Patents Assigned to Nippon Petrochemical Co., LTD
  • Patent number: 6296950
    Abstract: A method of producing a thermotropic liquid crystalline copolyester having an extremely small amount of out-gases comprising the steps of: (1) charging in a reactor 5-100 mol % of aromatic hydroxycarboxylic acid, 0-47.5 mol % of aromatic dicarboxylic acid and 0-47.5 mol % of aromatic diol, so that the sum of mol % of each material is 100 mol % and the molt of aromatic dicarboxylic acid and that of aromatic diol are substantially equal; (2) adding acetic anhydride of an amount which satisfies the formula, (B-C)/A≧1.04, “A” representing the total molar number of the hydroxy group in a reaction system, “B” representing the molar number of acetic anhydride to be added, and “C” representing the molar number of water present in the reaction system prior to addition of acetic anhydride; (3) acetylation; (4) melt polymerization; and (5) solid-phase polymerization.
    Type: Grant
    Filed: March 15, 2001
    Date of Patent: October 2, 2001
    Assignee: Nippon Petrochemical Co., LTD
    Inventors: Satoshi Murouchi, Yoshikuni Yamada, Toshitaka Kobayashi
  • Publication number: 20010014708
    Abstract: A method of producing a thermotropic liquid crystalline copolyester having an extremely small amount of out-gases comprising the steps of: (1) charging in a reactor 5-100 mol % of aromatic hydroxycarboxylic acid, 0-47.5 mol % of aromatic dicarboxylic acid and 0-47.5 mol % of aromatic diol, so that the sum of mol % of each material is 100 mol % and the mol % of aromatic dicarboxylic acid and that of aromatic diol are substantially equal; (2) adding acetic anhydride of an amount which satisfies the formula, (B−C)/A≧1.04, “A” representing the total molar number of the hydroxy group in a reaction system, “B” representing the molar number of acetic anhydride to be added, and “C” representing the molar number of water present in the reaction system prior to addition of acetic anhydride; (3) acetylation; (4) melt polymerization; and (5) solid-phase polymerization.
    Type: Application
    Filed: March 15, 2001
    Publication date: August 16, 2001
    Applicant: NIPPON PETROCHEMICAL CO., LTD.
    Inventors: Satoshi Murouchi, Yoshikuni Yamada, Toshitaka Kobayashi
  • Patent number: 6268419
    Abstract: A method of producing a thermotropic liquid crystalline copolyester having an extremely small amount of out-gases comprising the steps of: (1) charging in a reactor 5-100 mol % of aromatic hydroxycarboxylic acid, 0-47.5 mol % of aromatic dicarboxylic acid and 0-47.5 mol % of aromatic diol, so that the sum of mol % of each material is 100 mol % and the mol % of aromatic dicarboxylic acid and that of aromatic diol are substantially equal; (2) adding acetic anhydride of an amount which satisfies the formula, (B−C)/A≧1.04, “A” representing the total molar number of the hydroxy group in a reaction system, “B” representing the molar number of acetic anhydride to be added, and “C” representing the molar number of water present in the reaction system prior to addition of acetic anhydride; (3) acetylation; (4) melt polymerization; and (5) solid-phase polymerization.
    Type: Grant
    Filed: March 29, 2000
    Date of Patent: July 31, 2001
    Assignee: Nippon Petrochemical Co., LTD
    Inventors: Satoshi Murouchi, Yoshikuni Yamada, Toshitaka Kobayashi
  • Patent number: 6229675
    Abstract: A swing-type actuator for use in a magnetic disk unit which includes a magnetic head; an arm supporting the head and a movable coil acting in a magnetic circuit. The movable coil is composed of a coil bobbin having a conductive wire wrapped around the bobbin. The bobbin is produced by injection molding into the bobbin of a thermoplastic resin having a flexural modulus of at least 8×102 kgf/mm2 and a heat deformation temperature of at least 200° C. under a load of 18.6 kg/cm2. A junction member to which the arm and the bobbin are integrally fixed by insert molding is made of the same resin as the bobbin or another thermoplastic resin being selected from the group consisting of a polybutylene terephthalate resin, a polyphenylene sulfide resin, a polyamide, a polyether ether ketone resin and thermotropic liquid crystal polymer.
