Patents Assigned to Nippon Shokubai
  • Publication number: 20150218341
    Abstract: The present invention (a) provides, at low cost, a water absorbing agent (i) that has a suppressed amount of generated dust and a suppressed amount of dust that increases over time and (ii) that also has a high absorption capacity without load, a high absorption capacity under load, a high vertical diffusion absorbency under load, and a high absorbency in a short period of time, and (b) also provides a method for evaluating, in a short period of time, an amount of dust that increases over time. A particulate water absorbing agent of the present invention includes: a surface crosslinked polyacrylic acid (salt)-based water absorbent resin as a main component; a hydrophilic polymer compound; and a stabilizing agent.
    Type: Application
    Filed: August 27, 2013
    Publication date: August 6, 2015
    Applicant: NIPPON SHOKUBAI CO., LTD.
    Inventors: Yasuhisa Nakashima, Katsuyuki Wada, Hiroyuki Ikeuchi, Manabu Ueda
  • Patent number: 9096732
    Abstract: [Problem] To provide a pneumatic conveyance method for a water-absorbing resin powder substance, which is capable of suppressing property decrease of the water-absorbing resin powder substance, while suppressing obstruction phenomenon. [Solution] A conveyance method for a water-absorbing resin powder substance by pneumatic conveyance of the water-absorbing resin powder substance during a production step via a transportation pipeline, wherein a variation of a solid-gas ratio (R1/R2) exceeds 1 and is equal to or smaller than 7, provided that R1 (kg-resin/kg-air) stands for an initial solid-gas ratio at a start point of the transportation pipeline, and R2 (kg-resin/kg-air) stands for a terminal solid-gas ratio at a terminal point of the transportation pipeline is provided.
    Type: Grant
    Filed: March 26, 2009
    Date of Patent: August 4, 2015
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Kozo Nogi, Masatoshi Nakamura, Koji Matsumoto, Kazuma Awai
  • Patent number: 9096516
    Abstract: A method for producing N-vinyl-2-pyrrolidone by crystallization including: controlling a water content in a feed N-vinyl-2-pyrrolidone solution at an inlet of a crystallizer so as to be not lower than 0.7% by weight and not higher than 10% by weight based on the total weight of the N-vinyl-2-pyrrolidone solution; and supplying the feed N-vinyl-2-pyrrolidone solution to a crystallization process.
    Type: Grant
    Filed: May 17, 2011
    Date of Patent: August 4, 2015
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Hideto Sugiura, Toru Inaoka, Shigeyuki Nozaki, Yoshihisa Oka
  • Patent number: 9090725
    Abstract: The present invention aims to provide an amino group-containing polymer that is excellent in anti-soil redeposition property during washing and compatibility with surfactants, a method for producing thereof, and a detergent composition containing the amino group-containing polymer. The present invention is the amino group-containing polymer comprising a structural unit derived from an amino group-containing monomer having a specific structure and a structural unit derived from a nonionic monomer and/or an amino group-containing monomer other than the amino group-containing monomer described above.
    Type: Grant
    Filed: September 9, 2011
    Date of Patent: July 28, 2015
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Atsuro Yoneda, Daisuke Michitaka
  • Patent number: 9090577
    Abstract: PROBLEM There is provided a catalyst for producing ethylene oxide which is superior in catalytic selectivity and catalytic life (durability). SOLUTION There is provided a catalyst for producing ethylene oxide having a catalyst component supported on a carrier, wherein the carrier has specific surface area of 0.5 to 1.3 m2/g, Si content (SiO2 equivalent) of 0.1 to 5.0% by mass and Na content (Na2O equivalent) of 0.05 to 1.0% by mass, and the catalyst component is silver (Ag), cesium (Cs), rhenium (Re) and tungsten (W) or molybdenum (Mo).
