Patents Assigned to Nippon Petrochemical Co., LTD
  • Patent number: 4659840
    Abstract: Provided is a method for preparing diaryl iodonium salts represented by the formula:[Ar.sub.1 --I.sup..sym. --Ar.sub.2 ]HSO.sub.4.sup..crclbar.wherein Ar.sub.1 and Ar.sub.2 respectively are an aryl group which may be substituted with an electron donor group and which may be the same or different which comprises subjecting a compound represented by the formula Ar.sub.1 --H wherein Ar.sub.1 is as defined above and a compound Ar.sub.2 --I wherein Ar.sub.2 is as defined above to a coupling reaction in a sulfuric acid solution containing an oxidizing agent and diluted with a diluting agent to a concentration of 85% by weight or less at a reaction temperature in the range from -20.degree. to +35.degree. C.
    Type: Grant
    Filed: March 8, 1984
    Date of Patent: April 21, 1987
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Isoo Shimizu, Yasuo Matsumura, Yoshihisa Inomata
  • Patent number: 4656094
    Abstract: Novel multi-layer laminate articles of improved adhesion strength comprising at least two layers including a polyester resin layer and a layer of an epoxy group-containing olefin polymer or an olefin polymer composition comprising the epoxy group-containing polymer, are described. The epoxy group-containing olefin polymer is a copolymer of an olefin and an unsaturated glycidyl group-containing monomer or a copolymer of an olefin, an unsaturated glycidyl group-containing monomer and an ethylenically unsaturated monomer.
    Type: Grant
    Filed: July 12, 1985
    Date of Patent: April 7, 1987
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Shinji Kojima, Hirokazu Suzuki, Yuichi Orikasa
  • Patent number: 4656186
    Abstract: This invention relates to new fluorescent mono, di- or polyamide of an aminomonocarboxylic acid and a tetrapyrrole containing at least three carboxy groups of the structure: ##STR1## wherein Z is the amino acid residue and x is the tetrapyrrole residue and "n" is an integer from 1 to 4 inclusive.
    Type: Grant
    Filed: April 30, 1985
    Date of Patent: April 7, 1987
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Jerry C. Bommer, Bruce F. Burnham
  • Patent number: 4652616
    Abstract: A chlorinated ethylene copolymer resin having a chlorine content of 5-50% by weight obtained by chlorinating an ethylene copolymer resin by the aqueous suspension method at a temperature of 100.degree. C. or higher in at least one chlorination stage, said copolymer resin being obtained by copolymerizing ethylene and as at least one comonomer 0.02-2.0 mol % of a nonconjugated diene using a polymerization catalyst comprising a solid catalytic component containing at least magnesium and titanium and an organic aluminum compound and having a maximum peak temperature according to the differential scanning calorimetry (DSC) of 100.degree. C. or higher.
    Type: Grant
    Filed: April 3, 1985
    Date of Patent: March 24, 1987
    Assignees: Nippon Petrochemicals Co. Ltd., Osaka Soda Co.
    Inventors: Takeshi Kamiya, Kazuo Matsuura, Mituji Miyoshi, Kozo Misumi, Seiji Kadomatsu, Shinji Nose
  • Patent number: 4650818
    Abstract: This invention provides inorganic filler-containing polyolefine compositions with use of inorganic fillers together with novel coupling agents which are inexpensive and convenient to use.
    Type: Grant
    Filed: June 20, 1985
    Date of Patent: March 17, 1987
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Masataka Oka, Masami Furukawa, Shinji Kojima, Takeo Amatsu
  • Patent number: 4624976
    Abstract: A composition for modeling material comprising a synthetic resin, a wooden powder and an oil formulated and kneaded. The synthetic resin is a rubber-reinforced styrene resin. The oil is a hydrocarbon oil having a specified viscosity, and restriction of the content of an aromatic ring-forming carbon. The composition is formed into flat board, round rod, etc. and used as modeling material for shaping patterns or models.
    Type: Grant
    Filed: July 22, 1985
    Date of Patent: November 25, 1986
    Assignees: Nippon Petrochemicals Co., Ltd., Ube Cycon, Ltd.