    Type: Grant
    Filed: October 19, 1999
    Date of Patent: May 8, 2001
    Assignees: Nippon Petrochemicals Co., Ltd, Nittoku Giken Company, Ltd.
    Inventors: Kenji Tanaka, Hitoshi Hasegawa
  • Patent number: 6226152
    Abstract: A joined metal-resin plate body having a metal plate (1, 12) and a resin plate (2, 13) joined together, in which an insert member having a through-hole therein is embedded in the resin plate. The insert member is in close contact with the resin of the resin plate in the outer periphery of the insert member except for the faces where the through-hole opens. The metal plate has a metallic joining member (4, 16) adhered thereto. The resin plate is joined to the metal plate with the aid of the joining member fitted in the through-hole. The insert member and the surrounding resin have elastic stresses (F3, F4), which give rise to a sufficient joining strength among the joining member, the insert member and the resin plate. The stress of the surrounding resin is due to elastic deformation. The amount (V2-V3) of the elastic deformation is smaller than the amount (V2) of deformation of the insert member which can give rise to an elastic stress (F3) of the insert member.
    Type: Grant
    Filed: November 4, 1996
    Date of Patent: May 1, 2001
    Assignees: Nippon Petrochemicals, Co., Ltd., KabushikiKaisha Sansen
    Inventors: Kenji Tanaka, Ken Motoi
  • Patent number: 6172146
    Abstract: A hot melt composition comprising a specific ratio of: (a) an ethylene copolymer resin; (b) a modified aromatic petroleum resin having a specific weight-average molecular weight and produced by copolymerization using a Friedel-Crafts catalyst from a specific ratio of: (1) a polymerizable component of the thermal cracked oil fraction having boiling points in a specific range and obtained by the thermal cracking of petroleum hydrocarbons, and containing vinyltoluene and indene at specific contents, (2) a turpentine oil having a specific diene value, and (3) a phenol compound; and (c) a wax. It is possible to develop a hot melt composition having excellent heat stability and improved adhesion resistance to heat, which can be used as hot melt coating, printing ink, adhesive, and sealant, etc.
    Type: Grant
    Filed: January 27, 1998
    Date of Patent: January 9, 2001
    Assignee: Nippon Petrochemicals, Co. Ltd.
    Inventor: Hitoshi Yanagishita
  • Patent number: 6162871
    Abstract: A polyolefin resin composition containing an ethylene-.alpha.-olefin copolymer having: (A) a density d of 0.86 to 0.96 g/cm.sup.3 ; (B) a melt flow rate MFR of 0.01 to 200 g/10 min; (C) a molecular weight distribution Mw/Mn of 1.5 to 4.5; (D) a composition distribution parameter Cb of 1.08 to 2.00; and (E) an orthodichlorobenzene-soluble content X (wt %), at 25.degree. C. a density of d (g/cm.sup.3) and a melt flow rate MFR (wt %) satisfying that: (i) when the density (d) and the melt flow rate MFR satisfy relationship (I):d-0.008.times.logMFR.gtoreq.0.93 (I)the orthodichlorobenzene-soluble content X satisfies relationship (II):X<2.0 (II)(ii) when the density d and the melt flow rate MFR satisfy relationship (III):d-0.008.times.logMFR<0.93 (III)the orthodichlorobenzene-soluble content X satisfies relationship (IV):X<9.8.times.10.sup.3 .times.(0.9300-d+0.008.times.logMFR).sup.2 +2.
    Type: Grant
    Filed: October 5, 1998
    Date of Patent: December 19, 2000
    Assignee: Nippon Petrochemical Co., Ltd.
