Patents Assigned to Nippon Shokubai Kagaku Kogyo Co.
  • Patent number: 6335406
    Abstract: A method for the production of (D) an absorbent resin excelling in durability, which method comprises polymerizing (A) 30% by weight to saturated concentration of (A) an aqueous water-soluble ethylenically unsaturated monomer solution containing (B) 0.005 to 5 mol % of a cross-linking agent and (C) 0.001 to 1 mol % of a water-soluble chain transfer agent, both based on the amount of said monomer (A), and if necessary, the surface region of the resultant absorbent resin (D) is cross-linked with (E) a hydrophilic cross-linking agent capable of reacting with the functional group of the absorbent resin and an absorbent resin obtained by such method.
    Type: Grant
    Filed: March 1, 1993
    Date of Patent: January 1, 2002
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Kinya Nagasuna, Kenji Kadonaga, Kazumasa Kimura, Tadao Shimomura
  • Patent number: 6087002
    Abstract: A process for producing water-absorbent resins having an average particle diameter of 100 to 600 .mu.m and a particle diameter distribution of 0.35 or less by polymerizing an aqueous solution of a water-soluble ethylenically unsaturated monomer, pulverizing and sieving the polymer so obtained, and crosslinking the surface of the polymer powder.
    Type: Grant
    Filed: October 29, 1997
    Date of Patent: July 11, 2000
    Assignee: Nippon Shokubai Kagaku Kogyo Co. Ltd.
    Inventors: Kazumasa Kimura, Kinya Nagasuna, Takashi Namba, Kenji Kadonaga, Koji Miyake, Tadao Shimomura
  • Patent number: 5854318
    Abstract: A cement additive is added to increase flowability of a cement composition and to prevent a slump loss, but those characters are insufficient, or the cement additive becomes ununiform in the cement composition and causes a trouble of the hardening inferiority.Thus, to solve the subjects, the present invention provides a cement additive composed of a crosslinked polymer in which, between main chains having a water-soluble polymer structure of a molecular weight from 500 to 100,000, a bond having as a structural unit at least one group selected from divalent groups as shown in the following formula (I) is formed. ##STR1## ?In the formula (I), R.sup.1 and R.sup.2 independently denote any one of the following. ##STR2## However, R.sup.1 may not be required in a case of that R.sup.2 is the following. ##STR3## Moreover, R and R' independently denote an alkyl group of carbon number of 1 to 5.
    Type: Grant
    Filed: December 5, 1996
    Date of Patent: December 29, 1998
    Assignee: Nippon Shokubai Kagaku Kogyo Co, Ltd.
    Inventors: Hideyuki Tahara, Hiroshi Ito, Yasuhiro Mori, Makoto Mizushima
  • Patent number: 5641847
    Abstract: A swellable oil-absorbent agent formed of a cross-linked polymer (P) obtained by polymerizing a monomer component comprising 90 to 99.999% by weight of a monomer having as a main moiety thereof an alkyl (meth)acrylate the alkyl group of which has 10 to 16 carbon atoms and possessing one polymerizable unsaturated group in the molecular unit thereof and 0.001 to 10% by weight of a cross-linkable monomer possessing at least two polymerizable unsaturated groups in the molecular unit thereof (providing that the total of the amount of the polymerizable monomer and that of the cross-linkable monomer is 100% by weight).
    Type: Grant
    Filed: December 28, 1995
    Date of Patent: June 24, 1997
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Yoshiyuki Hozumi, Toru Inaoka, Tomoki Gomi, Takakiyo Goto, Toru Uno, Kenji Rakutani
  • Patent number: 5628975
    Abstract: A method for purifying exhaust gases from a diesel engine is provided. The method utilizes a flow through type honeycomb catalyst having parallel through-cells and (1) a cross-sectional area at the inlet part of an exhaust gas cut by a face vertical to the direction of the through-cells of 10 to 100 cm.sup.2, preferably 20 to 80 cm.sup.2, per liter of the displacement of the engine,(2) an hydraulic diameter of the through-cells of 1.00 to 2.00 mm, preferably 1.10 to 1.40 mm, and(3) the percentage of open frontal area at the inlet part of the exhaust gas of 40 to 95%, preferably 50 to 85%.