    Inventors: Osamu Amano, Atsushi Kaiya, Takao Tanaka, Hitoshi Akimura, Katsuhiro Tsujihata, Kouji Hirata
  • Patent number: 4620056
    Abstract: A method for producing an aromatic hydrocarbon easily and safely without the use of carrier-supported catalyst and is characterized in that an unsaturated compound having a double bond or bonds that are conjugated with the benzene ring is allowed to coexist in the process to alkylate a substituted aromatic hydrocarbon with olefins in the presence of 5 mM or more of metallic sodium and potassium compound to provide 3 mM or more of potassium ions relative to 1 mole of the substituted aromatic hydrocarbon, said substituted aromatic hydrocarbon having at least one alkyl group or alkylene group which has at least one hydrogen atom in the .alpha.-position relative to the aromatic ring of said substituted aromatic hydrocarbon.
    Type: Grant
    Filed: August 28, 1985
    Date of Patent: October 28, 1986
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Isoo Shimizu, Hideki Nomura, Kazumichi Uchida, Hitoshi Mitsuyuki
  • Patent number: 4604321
    Abstract: An adsorbing agent and a method of preparation thereof is disclosed, which agent is capable of selectively adsorbing mercury from various mercury-containing gaseous or aqueous media at high rate of efficiency. The agent essentially comprises a porous material having a specific surface area in excess of 10 m.sup.2 /g. and a conjugated diolefin lower polymer deposited in a predetermined amount on the porous material.
    Type: Grant
    Filed: September 27, 1984
    Date of Patent: August 5, 1986
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Mitsuo Okahara, Isao Ikeda
  • Patent number: 4576680
    Abstract: An internal sizing agent for paper making which produces excellent sizing effect and which can be used in neutral to alkaline regions without the ordinarily employed fixing agent such as aluminum sulfate. The sizing agent contains a specific reaction product and/or hydrogenation product of said reaction product, said reaction product being prepared by adding maleic anhydride to branched internal olefins having 14 to 36 carbon atoms which branched internal olefins are obtained by oligomerizing one member or a mixture of two or more of olefins having 6 to 18 carbon atoms.
    Type: Grant
    Filed: February 6, 1984
    Date of Patent: March 18, 1986
    Assignees: Nippon Petrochemicals Co., Ltd., Arakawa Kagaku Kogyo Kabushiki Kaisha
    Inventors: Kimio Kawatani, Takashi Fujikawa, Eiji Watanabe
  • Patent number: 4525317
    Abstract: A film or fibrous web which has been stretched by moving at least two laterally spaced first longitudinal portions gripped by a first gripping means along at least two arcuate divergent paths formed jointly by at least two radially disposed first pulleys and endless belt means trained arcuately therearound, is further stretched by moving at least two laterally spaced second longitudinal portions adjacent to the first longitudinal portions gripped by a second gripping means along at least two arcuate divergent paths contiguous to the first arcuate divergent paths, respectively, formed jointly by at least two second pulleys, respectively, disposed downstream of and close to the first pulleys in coplanar relation thereto and second endless belt means trained arcuately therearound. The film while being stretched is heated to a temperature suitable for stretching with heated air and the like, or is softened by immersing in a bath of solvent or plasticizer.
    Type: Grant
    Filed: June 10, 1983
    Date of Patent: June 25, 1985
    Assignees: Nippon Petrochemicals, Co., Ltd., Polymer Processing Research Institute Ltd.
    Inventors: Tokio Okada, Haruhisa Tani, Shigezo Kojima, Kazuhiko Kurihara, Hirosi Yazawa
  • Patent number: 4524017
    Abstract: Norbornane derivatives having hydrocarbon side chains, the processes for preparing the same and perfume compositions containing the same. The norbornane derivatives are represented by the following general formula (I) ##STR1## wherein C.sub.2 is an ethyl group, an ethylidene group or a vinyl group each connected to 5 or 6 position of the norbornane ring, each of R.sub.1 and R.sub.2 is a hydrogen atom or a methyl group, and R.sub.3 is a formyl group or a group represented by the following general formula (II) ##STR2## wherein R.sub.4 is a methyl group, an ethyl group, a n-propyl group or an isopropyl group, and X is a carbon atom of the norbornane ring. The above norbornane derivatives give a wide variety of woody fragrances and are useful as components for various perfume products.