    Inventors: Hideo Watanabe, Masahiko Sato, Masaaki Ikeda, Takaaki Hattori, Yoshihiro Hatakeyama, Naoki Miwa, Tatsuyuki Kamiya, Hisao Sakuma, Yuka Umeshima
  • Patent number: 6127293
    Abstract: The present invention provides a laminated body comprising a uniaxially stretched laminate composed of (I) a first thermoplastic resin layer and (II) an adhesion layer which has a lower melting point than said first thermoplastic resin layer (I) and is provided on at least one surface of said thermoplastic resin layer (I), said adhesion layer (II) being composed of a composition containing (A) 100 to 30% by weight of an .alpha.-olefin (co)polymer having a melt flow rate of 0.01 g to 100 g/10 minutes obtained by (co)polymerizing an .alpha.-olefin in the presence of a catalyst which includes at least one compound of a transition metal of Group IV in the Periodic Table containing a ligand having a cyclopentadienyl skeleton, and (B) up to 70% by weight of an olefin-based polymer; in one embodiment, the present invention relates to a nonwoven or woven fabric and a reinforced laminated body, each derived from the laminated body.
    Type: Grant
    Filed: January 14, 1999
    Date of Patent: October 3, 2000
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Masato Kimura, Katsumi Yano
  • Patent number: 6054086
    Abstract: An ultra-high molecular weight polyolefin having a viscosity average molecular weight of at least 500,000 is subjected to melt forming into a film, the thus obtained molten film or solid state film is transversely stretched while holding both the side edges of the film, the stretched film is longitudinally slitted into tapes, and then the thus obtained tapes are longitudinally stretched thereby to produce high-strength yarns easily. A number of slits are longitudinally or transversely made in films made of an ultra-high molecular weight polyolefin having a viscosity average molecular weight of at least 500,000 so that the films each take a meshy form when spread in the direction perpendicular to the slits, and the meshy form structures are stretched in the direction of the slits to prepare meshy webs having a high strength unidirectionally. At least one member selected from the thus prepared meshy webs is used as one nonwoven web, thereby producing a high-strength, web-crossed laminated nonwoven easily.
    Type: Grant
    Filed: March 19, 1996
    Date of Patent: April 25, 2000
    Assignees: Nippon Petrochemicals Co., Ltd., Polymer Processing Research Inst., Ltd.
    Inventors: Kazuhiko Kurihara, Hiroshi Yazawa
  • Patent number: 6051289
    Abstract: To provide a film for optical element made of liquid crystal polymer whose productivity and economical efficiency are improved; a laminated sheet formed by bonding this film to a polarizing plate; and an optical element which can be optically inspected, and used under an environment of high temperature and high moisutre, and whose surface hardness is so high that the surface is not easily damaged. A long laminated sheet for optical element comprising a liquid crystal polymer layer, and a polarizing film layer; and a long laminated sheet for optical element comprising at least a liquid crystal polymer film layer oriented in the direction oblique to the MD direction at a given angle, and a polarizing film layer.
    Type: Grant
    Filed: December 17, 1997
    Date of Patent: April 18, 2000
    Assignee: Nippon Petrochemicals, Co., Ltd
    Inventors: Yoshio Tsujimoto, Hiroyasu Ishikawa, Jun Mukai, Teruaki Yamanashi, Toshihiro Ichizuka, Kenji Hosaki
  • Patent number: 6033509
    Abstract: A method for laminating a porous sheet 1 and a coarse mesh reinforcing material 2 which includes an adhesive layer and is reinforced by drawing, by heat pressing with that adhesive layer in between, in which, (1) the heating temperature during heat pressing is equal to or above the melting point of the adhesive layer and equal to or below the melting point of the porous sheet, (2) a specific relationship is maintained among the difference between the heating temperature and the melting point of the adhesive layer, the difference between the heating temperature and the softening point of the porous sheet, and the heating time, and (3) the unrolling tension of the porous sheet is maintained at 200 to 550 g/mm.sup.2.
