Abstract: Methods for forming polar-functionalized isotactic and syndiotactic polypropylenes are provided, including amino-functionalized polypropylene. In embodiments, such a method comprises contacting a propylene monomer and a polar monomer comprising an amine group in the presence of an organozirconium catalyst and in the absence of a masking reagent, under conditions to induce a polymerization reaction between the propylene and polar monomers, thereby forming polar-functionalized polypropylene.
Type:
Grant
Filed:
December 4, 2020
Date of Patent:
December 12, 2023
Assignee:
Northwestern Unversity
Inventors:
Tobin J. Marks, Minglu Huang, Yanshan Gao