    Type: Grant
    Filed: March 30, 2010
    Date of Patent: July 28, 2015
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Takaaki Hashimoto, Tadashi Sento, Masahide Shima
  • Patent number: 9090718
    Abstract: The present invention provides a highly productive method for manufacturing a water-absorbing resin, the amounts of fine powder and dust of which are small, the amount of residual monomer of which is small, and whose absorption rate is high. That is, the method for manufacturing the water-absorbing resin of the present invention is a method for crosslinking and polymerizing an aqueous solution of an acid-group containing unsaturated monomer, and is characterized in that stationary polymerization is carried out in such a manner that a solid matter is added to the monomer aqueous solution, and an initiation temperature of the polymerization is adjusted to 40° C. or more or a maximum temperature of the polymerization is adjusted to 100° C. or more.
    Type: Grant
    Filed: March 22, 2007
    Date of Patent: July 28, 2015
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Shigeru Sakamoto, Hiroyuki Ikeuchi, Sayaka Machida
  • Patent number: 9079780
    Abstract: The present invention provides an alkali metal salt of fluorosulfonyl imide having favorable heat resistance and a reduced content of specific impurities and a water content, and provides a method for producing an alkali metal salt of fluorosulfonyl imide, which is capable of easily removing a solvent from a reaction solution. An alkali metal salt of fluorosulfonyl imide of the present invention is represented by the following general formula (I) and has a mass loss rate of 2% or less when the alkali metal salt of fluorosulfonyl imide is kept at 100° C. for 8 hours under an air current. A method for producing an alkali metal salt of fluorosulfonyl imide of the present invention comprises a step of concentrating a solution of the alkali metal salt of fluorosulfonyl imide by bubbling a gas into a reaction solution containing the alkali metal salt of fluorosulfonyl imide, and/or concentrating a solution of the alkali metal salt of fluorosulfonyl imide by thin layer distillation.
    Type: Grant
    Filed: May 27, 2011
    Date of Patent: July 14, 2015
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Yuichi Sato, Shimpei Sato, Yasunori Okumura
  • Patent number: 9079797
    Abstract: The present application relates to a production method for a polycarboxylic acid-based copolymer including a structural unit (I) derived from an unsaturated polyalkylene glycol ether-based monomer (a) and a structural unit (II) derived from an unsaturated carboxylic acid-based monomer (b), in which monomer components including the monomer (a) and the monomer (b) are polymerized using a peroxide and a reductant as polymerization initiators in combination while the pH during polymerization is controlled to 3 or less in the presence of a pH adjustor. The present application also relates to a polycarboxylic acid-based copolymer for a high-performance cement admixture including a structural unit (I) derived from an unsaturated polyalkylene glycol ether-based monomer (a) and a structural unit (II) derived from an unsaturated carboxylic acid-based monomer (b), and a nonpolymerizable organic sulfonic acid having a molecular weight of 300 or less and/or a salt thereof.
    Type: Grant
    Filed: May 8, 2009
    Date of Patent: July 14, 2015
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Hiroshi Kawabata, Noboru Sakamoto
  • Patent number: 9073845
    Abstract: This invention provides a method for producing acrolein and/or acrylic acid by catalytic gas-phase oxidation, which method makes it possible to carry out a continuous operation steadily for a long period of time while a high yield is maintained. This method is characterized by comprising filling each of reaction tubes of a fixed-bed multitubular reactor with at least two species of catalysts each of which essentially comprises, as catalytically active components, oxide of molybdenum, oxide of bismuth and oxide of iron and/or composite oxide of at least two of said elements, said at least two species of catalysts being different in the ratio of D1/D2, D1 denoting the proportion of the total pore volume of pores whose pore diameter falls within the range of at least 0.03 ?m and less than 0.3 ?m to the total pore volume of the whole pores, and D2 denoting the proportion of the total pore volume of pores whose pore diameter falls within the range of at least 0.
