Patents Assigned to Nouryon Chemicals International B.V.
  • Publication number: 20200165207
    Abstract: Urea derivatives, methods for preparing ethylene amines, and methods of polymer manufacturing are provided. An exemplary method for preparing ethylene amines with n ethylene units and n+1 amine groups wherein n is at least 4, or urea derivatives of said ethylene amines, includes reacting an ethanolamine-functional compound, an amine-functional compound, and a carbon oxide delivering agent, wherein the ethanolamine-functional compound is of the formula HO—(C2H4—NH—)qH, q is at least 1, the amine-functional compound is of the formula H2N—(C2H4—NH—)rH, r is at least 1, the sum q+r is at least 4 and wherein optionally one or more of the ethanol-amine functional compound or amine-functional compound are at least partly used as their cyclic carbamate derivative, or linear or cyclic urea derivative.
    Type: Application
    Filed: July 3, 2018
    Publication date: May 28, 2020
    Applicant: NOURYON CHEMICALS INTERNATIONAL B.V.
    Inventors: Eike Nicolas KANTZER, Karl Fredrik LAKE, Antoon Jacob Berend TEN KATE, Michiel Jozef Thomas RAAIJMAKERS, Rens VENEMAN, Rolf Krister EDVINSSON, Ina EHLERS, Michael Bertil Einar SARNING, Robert Kristoffer BERG, Hendrik VAN DAM
  • Publication number: 20200165212
    Abstract: A process is provided for preparing ethyleneamines of the formula NH2—(C2H4—NH—)pH wherein p is at least 3, or derivatives thereof wherein one or more units —NH—C2H4—NH— may be present as a cyclic ethylene urea unit or piperazine unit or between two units —NH—C2H4—NH— a carbonyl moiety is present. The process includes reacting an ethanolamine-functional compound OH—(C2H4—NH—)qH wherein q is at least 2, an amine-functional compound NH2—(C2H4—NH—)rH wherein r is at least 1, in the presence of a carbon oxide delivering agent, wherein the molar ratio of ethanolamine-functional compound to amine-functional compound is from about 0.05:1 to about 0.7:1 and the molar ratio of carbon oxide delivering agent to amine-functional compound is higher than the molar ratio of ethanolamine-functional compound to amine-functional compound, provided that the process does not comprise reacting 3 moles of ethylenediamine (EDA) and 1 mole of AEEA (aminoethylethanolamine) in the presence of 1.65 moles of urea at 280 deg C.
    Type: Application
    Filed: July 3, 2018
    Publication date: May 28, 2020
    Applicant: NOURYON CHEMICALS INTERNATIONAL B.V.
    Inventors: Michiel Jozef Thomas RAAIJMAKERS, Antoon Jacob Berend TEN KATE, Rens VENEMAN, Karl Fredrik LAKE, Slavisa JOVIC, Eike Nicolas KANTZER, Ina EHLERS, Rolf Krister EDVINSSON, Björn Patrik SKANSEN, Michael Bertil Einar SARNING, Jenny Valborg Therese ADRIAN MEREDITH, Hendrik VAN DAM
  • Publication number: 20200165187
    Abstract: A process for converting a feedstock comprising cyclic alkyleneureas into their corresponding alkyleneamines is provided. The process includes a CO2 removal step in which cyclic alkyleneureas are converted into their corresponding alkyleneamines by reacting cyclic alkyleneureas in the liquid phase with water with removal of CO2. The exemplary process further includes an amine removal step wherein cyclic alkyleneureas are converted in a reactive separation process into their corresponding alkyleneamines by reaction with an amine compound selected from the group of primary amines or secondary amines which have a higher boiling point than the alkyleneamines formed during the process.
    Type: Application
    Filed: August 7, 2018
    Publication date: May 28, 2020
    Applicant: NOURYON CHEMICALS INTERNATIONAL B.V.
