Abstract: There is provided a process for the formulation of an oil-in-water emulsion from a produced hydrocarbon crude which includes a water-in-oil emulsion. A substantially oil insoluble nonyl phenol emulsifier is added with agitation to the crude when such crude is at a temperature of from about 100.degree. to about 200.degree. F., in a quantity sufficient to formulate and then sustain an oil-in-water emulsion at pipeline conditions of temperature and shear. Water-content is from about 15 percent to about 35 percent by weight. Viscosity is sufficiently low for pipeline transportation. Any excess water is separated from the formed oil-in-water emulsion prior to pipelining. The oil-in-water emulsion is one that can easily be dewatered and desalted to the necessary marketing specifications at the downstream end of the pipeline, using known technology.

Abstract: There is provided a process for the formulation of an oil-in-water emulsion from a produced hydrocarbon crude which includes a water-in-oil emulsion. A surface-active chemical system is added with agitation to the crude when such crude is at a temperature of from about 100.degree. to about 200.degree. F., in a quantity sufficient to formulate and then sustain an oil-in-water emulsion at pipeline conditions of temperature and shear. Water-content is from about 15 percent to about 35 percent by weight. Viscosity is sufficiently low for pipeline transportation. Any excess water is separated from the formed oil-in-water emulsion prior to pipelining. The oil-in-water emulsion is one that can easily be dewatered and desalted to the necessary marketing specifications at the downsteam end of the pipeline, using known technology.

Abstract: A process for removing impurities from phosphoric acid, especially concentrated wet process phosphoric acid, comprises filtering phosphoric acid through a filter cake (e.g., diatomite) on a porous member at a temperature in the range of about 57.degree. C. to about 77.degree. C. The filter cake retains some phosphate values. A major portion of the phosphate values retained by the filter cake can be introduced into the phosphoric acid manufacturing process, as by slurrying the filter cake in water, separating the aqueous phase from the solid phase, and introducing the aqueous phase to a wet process phosphoric acid process (e.g., as a "gypsum" filter wash).

Abstract: There is provided a process for reduction of the nitrogen content of shale oil. The process comprises contacting shale oil with a low acid strength solvent in a first extraction zone, followed by contacting the shale oil with a high acid strength solvent in a second extraction zone. A portion of the high acid strength solvent containing extracted nitrogen-containing and non-nitrogen-containing compounds is passed to the first extraction zone and diluted to form low acid strength solvent, and at least a portion of the non-nitrogen-containing compounds redissolve into the shale oil in contact with the low acid strength solvent and are recovered. Thus, oil recovery is maximized at high nitrogen removal.

Abstract: A method of pyrolyzing and desulfurizing coal in a transport reactor to recover volatile fuel values and hydrogen by heating particulate coal entrained in a carrier gas substantially free of oxygen to a pyrolysis temperature in a zone within three seconds.

Abstract: Process for recovery of energy from geothermal fluids such as geothermal brine in a geothermal formation by injecting a water immiscible working fluid, preferably organic, typically a hydrocarbon, e.g. isobutane, into the geothermal formation containing a geothermal fluid such as hot brine, wherein the hydrocarbon working fluid is heated by direct heat exchange contact with the hot geothermal fluid in the formation, and employing the hot working fluid to drive a heat engine or turbine to produce work or electrical energy or to provide heat energy to a chemical process (e.g., alcohol manufacture). The cooled working fluid discharged from the turbine is reinjected into the geothermal formation. The working fluid preferably has a density which changes substantially with temperature to provide a substantial pressure difference for causing flow of heated working fluid up the production well. The density difference can be due to phase transfer from liquid to gas.

Abstract: Process and system for recovery of energy from geothermal brines and other hot water sources, which comprises direct contact heat exchange between the brine or hot water, and a hydrocarbon working fluid, e.g. n-butane, in a heat transfer column, the heat transfer column being operated at or above the critical pressure of the working fluid, and the hot brine or hot water feed being at a temperature at or above the critical temperature of the working fluid. The heated working fluid exiting the top of the heat transfer column is expanded through an expander to produce work. The discharge from the expander is cooled to condense working fluid which is separated in an accumulator, from condensed water vapor present in the working fluid, and the condensed working fluid is pressurized and fed back to the heat transfer column. Water from the accumulator can be fed to an H.sub.2 S removal system where good quality water can be recovered.

