Abstract: The invention relates to a process for preparing tert-butanol by reaction of a homogeneous mixture comprising water, tert-butanol and an isobutene-containing hydrocarbon mixture over an acidic ion-exchange resin at from 30 to 120° C., wherein the homogeneous mixture contains, at a proportion by mass of isobutene of above 10%, from 30 to 80% of the maximum amount of water made possible by the solubility of water in the mixture of tert-butanol and the isobutene-containing hydrocarbon mixture.
Type:
Grant
Filed:
December 19, 2003
Date of Patent:
February 20, 2007
Assignee:
Oxeno Olefinchemie GmbH
Inventors:
Bernhard Scholz, Franz Nierlich, Dieter Reusch, Silvia Santiago Fernandez, Andreas Beckmann, Wilfried Bueschken, Alfred Kaizik
Abstract: The present invention relates to the use of isononyl esters of benzoic acid as film-forming agents in compositions such as emulsion paints, mortars, plasters, adhesives, and varnishes, and also to compositions which comprise film-forming polymers and the isononyl ester of benzoic acid.
Abstract: Phosphites of the formula I and phosphite-metal complexes, their preparation and their use in catalytic reactions, in particular in processes for the hydroformylation of olefins, are described.
Abstract: Isobutene in isobutenic hydrocarbon mixtures is oligomerized over a solid acidic ion exchange resin, said acidic ion exchange resin containing, for example, sulfonic acid groups, some of whose protons have been exchanged for metal ions.
Type:
Grant
Filed:
August 6, 2003
Date of Patent:
January 9, 2007
Assignee:
Oxeno Olefinchemie GmbH
Inventors:
Andreas Beckmann, Franz Nierlich, Udo Peters, Wilfried Büschken, Lothar Kerker, Dietrich Maschmeyer, Dirk Röttger
Abstract: The invention relates to a process for preparing 1-octene from a C4 fraction from a cracker by telomerization of the 1,3-butadiene present in the C4 fraction from a cracker by means of methanol in the presence of a catalyst, hydrogenation of the telomer obtained in this way, dissociation of the hydrogenated telomer and work-up of the resulting dissociation product to give pure 1-octene.
Type:
Application
Filed:
May 6, 2004
Publication date:
December 14, 2006
Applicant:
Oxeno Olefinchemie GMBH
Inventors:
Jorg Krissmann, Dirk Rottger, Cornella Borgmann, Kerstin Kamper, Franz Nierlich, Alfred Kaizik, Udo Knippenberg, Rainer Malzkorn
Abstract: The present invention relates to a process for separating 2-butanol from tert-butanol/water mixtures using a membrane to reduce a water concentration to less than the limit concentration of the distillation boundary line connecting the two azeotropes TBA/water and SBA/water and is subsequently worked up by distillation.
Type:
Grant
Filed:
March 22, 2004
Date of Patent:
November 28, 2006
Assignee:
OXENO Olefinchemie GmbH
Inventors:
Andreas Beckmann, Dieter Reusch, Franz-Felix Kuppinger
Abstract: The invention relates to a process for the oligomerization of butenes, in which a stream which contains predominantly butenes and has been obtained by separation from a stream of hydrocarbons having a lower content of butenes, scrubbing and drying is fed to the oligomerization.
Abstract: The invention relates to a process for preparing methyl tert-butyl ether (MTBE) in qualities which are suitable for organic syntheses and for use as a specialty solvent from MTBE in fuel quality.
Type:
Application
Filed:
June 14, 2003
Publication date:
November 23, 2006
Applicant:
OXENO OLEFINCHEMIE GMBH
Inventors:
Fritz Obenaus, Wilhelm Droste, Bernhard Scholz, Franz Nierlich, Rainer Malzkorn, Udo Peters, Jochen Praefke, Richard Filipiak, Joachim Neumeister
Abstract: The present invention relates to a process for preparing a C13-alcohol mixture which is suitable, in particular, as precursor for the preparation of compounds having surfactant properties and of plasticizers.
Type:
Grant
Filed:
March 25, 2003
Date of Patent:
November 21, 2006
Assignee:
OXENO Olefinchemie GmbH
Inventors:
Alfred Kaizik, Walter Tötsch, Wilhelm Droste, Wilfried Büschken, Dirk Röttger, Klaus-Diether Wiese
Abstract: The present invention relates to a process for separating 2-butanol from tert-butanol/water by adding of tert-butanol such that the water concentration lowers to less than the limit concentration of the distillation boundary line connecting the two azeotropes TBA/water and SBA/water and is subsequently worked up by distillation.
