Patents Assigned to Nippon Petrochemicals Company
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Patent number: 5268410Abstract: A resin composition of wholly-aromatic thermotropic liquid crystal polyester resin containing 5 to 60% by weight of an inorganic filler selected from carbonates of alkaline earth metals, which is characterized in that the moisture content of the component materials to be fed to the melting step in preparation process of said composition is 0.1% by weight or lower. The resin composition and its formed articles are quite excellent in external appearance, thermal resistance, workability in plastics forming and especially in plating strength suitable for applying metal plating thereon.Type: GrantFiled: October 29, 1992Date of Patent: December 7, 1993Assignee: Nippon Petrochemicals Company, LimitedInventors: Jun Yamada, Hideo Watanabe, Tetsuo Shimizu
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Patent number: 5266362Abstract: A molded article of a composition obtained by dynamically heat-treating a thermoplastic resin and/or a rubbery substance in the presence of a crosslinking agent, or such composition with an inorganic filler incorporated therein, is subjected to the radiation of ultraviolet light not longer than 300 nm in wave length, whereby surface characteristics of the molded article can be improved without deterioration of such characteristics as rigidity, impact- and heat-resistance, dimensional stability and processability.Type: GrantFiled: November 22, 1991Date of Patent: November 30, 1993Assignees: Japan (Agency of Industrial Science and Technology), Nippon Petrochemicals Company, LimitedInventors: Kohichiroh Katoh, Motomi Nogiwa, Yoshiharu Iwasaki
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Patent number: 5265506Abstract: Method and apparatus for fabricating a perforated film comprising the steps of pinching a film material, (3) between a cutter roll (1) with cutting edges (12) and a backing roll (2) to press the cutting edges (12) to the film material (3) and driving, to rotate least one of the cutter roll (1) and the backing roll (2), to form holes such as slits in a film material. The apparatus is decelerated by a stop command signal of an apparatus, detecting the speed of the apparatus attaining a predetermined small speed, generating an advance stop signal when the apparatus is approaching a stop a condition, and displacing the backing roll (2) so that the cutter roll is separated from the backing roll.Type: GrantFiled: September 4, 1992Date of Patent: November 30, 1993Assignees: Nippon Petrochemicals Company, Limited, Polymer Processing Research Inst., Ltd.Inventors: Kintaro Aihara, Tadashi Honda
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Patent number: 5264409Abstract: An excellent pressure-sensitive copying material which has an excellent color developing rate, little odor, and neither offset nor bleeding, said copying material comprising an electron-accepting developer and a solution of an electron-donating color former which produces colors upon contacting with said color developer, wherein it is characterized in that the solvent of said solution comprises a mixture of 20 to 80 weight % of sec-butyldiphenylmethane, 5 to 50 weight % of sec-butyldiphenylethane (1,1) and 5 to 50 weight % of sec-butyldiphenylethane (1,2).Type: GrantFiled: March 10, 1992Date of Patent: November 23, 1993Assignee: Nippon Petrochemicals Company, LimitedInventors: Naoya Takahashi, Satoshi Narui, Yasuo Togami
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Patent number: 5262453Abstract: A cushion or trackbed material for use in a riding-ground is obtained by coating sand with a carboxyl-containing olefin polymer and an oxygen-containing wax.Type: GrantFiled: July 15, 1991Date of Patent: November 16, 1993Assignees: Nippon Oil Company, Limited, Nippon Petrochemicals Company, Limited, Nippon Hodo Company, LimitedInventors: Yutaka Watanabe, Kazuo Aoyama, Hisanobu Niwata, Sumio Ikeda, Katuaki Ishikawa, Yoshiteru Kato
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Patent number: 5260384Abstract: A polyethylene composition which has a wide molecular weight distribution and excellent balance among melt elasticity, flow characteristics and mechanical properties, and which is suitable for use in producing large-scaled hollow plastics articles. The composition comprises a higher molecular weight ethylene polymer or copolymer and a lower molecular weight ethylene polymer or copolymer which is specified in view of the content of o-dichlorobenzene and the ratio of the area under the elution temperature-eluate volume curve between 25.degree.to 90.degree. C. to the area under said curve of 90.degree. C. and above in temperature rising elution fractionation.Type: GrantFiled: September 4, 1992Date of Patent: November 9, 1993Assignee: Nippon Petrochemicals Company, Ltd.Inventors: Toshifumi Morimoto, Toshiyuki Miyauchi, Sumio Ikeda, Kunimichi Kubo, Narumi Ishikawa, Noboru Ikegami
