Patents Assigned to Nobel Hoechst Chimie
  • Patent number: 4105690
    Abstract: Condensation of the addition product of glyoxylic acid and amides with hydroxyaryl compounds is effected by a first step, wherein the reaction is carried out hot, at a temperature below 60.degree. C, of an aliphatic amide having at the most 4 carbon atoms selected from the group of acetamide, chloracetamide, propionamide, acrylamide and butyramide, on an aqueous solution of glyoxylic acid. Then in a second step, after the addition of acetic acid and gaseous hydrochloric acid, condensation is effected at a temperature below 35.degree. C of the carboxamidoglycolic acid with an excess reaching 500% of hydroxyaryl compound selected from the group comprising phenol and its alkyl derivatives, their halogen derivatives, polyphenols and their ethers and betanaphthol. After the condensation of said second step, the volatile products are removed by vacuum distillation.
    Type: Grant
    Filed: September 10, 1976
    Date of Patent: August 8, 1978
    Assignee: Nobel Hoechst Chimie
    Inventors: Yani Christidis, Alain Schouteeten
  • Patent number: 4088657
    Abstract: This is an improved process of manufacturing N-acyl derivatives of glycines .alpha.-substituted by radicals with an aromatic nature by condensation of the addition product of glyoxylic acid and an amide, with an aromatic compound. In a first stage, the reaction is carried out at low temperature, in a concentrated sulfuric medium, of an aliphatic nitrile of the formula R--C.tbd.N in which R is a radical selected from the group of substituted and unsubstituted, saturated and unsaturated alkyl radicals, with a concentrated aqueous solution of glyoxylic acid. Then in a second stage, the mixture obtained is condensed also at low temperature with a compound of aromatic nature not including a hydroxyl group and having at least one substitutable free hydrogen, and the resulting product is collected. The concentrated sulfuric acid may be supplemented with acetic acid during the second stage. A surface active agent may be also added in this stage.
    Type: Grant
    Filed: September 10, 1976
    Date of Patent: May 9, 1978
    Assignee: Nobel Hoechst Chimie
    Inventors: Yani Christidis, Alain Schouteeten
  • Patent number: 4074054
    Abstract: The method is for manufacturing imidazoles corresponding to the general formula: ##STR1## in which R represents hydrogen or an alkyl radical of 1 to 17 carbon atoms. Glyoxal is condensed with an aliphatic aldehyde and ammonia, in a hydroalcoholic medium at a pH comprised between 6 and 8. The glyoxal is in the form of its bisulfite combination and the ammonia being supplied by an ammonium salt of a weak acid.
    Type: Grant
    Filed: March 31, 1976
    Date of Patent: February 14, 1978
    Assignee: Nobel Hoechst Chimie
    Inventors: Yani Christidis, Dominique Depernet
  • Patent number: 4052364
    Abstract: Bis(hydroxyphenyl)-alkanoic acid esters the phenyl radicals of which are alkylated twice are prepared by alkylation of corresponding compounds carrying one alkyl radical at the nucleus, using isobutylene as alkylating agent. The alkanoic acid esters are obtained in crystalline form and are suitable as stabilizers for polyolefins.
    Type: Grant
    Filed: January 30, 1975
    Date of Patent: October 4, 1977
    Assignees: Nobel Hoechst Chimie, Hoechst Aktiengesellschaft
    Inventors: Yani Christidis, Otto Mauz, Eberhard Prinz
  • Patent number: 3996226
    Abstract: The invention relates to new industrial chemical compounds imparting anti-soiling properties on cellulose and synthetic fabrics said compounds having the general formula: ##STR1## IN WHICH A is a radical resulting from the removal of at least three atoms of hydrogen replaceable by methylols on atoms of nitrogen of a compound capable of supplying aminoplasts; R.sub.1 is either a hydrogen atom or an alkyl or acyl radical comprising less than 4 atoms of carbon; R.sub.2 is an aliphatic alkyl or acyl radical comprising at least 10 atoms of carbon or aliphatic alkyl or acyl radical comprising at least 10 atoms of carbon or an alkyl radical comprising at least 2 atoms of carbon and at least one halogen substituent; R.sub.3 is a radical resulting from the removal of a hydroxyl from the alcohol group of the addition product of 5 to 30 molecules of identical or different alkylene oxides on an alcohol or an acid; and m, n and p are equal to or greater than 1.
    Type: Grant
    Filed: March 3, 1975
    Date of Patent: December 7, 1976
    Assignee: Nobel Hoechst Chimie
    Inventors: Dimitri Savostianoff, Denise Dubos
  • Patent number: 3983114
    Abstract: A method of preparation of 6-aza uracile, comprising the steps of:A. Cyclization of semi-carbazone of glyoxylic acid by heating this latter with an excess of a trialkyl-silylation agent taken as a solvent and isolating the resulting product, namely the O-disilylated derivative of 6-aza uracile (or di-3,5 (trialkylsiloxy)1,2,4 triazine) andB. subjection of the product resulting from step a) to an acid hydrolysis.
    Type: Grant
    Filed: October 24, 1975
    Date of Patent: September 28, 1976
    Assignee: Nobel Hoechst Chimie
    Inventors: Yani Christidis, Jean-Claude Vallejos
  • Patent number: 3957739
    Abstract: A process of production of linear, water-soluble polymers and co-polymers of very high molecular weight in powder form, from monomers which are themselves soluble in water comprises operating in emulsion with an inversion of phase during the course of the operation with, as solvent, a hydrocarbon giving with water an azeotrope boiling at a temperature lower than 100.degree.C, and with, as emulsifying agent, a non-ionic emulsifying agent having a H.L.B between 8 and 13 in a proportion of 1.5 to 5 % of the total weight of the monomers and the solvents, initiating the polymerization at a temperature lower than 35.degree.C by adding the quantity of initiator of the Redox type to the whole of the reactants and especially carrying out the polymerization in a closed vessel without external cooling, until the maximum temperature is reached.
    Type: Grant
    Filed: November 27, 1974
    Date of Patent: May 18, 1976
    Assignee: Nobel Hoechst Chimie
    Inventors: Jean Cabestany, Erich Schaffer
  • Patent number: 3954874
    Abstract: An improvement to the process for preparing a polyhydric alcohol bromohydrin from the group consisting in the polymethylol-alkanes, penta-erythritols, amino-substituted polyhydric alcohols by the action of hydrobromic acid on the said polyhydric alcohol, consisting of effecting the reaction in an acetic medium with an aqueous solution of hydrobromic acid, eliminating the water during the course of the reaction by distillation of a water-acetic acid mixture rich in water, by means of an apparatus comprising a distillation column adapted to extract vapours at a temperature lower than 103.degree.C, collecting the resultant product, subjecting this latter to a transesterification reaction with a monohydric-alcohol of low molecular weight from the methanol group, and subjecting said product to a purification treatment.
    Type: Grant
    Filed: August 13, 1974
    Date of Patent: May 4, 1976
    Assignee: Nobel Hoechst Chimie
    Inventor: Yani Christidis