    Type: Grant
    Filed: March 28, 2013
    Date of Patent: July 7, 2015
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Tomoatsu Kawano, Hideo Onodera
  • Patent number: 9074030
    Abstract: Provided is a method for producing a water absorbent resin, which promotes the formation of interconnected voids (continuous gas bubbles) in a foamed polymer (foam-like water absorbent resin) by a more convenient method, and produces with high efficiency a water absorbent resin which exhibits a high water absorption rate even when stepped into a sheet form or a powder form in hygiene articles and the like.
    Type: Grant
    Filed: June 29, 2011
    Date of Patent: July 7, 2015
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Toshihiro Takaai, Hidenori Wada, Shinichi Fujino
  • Patent number: 9065150
    Abstract: The present invention provides a stable electrolyte material that provides high safety, exhibits favorable ionic conductivity not only at room temperature but also in the low temperature range at or below room temperature, has excellent reduction resistance, and can be suitably used as a material of a lithium ion cell. The electrolyte material includes, as essential components, a specific polymer having an ether bond in a side chain thereof, and a specific electrolyte salt.
    Type: Grant
    Filed: December 9, 2010
    Date of Patent: June 23, 2015
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Masashi Hashimoto, Akane Oguro, Naohiko Itayama, Kazuo Takei, Izuho Okada
  • Patent number: 9062140
    Abstract: An embodiment of the present invention allows for the production, with a high productivity, of a water-absorbent resin having an improved relationship between absorption capacity and water-soluble polymer, which are conflicting properties of the water-absorbent resin, being easily controlled for polymerization reaction, being of no odor, being less colored, and being of high absorption properties (high absorption capacity under load and high PPUP).
    Type: Grant
    Filed: April 6, 2006
    Date of Patent: June 23, 2015
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Hirotama Fujimaru, Kunihiko Ishizaki, Sei Nakahara
  • Patent number: 9051067
    Abstract: Provided is a production method for the particulate water-absorbing agent, which can collecting the fine powders generated during the producing process efficiently without worsening working environment, and also the particulate water-absorbing agent produced by the production method thereof. This production method includes (1) a polymerization step for obtaining a polymer gel, (2) a drying step for drying said polymer gel to obtain a particulate water-absorbing resin, (3) a classification step for sieving said particulate water-absorbing resin, (4) a surface cross-linking step for cross-linking the neighborhood of the surface of said particulate water-absorbing resin (5) a packaging step for filling a packaging material container with said particulate water-absorbing agent for packaging and (6) a transportation step for transporting the products produced in each of the steps to the other steps.
    Type: Grant
    Filed: March 13, 2009
    Date of Patent: June 9, 2015
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Kozo Nogi, Sumio Okuda, Keiji Inoue, Kazumasa Konishi, Toru Nishioka, Yusuke Watanabe
  • Patent number: 9044525
    Abstract: Provided is a water absorbent resin having excellent liquid permeability, water absorbent speed, anti-impact stability, and weather resistance. Provided is a polyacrylic acid (salt)-based water absorbent resin powder in which the water absorption capacity without load (CRC) is 30 to 45 [g/g], the water absorption capacity under load (AAP 0.3) is 20 to 35 [g/g], the water absorption capacity under load (AAP 0.7) is 10 to 28 [g/g], and the weight average particle diameter (D50) is 300 to 500 ?m, characterized by including p-methoxyphenol; having a degradable soluble component (0.05% L-A (saline) for 2 hours/60° C., one hour extraction rinse/room temperature) of 40% by weight or less; and having a internal gas bubbles ratio of 0.1 to 2.5%, as specified by the following equation.
    Type: Grant
    Filed: June 29, 2012
    Date of Patent: June 2, 2015
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Kazushi Torii, Reiko Nakatsuru, Yasuhisa Nakashima, Katsuyuki Wada, Kunihiko Ishizaki
  • Patent number: 9029596
    Abstract: A method for producing acrylic acid and/or an ester thereof from a raw material composition containing hydroxypropionic acid and/or an ester thereof, the method including the steps of: (a) evaporating the raw material composition; and (b) dehydrating the evaporated raw material composition by contact with a dehydration catalyst, wherein the total amount of hydroxypropionic acid and/or an ester thereof supplied in the step (b) is controlled to be 70% by mass or more based on 100% by mass of the total amount of hydroxypropionic acid and/or an ester thereof supplied in the step (a).