    Type: Grant
    Filed: January 24, 1994
    Date of Patent: May 13, 1997
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Makoto Horiuchi, Noboru Miyake, Toshimasa Kushihara, Koichi Saito
  • Patent number: 5498670
    Abstract: Disclosed herein are crosslinked spherical fine particles having good toughness, elastic properties, and chemical properties, and a process for producing the same, said fine particles being obtained by radical polymerization in the suspended state of a component [M] capable of radical polymerization containing a vinyl group-containing compound (V) capable of radical polymerization which is obtained by reaction of (a) a selected polyol, (b) an isocyanate group-containing compound, and (c) an active hydrogen-containing vinyl monomer capable of radical polymerization. Also disclosed herein are the secondary products of the crosslinked spherical fine particles, which include a coating composition and its derivatives (such as filmlike article, sheetlike article, adhesive filmlike article, and adhesive sheetlike article) and a peelable pressure-sensitive adhesive and peelable pressure-sensitive adhesive article.
    Type: Grant
    Filed: October 17, 1994
    Date of Patent: March 12, 1996
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Takahiro Aoyama, Mitsuo Nakazaki, Akikazu Banba, Masatoshi Yoshida, Toshiaki Matsunaga, Tsuneo Tsubakimoto
  • Patent number: 5484841
    Abstract: A method for the production of an aqueous dispersion of a long-chain alkyl graft polymer, which method comprises mixing an aqueous solution of a polyamine with a long-chain alkyl isocyanate and stirring the resultant mixture thereby causing reaction of said component reactants, and an aqueous release agent formed therefrom.
    Type: Grant
    Filed: October 13, 1994
    Date of Patent: January 16, 1996
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Kazuo Kodama, Toru Tsuda, Kazutomo Takahashi
  • Patent number: 5407610
    Abstract: In a method for molding a sheet which includes thermosetting resin materials reinforced with glass fiber or carbon fiber, the sheet includes a covering film always existing in a side which is not in contact with a mold face and, when the sheet and covering film are shaped along a mold face and the sheet is thermally cured, apparatus for dealing with an accidental breakage of the covering film is arranged on the side of the sheet which is covered by said covering film.
    Type: Grant
    Filed: July 22, 1993
    Date of Patent: April 18, 1995
    Assignees: Honda Giken Kogyo Kabushiki Kaisha, Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Katsumi Kohama, Hiromi Tanaka, Ryoichi Yugami, Tomohisa Abe, Daisuke Atobe, Hidemitsu Takizawa, Kenichi Ueda, Yuji Inagaki
  • Patent number: 5403821
    Abstract: This invention provides a drilling fluid containing additives composed of copolymers which are obtainable by an industrially favorable process and superior in heat-resisting property. Even though the additives are used in a relatively small amount, such an amount sufficiently prevents changes in the properties of drilling fluid due to various kinds of hard water components being contained in underground water or cement as well as due to sea water, and the additives are able to display the properties of drilling fluid constantly regardless of presence or absence of salts.Drilling fluid additives of the present invention are composed of a water-soluble copolymer (A) having an average molecular weight of 1,000-50,000. The water soluble copolymer (A) is composed of 40-99.5 mole percent of an unsaturated carboxylic acid monomer (I), as shown in the following general formula (I), and 0.5-60 mole percent of an unsaturated (meth)allylether monomer (II), as shown in the general formula (II).
    Type: Grant
    Filed: October 25, 1993
    Date of Patent: April 4, 1995
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Shorbu Shioji, Yoshio Irie, Teruaki Fujiwara
  • Patent number: 5374600
    Abstract: A swellable oil-absorbent agent formed of cross-linked polymer (P) obtained by polymerizing a monomer component comprising 90 to 99.999% by weight of a monomer having as a main moiety thereof an alkyl (meth)acrylate the alkyl group of which has 10 to 16 carbon atoms and possessing one polymerizable unsaturated group in the molecular unit thereof and 0.001 to 10% by weight of a cross-linkable monomer possessing at least two polymerizable unsaturated groups in the molecular unit thereof (providing that the total of the amount of the polymerizable monomer and that of the cross-linkable monomer is 100% by weight).
