of 5 to 15, and the proportion of the ethylene-based polymer (a) molecules having a molecular weight of 10,000 or less is 5.5% or more.
    Type: Application
    Filed: April 17, 2015
    Publication date: February 9, 2017
    Applicant: NIPPON A&L INC.
    Inventors: Kazuhiro ISHIGAKI, Kiyoshi IKAWA, Taisuke YUKAWA
  • Patent number: 9556302
    Abstract: Provided is a thermoplastic resin composition having excellent weather resistance, impact resistance, and fluidity and also excellent color developing properties and residence heat stability. A graft copolymer (A) prepared by graft polymerization of a certain amount of a specific monomer (a2)onto a certain amount of composite rubber (a1) composed of a conjugated diene rubber polymer and a cross-linked acrylic ester polymer. The tetrahydrofuran-soluble portion of the composite rubber (a1) has a weight-average molecular weight of 50000 or more in terms of polystyrene and a degree of swelling in toluene of 7.0 or more, or in the composite rubber contained in the graft copolymer, the number of particles having an equivalent-circle diameter of 150 nm or less is 50% or less of the total number of the composite rubber particles.
    Type: Grant
    Filed: July 11, 2012
    Date of Patent: January 31, 2017
    Assignee: NIPPON A&L INC.
    Inventors: Takumi Miyahiro, Masanori Ito, Seiji Tamai, Fumitoshi Takeda, Kazunori Takahashi, Tomoyoshi Akiyama, Hajime Tomita, Haruki Okuno, Shunsaku Kubota, Masaaki Okada, Atsushi Hashimoto, Yoshiaki Takada, Nobuyuki Nakashima, Jiichiro Yoshida, Takayoshi Fujiwara, Shouta Kosaka
  • Patent number: 9428674
    Abstract: A copolymer latex for adhesives contains a copolymer latex obtained by copolymerizing an aliphatic conjugated diene monomer with another monomer copolymerizable with this, an alkali metal salt of a carboxylic acid, and a divalent metal carbonate.
    Type: Grant
    Filed: February 19, 2014
    Date of Patent: August 30, 2016
    Assignee: NIPPON A & L INC.
    Inventors: Atsumi Tanemura, Kimio Misaki, Koichi Maki
  • Publication number: 20160122501
    Abstract: Provided are: a rubber composition (a silica master batch) that contains silica in a highly dispersed state, which is prepared by mixing a suspension with an emulsion of an emulsion-polymerized conjugated diene polymer and then coagulating the resultant mixture, wherein the suspension is prepared by highly dispersing wet silica, which does not undergo secondary coagulation yet, or silica, which is prepared by mechanically dissociating secondary coagulation masses of silica, in water and the emulsion-polymerized conjugated diene polymer contains a functional group that is reactive with silica or has high affinity for silica; and a method for producing the rubber composition. A clam (a small mass of a rubber) which contains silica in a highly dispersed state is hardly dried.
    Type: Application
    Filed: March 20, 2014
    Publication date: May 5, 2016
    Applicants: ETIC Inc., NIPPON A&L INC.
    Inventors: Iwakazu Hattori, Hisao Ono, Kimio Misaki, Hiroshi Miwata
  • Patent number: 9328186
    Abstract: A thermoplastic resin composition for vehicle lamp housings, includes: 5 to 80 parts by weight of a graft copolymer (A) obtained by graft polymerizing at least one monomer (a-2) selected from the group consisting of aromatic vinyl-based monomers, vinyl cyanide-based monomers, and (meth)acrylic ester-based monomers and maleimide-based monomers, under the presence of an acrylic ester-based rubbery polymer (a-1) having a weight average particle size of 100 to 400 nm; and 20 to 95 parts by weight of a (co)polymer (B) in which at least one monomer (a-2) selected from the group consisting of aromatic vinyl-based monomers, vinyl cyanide-based monomers, (meth)acrylic ester-based monomers and maleimide-based monomers is polymerized, in which a content of total volatiles at 260° C. is no more than 0.7% by weight of the composition overall, and a content of oligomer component having a weight average molecular weight of 200 to 1000 is no more than 0.3% by weight of the composition overall.
    Type: Grant
    Filed: February 28, 2011
    Date of Patent: May 3, 2016
    Assignee: NIPPON A&L INC.
    Inventors: Hajime Tomita, Takayoshi Fujiwara, Shunsaku Kubota, Suguru Koba
  • Publication number: 20160040046
    Abstract: A copolymer latex for adhesives contains a copolymer latex obtained by copolymerizing an aliphatic conjugated diene monomer with another monomer copolymerizable with this, an alkali metal salt of a carboxylic acid, and a divalent metal carbonate.
    Type: Application
    Filed: February 19, 2014
    Publication date: February 11, 2016
    Applicant: NIPPON A & L INC.
    Inventors: Atsumi TANEMURA, Kimio MISAKI, Koichi MAKI
  • Publication number: 20150274956
    Abstract: The invention relates to an emulsion for aqueous color comprising polymer particles having an average particle size of 20 to 80 nm as measured by the photon correlation method, and including 0.1 to 7 wt % of a structural unit derived from an ethylene-based unsaturated carboxylic acid monomer as the monomer component.
    Type: Application
    Filed: March 17, 2015
    Publication date: October 1, 2015
    Applicant: NIPPON A&L INC.