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Patent number: 5253323Abstract: A method of manufacturing a multimode optical transmission medium from a synthetic resin having the distribution of refractive index varying continuously in a fixed direction. In the method, the polymerization is caused to proceed utilizing the effect of diffusion or exclusion of a monomer in the gel formed at the polymerization initiating terminal. Therefore, this method is free from the defects of methods using conventional polymerization reactions, and has an extremely high productivity.Type: GrantFiled: April 15, 1992Date of Patent: October 12, 1993Assignees: Yasuhiro Koike, Nippon Petrochemicals Company, LimitedInventors: Yasuhiro Koike, Eisuke Nihei
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Patent number: 5248729Abstract: A thermoplastic resin composition is prepared by heat-treating a mixture of a thermoplastic resin substantially containing no olefinic unsaturated carbon-carbon bond and an elastomer having an olefinic unsaturated carbon-carbon bond, dynamically in the presence of a crosslinking agent, characterized in that as said elastomer there is used at least one member selected from the group consisting of styrene-butadiene-styrene block copolymer (SBS), styrene-isoprene-styrene block copolymer (SIS), 1,2-polybutadiene rubber and ethylene-propylene-diene random copolymer (EPDM), and that as said crosslinking agent there is used a dihydroaromatic compound or a polymer thereof.Type: GrantFiled: August 21, 1992Date of Patent: September 28, 1993Assignee: Nippon Petrochemicals Company LimitedInventors: Toshio Inoue, Shiyuji Kashiwase, Masaaki Miyazaki, Toshitsune Yoshikawa, Masaaki Kobayashi
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Patent number: 5240973Abstract: Surface characteristics of a molded article formed by a composition comprising at least two kinds of engineering plastics and a functionalized polyolefin resin or a composition comprising the said composition and an inorganic filler or a rubbery substance incorporated therein can be improved without deteriorating such characteristics as rigidity, impact resistance, heat resistance, dimensional stability and moldability, by radiating an ultraviolet light not longer than 300 nm in wavelength to the molded article, the said functionalized polyolefin resin containing at least one member selected from the group consisting of carboxylic acid group-, carboxylic ester group- or acid anhydride group-containing monomers, epoxy group-containing monomers, hydroxyl group-containing monomers, amino group-containing monomers, alkenyl cyclic iminoether derivatives and polyfunctional monomers.Type: GrantFiled: November 22, 1991Date of Patent: August 31, 1993Assignees: Japan as represented by Director General of Agency of Industrial Science and Technology, Nippon Petrochemicals Company, LimitedInventors: Kohichiroh Katoh, Motomi Nogiwa, Yoshiharu Iwasaki
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Patent number: 5240160Abstract: A rotary splitting tool for splitting a web of plastic material to fabricate a fibrillated web, comprising a rotatable body having a plurality of transverse ridges provided on the periphery in a circumferentially equidistant relationship and extending generally parallel to the central rotation axis, and rows of cutting edges provided on the transverse ridges, respectively. Convex walls are provided on the periphery of the body between the adjacent transverse ridges. The convex wall means receives a web to be split so that oscillation of the web during repeated operations of the cutting edges can be minimized to reduce noise and prevent irregular slits.Type: GrantFiled: February 28, 1992Date of Patent: August 31, 1993Assignees: Nippon Petrochemicals Company, Limited, Polymer Processing Research Inst., Ltd.Inventors: Hirotsune Okada, Tsutomu Matsuzaki, Kazuhiko Kurihara, Hiroshi Yazawa, Toshikazu Ohishi
