Patents Assigned to Paques Bio Systems B.V.
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Publication number: 20120115218Abstract: The invention relates to a bioreactor (1) comprising a reactor vessel (41) having a mixing chamber (3) separated by a partition (44) from a reaction chamber (2) located generally above the mixing chamber (3), the mixing chamber (3) having an inlet system (4) for influent or a mixture of influent and recycled material, wherein the inlet system (4) has an outlet opening (60-64) in the mixing chamber (3). In an embodiment the partition (44) has an opening (66) forming a connection between the mixing chamber (3) and the reaction chamber (2), wherein the outlet opening (60-64) of the inlet system (4) is directed at the opening in the partition. In an embodiment the mixing chamber (3) has a skeleton for reinforcing the mixing chamber.Type: ApplicationFiled: May 3, 2010Publication date: May 10, 2012Applicant: PAQUES BIO SYSTEMS B.V.Inventors: Douwe Frankena, Sjoerd Hubertus Jozef Vellinga
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Patent number: 6852305Abstract: A process is provided for the production of hydrogen sulphide from the bacterial reduction of a mixture of a liquid and elemental sulfur with an electron donor, such as hydrogen gas, carbon monoxide or organic compounds. The bacteria may be Desulforomonas sp. (mesophilic), Desulfotomaculum KT7 (thermophilic), etc. The liquid/sulfur mixture is at a pH ranging from 5 to 9, and the liquid/sulfur mixture contacts the bacteria at a hydraulic retention time of at least 1 day. The hydrogen sulphide is stripped from the liquid medium to produce a gas containing at least 1 volume percent hydrogen sulphide.Type: GrantFiled: November 25, 2003Date of Patent: February 8, 2005Assignee: Paques Bio Systems B.V.Inventors: Cees Jan Nico Buisman, Henk Dijkman
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Patent number: 6841072Abstract: Method and apparatus for the anaerobic purification of slurry which contains organic constituents. Slurry which is to be treated is fed periodically or continuously to a mixture-filled, substantially closed reactor (2), while the slurry is forcibly mixed with mixture (3) from the reactor. The mixture in the reactor is subjected to upward flow through it and to a hydrolysis process. The mixture is subjected to floatation by injection of a low-oxygen gas, such as biogas which originates from the reactor, and the floating layer of solids which is formed in the process is returned to the mixture in the reactor, while the low-particle liquid which is formed in the process is discharged as effluent.Type: GrantFiled: March 26, 2003Date of Patent: January 11, 2005Assignee: Paques Bio Systems B.V.Inventors: Sjoerd Hubertus Jozef Vellinga, Ronald Mulder
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Publication number: 20040115120Abstract: A process is provided for the production of hydrogen sulphide from the bacterial reduction of a mixture of a liquid and elemental sulfur with an electron donor, such as hydrogen gas, carbon monoxide or organic compounds. The bacteria may be Desulforomonas sp. (mesophilic), Desulfotomaculum KT7 (thermophilic), etc. The liquid/sulfur mixture is at a pH ranging from 5 to 9, and the liquid/sulfur mixture contacts the bacteria at a hydraulic retention time of at least 1 day. The hydrogen sulphide is stripped from the liquid medium to produce a gas containing at least 1 volume percent hydrogen sulphide.Type: ApplicationFiled: November 25, 2003Publication date: June 17, 2004Applicant: PAQUES BIO SYSTEM B.V.Inventors: Cees Jan Nico Buisman, Henk Dijkman
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Patent number: 6656722Abstract: The invention provides a process for removing and immobilizing arsenic from an arsenic-containing waste. It comprises oxidizing the arsenic to pentavalent arsenic in an aqueous medium, contacting the pentavalent arsenic with trivalent iron to form an insoluble iron-arsenic compound and separating precipitated iron-arsenic compound from the aqueous medium. The oxidation of arsenic is effected using oxidizing bacteria at a pH between 0.5 and 4 and at a temperature between 20 and 90° C. in the presence of a mineral catalyst such as pyrite.Type: GrantFiled: December 26, 2001Date of Patent: December 2, 2003Assignee: Paques Bio Systems B.V.Inventors: Renate Ruitenberg, Cees Jan Nico Buisman
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Patent number: 6656249Abstract: A method of removing hydrogen sulphide from a gas stream wherein the hydrogen sulphide is scrubbed from the gas phase by an aqueous solution, the hydrogen sulphide in the aqueous solution is biologically oxidized in a bioreactor to produce elemental sulphur, and the elemental sulphur is separated from the aqueous solution, characterized in that the gas stream to be treated is cooled to such a degree that at least sufficient water vapour condenses from the gas stream to compensate for the discharge stream for the purpose of removing salts. This means that no water need be supplied to the bioreactor. This method is suitable, in particular, for gas streams which contain hydrogen sulphide, the hydrogen sulphide having been obtained by catalytic conversion of sulphur compounds.Type: GrantFiled: September 10, 2001Date of Patent: December 2, 2003Assignee: Paques Bio Systems B.V.Inventors: Cees Jan Nico Buisman, Albert Joseph Hendrik Janssen, Robert Jan Van Bodegraven