Abstract: Method of mixing particulate materials comprising contacting a primary source and a secondary source thereof whereby resulting mixture ensues; preferably at least one of the two sources has enough motion to insure good mixing and the particulate materials may be heat treated if desired.Apparatus for such mixing comprising an inlet for a primary source, a reactor communicating therewith, a feeding means for supplying a secondary source to the reactor, and an inlet for the secondary source. Feeding means is preferably adapted to supply fluidized materials.

Abstract: A method is disclosed for implanting an embryo transplant from a donor mammal into the uterus of a recipient mammal. The method comprises making an incision in the lateral wall of the vagina of a recipient mammal posterior of the cervix. The uterine horn leading to an ovary having a corpus luteum thereon is positioned in proximity to the incision in the vaginal wall. The wall of the uterine horn is exposed through the incision in the vaginal wall. A hole is punctured through the exposed wall of the uterine horn. A cannula is inserted through the incision in the vaginal wall and through the hole in the wall of the uterine horn. The embryo transplant to be implanted in the recipient mammal is introduced through the cannula into the lumen of the uterine horn. After insertion of the embryo the cannula is withdrawn.

Abstract: Process and system for recovery of energy from geothermal brines and other hot water sources, which comprises direct contact heat exchange between the brine or hot water, and a hydrocarbon working fluid, e.g. n-butane, in a heat transfer column, the heat transfer column being operated at or above the critical pressure of the working fluid, and the hot brine or hot water feed being at a temperature at or above the critical temperature of the working fluid. The heated working fluid exiting the top of the heat transfer column is expanded through an expander to produce work. The discharge from the expander is cooled to condense working fluid which is separated in an accumulator, from condensed water vapor present in the working fluid, and the condensed working fluid is pressurized and fed back to the heat transfer column.

Abstract: Carbonaceous material is gasified in a first pyrolysis zone substantially in an absence of free oxygen by heating with a solid heating media. The carbonaceous material is conducted through the first pyrolysis zone in turbulent flow to provide for the rapid transfer of heat to effect the gasification.Gaseous products are recovered while char products are introduced into a second pyrolysis zone for additional gasification. The second pyrolysis zone is maintained substantially free of free oxygen. Gasification in the second pyrolysis zone is effected by the transfer of heat from a heating media to the char products produced in the first pyrolysis zone.Gaseous products from the second pyrolysis zone are recovered.The char products from the second pyrolysis zone can be heated to a temperature sufficient for use as a solid heating media.The gaseous product from the first pyrolysis zone, after separation from the char product, can be cooled to a lower temperature to condense a liquid product therefrom.

Abstract: Phosphoric acid is prepared from phosphate rock and sulfuric acid by using a reaction train comprising a dissolving slurry and a crystallization slurry maintained at different sulfate levels. Both inter and intra vessel circulation are used at high rates to minimize reagent concentration gradients and temperature gradients and provide a suitable crystallization environment. Preferably, the intra vessel circulation is substantially in plug flow, as through a draft tube.

Abstract: Process and system for recovery of energy from geothermal brines and other hot water sources, by direct contact heat exchange between the brine or hot water, and an immiscible working fluid, e.g. a hydrocarbon such as isobutane, in a heat exchange column, the brine or hot water therein flowing countercurrent to the flow of the working fluid. The column can be operated at subcritical, critical or above the critical pressure of the working fluid. Preferably, the column is provided with a plurality of sieve plates, and the heat exchange process and column, e.g.

Abstract: A process for efficiently recycling the water used in the various stages of a process for recovering glass from municipal trash. The invention comprises the separate treatment and recycling of the process water resulting from the first step separation of the incoming trash into a glass and inorganic constituent and an organic constituent for reuse in that step; the separate treatment and recycling of the process water emanating from the second step size classification to either the first or second steps; and, the treatment and recycling of the process water used in the froth flotation separation of the glass from the other inorganic constituents to any of the three steps in the process.