    Type: Grant
    Filed: September 27, 1993
    Date of Patent: December 20, 1994
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Yoshiyuki Hozumi, Toru Inaoka, Tomoki Gomi, Takakiyo Goto, Toru Uno, Kenji Rakutani
  • Patent number: 5338810
    Abstract: A method for the production of an acrylate by the neutralization reaction of acrylic acid and a basic substance, comprising sequentially (A) a step of supplying acrylic acid and said basic substance to water thereby subjecting them to a neutralization reaction while constantly retaining the neutralization ratio of acrylic acid within the neutralization reaction system in the range of 75 to 100 mol %, (B) a step of adjusting the neutralization ratio of acrylic acid within said neutralization reaction system in the range of 100.1 to 110 mol % by supplying said basic substance to said neutralization reaction system, (C) a step of retaining the neutralization ratio of acrylic acid within said neutralization reaction system in the range of 100.
    Type: Grant
    Filed: March 8, 1993
    Date of Patent: August 16, 1994
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Tadao Shimomura, Yoshio Irie, Hitoshi Takahashi, Katsuhiro Kajikawa, Jyunichi Saga, Teruaki Fujiwara, Takumi Hatsuda
  • Patent number: 5329026
    Abstract: A process for preparation of a 2-substituted-1,4-naphthoquinone which comprises oxidizing a 2-substituted naphthalene to obtain reaction products comprising a 2-substituted-1,4-naphthoquinone and a 6-substituted-1,4-naphthoquinone; adding a diene compound to the reaction products and heating the mixture to form a Diels-Alder reaction adduct between the diene compound and the 6-substituted-1,4-naphthoquinone in the reaction products; and separating the 2-substituted-1,4-naphthoquinone from the adduct.
    Type: Grant
    Filed: November 28, 1990
    Date of Patent: July 12, 1994
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Noboru Sugishima, Noriaki Ikeda, Yasushi Fujii, Ryuji Aoki, Yumi Hatta
  • Patent number: 5304324
    Abstract: A monodispersed glycol suspension having excellent dispersion stability at a pH within a wide range, comprising a monodispersed suspension in a glycol of spherical fine particles of an amorphous inorganic oxide having an average particle diameter of 0.15 to 5 micrometers and a relative particle size standard deviation of 1.0 to 1.5 and containing glycol bonded to its surface. This monodispersed suspension is useful as a raw material for the production of a polyester film having improved slipperiness.
    Type: Grant
    Filed: August 10, 1992
    Date of Patent: April 19, 1994
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Tadahiro Yoneda, Saburo Nakahara, Mitsuo Takeda, Midori Kamo
  • Patent number: 5286699
    Abstract: An exhaust gas purifying catalyst suppressing the generation of hydrogen sulfide obtained by coating and supporting on a honeycomb carrier of a monolithic structure a catalyst composition containing (a) activated alumina supporting platinum and/or palladium in the range of 5 to 30 weight % and rhodium in the range of 1 to 20 weight %, (b) a cerium oxide and (c) activated alumina, and optionally (d) an alkali metal and/or (e) a nickel oxide.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: February 15, 1994
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Tomohisa Ohata, Kazuo Tsuchitani, Eiichi Shiraiashi
  • Patent number: 5284909
    Abstract: An amphoteric polyelectrolite represented by the general formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are H or alkyl, R.sup.5 is H, alkyl or w-OH substituted alkyl, HY is monobasic acid, and Z is amide.
    Type: Grant
    Filed: October 13, 1992
    Date of Patent: February 8, 1994
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Kazutomo Takahashi, Koichi Yamamoto, Kazuo Kodama, Seiichi Suzuki, Takashi Tazaki, Yutaka Morimoto, Hideyuki Nishibayashi
  • Patent number: 5275759
    Abstract: A highly concentrated zirconia sol is produced by a method which comprises heating an aqueous solution of a zirconium salt in the presence of urea thereby obtaining a transparent zirconia sol, concentrating the zirconium sol with an ultrafilter membrane, and subjecting the concentrated zirconic sol to thermal concentration at a temperature of not higher than 80.degree. C. The sol thus obtained enjoys lasting stability. Optionally, this sol may incorporate therein a chelating agent and a compound of a metal other than zirconium. A slurry of the zirconia sol incorporating therein minute refractory particles is useful for the manufacture of a porous ceramic article. A ceramic product obtained by firing this slurry is advantageously used in a mold for casting.