    Type: Grant
    Filed: March 31, 1998
    Date of Patent: March 7, 2000
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Tsutomu Miyamoto, Fusao Tokuhiro, Hiroshi Shimizu, Masato Katou
  • Patent number: 5945020
    Abstract: There is provided a laminated heating structure comprising a molding layer (A) made of a thermotropic liquid crystal polymer, a conductive layer (B) for heating a protective coating layer (C) by applying an electric current therethrough, and the protective coating layer (C), provided that the layers (A), (B) and (C) are laminated in this order, and an inexpensive laminated heating structure excellent in heat resistance, dimensional accuracy and mechanical strength, reduced in electric power consumption, and shortened in build-up time.
    Type: Grant
    Filed: December 2, 1997
    Date of Patent: August 31, 1999
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Rikio Kuroda, Motomi Nogiwa, Yoshiharu Ogawa, Kazunori Hosomi
  • Patent number: 5874513
    Abstract: An ethylene-.alpha.-olefin copolymer having: (A) a density d of 0.86 to 0.96 g/cm.sup.3 ; (B) a melt flow rate MFR of 0.01 to 200 g/10 min; (C) a molecular weight distribution Mw/Mn of 1.5 to 4.5; (D) a composition distribution parameter Cb of 1.08 to 2.00; and (E) an orthodichlorobenzene-soluble content X (wt %), at 25.degree. C. a density of d (g/cm.sup.3) and a melt flow rate MFR (g/10 min) satisfying that: (i) when the density (d) and the melt flow rate MFR satisfy relationship (I):d-0.008.times.logMFR.gtoreq.0.93 (I)the orthodichlorobenzene-soluble content X satisfies relationship (II):X<2.0 (II)(ii) when the density d and the melt flow rate MFR satisfy relationship (III):d-0.008.times.logMFR<0.93 (III)the orthodichlorobenzene-soluble content X satisfies relationship (IV):X<9.8.times.10.sup.3 .times.(0.9300-d+0.008.times.logMFR).sup.2 +2.
    Type: Grant
    Filed: March 28, 1996
    Date of Patent: February 23, 1999
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Hideo Watanabe, Masahiko Sato, Masaaki Ikeda, Takaaki Hattori, Yoshihiro Hatakeyama, Naoki Miwa, Tatsuyuki Kamiya, Hisao Sakuma, Yuka Umeshima
  • Patent number: 5861202
    Abstract: The present invention provides a laminated body comprising a uniaxially stretched laminate composed of (I) a first thermoplastic resin layer and (II) an adhesion layer which has a lower melting point than said first thermoplastic resin layer (I) and is provided on at least one surface of said thermoplastic resin layer (I), said adhesion layer (II) being composed of a composition containing (A) 100 to 30% by weight of an .alpha.-olefin (co)polymer having a melt flow rate of 0.01 g to 100 g/10 minutes obtained by (co)polymerizing an .alpha.-olefin in the presence of a catalyst which includes at least one compound of a transition metal of Group IV in the Periodic Table containing a ligand having a cyclopentadienyl skeleton, and (B) up to 7% by weight of an olefin-based polymer; in one embodiment, the present invention relates to a nonwoven or woven fabric and a reinforced laminated body, each derived from the laminated body.
    Type: Grant
    Filed: December 13, 1995
    Date of Patent: January 19, 1999
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Masato Kimura, Katsumi Yano
  • Patent number: 5834087
    Abstract: The present invention provides a tile carpet comprising a sealer layer of a novel hot-melt type composition low in fumability (fuming property) and superior in a sealing effect and backing layers of a composition low in fumability. The tile carpet has a structure in which a backing layer (A) of a composition comprising an amorphous polyolefin and a filler containing magnesium hydroxide; a glass or polyester non-woven fabric; a backing layer (B) of a compositon comprising an amorphous polyolefin and a filler containing magnesium hydroxide; a glass or polyester crossed fabric; and a carpet cloth having a sealer layer (C) of a composition comprising, an amorphous polyolefin and a filler, are laminated to one another successively in this order.