    Type: Grant
    Filed: December 28, 2011
    Date of Patent: May 12, 2015
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Hiroshi Yoshida, Hisashi Kamei
  • Patent number: 9029599
    Abstract: A process for producing (meth)acrylic acid comprising the step of repeating a crystallization operation “n” times to produce purified (meth)acrylic acid from crude (meth)acrylic acid, wherein: the each crystallization operation comprises a crystallizing step and a melting step; a polymerization inhibitor is not added to a (meth)acrylic acid melt obtained in the melting step of the first to n?1th crystallization operation(s) and a (meth)acrylic acid solution subjected to the crystallizing step of the second to nth crystallization operation(s); and a concentration of a polymerization inhibitor in a (meth)acrylic acid solution subjected to the crystallizing step of the first crystallization operation is adjusted so that a concentration of the polymerization inhibitor in a (meth)acrylic acid solution subjected to the crystallizing step of the nth crystallization operation is 2 ppm by mass or higher.
    Type: Grant
    Filed: September 3, 2013
    Date of Patent: May 12, 2015
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Takashi Miyamoto, Yoshitake Ishii, Toyofumi Sakai
  • Patent number: 9023951
    Abstract: Disclosed is a method for producing a water absorbent resin, by which a surface-crosslinked water absorbent resin having excellent physical properties can be efficiently obtained at low cost, while assuring high productivity. When the production scale is increased to a continuous production on a huge scale (for example, 1 t/hr or more), the physical properties are improved and stabilized (for example, standard deviation of the physical properties is reduced) by a surface-crosslinking treatment, and the absorption against pressure (AAP) and liquid permeability (SFC) are further improved.
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: May 5, 2015
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Kozo Nogi, Kunihiko Ishizaki, Syuji Kanzaki
  • Patent number: 9012356
    Abstract: The purpose of the present invention is to provide a method for producing a water absorbent resin having improved physical properties, particularly, improved saline flow conductivity (SFC) and less amount of fine powder.
    Type: Grant
    Filed: November 16, 2012
    Date of Patent: April 21, 2015
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Koji Tachi, Hironori Sato, Kazushi Torii, Hiroyuki Ikeuchi
  • Patent number: 9006134
    Abstract: The application relates to the particulate water absorbing agent of the present invention composed primarily of a polyacrylic acid- or polyacrylate-based water absorbing resin and containing a chelating agent and a phosphorous compound. Accordingly, the particulate water absorbing agent composed primarily of a water absorbing resin achieves both excellent water absorbing properties and anti-coloring effect which would normally be incompatible. A particulate water absorbing agent for absorbent core is provided that is suitable for actual use.
    Type: Grant
    Filed: July 15, 2009
    Date of Patent: April 14, 2015
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Makoto Nagasawa, Hiroyuki Ikeuchi
  • Patent number: 8993656
    Abstract: The present invention discloses compositions and methods wherein polycarboxylate comb polymers are used as grinding additives. The comb polymers contain a carbon-containing backbone and pendant groups wherein oxyalkylene pendant groups contain one or more ether linkage groups for providing robustness to the polymer for resisting degradation during grinding and hence sustaining workability and strength of hydratable cementitious materials, such as cements, pozzolans, limestone, and other cementitious materials.
    Type: Grant
    Filed: January 15, 2010
    Date of Patent: March 31, 2015
    Assignees: W.R. Grace & Co.-Conn., Nippon Shokubai Co., Ltd.
    Inventors: Josephine Cheung, Denise Silva, Byong-Wa Chun, Masahiro Sato