    Inventors: Antoon Jacob Berend TEN KATE, Michiel Jozef Thomas RAAIJMAKERS, Karl Fredrik LAKE, Eike Nicolas KANTZER, Slavisa JOVIC, Rolf Krister EDVINSSON, Ina EHLERS, Hendrik VAN DAM, Rens VENEMAN
  • Publication number: 20200154703
    Abstract: This disclosure provides a composition comprising a mixture of molecules of Formula (I): {RO—[CH(CH3)CH2O)]b[CH2—CH2O]a}mP(?O)(O?X+)n (I), wherein R is chosen from linear or branched C10-C18 alkyl or alkenyl groups; a is 0 to 50, b is 0-30, and a+b>0; X+ is potassium, triethanolamine, or H, and m and n are each equal to 1 or 2, such that when m=1 then n=2, and when m=2 then n=1. Moreover, in the mixture some of the molecules have m=1 and n=2 and some of the molecules have m=2 and n=1, wherein the mole ratio of compounds where m=1 to compounds where m=2 is of from 1:1 to 3:1.
    Type: Application
    Filed: November 21, 2019
    Publication date: May 21, 2020
    Applicant: NOURYON CHEMICALS INTERNATIONAL B.V.
    Inventors: Hua YU, Mojahedul ISLAM, Christine PUGLISI
  • Patent number: 10647825
    Abstract: Peroxide masterbatch comprising: —15-55 wt % of one or more organic peroxides, —15-45 wt % of at least one copolymer of (i) ethylene or propylene and (ii) 1-butene and/or 1-octene, and 13-45 wt % of at least two types of fillers—filler type 1 and filler type 2—each having a different BET surface area: (i) filler type 1 being present in the masterbatch in a concentration of 3-15 wt % and having a BET surface area of more than 100 m2/g; (ii) filler type 2 being present in the masterbatch in a concentration of 10-30 wt % and having a BET surface area of 100 m2/g or less.
    Type: Grant
    Filed: November 21, 2017
    Date of Patent: May 12, 2020
    Assignee: NOURYON CHEMICALS INTERNATIONAL B.V.
    Inventors: Waldo Joseph Elisabeth Beek, Leonardus Bernardus Gerhardus Maria Nijhof
  • Publication number: 20200131115
    Abstract: A process for the preparation of a solid composition of an amino acid diacetic acid compound wherein the amino acid diacetic acid compound is methyl glycine-N,N-diacetic acid or a salt thereof, or glutamic N,N-diacetic acid or a derivative thereof, as well as the product obtained by such process are disclosed. The process includes feeding a saturated or oversaturated aqueous composition of the amino acid diacetic acid compound in an aqueous solvent to a drum dryer, wherein the aqueous composition is fed to the drum surface with a layer thickness of from about 0.1 to about 10 mm, the drum has a surface temperature of from about 80 to about 180° C., and the drum operates at a tangential speed of from about 0.1 to about 100 m/min. The method further includes removing the mass from the drum before a full revolution of the drum.
    Type: Application
    Filed: July 3, 2018
    Publication date: April 30, 2020
    Applicant: NOURYON CHEMICALS INTERNATIONAL B.V.
    Inventors: PAULUS JOHANNES CORNELIS VAN HAEREN, ROY DOPPEN, ELWIN SCHOMAKER, RAYMOND JEAN CÉCILE VAESSEN, MARCO YPMA, STIJN OUDENHOVEN, MARTIN HEUS
  • Publication number: 20200131455
    Abstract: A solid composition, methods for preparing and using the composition, and a rehydrated crystal are disclosed. An exemplary solid composition contains at least about 2 wt % of methyl glycine-N,N-diacetic acid trisodium salt of crystal type III, based on the total weight of crystalline methyl glycine-N,N-diacetic acid trisodium salt compounds, wherein the crystal type III is the form of a crystal, comprising a crystalline modification characterized by the reflections enlisted below when analyzed with X-ray diffraction analysis using Cu K? radiation: Type III 2? d (?) ?5.8 15.2? ?7.5 11.8? ?8.1 10.9? ?9.5 9.3 11.7 7.6 13.9 6.4 15.1 5.9 16.5 5.4 17.3 5.1 18.5 4.8 19.1 ?4.65 20.1 4.
