Abstract: In one or more embodiments, this application relates to tribotechnical additive and lubricant compositions based on self-assembled carbon nanoarchitectonics derived through nanoscale modifications of organosilane-functionalized nanocarbon with one or multiple combinations of organo-molybdenum, organo-boron, organo-sulfur, organo-phosphorus, and heterocyclic compounds. The novel lubricant is characterized by having a composition comprising (A) one or more types of the novel additive compositions, (B) Base oil//lubricant, and optionally (C) one or more additives selected from the group including antioxidants, dispersants, detergents, anti-wear additives, extreme pressure additives, friction modifiers, viscosity index modifiers, seal swell additives, defoamers, pour point depressants and corrosion/rust inhibitors.

Abstract: Disclosed herein are nanohybrid and nanocomposite compositions and methods. In a specific embodiment, the method for making a nanohybrid composition includes: contacting a carrier material with metallic salt precursors to make a first mixture, contacting the first mixture with a reducing agent reacting and a surface activated agent to make a second mixture, where the metallic salt precursors undergo chemical reduction to make metallic nanoparticles, and where the metallic nanoparticles are deposited onto the carrier material, contacting the second mixture with an organosilane coupling agent to make a nanohybrid composition.

Abstract: This invention relates to forming unique nanohybrid structures through selective integration of inorganic antimicrobial nanoparticles with other inorganic and organic materials and then, chemically bonding the nanohybrid structures to organic polymers for application as surface coatings, antimicrobial surfacing, food packaging, biomedical, agricultural, air-filtration/cleaning and water filtration/cleaning applications to kill, inhibit, and/or reduce the growth of pathogenic/infectious/contaminating microorganisms and their biofilms.

Abstract: Disclosed herein is a method for coating carbide substrates using nanostructured and a non-nanostructured layers. The coatings can be produced by the addition of a refining agent flow, particular hydrogen chloride gas, during deposition, and can be produced as multiple individual titanium and titanium-based nanostructured layers varying functional materials. The combination of a nanostructured layers and non-nanostructured layers can produce a cutting tool insert that exhibits longer usage life. In addition, pre-treating the substrate with a mixture of compressed air and and abrasive medium prior to coating the substrate and post-treating the coated substrate with a mixture of water and an abrasive can further enhance the wear resistance and life of the cutting tool.

Abstract: A coating for carbide substrates employs a nanostructured coating in conjunction with a non-nanostructured coating. The nanostructured coating is produced by the addition of a refining agent flow, particular hydrogen chloride gas, during deposition, and may be produced as multiple individual titanium and titanium-based nanostructured layers varying functional materials in a series. The combination of a nanostructured coating and non-nanostructured coating is believed to produce a cutting tool insert that exhibits longer life. Pre-treating the substrate with a mixture of compressed air and abrasive medium prior to coating the substrate and post-treating the coated substrate with a mixture of water and abrasive medium after the coating process is believed to further enhance the wear resistance and usage life of the cutting tool.

Abstract: In one or more embodiments, this application relates to tribotechnical additive and lubricant compositions based on self-assembled carbon nanoarchitectonics derived through nanoscale modifications of organosilane-functionalized nanocarbon with one or multiple combinations of organo-molybdenum, organo-boron, organo-sulfur, organo-phosphorus, and heterocyclic compounds. The novel lubricant is characterized by having a composition comprising (A) one or more types of the novel additive compositions, (B) Base oil//lubricant, and optionally (C) one or more additives selected from the group including antioxidants, dispersants, detergents, anti-wear additives, extreme pressure additives, friction modifiers, viscosity index modifiers, seal swell additives, defoamers, pour point depressants and corrosion/rust inhibitors.

Abstract: This invention relates to nanohybrid compositions derived from surface activation of halogenated and/or non-halogenated flame retardant (FR) materials with nanostructured copper and/or its oxides. The present disclosure also relates to polymer compositions manufactured by incorporating and reinforcing polymers/copolymers with nanohybrid compositions as flame retardant additives for enhanced fire resistance, smoke suppression, and antimicrobial capabilities. In one or more embodiments, the polymers and article of manufacture to which the particles are applied may have on or more of the following attributes: temperature adaptable flame retardant behavior, Enhanced suppression of flammable gas and smoke, catalysis of charring or thermal oxidative promotion of charring through the oxides of metals, enhanced heat sink behavior, and/or antimicrobial behavior.

Abstract: Ultrasonic spray deposition (USD) used to deposit a base layer on the substrate, followed by chemical vapor infiltration (CVI) to introduce a binder phase that creates a composite coating with good adherence of the binder to the initial phase particles and adherence of the composite coating to the substrate, is disclosed. We have used this process to create coatings consisting of cubic boron nitride (cBN), deposited using USD, and titanium nitride (TiN) applied using CVI in various embodiments. This process can be used with many materials not usable with other processes, including nitrides, carbides, carbonitrides, borides, oxides, sulphides and silicides. In addition, other binding or post-deposition treatment processes can be applied as alternatives to CVI, depending on the substrate, the coating materials, and the application requirements of the coating. Coatings can be applied to a variety of substrates including those with complex geometries.

Abstract: A physical configuration of multiple-layer coatings formed with at least one layer of coating containing cubic born nitride (cBN) particles with one or more layers in composite form containing cBN particles may have a thickness of each individual layer as thin as in the nanometer range, or as thick as in the range of a few microns and even up to tens of microns. The chemistry of the composite layer consists of any individual phase of (a) nitrides such as titanium nitride (TiN), titanium carbonitride (TiCN), and hafnium nitride (HfN); (b) carbides such as titanium carbide (TiC); and (c) oxides such as aluminum oxide (AI2O3) or any combination of the above phases, in addition to cBN particles. The coating or film can be stand-alone or on a substrate.