    Type: Grant
    Filed: November 13, 1992
    Date of Patent: January 4, 1994
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Shigemi Osaka, Kazuo Hata, Tsukawa Takahashi, Teruyuki Moto
  • Patent number: 5264495
    Abstract: A method for the production of a salt-resistant absorbent resin, which comprises subjecting an aqueous solution of at least one monomer component (A) selected from the group consisting of unsaturated carboxylic acids and salts thereof to aqueous solution polymerization in the presence of from 1 to 30 parts by weight, based on 100 parts by weight of said monomer component (A), of an absorbent resin (B).
    Type: Grant
    Filed: April 26, 1991
    Date of Patent: November 23, 1993
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Yoshio Irie, Katsuhiro Kajikawa, Hitoshi Takahashi, Teruaki Fujiwara
  • Patent number: 5262570
    Abstract: A method of producing ethylenediamines represented by the general formula ##STR1## wherein R represents a hydrogen atom, or a methyl or ethyl group, which comprises reacting an aziridine compound of the general formula ##STR2## wherein R is as defined, with ammonia in the gaseous phase in the presence of a solid acid catalyst. In another aspect, a method of producing ethylenediamines of the general formula (I), which comprises reacting a reaction product containing an aziridine compound of the general formula (II), obtained by the gaseous phase intramolecular dehydration reaction of an alkanolamine represented by the general formula ##STR3## wherein X represents the OH group or the NH.sub.2 group, Y represents the NH.sub.2 group when X is the OH group and the OH group when X is the NH.sub.2 group, and R is as defined,in the presence of a catalyst A, with ammonia in the gaseous phase in the presence of a solid acid catalyst (catalyst B).
    Type: Grant
    Filed: January 11, 1993
    Date of Patent: November 16, 1993
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Yuuji Shimasaki, Hideaki Tsuneki, Youichi Hino, Tetsuro Hayashi, Michio Ueshima
  • Patent number: 5254797
    Abstract: A catalyst composition including component A and component B, the component A being a carrier, preferably having a honeycomb structure, and being a single-component oxide or a multi-component composite oxide of at least one metal of titanium, silicon and zirconium, and the component B being a catalyst component deposited on the carrier of component A and being at least one member selected from the group of noble metals and other specifically limited metals and their oxides, is very effective for decomposing and removing poisonous organic chlorine compounds, such as dioxin and the like, or poisonous organic chlorine compound-forming substances contained in an exhaust gas exhausted from an incinerator of an incineration plant provided with the incinerator and a dust collector. In addition, and the generation of the poisonous organic chlorine compound from the incineration plant can be prevented.
    Type: Grant
    Filed: November 24, 1992
    Date of Patent: October 19, 1993
    Assignees: NGK Insulators, Ltd., Masakatsu Hiraoka, Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Yoshinori Imoto, Katsunosuke Hara, Masakatsu Hiraoka, Kunio Sano, Akira Inoue
  • Patent number: 5252184
    Abstract: An additive for paper production, comprising an amphoteric polymeric electrolyte having as an essential component thereof a structural unit represented by the following general formula I: ##STR1## wherein n is an integer in the range of 1 to 5, R.sup.1, R.sup.2, and R.sup.3 are independently hydrogen atom or an alkyl group, R.sup.4 is hydrogen atom, an alkyl group, or a hydroxyalkyl group, and a and b are jointly relative numerals such that the a/b ratio is in the range of 0.2 to 45.0), having at least part of the amino group of said amphoteric polymeric electrolyte neutralized, and possessing a cation equivalent amount (Cv) in the range of 1.0 to 15.0 meq/g, an anion equivalent amount (Av) in the range of 0.1 to 7.0 meq/g, and a Cv/Av ratio in the range of 0.2 to 45.0.
    Type: Grant
    Filed: October 21, 1991
    Date of Patent: October 12, 1993
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Yasumasa Tanaka, Koichi Yamamoto, Kazutomo Takahashi