Abstract: The present invention relates to a process for preparing aldehydes by hydroformylation of olefinically unsaturated compounds catalyzed by metals of groups 8 to 10 of the Periodic Table of the Elements in the presence of cyclic carbonic esters and ligands which contain no sulfonic acid or sulfonate group.
Abstract: The invention relates to a process for preparing tert-butanol (TBA) from isobutene-containing mixtures, in which at least part of the conversion is achieved with the aid of a reactive rectification.
Type:
Grant
Filed:
November 11, 2003
Date of Patent:
October 3, 2006
Assignee:
OXENO Olefinchemie GmbH
Inventors:
Dieter Reusch, Andreas Beckmann, Franz Nierlich, Axel Tuchlenski
Abstract: The invention relates to a process for preparing 1-octene by telomerization of 1,3-butadiene using a reducing agent in the presence of a telomerization catalyst and partial hydrogenation of the octadiene obtained in this way.
Type:
Grant
Filed:
September 18, 2002
Date of Patent:
October 3, 2006
Assignee:
OXENO Olefinchemie GmbH
Inventors:
Matthias Beller, Ralf Jackstell, Holger Klein, Dirk Roettger, Dietrich Maschmeyer, Silvia Santiago Fernandez
Abstract: N-Phenylpyrrolebisphosphines of the formula I metal complexes of these N-phenylpyrrolebisphosphines and their use in metal-catalyzed reactions.
Abstract: The invention relates to the hydrogenation of aromatic compounds, in particular the preparation of alicyclic polycarboxylic acids or esters of these, via ring hydrogenation of the corresponding aromatic polycarboxylic acids or esters of these, and also to catalysts suitable for this purpose.
Type:
Application
Filed:
April 26, 2003
Publication date:
August 17, 2006
Applicant:
Oxeno Olefinchemie GMBH
Inventors:
Michael Grass, Alfred Kaizik, Wilfried Buschken, Axel Tuchlenski, Dietrich Maschmeyer, Kurt-Alfred Gaudschun, Frank Brocksien
Abstract: A method for the continuous preparation of an alicyclic carboxylic acid or an ester of the alicyclic carboxylic acid. A plastic which incorporates the alicyclic carboxylic acid or an ester of the alicyclic carboxylic acid. An article made of a plastic which incorporates the alicyclic carboxylic acid or an ester of the alicyclic carboxylic acid. A liquid which incorporates the alicycic carboxylic acid or an ester of the alicyclic carboxylic acid.
Type:
Application
Filed:
January 3, 2006
Publication date:
July 27, 2006
Applicant:
OXENO OLEFINCHEMIE GMBH
Inventors:
Michael Grass, Burkhard Reeken, Axel Tuchlenski, Alfred Kaizik, Wilfried Buschken
Abstract: The invention relates to the preparation of alicyclic carboxylic acids or their derivatives by selective hydrogenation of the corresponding aromatic carboxylic acid (derivatives) in at least two series-connected reactors, at least one reactor being operated in loop operating mode. The catalyst volumes in the method are set in such a manner that the catalyst volume required, based on the conversion rate, is as low as possible.
Type:
Application
Filed:
December 29, 2005
Publication date:
July 20, 2006
Applicants:
DEGUSSA AG, OXENO OLEFINCHEMIE GMBH
Inventors:
Michael Grass, Burkhard Reeken, Axel Tuchlenski, Alfred Kaizik
Abstract: The invention relates to a process for preparing high-purity isobutene from industrial methyl tert-butyl ether (MTBE) and the economical utilization of the secondary streams.
Type:
Application
Filed:
July 11, 2003
Publication date:
June 22, 2006
Applicant:
OXENO OLEFINCHEMIE GMBH
Inventors:
Rainer Malzkorn, Franz Nierlich, Udo Peters, Axel Tuchlenski
Abstract: The invention relates to a process for preparing 1-octene by reacting 1,3-butadiene with a telogen of the formula H—X—Y—H, where X is O, N, S or P and Y is C, N or Si and X and Y bear, depending on their valence, further substituents, in the presence of a telomerization catalyst to form a telomer of the formula H2C?CH—CH2—CH2—CH2—CH?CH—CH2—X—Y—H, partially hydrogenating the telomer to form a 1-substituted 2-octene of the formula H3C—CH2—CH2—CH2—CH2—CH?CH—CH2—X—Y—H and dissociating the 1-substituted 2-octene to give 1-octene.
Abstract: The invention provides a process for the telomerization of acyclic olefins having at least two conjugated double bonds (I) or mixtures comprising such olefins by means of nucleophiles (II) using a palladium-carbene complex as catalyst.