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Patent number: 6630071Abstract: A process for the treatment of waste water containing heavy metals in which sulphur components and/or metals are biologically reduced to precipitate the metals as water-insoluble metal species, which are separated from the waste water. The biological reduction and the precipitation of the metal species are carried out in a moving sand bed, in which sand particles partly immobilize the bacteria and retain the precipitated metal species, treated waste water is separated from the precipitated metal species and the precipitated metal species are subsequently separated from the sand particles. Metals like selenium and uranium can be precipitated without sulphur components, whereas metals like antimony, cadmium, copper, zinc and the like are precipitated as sulphides.Type: GrantFiled: June 28, 2001Date of Patent: October 7, 2003Assignee: Paques Bio Systems B.V.Inventors: Cees Jan Nico Buisman, Hendrik Dijkman
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Patent number: 6485646Abstract: A process is described for the biological treatment of waste water containing ammonia, wherein the waste water is treated with sludge containing nitrifying bacteria in an aerated reactor, applying a sludge retention time in the reactor which favours nitrite-producing bacteria over nitrate-producing bacteria. The process is characterised by applying a hydraulic retention time in a continuously operated reactor, which is shorter than the sludge retention time as a result of part of the sludge being separated from the reactor effluent and being returned to the reactor. The performance of the nitrification is further improved by applying low oxygen and nitrite concentrations.Type: GrantFiled: March 30, 2001Date of Patent: November 26, 2002Assignee: Paques Bio Systems B.V.Inventors: Hendrik Dijkman, Marc Strous
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Patent number: 6221652Abstract: A process for the removal of sulphides, including hydrogen sulphide, carbonyl sulphide and carbon disulphide, from a gas stream by scrubbing the gas with an aqueous washing liquid and treating the washing liquid with sulphide-oxidizing bacteria in the presence of an electron acceptor and reusing the treated liquid as a washing liquid, wherein the scrubbing and the bacterial treatment are carried out in the same reactor and nitrate is used as the electron acceptor. The process is especially useful of desulphurising gas at high pressure, such as natural gas.Type: GrantFiled: May 7, 1999Date of Patent: April 24, 2001Assignee: Paques Bio Systems B.V.Inventors: Albert Jozef Hendrik Janssen, Cees Jan Nico Buisman
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Patent number: 6156205Abstract: A process for scrubbing a gas containing hydrogen sulphide and/or carbonyl sulphide, in which the spent scrubbing liquid is treated with autotrophic sulphide-oxidizing bacteria capable of oxidizing at high pH, and elemental sulphur is obtained, the elemental sulphur is separated and the treated scrubbing liquid is recycled to the gas scrubbing step. Before recycling, the scrubbing liquid may further be treated with heterotrophic thiosulphate-oxidizing bacteria which produce polythionate which is useful for further enhancing the sulphide-scrubbing capacity of the scrubbing liquid.Type: GrantFiled: January 25, 1999Date of Patent: December 5, 2000Assignee: Paques Bio Systems B.V.Inventors: Cees Jan Nico Buisman, Dimitri Yuri Sorokin, Joannes Gijsbrecht Kuenen, Albert Jozef Hendrik Janssen, Lesley Anna Robertson
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Patent number: 6045695Abstract: A process for the biological treatment of a spent caustic solution containing sulphides is disclosed, wherein the solution is introduced into an aerobic reactor containing sulphide-oxidising bacteria, and the sulphides are partly converted to elemental sulphur and partly to sulphate by controlling the redox potential in the reactor at a value below -300 mV (against an Ag/AgCl reference electrode), or below -97 (against a H.sub.2 reference electrode). Also disclosed is process for the biological treatment of an aqueous solution containing sulphides and/or mercaptans in an aerobic reactor, wherein the solution is treated in the presence of bacteria of the new species Methylophaga sulfidovorans.Type: GrantFiled: February 10, 1999Date of Patent: April 4, 2000Assignee: Paques Bio Systems B.V.Inventors: Albert Joseph Janssen, Gatze Lettinga, Cees Jan Nico Buisman, Jan Bontsema, Gerrit Van Straten, Johannes Gijsbrecht Kuenen, Jolyn Martha Maria De Zwart
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Patent number: 6019901Abstract: The invention provides a process for removing polyamine chelating agents from aqueous solutions comprising oxidising the chelating agents with oxygen in the presence of an equivalent amount of a transition metal such as iron, followed by biologically reducing the chelates in the presence of an electron donor, and optionally by membrane filtration. The biological reduction is carried out with denitrifying and/or sulphate-reducing bacteria.Type: GrantFiled: March 26, 1999Date of Patent: February 1, 2000Assignee: Paques Bio Systems B.V.Inventors: Wiebe Ruurd Abma, Cees Jan Nico Buisman
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Patent number: 5976868Abstract: An installation and a method are described for the treatment of a gas containing hydrogen sulphide, the gas (1) being washed in a first gas scrubber (5) with an alkaline wash liquid and the spent wash liquid (4) being treated in an aerobic reactor (6) with oxygen in the presence of sulphide-oxidising bacteria and the effluent (9) from the aerobic reactor (6) being re-used as wash liquid (3) and the elementary sulphur formed during the treatment with oxygen being removed from the effluent (19), the effluent (13) from which sulphur has been removed being treated in an anaerobic reactor (17) with sulphate-reducing bacteria and returned to the aerobic reactor (6). The installation and the method can also be used for simultaneous removal of SO.sub.2, COS, CS.sub.2, NH.sub.3 and HCN.Type: GrantFiled: December 23, 1997Date of Patent: November 2, 1999Assignee: Paques Bio Systems B.V.Inventor: Cees Jan Nico Buisman