    Type: Grant
    Filed: February 24, 1982
    Date of Patent: June 18, 1985
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Yoshiharu Inoue, Fumio Tanimoto, Hisao Kitano
  • Patent number: 4507516
    Abstract: A fuel composition comprising a hydrogenated material obtained by hydrogenating a reaction mixture ranging from C.sub.11 to C.sub.16 containing mainly compounds which comprise butadiene and cyclopentadiene as basic structural units, produced by reacting an acyclic conjugated diene with cyclopentadiene, dicyclopentadiene, an alkyl-substituted cyclopentadiene, or an alkyl-substituted dicyclopentadiene in accordance with Diels-Alder reaction an isomeric material prepared by isomerizing the hydrogenated material or the mixture of the hydrogenated material and the isomeric material.
    Type: Grant
    Filed: March 14, 1984
    Date of Patent: March 26, 1985
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Seiji Hirooka, Michiaki Torii
  • Patent number: 4489630
    Abstract: A method of slitting a continuous thermoplastic film comprises advancing the film longitudinally at a first speed along a peripheral surface of a roll rotating at a peripheral speed equal to or slightly greater than that of the film, and slitting the film while being advanced by pressing cutting edges of a rotating cutter against the peripheral surface of the roll. In order to prevent the cutting edges from being worn out and to form slits of uniform size and shape, the peripheral surface comprises an elastic layer of polymeric material, the cutting edges are heated above a temperature at which the film starts melting, the film and the elastic surface layer are cooled along their contacting surfaces with a cooling liquid, and the cutting edges are rotated at substantially the same peripheral speed as the roll. The invention also includes an apparatus for carrying out the method.
    Type: Grant
    Filed: September 17, 1982
    Date of Patent: December 25, 1984
    Assignees: Nippon Petrochemicals Co Ltd., Polymer Processing Research Institute Ltd.
    Inventors: Tokio Okada, Shigezo Kojima, Haruhisa Tani, Kazuhiko Kurihara, Hirosi Yazawa
  • Patent number: 4434128
    Abstract: A method and apparatus for stretching a thermoplastic polymer film in which the opposite selvages of the film are gripped by gripping means and are stretched transversely during heating by moving the selvages along two divergent arcuate paths lying in the same plane and extending over a predetermined circumferential range from a quater to a half of the full circumference of the circle containing the arcuate paths. In order to avoid drawbacks in the existing equipment such as irregular molecular orientation in and rupture of the film, the longitudinal travel of the film while being stretched is controlled by controlling means so that the central web portion is advanced by substantially the same distance as the gripped film selvages, whereby the amound of longitudinal movement of the film is held always constant throughout the width of the film.
    Type: Grant
    Filed: March 29, 1982
    Date of Patent: February 28, 1984
    Assignees: Nippon Petrochemicals Co., Ltd, Polymer Processing Research Institute, Ltd.
    Inventors: Tokio Okada, Shigezo Kojima, Haruhisa Tani, Kazuhiko Kurihara, Hirosi Yazawa
  • Patent number: 4349500
    Abstract: A method is disclosed for transversely stretching a fibrous or film-like material. The material is subjected to a monoaxial transverse stretch which progresses divergently along an arcuate track. An apparatus to implement this method is also disclosed, which essentially comprises a pair of pulleys and a pair of V-belts cooperating in releasably gripping therebetween opposite selvages of a given material, the pulleys being rotative in the same plane in opposite directions so that the material is stretched along a progressively diverging arcuate track.
    Type: Grant
    Filed: March 24, 1980
    Date of Patent: September 14, 1982
    Assignees: Nippon Petrochemicals Co., Ltd., Polymer Processing Research Institute, Ltd.