    Type: Application
    Filed: July 3, 2018
    Publication date: April 30, 2020
    Applicant: NOURYON CHEMICALS INTERNATIONAL B.V.
    Inventors: Elwin SCHOMAKER, Paulus Johannes Cornelis VAN HAEREN, Martin HEUS, Roy Gérard DOPPEN
  • Publication number: 20200131136
    Abstract: The present disclosure pertains to a process for preparing hydroxyethylethyleneamines, ethyleneamines, or mixtures thereof, and/or ethylene urea derivatives thereof. The process includes reacting diethanolamine with an amine-functional compound that includes at least two —NH— units of which at least one is selected from the group of primary amine groups and cyclic secondary amine groups. The amine-functional compound includes at least one —NH—CH2-CH2-NH— unit wherein one or more —NH—CH2-CH2-NH— units in the amine-functional compound may be present in the form of cyclic ethylene urea moieties, piperazine moieties, or linear ethylene urea moieties, in the presence of a carbon oxide delivering agent.
    Type: Application
    Filed: March 12, 2018
    Publication date: April 30, 2020
    Applicant: NOURYON CHEMICALS INTERNATIONAL B.V.
    Inventors: Antoon Jacob Berend TEN KATE, Michiel Jozef Thomas RAAIJMAKERS, Rens VENEMAN, Karl Fredrik LAKE, Robert Kristoffer BERG, Eike Nicolas KANTZER, Rolf Krister EDVINSSON, Hendrik VAN DAM, Ina EHLERS
  • Patent number: 10626263
    Abstract: Peroxide masterbatch comprising: —15-55 wt % of one or more organic peroxides, —15-45 wt % of one or more copolymers of at least two different monomers, the first monomer being ethylene or propylene, the second monomer being a vinyl monomer comprising at least four carbon atoms and optionally heteroatoms, —6-70 wt % of at least two filler types—filler type 1 and filler type 2—each having a different BET surface area: (i) filler type 1 being present in the masterbatch in a concentration of 3-30 wt % and having a BET surface area of more than 100 m2/g; (ii) filler type 2 being present in the masterbatch in a concentration of 3-40 wt % and having a BET surface area of 100 m2/g or less; wherein the masterbatch has the form of extrudates.
    Type: Grant
    Filed: November 21, 2017
    Date of Patent: April 21, 2020
    Assignee: Nouryon Chemicals International B.V.
    Inventor: Waldo Joseph Elisabeth Beek
  • Patent number: 10618980
    Abstract: The invention relates to temporary cross-linked cellulose ethers, a process to make them, as well as their use to influence the rheological profile of an aqueous medium in which they are dissolved. The temporary cross-linked cellulose ethers are characterized in that they are cellulose ethers that are Cross-linked with at least one or more compounds of the formula (C1-4 alkyl)-OC(O)CHOHO—(C1-4 alkyl).
    Type: Grant
    Filed: October 13, 2016
    Date of Patent: April 14, 2020
    Assignee: NOURYON CHEMICALS INTERNATIONAL B.V.
    Inventor: Hans Jonas Karlsson
  • Patent number: 10597492
    Abstract: The application relates to compositions comprising di-fatty-alkyl or -alkenyl polyalkylamines of the general formula (I) or (II), to a process for their preparation which involves a cyanoethylation step and a hydrogenation step, and their use as demulsifiers for oil-in-water emulsions, corrosion inhibitor, fuel additive, anti-scaling agent, asphalt additive, enhanced oil recovery agent for oil-wells, cutting-oil additive, and anti-static agent. The product show good performance combined with a favourable viscosity profile.
    Type: Grant
    Filed: February 24, 2017
    Date of Patent: March 24, 2020
    Assignee: NOURYON CHEMICALS INTERNATIONAL B.V.
