Abstract: The invention thus relates to a layer system (1) for the formation of a surface layer on a surface of a substrate, in particular on the surface of a tool, in particular on the surface of a shaping tool, wherein the layer system includes at least a first surface layer of the composition (VaMebMcXd)?(NuCvOw)?, where (a+b+c+d)=?, ?=100%, with respect to the atoms Va,Meb,Mc,Xd present in the layer, (u+v+w)=?. ?=100 with respect to the atoms N, C, O present in the layer, with the sum of all the atoms in the layer (?+?)=100 at %, where 40???80 at % applies, and where Meb is at least one element from the group of chemical elements including Zr, Hf, Nb, Ta, Mo, W, Ni, Cu, Sc, Y, La, Ce, Pr, Nd, Pm, Sm of the periodic system of chemical elements and Mc is at least one element of the group of chemical elements including Ti, Cr, and Xd is at least one element from the group of chemical elements including S, Se, Si, B of the periodic system of elements, where 0?u?100, 0?v?100 and 0?w?80.

Abstract: The invention relates to a protective coating, having the chemical composition CaSibBdNeOgHlMem, wherein Me is at least one metal of the group consisting of {Al, Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, W, Y, Sc, La, Ce, Nd, Pm, Sm, Pr, Mg, Ni, Co, Fe, Mn}, with a+b+d+e+g+l+m=1. According to the invention, the following conditions are satisfied: 0.45?a?0.98, 0.01?b?0.40, 0.01?d?0.30, 0?e?0.35, 0?g?0.20, 0?l?0.35, 0?m?0.20. The invention relates also to a coated member having a protective coating, as well as to a method for producing a protective coating, in particular a multilayer film for a member.