    Inventor: Yuto MURAI
  • Patent number: 9090728
    Abstract: A binder for secondary battery electrodes contains a copolymer latex obtained by emulsion polymerization of a monomer composition containing 12.0 to 39.5 wt % of an aliphatic conjugated diene-based monomer, 1.5 to 8.5 wt % of an unsaturated carboxylic acid alkyl ester monomer, 0.1 to 10.0 wt % of an ethylene-based unsaturated carboxylic acid monomer, and 42.0 to 86.4 wt % of a monomer that is copolymerizable therewith, wherein 50 to 100 wt % of the copolymer latex is toluene-insoluble.
    Type: Grant
    Filed: December 25, 2009
    Date of Patent: July 28, 2015
    Assignee: NIPPON A & L INC.
    Inventors: Takashi Matsuyama, Kimio Misaki
  • Publication number: 20140378568
    Abstract: A rubber-reinforced styrene type resin composition for resin foams, the resin foams having a specific gravity of 0.3 to 0.7 and a ratio of the thickness of a skin layer to the thickness of the resin foam of 0.3 to 20%; the composition comprising: 10 to 99% by weight of a rubber-reinforced styrene type resin (A) which is obtained by bulk polymerization of a rubber polymer and an aromatic vinyl monomer, a vinyl cyanide monomer, and if necessary, another monomer that is copolymerizable with these monomers, a weight average particle diameter of the rubber polymer being 0.7 to 3 ?m, and 1 to 90% by weight of a copolymer (B) which is obtained by copolymerizing an aromatic vinyl monomer, a vinyl cyanide monomer, and if necessary, another monomer that is copolymerizable with these monomers (with the total of the rubber-reinforced styrene type resin (A) and the copolymer (B) being 100% by weight).
    Type: Application
    Filed: January 11, 2013
    Publication date: December 25, 2014
    Applicant: NIPPON A&L INC.
    Inventors: Jiichiro Yoshida, Nobuyuki Nakashima
  • Publication number: 20140147660
    Abstract: Provided is a thermoplastic resin composition having excellent weather resistance, impact resistance, and fluidity and also excellent color developing properties and residence heat stability. A graft copolymer (A) prepared by graft polymerization of a certain amount of a specific monomer (a2) onto a certain amount of composite rubber (a1) composed of a conjugated diene rubber polymer and a cross-linked acrylic ester polymer. The tetrahydrofuran-soluble portion of the composite rubber (a1) has a weight-average molecular weight of 50000 or more in terms of polystyrene and a degree of swelling in toluene of 7.0 or more, or in the composite rubber contained in the graft copolymer, the number of particles having an equivalent-circle diameter of 150 nm or less is 50% or less of the total number of the composite rubber particles.
    Type: Application
    Filed: July 11, 2012
    Publication date: May 29, 2014
    Applicant: NIPPON A&L INC.
    Inventors: Takumi Miyahiro, Masanori Ito, Seiji Tamai, Fumitoshi Takeda, Kazunori Takahashi, Tomoyoshi Akiyama, Hajime Tomita, Haruki Okuno, Shunsaku Kubota, Masaaki Okada, Atsushi Hashimoto, Yoshiaki Takada, Nobuyuki Nakashima, Jiichiro Yoshida, Takayoshi Fujiwara, Shouta Kosaka
  • Publication number: 20120322945
    Abstract: A thermoplastic resin composition for vehicle lamp housings, includes: 5 to 80 parts by weight of a graft copolymer (A) obtained by graft polymerizing at least one monomer (a-2) selected from the group consisting of aromatic vinyl-based monomers, vinyl cyanide-based monomers, and (meth)acrylic ester-based monomers and maleimide-based monomers, under the presence of an acrylic ester-based rubbery polymer (a-1) having a weight average particle size of 100 to 400 nm; and 20 to 95 parts by weight of a (co)polymer (B) in which at least one monomer (a-2) selected from the group consisting of aromatic vinyl-based monomers, vinyl cyanide-based monomers, (meth)acrylic ester-based monomers and maleimide-based monomers is polymerized, in which a content of total volatiles at 260° C. is no more than 0.7% by weight of the composition overall, and a content of oligomer component having a weight average molecular weight of 200 to 1000 is no more than 0.3% by weight of the composition overall.
    Type: Application
    Filed: February 28, 2011
    Publication date: December 20, 2012
    Applicant: NIPPON A&L INC.
    Inventors: Hajime Tomita, Takayoshi Fujiwara, Shunsaku Kubota, Suguru Koba
  • Publication number: 20120264878
    Abstract: A binder for secondary battery electrodes contains a copolymer latex obtained by emulsion polymerization of a monomer composition containing 12.0 to 39.5 wt % of an aliphatic conjugated diene-based monomer, 1.5 to 8.5 wt % of an unsaturated carboxylic acid alkyl ester monomer, 0.1 to 10.0 wt % of an ethylene-based unsaturated carboxylic acid monomer, and 42.0 to 86.4 wt % of a monomer that is copolymerizable therewith, wherein 50 to 100 wt % of the copolymer latex is toluene-insoluble.
    Type: Application
    Filed: December 25, 2009
    Publication date: October 18, 2012
    Applicant: NIPPON A & L INC.
    Inventors: Takashi Matsuyama, Kimio Misaki