    Inventors: Hans Oskarsson, Lynnette Susan Bowen, John André Janiak, Elliot Isaac Band, Kristan Alexander Rus
  • Patent number: 10590064
    Abstract: The present invention relates to alanine N-acetic acid precursors of formula (i) COOM-CH(CH3)—NH—(CH2CN), wherein M is hydrogen (alanine N-monoacetonitrile), or (ii) COOM-CH(CH3)—N—(CH2CN)2, wherein 0 to 50% of all M is sodium or potassium and 50 to 100% of all M is hydrogen (alanine N,N-diacetonitrile and its partial sodium or potassium salts) comprising L-alanine to D-alanine in a range of from 75:25 to 50:50 (L:D), or (iii) COOM-CH(CH3)—N—(CH2CONH2)2, wherein M is hydrogen (alanine N,N-diacetamide), in the form of crystals, and relates to a process to prepare these precursors and their use, especially to give MGMA or MGDA.
    Type: Grant
    Filed: December 21, 2015
    Date of Patent: March 17, 2020
    Assignee: NOURYON CHEMICALS INTERNATIONAL B.V.
    Inventors: Albertus Jacobus Maria Bouwman, Hubertus Johannes Jongen, Roy Gérard Doppen, Martin Heus, Elwin Schomaker
  • Publication number: 20200048735
    Abstract: A collector composition and process to treat ores with a collector composition that comprises a nitrile group-containing compound of the formula (I) wherein R is a saturated or unsaturated, linear or branched, hydrocarbon group containing 8 to 26 carbon atoms, R? is a saturated or unsaturated, linear or branched, hydrocarbon group containing 1 to 26 carbon atoms or a hydrogen atom or (-(D)j-CnH2nCN) group or R-((A)m-(B))x group, A is (—O—CH2CH2—); (—O—CH(CH3)CH2—) or (—O—CH(CH2CH3)CH2—), B is (—O—CpH2p—), D is (—CH2CH2—O—); (—CH(CH3)CH2—O—) or (—CH(CH2CH3)CH2—O—), x is 0 or 1, R?? is hydrocarbon group containing 1 to 4 carbon atoms, Y is halide or methylsulfate, m, j are each independently an integer of 0-5, R?? is a saturated or unsaturated, linear or branched, hydrocarbon group containing 1 to 26 carbon atoms, and n and p are each independently an integer of 1 to 5.
    Type: Application
    Filed: March 20, 2018
    Publication date: February 13, 2020
    Applicant: NOURYON CHEMICALS INTERNATIONAL B.V.
    Inventors: Andrew Clist Lewis, Johan Siirak, Oijar Anders Cassel, Natalija Smolko-Schvarzmayr, Alberto Slikta
  • Patent number: 10543493
    Abstract: The present invention relates to a compound obtainable by reacting an N-acyl neutral amino acid or a salt thereof, or an N-acyl neutral amino acid oligopeptide or a salt thereof with a monohydroxy monocarboxylic acid or a salt thereof. This compound is useful as a collector in a process for froth flotation of non-sulfidic ores, especially phosphate ores. The invention also relates to a method which comprises the steps of a) conditioning a pulped phosphate ore, wherein the phosphate ore comprises a calcium phosphate mineral or a mixture of such minerals, and gangue minerals, with an effective amount of a calcium phosphate mineral collector reagent, which is the above-mentioned compound, and optionally other flotation aids and b) performing a froth flotation process to recover the calcium phosphate mineral(s).
    Type: Grant
    Filed: July 2, 2014
    Date of Patent: January 28, 2020
    Assignee: NOURYON CHEMICALS INTERNATIONAL B.V.
    Inventors: Natalija Smolko-Schvarzmayr, Anders Klingberg
  • Patent number: 10519064
    Abstract: The present invention relates to the use of an additive as well as a process to improve the adhesion of a mortar to a building substrate, wherein the mortar is mixed with said additive and is applied to a building substrate selected from the group of polystyrene-containing substrates, polyolefin-containing substrates or polyvinyl chloride-containing substrates, the additive containing (i) a plasticizer that is liquid at 50° C. or lower, has a boiling point of 100° C. or higher, and that has a solubility parameter ? 25° C. between 22.5 MPa1/2 and MPa1/2; (ii) optionally, a filler that has a BET surface area of at least 40 m2/g; (iii) optionally, a biopolymer, (iv) optionally, a protective colloid; and (v) optionally, a water-insoluble film-forming (co)polymer based on ethylenically unsaturated monomers. The invention also covers an additive and a kit of parts suitable for use in the above process.