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Patent number: 5238718Abstract: A multi-layered blow-molded bottle comprising at least two layers of a polyolefin resin (A), at least two layers of an adhesive resin (B) prepared by melt-reacting an olefin polymer (b.sub.1) with a rubber (b.sub.2) and an unsaturated carboxylic acid or a derivative thereof (b.sub.3) in the presence of an organic peroxide to obtain a product and adding a rubber (b.sub.4) to the product to melt-mix them with each other, and at least one layer of a barrier resin (C) selected from among polyamide, polycarbonate, polyester, polyvinylidene chloride and saponified ethylene-vinyl acetate polymer resins, which are laminated in the order of A/B/C/B/A.Type: GrantFiled: May 29, 1991Date of Patent: August 24, 1993Assignee: Nippon Petrochemicals Company, LimitedInventors: Katsumi Yano, Shigemitsu Kambe
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Patent number: 5223566Abstract: A thermoplastic resin composition for extrusion molding superior in the balance of mechanical properties and moldability is obtained by using a partially crosslinked product obtained by dynamically heat-treating:(A) 100-1 wt % of an .alpha.-olefin (co)polymer of C.sub.2 to C.sub.8 ;(B) 0-99 wt % of a rubbery substance;0.01-7 parts by weight, based on 100 parts by weight of the components (A)+(B), of at least one crosslinking agent selected from:(C) a dihydroaromatic series compound or a polymer thereof,(D) an ether series compound,(E) a tetrahydroaromatic series compound, and(F) a cyclopentane series compound; and(G) 0.01-7 parts by weight of a polyfunctional monomer based on 100 parts by weight of the components (A)+(B).Type: GrantFiled: May 30, 1991Date of Patent: June 29, 1993Assignee: Nippon Petrochemicals Company, LimitedInventors: Fuyuki Aida, Tsutomu Miyamoto
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Patent number: 5221781Abstract: A thermoplastic resin composition well-balanced in rigidity, resistance to impact and to heat, dimensional stability, flame retardance and moldability, prepared by incorporating an inorganic filler and/or a flame retardant into a thermoplastic resin composition containing a partially crosslinked product obtained by dynamically heat-treating a thermoplastic resin and/or a rubbery substance in the presence of at least one crosslinking agent selected from a dihydroaromatic series compound or a polymer thereof, an ether series compound, a tetrahydroaromatic series compound, and a cyclopentane series compound, and also in the presence of a polyfunctional monomer.Type: GrantFiled: July 2, 1991Date of Patent: June 22, 1993Assignee: Nippon Petrochemicals Company, LimitedInventors: Fuyuki Aida, Tsutomu Miyamoto, Masaaki Miyazaki
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Patent number: 5221782Abstract: A composition for injection molding well-balanced in rigidity, impact resistance, appearance of molded products and moldability is obtained by using as an essential component a partially crosslinked product being prepared by dynamically heat-treating:(A) 40-100% by weight of an .alpha.-olefin (co)polymer resin having 2 to 8 carbon atoms;(B) 0-60% by weight of rubbery substance; 0.01-0.07 parts by weight, based on 100 parts by weight of said components (A)+(B), of at least one crosslinking agent selected from:(C) a dihydroaromatic compound or a polymer thereof,(D) an ether family compound,(E) a tetrahydroaromatic compound, and(F) a cyclopentane family compound; and(G) 0.01-7 parts by weight of a polyfuncational monomer based on 100 parts by weight of said components (A)+(B).Type: GrantFiled: July 2, 1991Date of Patent: June 22, 1993Assignee: Nippon Petrochemicals Company, LimitedInventors: Fuyuki Aida, Tsutomu Miyamoto, Masaaki Miyazaki
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Patent number: 5221766Abstract: A method for producing .alpha.-(p-isobutylphenyl)-propionic acid with a high selectivity and high purity. The method is characterized in that .alpha.-(p-isobutylphenyl)propionaldehyde is oxidized at temperatures not higher than -12.degree. C. in the presence of an acid using a hypohalogenite. The acid is an inorganic acid such as sulfuric acid, phosphoric acid and hydrochloric acid and the hypohalogenite may be sodium salts, potassium salts or calcium salts of hypochlorous acid or hypobromous acid.Type: GrantFiled: April 7, 1992Date of Patent: June 22, 1993Assignee: Nippon Petrochemicals Company, LimitedInventors: Isoo Shimizu, Yasuo Matsumura
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Patent number: 5202396Abstract: A process for feeding a powder catalyst with a gas intermittently to a high-pressure fluidized bed reactor for the vapor phase polymerization of olefin, wherein the cross section of a catalyst feed pipe is reduced midway through the pipe to thereby make continual catalyst feeding possible and prevent the formation of a lump polymer.Type: GrantFiled: March 19, 1992Date of Patent: April 13, 1993Assignee: Nippon Petrochemicals Company, LimitedInventors: Kunimichi Kubo, Motokazu Watanabe, Mamoru Yoshikawa, Masatoshi Morikawa, Yoshihisa Yamaguchi