    Inventors: Masahide Yazawa, Haruhisa Tani, Kazuhiko Kurihara, Hiroshi Yazawa
  • Patent number: 4341665
    Abstract: An acylnorbornanone acetal is represented by the formula: ##STR1## (wherein R.sub.1 is a saturated hydrocarbon group having 2 to 7 carbon atoms and R.sub.2 is a hydrogen atom or a hydrocabon group having 1 to 10 carbon atoms). The acylnorbornanone acetal is prepared by oxidizing an .alpha.-hydroxyalkylnorbornanone acetal represented by the formula: ##STR2## (wherein R.sub.2 is a hydrogen atom or a hydrocarbon group having 2 to 7 carbon atoms). The perfume composition contains as a perfume component the acylnorbornanone acetal as represented above.
    Type: Grant
    Filed: March 5, 1981
    Date of Patent: July 27, 1982
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Yoshiharu Inoue, Fumio Tanimoto, Hisao Kitano
  • Patent number: 4335070
    Abstract: A reticular web of thermoplastic resin composed of split or slit fibers is longitudinally fed around a system of nip rollers as it is transversely spread along its selvages which then longitudinally shorten into contact with small-diameter end portions of one of the nip rollers. At least one dimensionally stable thread is attached to and along each of the web selvages to reinforce the latter. The web thus laterally spread is caused to heat-shrink at its middle portion on a heated drum until the middle portion is of substantially the same length as that of the selvages. Each of the selvages including the thread has a basis weight which is substantially the same as or smaller than that of the middle portion. The selvages of the reticular web thus treated are rendered dimensionally stable for guidance of the web in a manner to keep the latter constant widthwise while the web is wound around or reeled out from a take-up roll.
    Type: Grant
    Filed: January 7, 1981
    Date of Patent: June 15, 1982
    Assignees: Nippon Petrochemicals Co., Ltd., Polymer Processing Research Institute, Ltd.
    Inventors: Masahide Yazawa, Hiroshi Yazawa, Haruhisa Tani, Kazuhiko Kurihara
  • Patent number: 4331624
    Abstract: Longitudinal and transverse stretching of a tubular film is effected by gripping opposite selvages of the tubular film between a pair of substantially coplanar pulleys and a pair of endless belt means trained arcuately around the pulleys, respectively, and by rotating the pulleys at a peripheral speed greater than a speed of feed of the tubular film. As the film selvages progress along a pair of arcuate divergent paths, respectively, around the pulleys, the film is heated, reversed in direction of travel, and cut along the selvages into a pair of biaxially stretched sheets. Before stretching of the film, live steam is introduced into the tubular film for heating the same.
    Type: Grant
    Filed: October 10, 1980
    Date of Patent: May 25, 1982
    Assignees: Nippon Petrochemicals Co., Ltd., Polymer Processing Research Institute Ltd.
    Inventors: Masahide Yazawa, Hiroshi Yazawa, Haruhisa Tani, Kazuhiko Kurihara
  • Patent number: 4331569
    Abstract: The substituted norbornanones represented by general formula (I): ##STR1## (wherein R.sub.1 is an alkenyl group having 2 or 3 carbon atoms or an alkylidene group having 1 to 3 carbon atoms and R.sub.2 is a saturated hydrocarbon group having 2 to 7 carbon atoms with the dotted line between the two carbon atoms indicating a single bond when R.sub.1 is an alkenyl group and a double bond when R.sub.1 is an alkylidene group) are useful for perfume compositions. The substituted norbornanones represented by the general formula (I) may be prepared from the corresponding alkenyl or alkylidene norbornanones with diols in the presence of an acid catalyst.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: May 25, 1982
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Yoshiharu Inoue, Fumio Tanimoto, Hisao Kitano
  • Patent number: RE32162
    Abstract: A solvent for the pressure sensitive record material which consists of a normally liquid compound having 13 to 18 Carbon atoms and being represented by the following general formula: ##STR1## in which each of R.sub.1 to R.sub.5 is hydrogen, methyl group or etyl group R.sub.6 is hydrogen, methyl, ethyl, iso-propyl, n-propyl, tert-buthyl or sec-buthyl group; and the preparation method of the above solvent from styrene and C.sub.7 -C.sub.10 aromatic hydrocarbons using sulfuric acid as the catalyst.
    Type: Grant
    Filed: August 29, 1979
    Date of Patent: May 27, 1986
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Atsushi Sato, Yoshiaki Aida, Isoo Shimizu