    Type: Grant
    Filed: March 24, 2016
    Date of Patent: December 31, 2019
    Assignee: NOURYON CHEMICALS INTERNATIONAL B.V.
    Inventors: Hongli Willimann, Robert Koelliker, Andrey Petrovich Pustovgar, Hans Wicki, Urs Heini, Thomas Aberle
  • Patent number: 10472442
    Abstract: The invention relates to a specific copolymer obtainable by co-polymerizing at least the following monomers: —more than 80 wt % of at least one bicyclic (meth)acrylate ester, —0.05 to 15% w/w styrene, and —optionally other ethylenically unsaturated monomers, as well as to the way to synthesize them and the use of such polymers to modify the rheology of a liquid in which they are soluble.
    Type: Grant
    Filed: February 3, 2017
    Date of Patent: November 12, 2019
    Assignee: NOURYON CHEMICALS INTERNATIONAL B.V.
    Inventors: John Socrates Thomaides, John M. Morales, Qiwei He, Damien Christian Vadillo, Michael Timothy Philbin
  • Patent number: 10472320
    Abstract: The present invention relates to a process to prepare N,N?-di(2-hydroxybenzyl) ethylenediamine-N,N?-diacetic acid and salts thereof (HBED) comprising a reaction between formaldehyde, ethylenediamine diacetic acid or a salt thereof (EDDA) and phenol, wherein the reaction mixture contains 0.2 to 1.1 molar equivalents of alkali metal ions on the basis of the molar amount of EDDA and the reaction mixture is processed by a step in which at least part of the organic compounds other than the formed HBED are removed from the reaction mixture, and optionally recycled, during which step at least 50% and up to and including 100% of the alkali metal ions in the reaction mixture are potassium ions, to products obtainable by such process and their use.
    Type: Grant
    Filed: June 23, 2016
    Date of Patent: November 12, 2019
    Assignee: NOURYON CHEMICALS INTERNATIONAL B.V.
    Inventors: Adrianus Maria Reichwein, Hubertus Johannes Jongen, Marjolein Groote
  • Patent number: 10428010
    Abstract: The present invention relates to a process to convert cyclic alkylene ureas into their corresponding alkylene amines wherein the process is performed by reaction with an amine compound, and wherein the amine compound comprises a primary amine, a cyclic secondary amine or a tertiary bicyclic amine.
    Type: Grant
    Filed: February 10, 2017
    Date of Patent: October 1, 2019
    Assignee: Nouryon Chemicals International B.V.
    Inventors: Rolf Krister Edvinsson, Eike Nicolas Kantzer, Per Fredrik Olmo Larsson, Karl Fredrik Lake, Antoon Jacob Berend Ten Kate, Ulf Schröder, Johan Salman Malmberg
  • Patent number: 10428011
    Abstract: The present invention relates to a process to prepare ethyleneamines of the formula NH2—(C2H4—NH—)pH wherein p is at least 3 or derivatives thereof wherein one or more units —NH—C2H4—NH— may be present as a cyclic ethylene urea unit or between two units —NH—C2H4—NH— a carbonyl moiety is present, by reacting an ethanolamine-functional compound, an amine-functional compound in the presence of a carbon oxide delivering agent, wherein the molar ratio of ethanolamine-functional compound to amine-functional compound is at least 0.7:1 and the molar ratio of carbon oxide delivering agent to amine-functional compound is at least 0.05:1.
    Type: Grant
    Filed: February 10, 2017
    Date of Patent: October 1, 2019
    Assignee: Nouryon Chemicals International B.V.
    Inventors: Rolf Krister Edvinsson, Eike Nicolas Kantzer, Per Fredrik Olmo Larsson, Karl Fredrik Lake, Antoon Jacob Berend Ten Kate