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Patent number: 5200122Abstract: Surface characteristics of a molded article formed by a composition including a polypropylene resin, an engineering plastic and a functionalized polyolefin resin or a composition including the said composition and an inorganic filler or a rubbery substance incorporated therein can be improved without deteriorating such characteristics as rigidity, impact resistance, heat resistance, dimensional stability and moldability, by radiating an ultraviolet light not longer than 300 nm in wavelength to the molded article, the said functionalized polyolefin resin containing at least one member selected from the group consisting of carboxylic acid group-, carboxylic ester group- or acid anhydride group-containing monomers, epoxy group-containing monomers, hydroxyl group-containing monomers, amino group-containing monomers, alkenyl cyclic iminoether derivatives and polyfunctional monomers.Type: GrantFiled: November 25, 1991Date of Patent: April 6, 1993Assignees: Japan as represented by Director Science and Technology, Nippon Petrochemicals Company, LimitedInventors: Koichiroh Katoh, Motomi Nogiwa, Yoshiharu Iwasaki
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Patent number: 5190704Abstract: Surface characteristics of a molded article formed by a composition including a thermoplastic resin and a functionalized polyolefin resin or a composition incorporating the above composition and an inorganic filler or a rubbery substance incorporated therein can be improved without deteriorating such characteristics as rigidity, impact resistance, heat resistance, dimensional stability and moldability, by radiating an ultraviolet light not longer than 300 nm in wavelength to the molded article, the said functionalized polyolefin resin containing at least one member selected from the group consisting of carboxylic acid group-, carboxylic ester group- or acid anhydride group-containing monomers, epoxy group-containing monomers, hydroxyl group-containing monomers, amino group-containing monomers, alkenyl cyclic iminoether derivatives and polyfunctional monomers.Type: GrantFiled: November 22, 1991Date of Patent: March 2, 1993Assignees: Agency of Industrial Science and Technology, Nippon Petrochemical Company, LimitedInventors: Kohichiroh Katoh, Motomi Nogiwa, Yoshiharu Iwasaki
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Patent number: 5189106Abstract: A polyethylene composition which has excellent flow characteristics and mechanical properties, especially low temperature mechanical properties as well as thermal stability, elasticity and workability for molding. The polyethylene composition comprises 20 to 80 wt. % of an ethylene-.alpha.-olefin copolymer of higher molecular weight having (a) intrinsic viscosity (.eta..sub.1) of 1.2 to 9.0 dl/g, (b) density (d.sub.1) of 0.890 to 0.935 g/cm.sup.3 (c) a specific areal ratio calculated with an elution temperature-eluate volume curve in elution fractionation, and (d) a specific quantity of the content which is soluble in 25.degree. C. o-dichlorobenzene, and 80 to 20 wt. % of ethylene homopolymer or ethylene-.alpha.-olefin copolymer of lower molecular weight having (e) intrinsic viscosity (.eta..sub.2) of 0.2 to 1.6 dl/g, (f) density (d.sub.2) of 0.890 to 0.980 g/cm.sup.3 and, wherein the above (.eta..sub.1) is larger than (.eta..sub.2), and the prepared composition has an intrinsic viscosity (.eta.) of 0.Type: GrantFiled: December 30, 1991Date of Patent: February 23, 1993Assignee: Nippon Petrochemicals Company, LimitedInventors: Toshifumi Morimoto, Takaaki Hattori, Noboru Ikegami, Hirofumi Nishibu, Toshiyuki Miyauchi, Kunimichi Kubo
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Patent number: 5182064Abstract: A method for producing a fiber reinforced plastic rod having ribs on its surface by impregnating a reinforcing material which has continuous long fiber bundles with an uncured liquid resin. A rib forming member is separately prepared by impregnating a fiber bundle reinforcing material with an uncured liquid resin. A fiber reinforced plastic rod is formed by helically applying the rib forming member to the surface of the substrate forming member and together curing the two members into an integral body. A fiber reinforced plastic rod, prepared in accordance with this method, is also described.Type: GrantFiled: June 14, 1991Date of Patent: January 26, 1993Assignee: Nippon Petrochemicals Company, LimitedInventors: Hitoharu Ishizuka, Reiko Kubo