Abstract: Disclosed are solid, readily water-soluble addition polymers of acid addition salts of methacrylic acid and a 2-mono(lower)alkylaminoethyl methacrylate, whose lower alkyl group has up to 6 carbons and is straight or branched chain or cyclic. These polymers are insoluble in pentane, hexane and butane below their boiling points, and their aqueous solutions show amphoteric activity. These polymers result from polymerizing the starting monomeric acid addition salt of methacrylic acid and a 2-mono(lower)alkylaminoethyl methacrylate in the ratio of from about one mol to about 1.5 mols of one of them per mol of the other. Also disclosed is the method of producing these addition polymers by heating the starting acid addition salt under pressure in a low boiling aliphatic solvent at a temperature above its boiling point, from which after lowering the temperature the resulting addition polymer readily is separated as a light weight finely divided product.
Abstract: An apparatus that comprises (a) a fluid-tightly closeable materials-treating or reaction chamber with at least its body portion substantially completely enclosed by a temperature-control fluid chamber provided by its being surrounded by a temperature-control fluid jacket, (b) means to rotate the jacketed chamber end over end about an axis substantially normally transverse to its central axis, (c) divider-baffling means dividing its temperature-control fluid chamber into a plurality of, such as four, substantially similar and independent control-fluid compartments or quadrants, (d) temperature-control fluid ingress means which enable feeding temperature-control fluid into such quadrant while the reactor is rotating, (e) means in each compartment or quadrant to affect the flow of fluids through it to provide substantially uniform overall heat transfer from each of them; and (f) fluid egress means to enable discharging heat-control fluid from these compartments during the rotation.
Abstract: Disclosed is a method of conducting under selected temperature conditions and with agitation a chemical operation which requires agitating a liquid phase under selected conditions, by enclosing the involved starting materials in a liquid-tightly enclosed cylindrical operating zone by a zone-enclosure that is a heat conductor and is of greater length than diameter and is enveloped by a subdivided temperature-control fluid-confining zone, and agitating the operating zone contents by rotating the operating zone with the fluid-confining zone while feeding temperature-control fluid through the temperature-control zone. Also enclosed is the apparatus that provides the cylindrical operating zone enveloped by the temperature-control zone.
Abstract: Water-soluble, polymerizable, acid addition salts of methacrylic acid and 2-mono-(lower)alkylanimoethyl methacrylate whose lower alkyl group is straight or branched chain or cyclic and has up to about 6 carbon atoms, said addition salt includes its methacrylic acid and methacrylate components in the ratio of from about one mole to about 1.5 moles of one of them per mole of the other.
Abstract: An aqueous suspending agent solution or vehicle useful for suspension polymerization of a styrene-monomer such as styrene as well as derivatives of it and also mixtures with it to produce styrene-polymers. Also included is a suspension polymerization batch, as well as an improvement in the method, for the suspension polymerization of a styrene-monomer.