Abstract: In the recovery of energy from geothermal brines and other water containing or hot water sources, such brine or hot water under pressure is introduced into direct heat exchange contact with a working fluid such as isobutane, the resulting hot isobutane is expanded in a turbine to produce work, the turbine discharge is condensed and returned to the heat exchanger and the cooled brine is withdrawn from the column. The present invention is directed to recovery of working fluid dissolved and/or entrained in the spent geothermal brine or water withdrawn from the direct contact heat exchanger, including the steps of settling the brine in a settling tank to recover some of the isobutane, flashing the remaining brine to flash off additional isobutane and steam stripping the spent brine to drive off further isobutane, the recovered isobutane in each of the steps being recycled to the direct contact heat exchanger.

Abstract: In a continuous process for recovery of liquid hydrocarbons from a solid carbonaceous material by pyrolysis of the carbonaceous material in the presence of a particulate source of heat, particulate contamination of the liquid hydrocarbons is minimized. This is accomplished by removing fines from the solid carbonaceous material feed stream before pyrolysis, removing fines from the particulate source of heat before combining it with the carbonaceous material to effect pyrolysis of the carbonaceous material, and providing a coarse fraction of reduced fines content of the carbon containing solid residue resulting from the pyrolysis of the carbonaceous material before oxidizing carbon in the carbon containing solid residue to form the particulate source of heat.

Abstract: The invention comprises a multi-vessel reaction apparatus useful for reacting phosphate rock and sulfuric acid in which the reaction slurry undergoes intra- and inter- vessel circulation (preferably through a draft tube). The solution portion of the slurry in a first vessel or set of vessels (the "dissolver") is preferably maintained at at lower sulfate ion concentration and the solution portion of the slurry in the second vessel or system of vessels (the "crystallizer") is preferably maintained at a positive sulfate ion concentration. Also preferred are means for maintaining the second vessel or set of vessels at a reduced pressure. Most preferred is that means be included in at least one said vessel for incorporating a crystal modifier (e.g. a sulfonic acid, a sulfonic acid salt, tall oil fatty acids or alkoxylated or esterified tall oil fatty acids) in the crystallizer. The system can be used in the anhydrite, hemihydrate or gypsum types of processes.

Abstract: A mixture of a high density particulate inorganic heat source and a low density particulate carbon containing residue formed in the pyrolysis of a solid waste is passed along with some entrained pyrolytic oil to a fluidized bed of particles, where a gas is injected to strip the entrained pyrolytic oil from the particles, and a mixture of a high density particulate heat source and low density particulate carbon containing solid residue of pyrolysis are separated from an intermediate point of the fluidized bed and passed to a decarbonization zone, where the carbon containing solid residue of pyrolysis is decarbonized to form a high density particulate inorganic solid heat source for use as the source of heat in the pyrolysis of organic solid waste.

Abstract: The gas stream obtained from the pyrolysis of solid organic wastes and containing chlorine in the form of hydrogen chloride is processed to obtain a substantially chlorine free pyrolytic oil.The gas stream is first contacted with a hydrocarbon immiscible with the pyrolytic oils to quench the gas stream and reduce the gas stream temperature close to the dew point of water. This forms a two phase condensate of the quench hydrocarbon and pyrolytic oil. The phases are separated, the pyrolytic oil recovered and the hydrocarbon recycled as the quench. The resultant gas stream is then treated for removal of hydrogen chloride from the gas stream for disposal or recovery of hydrochloric acid.

Abstract: Water immiscible organic acid phosphates used in conjunction with water immiscible organic sulfonic acids results in an improved process for the purification of phosphoric acid. An increase in the extraction of ionic metallic impurities and a decrease in the extraction of P.sub.2 O.sub.5 values from the aqueous phosphoric acid phase .[.is.]. .Iadd.are .Iaddend.observed in the improved solvent extraction process.