    Type: Grant
    Filed: February 19, 1997
    Date of Patent: November 10, 1998
    Assignees: Nippon Petrochemicals Co. Ltd., Suminoe Orimono Kabushiki Kaisha
    Inventors: Teruo Kajikawa, Yasuhiko Ganno, Junichi Takeda, Shuichi Yonezawa
  • Patent number: 5791030
    Abstract: A relatively inexpensive web widening apparatus which is suitable for the manufacture of a widened web having a large width and a lightweight web while maintaining a high widening ratio and the uniformity of the web and can be operated with ease at a high efficiency comprises a widening tool in contact with the web, having first and second groups of widening plates arranged in a width direction of the web to face each other, at least one pair of cross guiders which can nip both side end portions of the web, and guide means for moving the widening plates of the first and second groups in such a manner that the interval between the widening plates expands gradually as they rotate and then narrows gradually.
    Type: Grant
    Filed: August 25, 1997
    Date of Patent: August 11, 1998
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Kintaro Aihara, Kazuhiko Kurihara, Hiroshi Yazawa, Yuki Kuroiwa, Shuichi Murakami
  • Patent number: 5759647
    Abstract: A long tubular article characterized by having a smooth surface and a substantially uniform wall thickness in the circumferential direction and the longitudinal direction and by being produced by injection molding a thermoplastic resin and a method for the injection molding.
    Type: Grant
    Filed: December 27, 1994
    Date of Patent: June 2, 1998
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Rikio Kuroda, Sadahiro Nishimura, Akio Hashimoto
  • Patent number: 5723388
    Abstract: The present invention provides a prepreg obtained by stretching a material including, as a main component, an ultra-high-molecular-weight polyethylene having an intrinsic viscosity of 5-50 dl/g as measured at 135.degree. C. in decalin, to a total draw ratio of at least 20, subjecting the resulting stretched polyethylene material to a splitting treatment, and impregnating the resulting material with a thermosetting resin. The split stretched polyethylene material has improved adhesion to the impregnant resin and can be used as a good base material for prepreg.
    Type: Grant
    Filed: January 7, 1997
    Date of Patent: March 3, 1998
    Assignees: Nippon Oil Co., Ltd., Nippon Petrochemicals Co., Ltd., Polymer Processing Research Institute Ltd.
    Inventors: Seizo Kobayashi, Kazutosi Nomiyama, Yoshimu Iwanami, Sumio Yoshida, Kazuhiko Kurihara, Hiroshi Yazawa
  • Patent number: 5719742
    Abstract: A metallized plastic film capacitor is here disclosed which is impregnated with an electrically insulating oil composition comprising 10 to 95% by weight of an aromatic hydrocarbon having at least 3 benzene rings and 90 to 5% by weight of an olefin oligomer containing 7% by weight or less of a fraction having a molecular weight of 500 or less and 2% by weight or less of a fraction having a molecular weight of 400 or less.
    Type: Grant
    Filed: November 19, 1996
    Date of Patent: February 17, 1998
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventor: Kunio Sugisawa
  • Patent number: 5698023
    Abstract: This invention provides a process for producing copper phthalocyanine pigments which comprises reacting either phthalic anhydride or its derivatives with urea and a copper-containing substance, or either phthalonitrile or its derivative with a copper-containing substance in a reaction solvent by heating characterized in that an alkylxylene ingredient having a branched C4 side-chain represented by the following formula (1) is used as the reaction solvent: ##STR1##
    Type: Grant
    Filed: March 18, 1996
    Date of Patent: December 16, 1997
    Assignee: Nippon Petrochemical Co., Ltd.
    Inventors: Tsutomu Takashima, Kikuo Sasaki, Hideyuki Dohi